Sequentially sampled gas hydrate water,coupled with pore water and bottom water isotopic and ionic signatures at the Kukuy mud volcano,Lake Baikal: ambiguous deep-rooted source of hydrate-forming water     

Hirotsugu Minami  Akihiro Hachikubo  Hirotoshi Sakagami  Satoshi Yamashita  Yusuke Soramoto  Tsuyoshi Kotake  Nobuo Takahashi  Hitoshi Shoji  Tatyana Pogodaeva  Oleg Khlystov  Andrey Khabuev  Lieven Naudts  Marc De Batist 《Geo-Marine Letters》2014,34(2-3):241-251

The isotopic and ionic composition of pure gas hydrate (GH) water was examined for GHs recovered in three gravity cores (165–193 cm length) from the Kukuy K-9 mud volcano (MV) in Lake Baikal. A massive GH sample from core St6GC4 (143–165 cm core depth interval) was dissociated progressively over 6 h in a closed glass chamber, and 11 sequentially collected fractions of dissociated GH water analyzed. Their hydrogen and oxygen isotopic compositions, and the concentrations of Cl^– and HCO₃ ^– remained essentially constant over time, except that the fraction collected during the first 50 minutes deviated partly from this pattern. Fraction #1 had a substantially higher Cl^– concentration, similar to that of pore water sampled immediately above (135–142 cm core depth) the main GH-bearing interval in that core. Like the subsequent fractions, however, the HCO₃ ^– concentration was markedly lower than that of pore water. For the GH water fractions #2 to #11, an essentially constant HCO₃ ^–/Cl^– ratio of 305 differed markedly from downcore pore water HCO₃ ^–/Cl^– ratios of 63–99. Evidently, contamination of the extracted GH water by ambient pore water probably adhered to the massive GH sample was satisfactorily restricted to the initial phase of GH dissociation. The hydrogen and oxygen isotopic composition of hydrate-forming water was estimated using the measured isotopic composition of extracted GH water combined with known isotopic fractionation factors between GH and GH-forming water. Estimated δD of ?126 to ?133‰ and δ¹⁸O of ?15.7 to ?16.7‰ differed partly from the corresponding signatures of ambient pore water (δD of ?123‰, δ¹⁸O of ?15.6‰) and of lake bottom water (δD of ?121‰, δ¹⁸O of ?15.8‰) at the St6GC4 coring site, suggesting that the GH was not formed from those waters. Observations of breccias in that core point to a possible deep-rooted water source, consistent with published thermal measurements for the neighboring Kukuy K-2 MV. By contrast, the pore waters of core St6GC4 and also of the neighboring cores GC2 and GC3 from the Kukuy K-9 MV show neither isotopic nor ionic evidence of such a source (e.g., elevated sulfate concentration). These findings constrain GH formation to earlier times, but a deep-rooted source of hydrate-forming water remains ambiguous. A possible long-term dampening of key deep-water source signatures deserves further attention, notably in terms of diffusion and/or advection, as well as anaerobic oxidation of methane.  相似文献   

Physics of seasonally ice-covered lakes: a review   总被引：2，自引：0，他引：2  

Georgiy Kirillin  Matti Lepp?ranta  Arkady Terzhevik  Nikolai Granin  Juliane Bernhardt  Christof Engelhardt  Tatyana Efremova  Sergey Golosov  Nikolai Palshin  Pavel Sherstyankin  Galina Zdorovennova  Roman Zdorovennov 《Aquatic Sciences - Research Across Boundaries》2012,74(4):659-682

  相似文献   

Solubility of the assemblage albite+K-feldspar+andalusite+quartz in supercritical aqueous chloride solutions at 650 °C and 2 kbar     

Tatyana M. Pak  Christoph A. Hauzenberger  Lukas P. Baumgartner   《Chemical Geology》2003,200(3-4):377-393

