Mercury speciation in surface and deep waters of the Mediterranean Sea     

Jože Kotnik  Milena Horvat  Emmanuel Tessier  Nives Ogrinc  Mathilde Monperrus  David Amouroux  Vesna Fajon  Darija Gibičar  Suzana Žižek  Francesca Sprovieri  Nicola Pirrone 《Marine Chemistry》2007

Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg⁰, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.  相似文献   

Hydrogen and Helium under high pressure: A case for a classical theory of dense matter     

Vladan čelebonović 《Earth, Moon, and Planets》1989,45(3):291-298

When subject to high pressure, H₂ and ³He are expected to undergo phase transitions, and to become metallic at a sufficiently high pressure. Using a semiclassical theory of dense matter proposed by Savi and Kaanin, calculations of phase transition and metallisation pressure have been performed for these two materials. In hydrogen, metallisation occurs at p _M= (3.0 ± 0.2) Mbar, while for helium the corresponding value is p _M= (106 ± 1) Mbar. A phase transition occurs in helium at p _tr= (10.0 ± 0.4) Mbar. These values are close to the results obtainable by more rigorous methods. Possibilities of experimental verification of the calculations are briefly discussed.  相似文献   

The ionization balance of the Fe in the solar corona for a non-Maxwellian electron distribution function     

Elena Dzifčáková 《Solar physics》1992,140(2):247-267

The ionization equilibrium of the Fe in the solar corona for a non-Maxwellian electron distribution with an enhanced number of particles in the high-energy tail is presented. A parametric form of the distribution function is used to demonstrate the changes in the ionization equilibrium with changes in the shape of the distribution. The results over the range of temperature 10⁵ K T 10⁸ K for different deviations of the distribution from a Maxwellian are given in tabular form. The results can be used for specific applications in the solar corona, especially in the active corona, where deviations from the Maxwellian distribution can be significant.  相似文献   

Croatia as a Danube country     

Ivan Crkvenčić Ph.D.  Adolf Malić Ph.D. 《GeoJournal》1996,38(4):455-462

Among the three principal regional units of Croatia, i.e. the elongated and spacious Adriatic littoral (with numerous islands), the relatively small and narrow mountainous belt (the Croatian transit doorway) and the Pannonian/peri-Pannonian region, the latter is the largest and accounts for 54 percent of the surface area and 66 percent of the population of Croatia (1991 census). It is part of the Pannonian (or Carpathian) basin, or the central Danube basin, so that Croatia is simply by its position a Danube country. Its Danube character is also highlighted by the fact that the Pannonian/peri-Pannonian region of Croatia through the Sava and Drava Rivers is directly linked to the navigable Danube, which is the historical and ethnic eastern boundary of Croatia. Croatia is an old historical Danube nation and country, although it has nominally appeared as a state after the break-up of Yugoslavia, and its international recognition as an independent state (1992).  相似文献   

Energy balance of simple elastodynamic sources     

Václav Vavryčuk 《Pure and Applied Geophysics》1994,143(4):563-586

Complete relations are derived for energy and energy flux of elastic waves generated by an isotropic and double-couple source in a perfectly elastic, homogeneous, isotropic, and unbounded medium. In the energy balance of elastodynamic sources near-field waves play an essential role, transforming static energy into wave energy, andvice versa. For explosive and dislocation sources, the sources surface radiates a positive wave energy that is partially distributed to the medium transforming into static energy. For implosive and antidislocation sources, the source surface generates elastic waves, but it does not necessarily imply that it also radiates a positive wave energy. The energy transported by waves can originate in gradual transformation of the static-to-wave energy during propagation of waves through a stressed medium.On leave from Geophysical Institute, Czech Academy of Sciences, Boní II/1401, 41 31, Praha 4 Czech Republic  相似文献   

Dynamics of the plasmasphere in the dusk sector as observed in the outer ionosphere     

