Lipid biogeochemistry of Phormidium and Microcoleus mats     

Joan O. Grimalt  Rutger de Wit  Pilar Teixidor  Joan Albaigs 《Organic Geochemistry》1992,19(4-6)

A study on the predominant sources of organic matter and the main diagenetic processes in two different cyanobacterial mats from evaporite-controlled environments was performed. Fatty acids, hydrocarbons, alcohols, ketones and aldehydes were anlyzed in selected millimetre and submillimetre core sections. The changes in lipid composition were evaluated by comparison with the vertical distributions of the populations observed by optic microscopy and with the lipid patterns of enrichment cultures of species such as cyanobacteria, diatoms, purple bacteria, sulphate-reducers and methanogens obtained from the mats.The cyanobacteria Phormidium valderianum and Microcoleus chthonoplastes are the predominant primary producers, and occur almost as monocultures in the respective top layers. However, these mat-forming organisms only leave minor features in the solvent-extractable lipid sedimentary record. The predominant fatty acid distributions parallel the composition observed in the enrichment cultures of purple bacteria and appear mixed with acids characteristic of heterotrophic eubacteria such as sulphate-reducers. The concentrations of these lipids are, however, 5–10 times lower than the cyanobacterial acids from the top layer. De novo heterotrophic eubacterial synthesis is also observed in cases such as the highly branched isoprenoid eicosenes, the major hydrocarbon in the deep layers (>2 mm) of the Phormidium mat. Other major diagenetic changes involve dehydration and hydrogenation. These two processes take place concurrently under anoxic conditions and have been observed among the sterols and the isoprenoid alcohols. Significant amounts of 5ß(H)-stanols were observed in the more reducing sections where molecular indicators of methanogenic bacteria were also found.  相似文献   

The Marianas-San Marcos vein system: characteristics of a shallow low sulfidation epithermal Au–Ag deposit in the Cerro Negro district,Deseado Massif,Patagonia, Argentina     

Conrado Permuy Vidal  Diego M. Guido  Sebastián M. Jovic  Robert J. Bodnar  Daniel Moncada  Joan Carles Melgarejo  Willis Hames 《Mineralium Deposita》2016,51(6):725-748

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Evaluating prey capture by larval mummichogs (Fundulus heteroclitus) as a potential biomarker for contaminants     

Weis JS  Samson J  Zhou T  Skurnick J  Weis P 《Marine environmental research》2003,55(1):27-38

We evaluated larval prey capture as a "behavioral biomarker" of contamination by examining feeding behavior of larval mummichogs (Fundulus heteroclitus) from many different sites, including a severely contaminated "Superfund" site, moderately contaminated sites, and reference areas. Prey capture ability was related to sediment contaminant levels. The levels of contaminants at a site were highly correlated with each other, so that the impact of individual contaminants was confounded. The number of captures of brine shrimp by mummichog larvae from all sites was highly variable, but significant negative correlations of prey capture were seen with mercury, lead, zinc, cadmium, and PCBs. As observed previously with adults, polyaromatic hydrocarbons (PAHs) did not appear to impair prey capture ability. The only site in which prey capture rates of 8-day old larvae were severely affected was the most highly contaminated Superfund site, Berry's Creek, NJ. This implies that larval prey capture is not as sensitive a behavioral biomarker for contamination as adult behavior studied previously.  相似文献   

Geographic and bathymetric trends in abundance, biomass and body size of four grenadier fishes along the Iberian coast in the western Mediterranean     

Joan Moranta  Enric Massutí  John D.M. Gordon 《Progress in Oceanography》2007,72(1):63-83

The present study is a mesoscale analysis of latitude and depth related trends in abundance, biomass and body size of the four grenadier species Caelorinchus caelorhincus, Hymenocephalus italicus, Nezumia aequalis and Trachyrinchus scabrus inhabiting the deep western Mediterranean. We have analysed data from seven annual bottom trawl surveys, carried out down to 800 m depth along the Iberian Mediterranean coast covering a distance of approximately 1200 km. The objectives were to establish general patterns in the mesoscale distribution of abundance, biomass and body size of deep-water grenadier fishes and also analyse the consistency of the bathymetric distribution of these parameters along a large latitudinal gradient. Five complementary series of analyses have been completed. The first focussed on describing the general patterns of abundance and size by correspondence canonical analysis, CCA, in the area. The second and third series focussed on the existence of temporal, geographical and bathymetric trends of abundance, weight and mean size by analysis of covariance, ANCOVA and multiple regression analysis. The fourth series compared the frequency distributions of body length. Finally, the last series focussed on the patterns of abundance versus size. The total number of individuals of all four grenadier species captured in 260 bottom trawls amounted to 27,435 and their weight was 1404 kg. No general trends for the four species have been observed between years. All four species showed a general pattern of increasing size with depth, which, except in the case of C. caelorhincus, was consistent along a large latitudinal gradient. Nezumia aequalis was unique in showing the same noticeable trend of increasing abundance with depth along the entire latitudinal range, but with clear differences in the intercepts. The abundance of N. aequalis and C. caelorhincus decreased significantly northwards. Hymenocephalus italicus was the least abundant species and had a homogeneous distribution without any specific trend along the entire latitudinal range analysed. The distribution of T. scabrus in the Mediterranean seemed to be more localised. Higher abundances were found to the north and south of the latitudinal gradient with lower values between. The grenadiers studied also showed a general trend of decreasing mean size northwards, except in the case of the smallest species, H. italicus. The relation between abundance and body size differed between sectors for the whole grenadier population and species-specific variations were also observed. The relationship between individual body mass and population density fit well to a second-order polynomial function rather than to a linear regression, showing a significant trend for density to increase with increasing size until some mid-point, then to decline with increasing size thereafter. The observed latitudinal gradient in the distribution patterns of grenadiers along the upper slope of the western Mediterranean can be discussed in relation to direct and indirect factors of biogeographic, environmental and anthropogenic origin.  相似文献   

