Determination of Chromium, Nickel, Copper and Zinc in Milligram Samples of Geological Materials Using Isotope Dilution High Resolution Inductively Coupled Plasma-Mass Spectrometry     

Akio Makishima  Katsura Kobayashi  Eizo Nakamura 《Geostandards and Geoanalytical Research》2002,26(1):41-51

A simple and accurate method for the determination of Cr, Ni, Cu and Zn at μg g^?1 levels in milligram‐sized bulk silicate materials is reported using isotope dilution high‐resolution inductively coupled plasma‐mass spectrometry (HR‐ICP‐MS) with a flow injection system. Silicate samples with Cr, Ni, Cu and Zn spikes were digested with HF‐HBr and Br₂, and subsequently decomposed at 518 K in a Teflon bomb. In this procedure, all sulfides and chromite, major hosts of these elements, were completely decomposed, thus allowing for isotope equilibration between the sample and spike. Magnesium and Al fluorides formed after the digestion of the sample were removed by centrifugation, and the supernatant was directly aspirated into a HR‐ICP‐MS at a mass resolution of 7500, where interfering oxide ions, ArO⁺, CaO⁺, TiO⁺, CrO⁺ and VO⁺, were separated from Cr⁺, Ni⁺, Cu⁺ and Zn⁺. No matrix effects were observed down to a dilution factor of 50. Detection limits for these elements in silicate samples were < 0.04 μg g^?1. The effectiveness of the technique was demonstrated by the analysis of 13 to 40 mg test portions of USGS and GSJ silicate reference materials with a major element composition ranging from andesite to peridotite, in addition to 8‐23 mg of the Smithsonian reference Allende. Both the reproducibility and the deviation from the reference value for most reference materials of various rock types were < 9%, and thus confirm that the method gives accurate analytical results for small sample sizes over a wide range of Cr, Ni, Cu and Zn contents. This method is, therefore, suitable for analysing small and/or precious bulk samples, such as meteorites, mantle peridotites and mineral separates, and for the characterisation of silicate and sulfide minerals for use as calibration samples in secondary ion mass spectrometry or laser ablation ICP‐MS.  相似文献   

Water-weakened lower crust and its role in the concentrated deformation in the Japanese Islands     

Yoshihisa Iio  Takeshi SagiyaYoji Kobayashi  Ichiro Shiozaki 《Earth and Planetary Science Letters》2002,203(1):245-253

The nature and origin of the concentrated deformation zone along the Japan Sea coast (NKTZ: Niigata-Kobe tectonic zone) was investigated by carefully analyzing the GPS data and qualitatively modeling the lower crust in NKTZ. It was concluded that this deformation zone is not a plate boundary between the Amurian plate (AMU) and the North America plate but is rather an internal deformation zone near the eastern margin of AMU. The data previously obtained on the conductivity anomalies in the lower crust and the ³He/⁴He ratios suggest that the concentrated deformation in NKTZ results from the lower crust in NKTZ being weakened by a high water content. The high water content is thought to result from the dehydration of subducting slabs. NKTZ has a higher water content in the lower crust than other regions do because there is no Philippine Sea plate (PHS) seismic slab beneath NKTZ. In other regions, it is estimated that the mantle wedge above the seismic Philippine Sea slab prevents the water dehydrated from the slab from rising to the lower crust, and that the lithosphere within PHS itself prevents the water dehydrated from the Pacific plate from rising up through it.  相似文献   

Policies and Practices for an Antiracist Geography at the Millennium     

Linda Peake  Audrey Kobayashi 《The Professional geographer》2002,54(1):50-61

As we enter the new millennium, geographers have a momentous opportunity to reflect upon the historical development of our discipline and the academic culture within which it thrives, with the aim of setting out an antiracist agenda. We advocate a fundamental refashioning of the discipline, not simply an extension of its research agenda; for racism, like gender, is not just another item in the lexicon of geographical subjects. The agenda includes, but is not limited to: clarifying relations between racism and law; racism and immigration policy; racism and poverty; and mobilizing racialized groups around policy issues. These items need to be addressed both through scholarship and through activism, as centering geographical practices in the streets rather than in the academy impels not only more effective social change, but also new theoretical understanding of geographies of engagement. Our agenda for antiracist geography also involves three aspects of institutional change: to build up on and extend traditional geographical scholarship; to change the basis of the discipline by extending the principles of antiracism throughout our institutional practices, particularly in the classroom; and to change the face of the discipline by increasing the participation and contributions of geographers of color.  相似文献   

Origin of the metamorphosed clasts in the CV3 carbonaceous chondrite breccias of Graves Nunataks 06101, Vigarano,Roberts Massif 04143, and Yamato‐86009     

Kaori Jogo  Motoo Ito  Shigeru Wakita  Sachio Kobayashi  Jong Ik Lee 《Meteoritics & planetary science》2019,54(5):1133-1152