The solubility of the high grade pelite assemblage albite+K-feldspar+andalusite+quartz at 650 °C and 2 kbar was determined in aqueous solutions over a total chloride range of 0.01–3 m_Cl^tot using rapid-quench hydrothermal technique. The concentration of Na, K, Si, and Al was determined in the fluid phase after quench. The K/Na ratio was determined by approaching the equilibrium from below and above. It is 0.34 at low chloride concentrations and decreases slightly to 0.31 with increasing total chloride. Silica and aluminum concentrations were determined only from undersaturation. The silica solubility is found to be independent of chloride concentration and is 0.13 molal. Aluminum is nearly independent of chloride concentration decreasing only slightly from 0.0015 to 0.0007 molal. Comparison of the experimental data with thermodynamic model calculations demonstrates that the silica concentrations are well predicted, while significant differences exist between individual databases for Al speciation and its total concentration. Al concentrations are underestimated by up to 10 to 15 orders of magnitude using the SUPCRT92 database. Predicted K/Na ratios are underestimated by up to 30%. The best predictions achieved for this simplified high-grade pelite assemblage are those using the SUPCRT92 database with revised thermodynamic data for feldspars and K- and Na-species (J. Phys. Chem. Ref. Data 24 (1995) 1401) and additional Al-species (Am. J. Sci. 295 (1995) 1255; Geochim. Cosmochim. Acta 61 (1997) 2175). The use of ideal mixing for neutral complexes in combination with the extended Debye–Hückel activity model for the charged species yields the most compatible speciation model.  相似文献   

Sub-surface precipitation of salts in supercritical seawater   总被引：2，自引：0，他引：2  

Martin Hovland  Tatyana Kuznetsova†  Håkon Rueslåtten‡  Bjørn Kvamme†  Hans Konrad Johnsen¶  Gunnar E. Fladmark§  Andreas Hebach† 《Basin Research》2006,18(2):221-230

Extremely low solubility of typical seawater salts within certain supercritical sections of their pressure–temperature composition space is a proven experimental fact. Its consequences are often referred to as either 'shock crystallization' or 'out-salting'. Our alternative model for the formation of salt deposits hypothesizes that high temperatures and pressures characteristic for the high heat-flow zones of tectonically active basins may bring submarine brines into the out-salting regions and result in the accumulation of geological-scale salt depositions.
To confirm the laboratory observations, molecular-scale simulations (molecular dynamics) have been employed to study structural changes in a model seawater system where temperature increased from ambient to near-critical and supercritical. Fluid properties and phase transition regions extracted from the simulations were then used as input parameters for a reservoir simulator program to model out-salting in a simple hydrothermal geological system. Both numerical simulations and laboratory experiments confirm that supercritical out-salting is a viable process of geological significance for the formation and accumulation of evaporites. We suggest two regions where hydrothermally associated salts may be depositing today: Atlantis II Deep, in the Red Sea, and Lake Asale, Ethiopia.  相似文献   

Evaluating ecological quality in the north-eastern Black Sea coastal zone   总被引：1，自引：0，他引：1  

Wilson JG  Komakhidze A  Osadchaya T  Alyomov S  Romanov A  Tediashvili M 《Marine pollution bulletin》2008,57(1-5):202-207