The effect of pressure on the solubility of amorphous silica in seawater at 0°C     

Joan D. Willey   《Marine Chemistry》1974,2(4):239-250

The solubility of amorphous silica in seawater at 0°C and from 1 to 1,220 atm. was found to be a linear function of pressure above 270 atm., but to deviate from linearity below that pressure. Using a quadratic derivation of Planck's equation, ΔV for the dissolution was found to be −16.5 cm³mole⁻¹, and Δk was found to be −4.4 · 10⁻² cm³ mole⁻¹ atm⁻¹∂Δk/∂P was found to be 27.2 · 10⁻⁵ cm³ mole⁻¹ atm⁻² which is too significant a factor to allow the commonly made assumption that ∂Δk/∂P =0. North's (1973) model of hydration suggests that this non-zero ∂Δk/∂P may indicate that the silicic acid molecule is more extensively hydrated at lower pressures.If the pressure in an experiment is suddenly lowered to atmospheric pressure after equilibrium solubility had been attained at the higher pressure, the precipitation that occurs to reduce the resulting supersaturation is complete within one hour in the experimental system used in this study.  相似文献   

Dissolved silica concentrations and reactions in pore waters from continental slope sediments offshore from Cape Hatteras, North Carolina, USA     

Joan D. Willey  Arthur J. Spivack 《Marine Chemistry》1997,56(3-4)

The pore water concentrations of dissolved silica in sediment cores from the continental slope offshore from Cape Hatteras, North Carolina, varied from 150 to almost 700 μ,M with depth in the top 40 cm of sediment. Sediment cores from 630 to 2010 m depth had very similar profiles of dissolved silica in their pore waters, even though these cores came from regions greatly different in slope, topography, sedimentation rate, and abundance of benthic macrofauna. Cores from 474 to 525 m were more variable, both with respect to pore water dissolved silica profiles, and with respect to sediment texture. Experiments indicate that both the rate of dissolution of silica and the saturation concentration decrease as sediment depth below the sediment-seawater interface increases. These data are consistent with depletion of a reactive silica phase in surface sediment, which may be radiolarian tests, or the alteration of biogenic silica to a less reactive form over time. Experimental results suggest that the pore water dissolved silica concentration in sediments below the top few centimeters may be higher than the sediments could now achieve. The flux of dissolved silica out of these sediments is estimated to be 15 μmoles cm⁻² yr⁻¹.  相似文献   

Coastal uplift rate at Matanzas (Cuba) inferred from MIS5e phreatic overgrowths on speleothems          下载免费PDF全文

Jo De Waele  Ilenia M. D'Angeli  Nicola Tisato  Paola Tuccimei  Michele Soligo  Joaquín Ginés  Angel Ginés  Joan J. Fornós  Igor M. Villa  Esteban R. Grau González  Stefano M. Bernasconi  Tomaso R. R. Bontognali 《地学学报》2017,29(2):98-105

Many morphological elements in Cuba's landscape (e.g. marine terraces, tidal notches) demonstrate that coastal uplift has taken place, but the rate at which this occurs is not known. Carbonate phreatic overgrowths on speleothems have been found in a cave in Central North Cuba, ~1 km from the present coastline at 16 m asl. They form exceptional and unique mushroom‐shaped speleothems and balconies decorating the walls of the rooms. These phreatic overgrowths on speleothems (POS) formed at the oscillating air–water interface in sea‐level controlled anchialine lakes. U/Th dating of these overgrowths suggests ages that are compatible with the Marine Isotope Stage 5e (i.e. 130–115 ka). These POS have fixed this sea‐level highstand and demonstrate that this part of Cuba has been subjected to a much lower uplift rate than previously reported, that is, less than 0.1 mm/year since the last interglacial.  相似文献   

Maada’oonidiwag gete-dibaajimowen (“sharing old stories”): reflections on a place-based reparatory research partnership in Nbisiing Anishinaabeg Territory     