We observed metamorphosed clasts in the CV3 chondrite breccias Graves Nunataks 06101, Vigarano, Roberts Massif 04143, and Yamato‐86009. These clasts are coarse‐grained polymineralic rocks composed of Ca‐bearing ferroan olivine (Fa_24–40, up to 0.6 wt% CaO), diopside (Fs_7–12Wo_44–50), plagioclase (An_52–75), Cr‐spinel (Cr/[Cr + Al] = 0.4, Fe/[Fe + Mg] = 0.7), sulfide and rare grains of Fe‐Ni metal, phosphate, and Ca‐poor pyroxene (Fs₂₄Wo₄). Most clasts have triple junctions between silicate grains. The rare earth element (REE) abundances are high in diopside (REE ~3.80–13.83 × CI) and plagioclase (Eu ~12.31–14.67 × CI) but are low in olivine (REE ~0.01–1.44 × CI) and spinel (REE ~0.25–0.49 × CI). These REE abundances are different from those of metamorphosed chondrites, primitive achondrites, and achondrites, suggesting that the clasts are not fragments of these meteorites. Similar mineralogical characteristics of the clasts with those in the Mokoia and Yamato‐86009 breccias (Jogo et al. 2012 ) suggest that the clasts observed in this study would also form inside the CV3 chondrite parent body. Thermal modeling suggests that in order to reach the metamorphosed temperatures of the clasts of >800 °C, the clast parent body should have accreted by ~2.5–2.6 Ma after CAIs formation. The consistency of the accretion age of the clast parent body and the CV3 chondrule formation age suggests that the clasts and CV3 chondrites could be originated from the same parent body with a peak temperature of 800–1100 °C. If the body has a peak temperature of >1100 °C, the accretion age of the body becomes older than the CV3 chondrule formation age and multiple CV3 parent bodies are likely.  相似文献   

Induction of female‐to‐male sex change in a large protogynous fish,Choerodon schoenleinii          下载免费PDF全文

Taku Sato  Masato Kobayashi  Takayuki Takebe  Narisato Hirai  Koichi Okuzawa  Sayumi Sawaguchi  Takahiro Matsubara  Tomofumi Yamaguchi  Rihito Shinoda  Masahiko Koiso  Kazuhisa Teruya 《Marine Ecology》2018,39(1)

Most behavioral studies on hermaphroditic fishes have focused on small‐sized species, which are tractable for research. Although many species of large hermaphroditic fishes are important fishery resources, their proximate mechanisms (visual, chemical and/or behavioral cues) in the social regulation of sex change have not been determined. Determination of these would inform resource management and aquaculture. In order to get closer to understanding the proximate mechanisms underlying the social regulation of female‐to‐male sex change in large hermaphroditic fishes, this study reports situations that induced female‐to‐male sex change in black‐spot tuskfish, Choerodon schoenleinii, a species of large protogynous fish, in massive laboratory tanks. The situations differed in the possibility of male‐to‐female tactile contact and in the group sex ratio, enabling us to infer plausible proximate mechanisms underlying sex change induction. Tactile contact between individuals is suspected to be closely related to the incidence of female‐to‐male sex change in C. schoenleinii. Visual and chemical cues alone may be insufficient to inhibit such sex changes. Male‐to‐female tactile contact may have an important influence on female‐to‐male sex change, i.e., inhibition of this sex change, in this species. The effect of sex ratio of a social group on the incidence of sex change may be due to the relative frequency and intensity of male tactile contact with each female, which may vary with the number of females. In the absence of a dominant male, tactile contact among females may affect the incidence of sex change, as well as determine which individuals change sex.  相似文献   

Polarization Calibration of the <Emphasis Type="Italic">Chromospheric Lyman-Alpha SpectroPolarimeter</Emphasis> for a 0.1% Polarization Sensitivity in the VUV Range. Part II: In-Flight Calibration     

G. Giono  R. Ishikawa  N. Narukage  R. Kano  Y. Katsukawa  M. Kubo  S. Ishikawa  T. Bando  H. Hara  Y. Suematsu  A. Winebarger  K. Kobayashi  F. Auchère  J. Trujillo Bueno  S. Tsuneta  T. Shimizu  T. Sakao  J. Cirtain  P. Champey  A. Asensio Ramos  J. Štěpán  L. Belluzzi  R. Manso Sainz  B. De Pontieu  K. Ichimoto  M. Carlsson  R. Casini  M. Goto 《Solar physics》2017,292(4):57

