Inhibition of primary production by UV-B radiation in an arctic bay – model calculations     

Sten-Åke Wängberg  Kristin I. M. Andreasson  Kristine Garde  Kim Gustavson  Peter Henriksen  Thomas Reinthaler 《Aquatic Sciences - Research Across Boundaries》2006,68(2):117-128

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Geochemical and mineralogical properties of sulfide-bearing fine-grained sediments in Finland     

H. Deng  M. Åström  A. Björklund 《Environmental Geology》1998,36(1-2):37-44

 The geochemical and mineralogical characteristics of bulk samples and various size fractions of sulfide-bearing fine-grained sediments in the Petalax area, western Finland, were studied with ICP-AES (aqua regia digestion and "total" digestion) and X-ray diffraction. The sediments, which are dominated by particles <0.06 mm (clay and silt size), are composed of phyllosilicates (micas, kaolinite, chlorite, vermiculite), quartz, feldspars, amphiboles, organic matter, and secondary S minerals. The chemical analyses show that Na, Ca, and Sr are enriched in the silt and sand fractions, that Zr is enriched in the silt fraction, and that the concentrations of all other studied metals (Al, Ba, Co, Cr, Cu, Fe, K, La, Mg, Mn, Nb, Ni, Sc, Th, Ti, V, Y, and Zn) increase from the sand to the clay fraction. Sodium, Ca, and Sr occur largely in poorly dissolved feldspars, which explains the distribution of these metals in the sediments. The increase in the concentrations of most metals in the clay fraction is interpreted to be the result mainly of an increase in phyllosilicates in this size fraction. A geochemical comparison between the sulfide-bearing fine-grained sediments and glacial till shows that the former are enriched in several potentially toxic metals. It is therefore argued that the hydrological and ecological problems associated with the sulfide-bearing sediments are related not only to the production of acidity in oxidized layers, but also to mobilization and dispersion of toxic metals. Strategies to minimize damage of freshwater systems in areas covered with sulfide-bearing fine-grained sediments are suggested. Received: 20 February 1997 · Accepted: 25 August 1997  相似文献   

The qualitative character of the global electrical conductivity of the earth     

R.S. Anderssen  J.F. Devane  S.-Å Gustafson  D.E. Winch 《Physics of the Earth and Planetary Interiors》1979,20(1):p15-p21

A spectral stacking and smoothing procedure has been applied to unbroken hourly values of H and Z, for 1964 and 1965, from 17 observatories, in order to estimate the magnitude and phase of the P₁⁰ response of the Earth to long-period geomagnetic fluctuations. Exploratory techniques have been used to gauge when sufficient smoothing has been applied, and to identify the qualitative character of the global electrical conductivity of the Earth.  相似文献   

Evolution of earthquake losses in Portuguese residential building stock     

Maria Luísa Sousa  Alfredo Campos Costa 《Bulletin of Earthquake Engineering》2016,14(7):2009-2029

The evolution of the expected earthquake losses in different Portuguese regions was studied in order to determine whether the natural regeneration of buildings could contribute to the mitigation of seismic risk, although the building exposure has increased over time in most analysed regions. To achieve this goal, five inter-related risk indicators were estimated, based on the Portuguese censuses’ surveys of residential buildings and inhabitants obtained in two different moments in time: 2001 and 2011. The FEMA (2008) approach was used to estimate the risk indicators, i.e., the Annualized Economic and Human earthquake Losses, either in absolute terms or normalised by building and population exposure. This study offers a perspective of the seismic risk in the Portuguese mainland, provides a comparison of risk levels between different epochs, and analyses the obtained results in order to compare the risk among Portuguese regions. It is important to mention that the comparison of economic losses based on the building stocks surveyed in 2001 and in 2011 took into account the Portuguese inflation rate in that time interval. The main findings of the study show that the natural regeneration of the residential housing stock contributes to the reduction of the expected seismic economic losses in Portugal, at an average rate of 14 % per 10 years, and to the reduction of the expected annualized human losses to almost one half after 10 years. The results support the conclusion that the natural regeneration of the residential housing stock contributed to the mitigation of the seismic risk in mainland Portugal, in the 10 year period under analysis, even though there was an increase of the building exposure in the region.  相似文献   