Anthropogenic pressures have resulted in measurable impacts on the coastal ecosystems of the northern (Sevastopol Bay, Ukraine) and eastern (Batumi aquatoria, Georgia) Black Sea. Indices suggest that major impacts are relatively localized and are comparable to similar situations in the northern Atlantic. In contrast, biodiversity was appreciably lower than from comparable north Atlantic waters. The number of macrobenthic species was typically round 50, less than half the number that might be expected from similar exercises in US or European waters. Site-specific indices likewise indicated a somewhat lower diversity within communities, yielding metrics which would indicate a measure of stress in N. Atlantic situations. Microbial status was generally good, although regions close to urbanisation did not comply with standards laid down in the current EC Bathing Water Directive (76/EC/160). Likewise viruses were more commonly, although not exclusively, associated with urban locations, as were phages. Microbial investigation of the sediments confirmed the presence of heterotrophic and oil-oxidising bacteria. Abundance of the latter was closely correlated to the degree of oil contamination of the sediments, and to temperature, although for both, the results showed that the increase in bacterial abundance did level off beyond a certain point. Numbers of oil-oxidising bacteria in the water column displayed a classical response to temperature, with abundance doubling over a 10-degree C rise in temperature. Overall the results suggest that while indices in current use are useful in evaluating coastal quality in the Black Sea, some adjustments would be necessary especially in the establishment of baseline or reference values.  相似文献   

Pattern of vertical velocity in the Lofoten vortex (the Norwegian Sea)     

Igor Bashmachnikov  Tatyana Belonenko  Pavel Kuibin  Denis Volkov  Victor Foux 《Ocean Dynamics》2018,68(12):1711-1725

Mean radial distributions of various dynamic characteristics of the permanently existing anticyclonic Lofoten vortex (LV) in the Norwegian Sea are obtained from an eddy-permitting regional hydrodynamic MIT general circulation model. It is shown that the model adequately reproduces the observed 3D thermohaline and dynamic structure of the vortex. The obtained radial distribution of the mean vertical velocity is found to form a complex structure: with the upward fluxes along the axis in and above the anticyclonically rotating LV core, compensated by the downward fluxes in the vortex skirt. These vertical motions maintain the vortex potential energy anomaly against dissipation. This secondary circulation is generated by the centrifugal force and, to a lesser extent, by the horizontal dispersion of the vortex energy, both intensified towards the sea surface. Below the vortex core, the maximum downward vertical velocity converges towards the vortex axis with depth. At these depth levels, the secondary circulation is forced by Ekman divergence in the bottom mixed layer. The theory of columnar vortices with helical structure, applied to the LV, relate the radial profiles of the vertical velocity with those of the horizontal circulation. The theoretically predicted the radial patterns of the mean vertical velocity in the LV were close to those, obtained from the primitive equation ocean model, when approximating the radial patterns of the azimuthal velocity with the Rayleigh profile.  相似文献   

Ectomycorrhiza of <Emphasis Type="Italic">Larix sibirica</Emphasis> Ledeb. along the gradients of main ecological factors and elevation at the Northern and Subpolar Urals     

Tatyana Alexandrovna Sizonenko  Yuriy Alexandrovich Dubrovskiy 《山地科学学报》2018,15(12):2603-2613

Siberian larch (Larix sibirica Ledeb.) forests cover the largest areas in the Eurasian boreal zone, but there are insufficient data on its root system including the structure and functional traits of ectomycorrhizas (EM). The aim of this research is to find out if the morphological parameters of Larix sibirica EMs responded to the changes in elevation and main ecological factors (soil humidity, soil richness, soil acidity and habitat illumination). Using light microscopy, we studied EM diameter, root diameter, mantle width, and mantle volume share, share of tannin cells layers, EM density and EM length of Larix sibirica in two main types of plant communities along the elevation gradient at the Northern and Subpolar Urals. Differences in the environment were traced using phytoindication approach and the Ellenberg ecological scales. All the studied traits depend on the elevation and studied ecological factors. The diversity of fungal mantles is low, and the proportion of unstructured and pseudoparenchymatous mantles is high in response to the deterioration of the humidity, soil nitrogen content and acidity at higher-altitude habitats. Results of EM quantitative parameters measurements confirmed this pattern. We found a decline in the EM linear dimensions accompanied by a compensatory growth of the EM density with the raised elevation and the deterioration of environmental conditions.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987110000162     

