Metalliferous coals: A review of the main genetic and geochemical types     

Vladimir V. Seredin  Robert B. Finkelman 《International Journal of Coal Geology》2008,76(4):253-289

This paper presents a review of the genetic types and geochemical processes that have formed ‘metalliferous’ coals around the world. Primary attention is given to elements in coal that are currently being extracted from coal as raw material (Ge and U) or have, in our opinion, the best chance for such use (REE, Ag, Au, and PGE). Coals with anomalously high concentrations of other metals having potential for economic by-product recovery (Be, Sc, V, Ga, Sb, Cs, Mo, W, and Re) are briefly considered. Original data and a survey of the literature indicate that metalliferous coals are in many coal basins. Ore formation in coal-bearing structures may occur during peat accumulation, during diagenesis of the organic matter, or by epigenesis. Various metals are supplied to sedimentary basins as minerals that are transported by water and wind or as ionic species in surface water and descending and ascending underground water and may be incorporated into peat or coals. The modes of occurrence of metals in the enriched coals are diverse. The data presented in this review indicates that metalliferous coals should be regarded as promising for economic recovery for by-products in the course of coal mining and combustion.  相似文献   

Sedimentation History of Neogene Lacustrine Sediments of Suseocka Bela Stena Based on Geochemical Parameters (Valjevo-Mionica Basin, Serbia)     

Aleksandra AJNOV  Vladimir SIMI  Branimir JOVANIEVI  Olga CVETKOVI  Radovan DIMITRIJEVI  Nenad GRUBIN 《《地质学报》英文版》2008,82(6)

Sediments of the western part of the Valjevo-Mionica basin (Serbia) were examined both geochemically and mineralogically to explain, on the basis of their sedimentological characteristics, the causes of changes in their qualitative and quantitative composition. A total of 62 samples obtained from the drillhole at depths up to 400 m was investigated. Using correlation of the obtained data, six geochemical zones were defined, two of which being specially distinguished by their mineralogical, geochemical and sedimentological characteristics. The first one, upper zone A, consists of banded marlstones interbedded with clay and oil shales and is characterized by presence of analcite and searlesite. These minerals and very high contents of Na2O indicate sedimentation in alkaline conditions with increased salinity in arid climate. That provided pronounced water stratification, as well as higher bioproductivity in the basin and sedimentary organic matter preservation. Therefore, the zone A sediments are characterized by high organic matter contents of the type which provides good potential for production of liquid hydrocarbons. Another specific zone, zone F, contains sediments with very high MgO, K2O and Li concentrations. Their geochemical correlation, as well as almost complete absence of illite in this zone, indicates the presence of interstratified clay mineral type illite-saponite (lithium-bearing Mg-smectite).  相似文献   

Circulation weather types and their influence on precipitation in Serbia     

Suzana Putniković  Ivana Tošić  Vladimir Đurđević 《Meteorology and Atmospheric Physics》2016,128(5):649-662

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An Investigation of the Reliability of HF Acid Mixtures in the Bomb Digestion of Silicate Rocks for the Determination of Trace Elements by ICP‐MS          下载免费PDF全文

Olga Okina  Sergey Lyapunov  Mariya Avdosyeva  Boris Ermolaev  Vladimir Golubchikov  Anatoly Gorbunov  Victor Sheshukov 《Geostandards and Geoanalytical Research》2016,40(4):583-597

The influence of the mixtures HF‐HNO₃ and HF‐NH₄F‐HNO₃ in bomb digestion for trace element determination from different rock types was studied using ICP‐MS. It is shown that the HF concentration, not the ratio of reagents in the decomposing mixture, controls the digestion process of a rock. Data for Zr in the granite G‐2 as a function of HF concentration gave the same results as reaction mixtures of various compositions. A complete digestion in 50‐mg sample bombs was achieved by 1.0 ml of HF alone, or with a mixture of other acids at a HF concentration of at least 35% m/m at 196 °C over 18 h. The results of the analysis of basalts BCR‐1, BIR‐1, mica schist SDC‐1, shale SBC‐1, granites G‐2, SG‐1A, garnet‐biotite plagiogneiss GBPg‐1, rhyolite RGM‐1, granodiorite GSP‐1, trachyandesite MTA‐1 and rhyolite MRh‐1 are given and compared against available data. The reproducibility of the element determinations by ICP‐MS and XRF as an independent non‐destructive analysis for a quality check in the range of concentrations typical for routine rock samples is given.  相似文献   

