The effects of clay minerals and organic matter on nanoscale pores in Lower Paleozoic shale gas reservoirs,Guizhou, China     

Yuantao Gu  Quan Wan  Wenbin Yu  Xiaoxia Li  Zhongbin Yu 《中国地球化学学报》2018,37(6):791-804

In organic-rich gas shales, clay minerals and organic matter (OM) have significant influences on the origin, preservation, and production of shale gas. Because of the substantial role of nanoscale pores in the generation, storage, and seepage of shale gas, we examined the effects of clay minerals and OM on nanoscale pore distribution characteristics in Lower Paleozoic shale gas reservoirs. Using the Niutitang and Longmaxi shales as examples, we determined the effects of clay minerals and OM on pores through sedimentation experiments. Field emission–scanning electron microscopy combined with low-pressure N₂ adsorption of the samples before and after sedimentation showed significant differences in pore location and pore size distribution between the Niutitang and Longmaxi shales. Nanoscale pores mostly existed in OM in the Longmaxi shale and in clay minerals or OM–clay composites in the Niutitang shale. The distribution differences were attributed largely to variability in thermal evolution and tectonic development and might account for the difference in gas-bearing capacity between the Niutitang and Longmaxi reservoirs. In the nanoscale range, mesopores accounted for 61–76% of total nanoscale pore volume. Considerably developed nanoscale pores in OM were distributed in a broad size range in the Longmaxi shale, which led to good pore connectivity and gas production. Numerous narrow pores (i.e., pores?<?20 nm) in OM–clay composites were found in the Niutitang shale, and might account for this shale’s poor pore connectivity and low gas production efficiency. Enhancing the connectivity of the mesopores (especially pores?<?20 nm and those developed in OM–clay composites) might be the key to improving development of the Niutitang shale. The findings provide new insight into the formation and evolutionary mechanism of nanoscale pores developed in OM and clay minerals.  相似文献   

Metallogeny of the Baiyangping Lead‐Zinc Polymetallic Ore Concentration Area,Northern Lanping Basin of Yunnan Province,China     

WANG Xiaohu  SONG Yucai  ZHANG Hongrui  LIU Yingchao  PAN Xiaofei  GUO Tao 《《地质学报》英文版》2018,92(4):1486-1507

The Lanping Basin in the Nujiang‐Lancangjiang‐Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment‐hosted Pb‐Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India‐Asia continental collisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the ore‐forming elements in the east ore belt are mainly Pb‐Zn‐Sr‐Ag, while Pb‐Zn‐Ag‐Cu‐Co elements are dominant in the west ore belt. Comparative analysis of the C‐O‐Sr‐S‐Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore‐forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb‐Zn mineralization age of both ore belts was contemporary and formed in the same metallogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship.  相似文献   

小兴安岭霍吉河钼矿床成矿过程——透岩浆成矿作用     

王泉  刘东舟  郭鸿斌 《地质与资源》2018,27(3):243-250

传统上将小兴安岭霍吉河钼矿床归类为斑岩型钼矿.通过对矿区地质特征的研究,即矿区无斑岩体、矿体围绕隐爆角砾岩呈环状出露、石英细脉-网脉状和浸染状矿石结构、成矿年龄明显晚于赋矿围岩形成时间等,认为该矿床是透岩浆成矿作用的结果.早中生代伊春-延寿花岗岩岩基带上相伴的大型-超大型钼矿是典型的透岩浆成矿作用的产物,是岩基后成矿作用.  相似文献   

大兴安岭十八站—韩家园地区晚中生代火山岩年龄、地球化学特征及其构造意义     

柴明春  王泉  赵国英  高溯  曹昆 《地质通报》2018,37(10):1866-1881

大兴安岭十八站—韩家园地区发育晚中生代基性-中酸性火山岩。选取粗面安山岩、粗面岩、流纹岩进行年代学和岩石地球化学研究。粗面安山岩LA-ICP-MS锆石U-Pb年龄为125.2±0.9 Ma,为早白垩世火山作用的产物。岩石地球化学特征表明,中酸性火山岩属于高钾钙碱性-钾玄岩系列。岩石稀土元素总量∑REE=121.42×10~(-6)~154.43×10~(-6),轻、重稀土元素分异明显(La/Yb)_N=19.25~31.98,在稀土元素配分图上显示右倾型,除一个流纹岩样品具显著负Eu异常外,多数样品无明显Eu负异常(δEu=0.45~0.90)。岩石具弱富集大离子亲石元素Ba、Sr,明显亏损高场强元素Nb、Ta、Ti的特征。结合区域资料,认为十八站—韩家园地区早白垩世中酸性火山岩形成于蒙古-鄂霍茨克洋闭合机制下后碰撞伸展背景。粗面安山岩、粗面岩和流纹岩系同源岩浆部分熔融与结晶分异作用的结果,岩浆来源于受俯冲流体交代的富集岩石圈地幔。  相似文献   