Raissa M. Lobatskay  Tatyana G. Krasnoramenskaya 《地学前缘(英文版)》2010,1(1):133-141

<正>Fault-block structures of the Altay-Sayan folded area(ASFA) southeastern Siberia of Russia were used as the basis for creating a 3-D model.The surface structures were projected to depths by previous correlations between long and deep faults,with all layers and deformation factors defined. The mean deformation factor(Ds) is 0.12 unit/km~3 in the upper layer,0.012 unit/km~3 in the intermediate layer,and 0.007 unit/km~3 in the lower layer of the 3-D ASFA neotectonic model.Ds allows correlation of the three distinguished layers with rheological bodies that differ in their potential for accumulating elastic energy.3-D modeling can be used as a methodological approach to projections in seismic prone areas such as the Krasnoyarsk region,for earthquake-hazard monitoring.  相似文献   

The distribution and utility of sea‐level indicators in Eurasian sub‐Arctic salt marshes (White Sea,Russia)     

Andrew C. Kemp  Benjamin P. Horton  Daria Nikitina  Christopher H. Vane  Marina Potapova  Elizabeth Weber‐Bruya  Stephen J. Culver  Tatyana Repkina  David F. Hill 《Boreas: An International Journal of Quaternary Research》2017,46(3):562-584

In support of efforts to reconstruct relative sea level (RSL), we investigated the utility of foraminifera, diatoms and bulk‐sediment geochemistry (δ¹³C, C:N and parameters measured by Rock‐Eval pyrolysis) as sea‐level indicators in Eurasian sub‐Arctic salt marshes. At three salt marshes (<15 km apart) in Dvina Bay (White Sea, Russia), we collected surface sediment samples along transects from subtidal to Taiga forest environments. Foraminifera at all sites formed bipartite assemblages, where elevations below mean high higher water (MHHW) were dominated by Miliammina spp. and elevations between MHHW and the highest occurrence of foraminifera were dominated by Jadammina macrescens and Balticammina pseudomacrescens. Five high‐diversity groups of diatoms were identified and they displayed pronounced variability amongst the study sites. Bulk‐sediment geochemistry recognized two groups (clastic‐dominated environments below MHHW and organic‐rich environments above MHHW). As one group included subtidal elevations and the other included supratidal elevations, we conclude that the measured geochemical parameters are not stand‐alone sea‐level indicators. Core JT2012 captured a regressive sediment succession of clastic, tidal‐flat sediment overlain by salt‐marsh organic silt and freshwater peat. The salt‐marsh sediment accumulated at 2804±52 years before present and preserved foraminifera (Jadammina macrescens and Balticammina pseudomacrescens) with good analogy to modern assemblages indicating that RSL was +2.60±0.47 m at this time. Diatoms confirm that marine influence decreased through time, but the lack of analogy between modern and core assemblages limited their utility as sea‐level indicators. Geochemical parameters also indicate a reduction in marine influence through time. We conclude that RSL reconstructions derived from salt‐marsh sediment preserved beneath Eurasian sub‐Arctic peatlands can provide valuable insight into the spatio‐temporal evolution of the Fennoscandian and Eurasian ice sheets.  相似文献   

Numerical Simulation of the Orbital Evolution of Near-Earth Asteroids Close to Mean Motion Resonances     

Larisa Bykova  Tatyana Galushina 《Celestial Mechanics and Dynamical Astronomy》2002,82(3):265-284

The dynamics of near-Earth asteroids near mean motion resonances with the Earth or other planets is considered. The probability domains of the motion of some near-Earth asteroids close to low-order resonances are presented. The investigations have been carried out by means of a numerical integration of differential equations, taking into account the perturbations from the major planets and the Moon. For each investigated object an ensemble of 100 test particles with orbital elements nearby those of the nominal orbit has been constructed and its evolution has been retraced over the time interval (–3000, +3000 years). The initial set of orbits has been generated on the basis of probable variations of the initial orbital elements obtained from the least square analysis of observations.This revised version was published online in October 2005 with corrections to the Cover Date.  相似文献