First geophysical and shallow ice core investigation of the Kazbek plateau glacier,Caucasus Mountains     

Stanislav S. Kutuzov  Vladimir N. Mikhalenko  Alexi M. Grachev  Patrick Ginot  Ivan I. Lavrentiev  Anna V. Kozachek  Victoria V. Krupskaya  Alexey A. Ekaykin  Levan G. Tielidze  Pavel A. Toropov 《Environmental Earth Sciences》2016,75(23):1488

First-ever ice core drilling at Mt. Kazbek (Caucasus Mountains) took place in the summer of 2014. A shallow ice core (18 m) was extracted from a plateau at ~4500 m a.s.l. in the vicinity of the Mt. Kazbek summit (5033 m a.s.l.). A detailed radar survey showed that the maximum ice thickness at this location is ~250 m. Borehole temperature of ?7 °C was measured at 10 m depth. The ice core was analyzed for oxygen and deuterium isotopes and dust concentration. From the observed seasonal cycle, it was determined that the ice core covers the time interval of 2009–2014, with a mean annual snow accumulation rate of 1800 mm w. eq. Multiple melt layers have been detected. δ¹⁸O values vary from ?25 to ?5‰. The dust content was determined using a particle sizing and counting analyzer. The dust layers were investigated using scanning electron microscopy and X-ray diffraction analysis. Dust can be separated into two categories by its origin: local and distant. Samples reflecting predominantly local origin consisted mainly of magmatic rocks, while clay minerals were a characteristic of dust carried over large distances, from the deserts of the Middle East and Sahara. The calculated average dust flux over three years at Kazbek was of 1.3 mg/cm² a^?1. Neither δ¹⁸O nor dust records appear to have been affected by summer melting. Overall, the conditions on Kazbek plateau and the available data suggest that the area offers good prospects of future deep drilling in order to obtain a unique environmental record.  相似文献   

Exploring national decarbonization pathways and global energy trade flows: a multi-scale analysis     

Steve Pye  Christophe McGlade  Chris Bataille  Gabrial Anandarajah  Amandine Denis-Ryan  Vladimir Potashnikov 《Climate Policy》2016,16(4):S92-S109

The role of fossils fuels in national economies will change radically over the next 40 years under a strong climate regime. However, capturing this changing role through national-based analyses is challenging due to the global nature of fossil fuel demand and resulting trade patterns. This article sets out the limitations of existing national-scale decarbonization analyses in adequately capturing global conditions and explores how the introduction of a global modelling framework could provide vital insights, particularly for those countries that are dependent on fossil fuel exports or imports.

The article shows that fossil fuel use will significantly decline by 2050, although gas will have an important transition role. This leaves large fossil fuel exporters exposed, the extent of which is determined by mitigation action in different regions and especially by the pathways adopted by the larger Asian economies. We find that global-scale models provide critical insights that complement the more detailed national analyses and should play a stronger role in informing deep decarbonization pathways (DDPs). They also provide an important basis for exploring key uncertainties around technology uptake, mitigation rates and how this plays out in the demand for fossil fuels. However, use of global models also calls for improved representation of country specifics in global models, which can oversimplify national economic and political realities. Using both model scales provides important insights that are complementary but that can challenge the other’s orthodoxy. However, neither can replace the other’s strengths.