大兴安岭十八站—韩家园地区中酸性侵入岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其地质意义     

柴明春  赵国英  覃小锋  王泉  高溯  曹昆 《地质论评》2018,64(3):569-583

大兴安岭北部塔河县十八站—呼玛县韩家园地区发育早古生代中酸性侵入岩。文章选取二长闪长岩和二长花岗岩开展岩石年代学与地球化学研究。二长闪长岩LA-ICP-MS锆石U-Pb年龄为512.4±3.5 Ma,为早—中寒武世岩浆作用的产物。岩石地球化学分析表明,中酸性侵入岩归属于准铝质—弱过铝质(A/CNK=0.77~1.04)钙碱性—高钾钙碱性系列。岩石稀土总量∑REE=69.51×10~(-6)~275.83×10~(-6),轻重稀土分异明显(La/Yb)_N=9.11~26.64。在稀土元素配分图上,显示为LREE富集、HREE相对平缓的右倾型,Eu异常不显著(δEu=0.90~1.35)。微量元素组成具明显富集大离子亲石元素Ba、Sr,显著亏损高场强元素Nb、Ta、Ti的特征。结合区域资料和本文研究,初步分析认为早古生代侵入体形成于活动大陆边缘或岛弧环境,为前古亚洲洋闭合背景下萨拉伊尔造山作用的产物。  相似文献   

川西北下二叠统栖霞组微生物丘的发现及地质意义^*     

全子婷  谭秀成  张本健  唐浩  罗冰  杨迅  张亚  肖笛  汤艳玲 《古地理学报》2021,23(6):1110-1124

通过野外露头与钻井剖面的室内外分析,确认在四川盆地西北部(川西北)下二叠统栖霞组中发育有微生物丘,它们主要由凝块灰(云)岩、叠层灰(云)岩和微生物粘结颗粒灰(云)岩等组成。这些微生物碳酸盐岩发育较为典型的凝块、叠层、窗格、粘结等组构。微生物丘大小不一,实测高度一般为几十厘米至几米,宽度通常变化于几米至几十米之间,具有底平顶凸的典型丘形外貌,以发育向上变浅的沉积序列为特征,一般由丘基、丘核、丘盖3个微相组成,也可与颗粒滩共同构成微生物丘滩复合体。基于区域古地理背景和微生物丘特征的剖析,认为川西北地区栖霞期沉积环境总体受限,推测为半局限—局限台地环境,水深较浅,能量普遍不高;海平面频繁的相对升降变化和微生物丘的侧向迁移叠置,导致发育于缓坡背景下的碳酸盐岩台地极易受限,引起早期沉积物发生与丘滩发育密切相关的准同生期白云石化作用。因此,微生物丘滩复合体是栖霞组白云岩储集层发育的物质基础,台缘坡折带、台内缓坡折带和高地是栖霞组白云岩储集层发育的有利区带,这对寻找规模性层位不稳定的带状白云岩储集层具有重要的指导作用,并将大大拓展栖霞组白云岩储集层的勘探领域。  相似文献   

2015年济南地区雾霾天气过程大气物理量特征初步分析     

崔雅琴  张佃国  王洪  刘泉  张骞  张洪生 《大气科学》2019,43(4):705-718

文中对比分析了2015年29个雾、霾及雾霾混合天气过程中,章丘探空站L波段探空雷达和山东省气象局院内德国14通道地基微波辐射计观测的温度资料。对观测数据实施了质量控制,检验了精度和可信度,统计分析了宏观物理参量特征和日变化规律。针对雾、霾及雾霾天气过程各选取了一个个例进行分析,分析了大气中PM_2.5、PM₁₀、SO₂、NO₂、O₃、CO含量的变化情况,分析了相对湿度、液态水路径和综合水汽含量等的变化情况。结果表明:两种观测数据一致性较好,拟合优度高于0.97;贴地逆温层存在一定的季节变化,悬垂逆温层存在一定的差异,逆温层的变化、污染参量变化与雾霾的形成有密切关系;不同天气背景对大气物理参量有较大的影响,PM₁₀、AQI（空气质量指数）和CO均在相同时间段出现峰值,有明显的起伏;CO峰值雾霾天气中尤为明显,由早到晚随时间峰值逐渐增大,雾天和霾天峰值较小,雾霾天气明显大于雾天或霾天。  相似文献   