Hemsworth  Katie  Greer  Kirsten  Paulin  Megan  Sutherland  Kiethen  McLeod Shabogesic  Joan 《GeoJournal》2021,87(2):267-280

In this paper, we reflect on an emerging community-based partnership rooted in place-based reparative research. Braiding knowledges (Atalay, 2012) from Nbisiing Anishinaabeg communities, northern Ontario universities, and multi-scalar museums, the partnership focuses on repatriation, reparative environmental histories, and action-based research in the context of settler colonialism and climate change. We reflect on ongoing projects that attempt to put Anishinaabe gikendaasowin (knowledge) into action alongside historical geographical research. We discuss how the partnership resonates with community geography values of relationship, collaboration, equity, and reciprocity, and urge non-Indigenous geographers to acknowledge how Indigenous knowledges and approaches have shaped these ideas long before geography became a discipline. We contend that historical geographers have a deeper role to play in community geography scholarship, citing examples of two projects related to (1) repatriation of Anishinaabeg cultural heritage and (2) storymapping through historical Geographic Information Systems (HGIS). However, we argue, geographers must continue to acknowledge their own positionality in a discipline that was built through settler colonial violence and knowledge production. Finally, we reflect on the role of academic institutions in facilitating First Nation-university-museum partnerships through access to funding, space, and databases, while addressing the challenges of relying on institutional support for reparatory and decolonizing projects.

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Influence of dissolved organic carbon on photochemically mediated cycling of hydrogen peroxide in rainwater     

Robert J. Kieber  Jeremy Smith  Katherine M. Mullaugh  Melissa W. Southwell  G. Brooks Avery Jr.  Joan D. Willey 《Journal of Atmospheric Chemistry》2009,64(2-3):149-158

The influence of sunlight and dissolved organic carbon (DOC) on the photochemically mediated cycling of hydrogen peroxide (H₂O₂) was investigated in rainwater samples collected in Wilmington, North Carolina USA. Upon exposure to simulated sunlight 14 of 19 authentic rainwater samples exhibited significant decreases in H₂O₂. The concentration of hydrogen peroxide did not change significantly in organic-free synthetic rainwater spiked with H₂O₂ in the light or in dark controls suggesting that the loss was not due to direct photolysis or dark mediated reactions. There was a significant correlation between pseudo-first order rate constants of H₂O₂ decay and initial H₂O₂ concentrations. There was also a significant correlation between the rate constant and the abundance of DOC suggesting that rainwater organic carbon plays an important role during photolytic decay either via direct reaction or indirectly through production of peroxide reactive species or scavenging of peroxide generating radicals. Several rain samples exhibited an initial increase in H₂O₂ during the first 2 h of irradiation. These increases were generally small and most likely do not represent a significant input of peroxide in precipitation. The photo-induced destruction of H₂O₂ is important because it may partly explain the late afternoon decrease of peroxide concentrations observed in earlier field studies and the substantial under saturation (<10%) of this oxidant in rainwater compared with gas phase concentrations.  相似文献   

Study of the total lightning activity in a hailstorm   总被引：1，自引：0，他引：1  

Joan Montany  Serge Soula  Nicolau Pineda  Oscar van der Velde  Pere Clapers  Glria Sol  Joan Bech  D. Romero 《Atmospheric Research》2009,91(2-4):430-437

A thunderstorm that developed over northeastern Spain on 16 June 2006 is analyzed. This severe thunderstorm produced hailstones as large as 40 mm and had a lifetime of 3 h and 30 min. Radar cross-sections show strong vertical development with cloud echo tops reaching an altitude of 13 km. The specific characteristics of the lightning activity of this storm were: (i) a large amount (81%) of negative cloud-to-ground (−CG) flashes with very low peak currents (< 10 kA in absolute value), (ii) a very large proportion of intra-cloud (IC) flashes with an IC/CG ratio reaching about 400, (iii) a large number of “short” IC flashes (with only 1-VHF source according to SAFIR detection), (iv) a large increase of the −CG flash rate and of the CG proportion near the end of the storm. The rate of −CG flashes with a low peak current were observed to evolve similarly to the rates of IC flashes. Most of them have been assumed to be IC flashes misclassified by the Spanish Lightning Detection Network (SLDN). They have been filtered as it is usually done for misclassified +CG flashes. After this filtering, CG flash rates remained very low (< 1 min^− 1) with +CG flashes sometimes dominant. All the particular lightning activity characteristics similar to those observed in the Severe Thunderstorm Electrification and Precipitation Study (STEPS) campaigns support the hypothesis that this thunderstorm could have had an inverted-polarity or complex charge structure. The maximum IC flash rate (67 min^− 1) peaked 24 min before the presence of reflectivity higher than 60 dBZ. The IC activity abruptly decreased during the period when reflectivity was dramatically increasing. The time of maximum reflectivity observed by radar was consistent with the times of reported hail at the ground.  相似文献