Heavily fractionated noble gases in an acid residue from the Klein Glacier 98300 EH3 chondrite     

Daisuke Nakashima  Ulrich Ott  Tomoki Nakamura 《Geochimica et cosmochimica acta》2010,74(17):5134-5149

Noble gases were measured both in bulk samples (stepped pyrolysis and total extraction) and in a HF/HCl residue (stepped pyrolysis and combustion) from the Klein Glacier (KLE) 98300 EH3 chondrite. Like the bulk meteorite and as seen in previous studies of bulk type 3 E chondrites (“sub-Q”), the acid residue contains elementally fractionated primordial noble gases. As we show here, isotopically these are like those in phase-Q of primitive meteorites, but elementally they are heavily fractionated relative to these. The observed noble gases are different from “normal” Q noble gases also with respect to release patterns, which are similar to those of Ar-rich noble gases in anhydrous carbonaceous chondrites and unequilibrated ordinary chondrites (with also similar isotopic compositions). While we cannot completely rule out a role for parent body processes such as thermal and shock metamorphism (including a later thermal event) in creating the fractionated elemental compositions, parent body processes in general seem not be able to account for the distinct release patterns from those of normal Q noble gases. The fractionated gases may have originated from ion implantation from a nebular plasma as has been suggested for other types of primordial noble gases, including Q, Ar-rich, and ureilite noble gases. With solar starting composition, the corresponding effective electron temperature is about 5000 K. This is lower than inferred for other primordial noble gases (10,000-6000 K). Thus, if ion implantation from a solar composition reservoir was a common process for the acquisition of primordial gas, electron temperatures in the early solar system must have varied spatially or temporally between 10,000 and 5000 K.Neon and xenon isotopic ratios of the residue suggest the presence of presolar silicon carbide and diamond in abundances lower than in the Qingzhen EH3 and Indarch EH4 chondrites. Parent body processes including thermal and shock metamorphism and a late thermal event also cannot be responsible for the low abundances of presolar grains. KLE 98300 may have started out with smaller amounts of presolar grains than Qingzhen and Indarch.  相似文献   

Impacts of tectonic and orbital forcing on East African climate: a comparison based on global climate model simulations   总被引：1，自引：1，他引：0  

Frank Kaspar  Kerstin Prömmel  Ulrich Cubasch 《International Journal of Earth Sciences》2010,99(7):1677-1686

A global atmosphere–ocean model has been forced with topographic and orbital scenarios in order to evaluate the relative role of both factors for the past climate of East Africa. Forcing the model with a significantly reduced topography in Eastern and Southern Africa leads to a distinct increase in moisture transport from the Indian Ocean into the eastern part of the continent and increased precipitation in Eastern Africa. Simulations with step-wise reduced height show that this climate change occurs continuously with the change in topography, i.e., an abrupt change of local climatic features with a critical height is not found. Simulations of the last interglacial (at 125,000 years before present, i.e., the Eemian interglacial) and the last glacial inception (at 115,000 years before present) are used as examples for the role of orbital-induced changes in insolation. Here, changes in meridional temperature gradients lead to modifications in moisture transport of similar order of magnitude, but with different spatial and seasonal structure. For the Eemian interglacial, a distinct increase in summer moisture transport from the Atlantic deep into the continent at around 20°N is simulated.  相似文献   

Long-Term Observations of Isotope Ratio Accuracy and Reproducibility Using Quadrupole ICP-MS     

Thomas Ulrich  Balz S. Kamber  Jon D. Woodhead  Lizzy A. Spencer 《Geostandards and Geoanalytical Research》2010,34(2):161-174