J. Bošková  F. Jiříček  J. Šmilauer  P. Tříska 《Studia Geophysica et Geodaetica》1994,38(1):82-92

Summary Direct measurements of the thermal plasma parameters in the topside ionosphere reveal variations of the plasmasphere boundary in the dusk sector. The ACTIVE satellite's near-polar orbits at altitudes of 500 – 1800 km around winter solstice 1989 were used to study the bulge region of the plasmasphere during intervals with different levels of geomagnetic agitation. The narrow, sharply defined trough in electron concentration corresponding to the plasmapause under quiet conditions situated at L = 6 – 7 moved to lower L-values with increasing geomagnetic activity. This narrow trough can be found in all main ion constituents. During periods of moderate geomagnetic activity, following the onset of a weak magnetic storm, a portion of the plasmaspheric bulge region was separated from the main plasmaspheric body. This can be seen in the outer ionosphere as an inner narrow trough at lower L-value. Troughs in light ions need no longer coincide with this in electron concentration. He⁺ is the most sensitive constituent reflecting the dusk sector plasmaspheric situation at this altitude.Dedicated to the Memory of Professor Karel P  相似文献   

Ab initio calculated electron densities for tetrahedral sheet [H2Si2O5]∞ in phyllosilicates     

Ľ. Benco  Ľ. Smrčok 《Physics and Chemistry of Minerals》1994,21(6):401-406

Periodic ab initio Hartree-Fock LCAO calculations have been carried out on the two dimensional sheet of SiO₄ tetrahedra, representing one of the basic constituting units of layer silicates, using Huzinaga's DZP basis sets. The influence of the basis set on the chemical bonding picture is characterized by Mulliken atomic charges and by electron density maps. Silicon atomic charges +1.6 ¦e¦ are more realistic than those +2.4 ¦e¦ reported for smaller basis sets. The silicon d orbital population is found to be 0.6 in close agreement with molecular data. Electron density maps indicate the absence of charge density in the center of the ditrigonal cavity. The charge buildup of nonbonding basal oxygen orbitals is directed mainly downwards perpendicular to the sheet plane.  相似文献   

Geomagnetic activity as a possible cause of changes in the middle atmosphere and troposphere; observations made in Prague in the years 1932–1987     

Josef Bochníček  Josef Pýcha 《Studia Geophysica et Geodaetica》1994,38(1):103-107

Summary A possible relation between the 10-day, 1-month, and 2-month geomagnetic as well as solar activity, characterized by Kp and Wolf's number R, and temperatures measured at the Prague-Klementinum meteorological station in January–February of the years 1932–1987 was sought. It was found that:1) Kp correlates with the temperature in Prague better than Wolf's number R.2) If the QBO phase is taken into account, the correlations improve.3) Even if the correlations improves with increasing length of the subintervals into which the individual winter periods (January-February) were derived, their statistical significance declines.  相似文献   

Dust particle and solar radiation     

J. Klačka  J. Kaufmannová 《Earth, Moon, and Planets》1993,61(1):63-65

Influence of the solar radiation (electromagnetic and corpuscular - solar wind) on the motion of the interplanetary dust particle is investigated. The ratio time of inspiralling toward the Sun: time of inspiralling neglecting the change of mass of the particle is presented as a function of initial eccentricities.  相似文献   

Problems connected with the tangential metric coefficient in the Schwarzschild metric: A possible solution     

Pavel Voráček 《Astrophysics and Space Science》1982,81(1-2):85-94

Four situations are shown where the Schwarzschild metric cannot be used or is subject to unsurmountable problems. The first is the question of a metric useful for PPN-formalism checking different gravitational theories. The second problem occurs in connection with Mach's principle, when the flatness of the spacetime inside a massive hollow sphere is a generally accepted solution. The metrical discontinuity on the same spherical shell is a third problem. The fourth one is the anisotropy of the mass-energy of a test particle in the gravitational field. Three principles for solution are proposed:

1. The space is not dilated, but rather contracted, in the gravitational field; then the measurement-rods are shorter and measured distances have greater magnitudes.
2. The potential energy is to be related to a potential level where a stationary observer is placed and the general relativistic potential must be used.
3. A new metric must be introduced which is distinct from the Schwarzschild metric, so that the space in the gravitational field is warped isotropically.

Then the problems stated are shown to be easily solvable.  相似文献