The analytical continuation bias in geoid determination using potential coefficients and terrestrial gravity data   总被引：1，自引：1，他引：0  

J. Ågren 《Journal of Geodesy》2004,78(4-5):314-332

One important application of an Earth Gravity Model (EGM) is to determine the geoid. Since an EGM is represented by an external-type series of spherical harmonics, a biased geoid model is obtained when the EGM is applied inside the masses in continental regions. In order to convert the downward-continued height anomaly to the corresponding geoid undulation, a correction has to be applied for the analytical continuation bias of the geoid height. This technique is here called the geoid bias method. A correction for the geoid bias can also be utilised when an EGM is combined with terrestrial gravity data, using the combined approach to topographic corrections. The geoid bias can be computed either by a strict integral formula, or by means of one or more terms in a binomial expansion. The accuracy of the lowest binomial terms is studied numerically. It is concluded that the first term (of power H²) can be used with high accuracy up to degree 360 everywhere on Earth. If very high mountains are disregarded, then the use of the H² term can be extended up to maximum degrees as high as 1800. It is also shown that the geoid bias method is practically equal to the technique applied by Rapp, which utilises the quasigeoid-to-geoid separation. Another objective is to carefully consider how the combined approach to topographic corrections should be interpreted. This includes investigations of how the above-mentioned H² term should be computed, as well as how it can be improved by a correction for the residual geoid bias. It is concluded that the computation of the combined topographic effect is efficient in the case that the residual geoid bias can be neglected, since the computation of the latter is very time consuming. It is nevertheless important to be able to compute the residual bias for individual stations. For reasonable maximum degrees, this can be used to check the quality of the H² approximation in different situations.Acknowledgement The author would like to thank Prof. L.E. Sjöberg for several ideas and for reading two draft versions of the paper. His support and constructive remarks have improved its quality considerably. The valuable suggestions from three unknown reviewers are also appreciated.  相似文献   

The Palaeoproterozoic Kristineberg VMS deposit, Skellefte district, northern Sweden, part I: geology     

Hans Årebäck  Timothy J. Barrett  Stig Abrahamsson  Pia Fagerström 《Mineralium Deposita》2005,40(4):351-367

The Kristineberg volcanic-hosted massive sulphide (VMS) deposit, located in the westernmost part of the Palaeoproterozoic Skellefte district, northern Sweden, has yielded 22.4 Mt of ore, grading 1.0% Cu, 3.64% Zn, 0.24% Pb, 1.24 g/t Au, 36 g/t Ag and 25.9% S, since the mine opened in 1941, and is the largest past and present VMS mine in the district. The deposit is hosted in a thick pile of felsic to intermediate and minor mafic metavolcanic rocks of the Skellefte Group, which forms the lowest stratigraphic unit in the district and hosts more than 85 known massive sulphide deposits. The Kristineberg deposit is situated lower in the Skellefte Group than most other deposits. It comprises three main ore zones: (1) massive sulphide lenses of the A-ore (historically the main ore), having a strike length of about 1,400 m, and extending from surface to about 1,200 m depth, (2) massive sulphide lenses of the B-ore, situated 100–150 m structurally above the A-ore, and extending from surface to about 1,000 m depth, (3) the recently discovered Einarsson zone, which occurs in the vicinity of the B-ore at about 1,000 m depth, and consists mainly of Au–Cu-rich veins and heavily disseminated sulphides, together with massive sulphide lenses. On a regional scale the Kristineberg deposit is flanked by two major felsic rock units: massive rhyolite A to the south and the mine porphyry to the north. The three main ore zones lie within a schistose, deformed and metamorphosed package of hydrothermally altered, dominantly felsic volcanic rocks, which contain varying proportions of quartz, muscovite, chlorite, phlogopite, pyrite, cordierite and andalusite. The strongest alteration occurs within 5–10 m of the ore lenses. Stratigraphic younging within the mine area is uncertain as primary bedding and volcanic textures are absent due to strong alteration, and tectonic folding and shearing. In the vicinity of the ore lenses, hydrothermal alteration has produced both Mg-rich assemblages (Mg-chlorite, cordierite, phlogopite and locally talc) and quartz–muscovite–andalusite assemblages. Both types of assemblages commonly contain disseminated pyrite. The sequence of volcanic and ore-forming events at Kristineberg is poorly constrained, as the ages of the massive rhyolite and mine porphyry are unknown, and younging indicators are absent apart from local metal zoning in the A-ores. Regional structural trends, however, suggest that the sequence youngs to the south. The A- and B-ores are interpreted to have formed as synvolcanic sulphide sheets that were originally separated by some 100–150 m of volcanic rocks. The Einarsson zone, which is developed close to the 1,000 m level, is interpreted to have resulted in part from folding and dislocation of the B-ore sulphide sheet, and in part from remobilisation of sulphides into small Zn-rich massive sulphide lenses and late Au–Cu-rich veins. However, the abundance of strongly altered, andalusite-bearing rocks in the Einarsson zone, coupled with the occurrence of Au–Cu-rich disseminated sulphides in these rocks, suggests that some of the mineralisation was synvolcanic and formed from strongly acidic hydrothermal fluids. Editorial handling: P. Weihed  相似文献   