High precision isotope ratio and trace element determination can be achieved with modern quadrupole ICP-MS provided that short and long-term instrument performance is accurately monitored. Here we present results for the isotope ratios ⁶Li/⁷Li, ¹⁴⁷Sm/¹⁴⁹Sm, ¹⁶⁰Dy/¹⁶¹Dy, ²⁰⁷Pb/²⁰⁶Pb, ²⁰⁸Pb/²⁰⁶Pb, ²⁰⁶Pb/²⁰⁴Pb and ²³⁵U/²³⁸U with which we determined long-term isotope ratio stability of relevance to both trace element and isotope determination. With respect to trace element determination, we first present long-term observations regarding oxide formation rates of Ba and Nd on light REE and heavy REE, as well as Zr on Ag. These showed good correlations and could be used to correct effectively the interference. The efficacy of this correction was demonstrated with analyses of the rock reference material BHVO-2 at both low and high oxide formation rates. Next, we studied the long-term reproducibility of a Dy isotope ratio that was measured to correct for the isobaric interference on Gd. It was found that, regardless of tuning condition, the ratio reproduced very well (0.58% RSD, 1s) and that the estimate of the Gd concentration did not suffer from the large correction (> 10%) caused by the Dy isobar. Long-term reproducibilities of Li, Sm and U isotope ratios, required for accurate mass bias correction when isotopically enriched internal standards of these elements are employed, were measured in the rock reference materials AGV-2 and JA-3 over a time period of up to 3 years. As expected, the Li isotope ratio showed the largest variability (RSD = 7%), but the other two ratios had relative external reproducibilities of only 1.01% (1s, U) and 0.67% (Sm). The mass bias-induced scatter in measurements for Sm and U was so small that the internal standard correction was effective, even for samples with high concentrations of these elements. With regard to Pb-isotope ratio determination, we also present long-term reproducibility for NIST SRM 982, run as an unknown and two accuracy tests for Pb separated from granitoids and from meteorites. It is demonstrated that the obtained ratios, including those involving ²⁰⁴Pb, are accurate relative to MC-ICP-MS determinations and of comparable precision to conventional TIMS analysis. The excellent agreement between all data sets shows the potential of modern quadrupole ICP-MS instrumentation for Pb-isotope determination, particularly for samples with very low Pb content.  相似文献   

Fragility curves for masonry structures submitted to permanent ground displacements and earthquakes   总被引：1，自引：1，他引：0  

C. Negulescu  T. Ulrich  A. Baills  D. M. Seyedi 《Natural Hazards》2014,74(3):1461-1474

Usually, the vulnerability of structures is treated considering only one single hazard, for example either seismic hazard or ground instability. However, historical monuments, cultural heritage structures or old masonry structures can be affected, over the past centuries of existence, by a succession of different hazards. The objective of this paper was to quantify the changes in the seismic vulnerability of a given structure previously damaged by quasi-static differential settlements. In view of this, a soil-structure model of the masonry building is constructed using TREMURI software by putting springs at the base of the building to account for the soil behaviour. Classical empirical relationships are used for setting the mechanical properties of these foundation springs. The chosen equations are valid for both static and dynamic situations. The soil-structure model is first submitted to differential settlements with maximum magnitudes ranging from 5 to 25 cm. Then, the damaged structures are submitted to a set of time-histories. Fragility curves taking into consideration permanent differential settlements are finally obtained, using a modified regression technique accounting for the presence of residual drift due to the prior static loading.  相似文献   

Tying platform drowning to perturbations of the global carbon cycle with a δ¹³C_Org-curve from the Valanginian of DSDP Site 416     

Ulrich G. Wortmann  & Helmut Weissert 《地学学报》2000,12(6):289-294

The carbonate carbon isotope record of the Phanerozoic is marked by repeated high-amplitude excursions towards more positive values. Although the interpretation of C-isotope events remains controversial, they are regarded as a proxy of the global C-cycle. Using δ¹³C_Org-measurements of samples from DSDP Site 416, it is shown that a classic example of platform drowning coincided with the onset of the mid-Valanginian carbon-cycle excursion. Widespread carbonate platform drowning would have contributed to the observed positive shift in the C-isotope record. As choking of carbonate production was compensated by increased organic production, both processes favoured a shift in marine carbon partitioning from the oxidized to the reduced carbon reservoir. This would have resulted in an increased flux of CO₂ from the atmosphere into the marine and sedimentary carbon reservoir.  相似文献   