Effects of chemical environment on the solubility and incorporation mechanism for hydrogen in olivine     

Quan Bai  D. L. Kohlstedt 《Physics and Chemistry of Minerals》1993,19(7):460-471

To investigate the solubility and the sites of incorporation of hydrogen in olivine as a function of point defect concentration, two-stage high-temperature annealing experiments have been carried out. The first annealing stage (the dry preannealing stage) was conducted at a total pressure of 0.1 MPa, a temperature of 1300° C and various oxygen fugacities in the range 10^?11–10^?4 MPa for times > 12 h. In these heat treatments, the samples were buffered against either orthopyroxene or magnesiowustite, or they remained unbuffered. The second annealing stage (the hydrothermal annealing stage) was performed at 300 MPa and 900–1050 ° C under a hydrogen fugacity of ～ 158 MPa for 1–5 h. Infrared spectra from the annealed samples revealed two distinct groups of bands. Group I bands occurred at wavenumbers in the range 3450–3650 cm^?1, while Group II bands occurred in the range 3200–3450 cm^?1. The hydrogen solubility associated with Group I bands is proportional to f _{O 2} to the 1/6 power for samples preannealed in contact with orthopyroxene, to the 1/3 power for samples preannealed in contact with magnesiowustite, and to the 1/13 power for samples preannealed in the absence of a solid-state buffer. The hydrogen concentration for Group II bands varies with f _{o 2} to the 1/3 power for opxbuffered samples, to the 1/2 power for mw-buffered samples, and to the 1/3 power for unbuffered samples. The dependence of hydrogen solubility on oxygen fugacity and orthopyroxene activity suggests that hydrogen is incorporated into the olivine structure via association with point defects. The presence of two distinct groups of absorption bands indicates that hydrogen is associated with two distinct lattice defects. The following point defect model for the mechanism of incorporation of hydrogen in olivine is consistent with these results: Hydrogen ions responsible for the Group I bands are associated with doubly charged oxygen interstitials, while hydrogen ions responsible for the Group II bands are associated with singly charged oxygen interstitials. Furthermore, the infrared bands observed in naturally derived olivines are present in spectra from our hydrothermally annealed crystals. Thus, the mechanisms of incorporation of hydrogen in olivine under geological conditions are the same as those operative under laboratory conditions. The maximum solubility reached in these experiments was ～ 360H/10⁶Si, which corresponds to ～ 0.002 wt% of H₂O. This value is a lower bound for the solubility of hydrogen in olivine under upper mantle conditions.  相似文献   

The typing of Au and base-metal occurrences by plasma/mass spectrometry: initial results     

R.G. Smith  E.J. Brooker  D.J. Douglas  E.S.K. Quan  G. Rosenblatt 《Journal of Geochemical Exploration》1984,21(1-3)

This paper discusses the application of the newly developed ELAN 250 I.C.P./mass spectrometer to exploration geochemistry. This instrument combines an inductively coupled plasma with a quadrupole mass spectrometer. The combination of these two existing technologies makes it possible for the first time to perform stable-isotope and elemental analysis rapidly and concurrently.Particular attention is paid to the use of lead isotopes to type Au and base-metal occurrences. Data are presented on galena samples obtained from the Geological Survey of Canada and the Royal Ontario Museum. Consideration is also given to the potential usefulness of Pb isotopes and trace-element data to type mineral occurrences and to identify new ones.  相似文献   

皖南麻姑山铜钼矿床成因初探   总被引：1，自引：0，他引：1  

卡育才 《江苏地质》1995,19(1):17-20

皖南麻姑山铜钼矿床成因初探卞育才（江苏省苏州市吴县铜矿，吴县，２１５１５１）关键词：铜矿，钼矿，矽长岩，成因，安徽南部。ＯｎｔｈｅＯｒｉｇｉｎｏｆＭａｇｕｓｈａｎＣｕ－ＭｏＤｅｐｏｓｉｔｉｎＳｏｕｔｈｅｒｎＡｎｈｕｉ￥ＢｉａｎＹｕｃａｉＡｂｓｔｒａｃ...  相似文献