The Chromospheric Lyman-Alpha SpectroPolarimeter is a sounding rocket instrument designed to measure for the first time the linear polarization of the hydrogen Lyman-\({\upalpha }\) line (121.6 nm). The instrument was successfully launched on 3 September 2015 and observations were conducted at the solar disc center and close to the limb during the five-minutes flight. In this article, the disc center observations are used to provide an in-flight calibration of the instrument spurious polarization. The derived in-flight spurious polarization is consistent with the spurious polarization levels determined during the pre-flight calibration and a statistical analysis of the polarization fluctuations from solar origin is conducted to ensure a 0.014% precision on the spurious polarization. The combination of the pre-flight and the in-flight polarization calibrations provides a complete picture of the instrument response matrix, and a proper error transfer method is used to confirm the achieved polarization accuracy. As a result, the unprecedented 0.1% polarization accuracy of the instrument in the vacuum ultraviolet is ensured by the polarization calibration.  相似文献   

The transition zone chlorophyll front, a dynamic global feature defining migration and forage habitat for marine resources   总被引：2，自引：0，他引：2  

Jeffrey J. Polovina  Evan Howell  Donald R. Kobayashi  Michael P. Seki 《Progress in Oceanography》2001,49(1-4)

Pelagic ecosystem dynamics on all temporal scales may be driven by the dynamics of very specialized oceanic habitats. One such habitat is the basin-wide chlorophyll front located at the boundary between the low chlorophyll subtropical gyres and the high chlorophyll subarctic gyres. Global satellite maps of surface chlorophyll clearly show this feature in all oceans. In the North Pacific, the front is over 8000 km long and seasonally migrates north and south about 1000 km. In the winter this front is located at about 30–35°N latitude and in the summer at about 40–45°N. It is a zone of surface convergence where cool, vertically mixed, high chlorophyll, surface water on the north side sinks beneath warm, stratified, low chlorophyll water on the south side. Satellite telemetry data on movements of loggerhead turtles and detailed fisheries data for albacore tuna show that both apex predators travel along this front as they migrate across the North Pacific. The front is easily monitored with ocean color satellite remote sensing. A change in the position of the TZCF between 1997 and 1998 appears to have altered the spatial distribution of loggerhead turtles. The position and dynamics of the front varied substantially between the 1998 El Niño and the 1999 La Niña. For example, from May to July 1999 the transition zone chlorophyll front (TZCF) remained between about 35°N and 40°N latitude showing very little meandering, whereas in 1998, during the same period, the TZCF exhibited considerable meandering and greater monthly latitudinal movement. Catch rates for albacore were considerably higher in 1998 than in 1999, and we hypothesize that a meandering TZCF creates regions of convergence, which enhances the foraging habitat for apex predators along the front.  相似文献   

Production of the Blood Pressure Lowing Peptides from Brown Alga （ Undaria pinnatifida ）     

Sato Minoru Oba Takashi Hosokawa Takao Yamaguchi Toshiyasu Nakano Toshiki Saito Tadao Muramoto Koji Kahara T akashi Funayama Katsura Kobayashi Akio Nakano Takahisa 《中国海洋大学学报(英文版)》2005,4(3):209-213

Brown alga （ Undaria pinnatifida） was treated with alginate lyase and hydrolyzed using 17 kinds of proteases and the inhibitory activity of the hydrolysates for the angiotensin-I-converting enzyme （ACE） was measured. Four hydrolysates with potent ACE-inhibitory activity were administered singly and orally to spontaneously hypertensive rats （SHRs）. The systolic blood pressure of SHRs decreases significantly after single oral administration of the brown alga hydrolysates by pro- tease S ＇ Amano＇ （from Bacillus stearothermophilus） at the concentration of 10 （mg protein） （kg body weight）^ - 1. In the 17 weeks of feeding experiment, 7-week-old SHRs were fed standard diet supplemented with the brown alga hydrolysates for 10 weeks. In SHRs fed 1.0 and 0.1% brown alga hydrolysates, elevating of systolic bloodpressure was significantly suppressed for 7 weeks. To elucidate the active components, the brown alga hydrolysates were fractionated by 1-butanol extraction and HPLC on a reverse-phase column. Seven kinds of ACE-inhibitory peptides were isolated and identified by amino acid composition analysis, sequence analysis, and LC-MS with the results Val-Tyr, Ile-Tyr, Ala-Trp, Phe-Tyr, Val-Trp, Ile-Trp, and Leu-Trp. Each peptide was determined to have an antihypertensive effect after a single oral administration in SHRs. The brown alga hydrolysates were also confirmed to decrease the blood pressure in humans.  相似文献   

A new method to calculate normal modes     

Naoki Kobayashi 《Geophysical Journal International》2007,168(1):315-331

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INVERSION OF STRIKE-SLIP MOVEMENTS ALONG THE YARLUNG ZANGBO SUTURE ZONE, TIBET     

Kobayashi Kenta  Matsuoka Atsushi  Yang Qun  Nagahashi Toru  Takei Masahiko  Zeng Qinggao  Wang Yujin 《地学前缘》2000,(Z1)

INVERSION OF STRIKE-SLIP MOVEMENTS ALONG THE YARLUNG ZANGBO SUTURE ZONE, TIBET  相似文献