A system for line profile studies at the 150-foot tower on Mount Wilson     

Roger K. Ulrich  Larry Webster  John E. Boyden  Nick Magnone  Richard S. Bogart 《Solar physics》1991,135(2):211-241

We describe enhancements to the hardware and software for the 150-foot tower system on Mt. Wilson which make possible the acquisition of high precision line profile measurements. This system utilizes the 75-foot pit spectrograph with a photomultiplier detector system to scan line profiles repeatedly in order to study variations induced by the passage of waves vertically through the solar atmosphere. Oscillations of line profile parameters with an amplitude as low as 1.7 m s^–1 have been detected with this system using integrated sunlight. Phase relations between oscillations of different parts of the line profile are appropriate to upward energy transport. Consistent with the previous conclusion by Mein and Schmieder (1981), we find that the magnitude of the energy transport is compatible with the 5-min oscillations making an important contribution to the heating of the low chromosphere.The Mount Wilson Observatory is operated by the Mount Wilson Institute under agreement with the Carnegie Institution of Washington.  相似文献   

The Munich Near-Infrared Cluster Survey – I. Field selection, object extraction and photometry     

N. Drory †‡  G. Feulner †  R. Bender †  C.S. Botzler  U. Hopp †  C. Maraston  C. Mendes de Oliveira †  J. Snigula † 《Monthly notices of the Royal Astronomical Society》2001,325(2):550-562

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Time variable Earth’s gravity field from SLR satellites   总被引：4，自引：4，他引：0  

Krzysztof Sośnica  Adrian Jäggi  Ulrich Meyer  Daniela Thaller  Gerhard Beutler  Daniel Arnold  Rolf Dach 《Journal of Geodesy》2015,89(10):945-960

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Benchmarks for multicomponent reactive transport across a cement/clay interface     

Nicolas C. M. Marty  Olivier Bildstein  Philippe Blanc  Francis Claret  Benoit Cochepin  Eric C. Gaucher  Diederik Jacques  Jean-Eric Lartigue  Sanheng Liu  K. Ulrich Mayer  Johannes C. L. Meeussen  Isabelle Munier  Ingmar Pointeau  Danyang Su  Carl I. Steefel 《Computational Geosciences》2015,19(3):635-653

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A Multi-Observatory Inter-Comparison of Line-of-Sight Synoptic Solar Magnetograms     

P. Riley  M. Ben-Nun  J. A. Linker  Z. Mikic  L. Svalgaard  J. Harvey  L. Bertello  T. Hoeksema  Y. Liu  R. Ulrich 《Solar physics》2014,289(3):769-792

The observed photospheric magnetic field is a crucial parameter for understanding a range of fundamental solar and heliospheric phenomena. Synoptic maps, in particular, which are derived from the observed line-of-sight photospheric magnetic field and built up over a period of 27 days, are the main driver for global numerical models of the solar corona and inner heliosphere. Yet, in spite of 60 years of measurements, quantitative estimates remain elusive. In this study, we compare maps from seven solar observatories (Stanford/WSO, NSO/KPVT, NSO/SOLIS, NSO/GONG, SOHO/MDI, UCLA/MWO, and SDO /HMI) to identify consistencies and differences among them. We find that while there is a general qualitative consensus, there are also some significant differences. We compute conversion factors that relate measurements made by one observatory to another using both synoptic map pixel-by-pixel and histogram-equating techniques, and we also estimate the correlation between datasets. For example, Wilcox Solar Observatory (WSO) synoptic maps must be multiplied by a factor of 3?–?4 to match Mount Wilson Observatory (MWO) estimates. Additionally, we find no evidence that the MWO saturation correction factor should be applied to WSO data, as has been done in previous studies. Finally, we explore the relationship between these datasets over more than a solar cycle, demonstrating that, with a few notable exceptions, the conversion factors remain relatively constant. While our study was able to quantitatively describe the relationship between the datasets, it did not uncover any obvious “ground truth.” We offer several suggestions for how this may be addressed in the future.  相似文献