Policy relevance:

In recent years, how global fossil fuel markets will evolve under different climate regimes has been subject to much debate and analysis. This debate includes whether investments in fossil fuel production still make sense or will be exposed in the future to liabilities associated with high carbon prices. This is important for governments who need to develop coherent policy in relation to fossil fuel sectors and their role as drivers of economic growth and in providing for domestic energy needs. This article argues that national analyses need to be fully cognizant of the global-scale transition, which can be informed by using a multi-scale modelling approach.  相似文献   

The effect of pressure on sulphur speciation in mid- to deep-crustal arc magmas and implications for the formation of porphyry copper deposits   总被引：1，自引：0，他引：1  

Vladimir Matjuschkin  Jon D. Blundy  Richard A. Brooker 《Contributions to Mineralogy and Petrology》2016,171(7):66

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Recurrent transitions to Little Ice Age-like climatic regimes over the Holocene     

Helama  Samuli  Stoffel  Markus  Hall  Richard J.  Jones  Phil D.  Arppe  Laura  Matskovsky  Vladimir V.  Timonen  Mauri  N&#;jd  Pekka  Mielik&#;inen  Kari  Oinonen  Markku 《Climate Dynamics》2021,56(11):3817-3833

Holocene climate variability is punctuated by episodic climatic events such as the Little Ice Age (LIA) predating the industrial-era warming. Their dating and forcing mechanisms have however remained controversial. Even more crucially, it is uncertain whether earlier events represent climatic regimes similar to the LIA. Here we produce and analyse a new 7500-year long palaeoclimate record tailored to detect LIA-like climatic regimes from northern European tree-ring data. In addition to the actual LIA, we identify LIA-like ca. 100–800 year periods with cold temperatures combined with clear sky conditions from 540 CE, 1670 BCE, 3240 BCE and 5450 BCE onwards, these LIA-like regimes covering 20% of the study period. Consistent with climate modelling, the LIA-like regimes originate from a coupled atmosphere–ocean–sea ice North Atlantic-Arctic system and were amplified by volcanic activity (multiple eruptions closely spaced in time), tree-ring evidence pointing to similarly enhanced LIA-like regimes starting after the eruptions recorded in 1627 BCE, 536/540 CE and 1809/1815 CE. Conversely, the ongoing decline in Arctic sea-ice extent is mirrored in our data which shows reversal of the LIA-like conditions since the late nineteenth century, our record also correlating highly with the instrumentally recorded Northern Hemisphere and global temperatures over the same period. Our results bridge the gaps between low- and high-resolution, precisely dated proxies and demonstrate the efficacy of slow and fast components of the climate system to generate LIA-like climate regimes.

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Seismic Hazard Assessment Problem in a Big Data World     

Vladimir G. Kossobokov 《《地质学报》英文版》2018,92(Z1):269-269

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Comparison of split window algorithms to derive land surface temperature from satellite TIRS data     

Sajad Zareie  Kazem Rangzan  Hassan Khosravi  Vladimir Modestovich Sherbakov 《Arabian Journal of Geosciences》2018,11(14):391

Remote sensing data can be used as the basis for meteorological data. Due to the limitations of meteorological stations on the Earth, derivation of land surface temperature is one of the most important aspects of the remote sensing application in climatology studies. In the present study, Landsat-8 thermal infrared sensor data of the scene located over Khuzestan province with row/path of 165/38 were used to derive land surface temperature (LST). Normalized difference vegetation index (NDVI), fraction of vegetation cover, satellite brightness temperature, and land surface emissivity were calculated as the vital criteria to derive LSTs using the split window algorithms. LST determination was performed by nine different split window algorithms. Eventually, LST products were evaluated using ground-based measurements at the meteorological stations of the study area. The results showed that algorithm of Coll and Casselles had a highest accuracy with RMSE 1.97 °C, and Vidal’s method presented the lowest accuracy to derive LST with RMSE 4.11 °C. According to the results, regions with high density of vegetation and water resources have lowest diurnal temperature and regions with bare soils and low density of vegetation have a highest diurnal temperature. Results of the study indicated that LST algorithm accuracy is an important factor in the environmental and climate change studies.  相似文献