Alteration paragenesis and mineral chemistry of the Tjårrojåkka apatite–iron and Cu (-Au) occurrences, Kiruna area, northern Sweden     

Åsa Edfelt  Robin N. Armstrong  Martin Smith  Olof Martinsson 《Mineralium Deposita》2005,40(4):409-434

The northern Norrbotten area in northern Sweden, is an important mining district and hosts several deposits of Fe-oxide Cu-Au-type. One of the best examples of spatially, and possibly genetically, related apatite–iron and copper–gold deposits in the region is at Tjårrojåkka, 50 km WSW of Kiruna. The deposits are hosted by strongly sheared and metamorphosed intermediate volcanic rocks and dolerites and show a structural control. The Tjårrojåkka iron deposit is a typical apatite–iron ore of Kiruna-type and the Tjårrojåkka copper occurrence shows the same characteristics as most other epigenetic deposits in Norrbotten. The host rock has been affected by strong albite and K-feldspar alteration related to mineralisation, resulting in an enrichment of Na, K, and Ba. Fe and V were depleted in the altered zones and added in mineralised samples. REE were enriched in the system, with the greatest addition related to mineralisation. Y was also mobile associated with albite alteration and copper mineralisation. The Tjårrojåkka iron and copper deposits show comparable hydrothermal alteration minerals and paragenesis, which might be a product of common host rock and similarities in ore fluid composition, or overprinting by successive alteration stages. Mineralogy and mineral chemistry of the alteration minerals (apatite, scapolite, feldspars, amphiboles, and biotite) indicate a higher salinity and Ba/K ratio in the fluid related to the alterations in the apatite–iron occurrence than in the copper deposit, where the minerals are enriched in F and S. The presence of hematite, barite, and in SO₄ in scapolite suggests more oxidising-rich conditions during the emplacement of the Tjårrojåkka-Cu deposit. From existing data it might be suggested that one evolving system created the two occurrences, with the copper mineralisation representing a slightly later product.  相似文献   

The Palaeoproterozoic Kristineberg VMS deposit, Skellefte district, northern Sweden. Part II: chemostratigraphy and alteration     

Timothy J. Barrett  Wallace H. MacLean  Hans Årebäck 《Mineralium Deposita》2005,40(4):368-395

The Kristineberg massive sulfide deposit is hosted by metamorphosed volcanic and subvolcanic rocks of the Palaeoproterozoic Skellefte Group. The deposit consists of: (1) two main massive sulfide horizons, the A-ores and B-ores, which dip steeply southwards and are separated by 100–150 m; and (2) the Einarsson Zone, a complex interval of Cu–Au-rich ‘stockwork‘ sulfides and small massive sulfide lenses in altered and deformed rocks near the 1,000 m level. The Einarsson Zone occurs some 20–100 m south of the B-ores. There are no definite younging indicators in the mine sequence. In many areas of the mine, the original host rocks are impossible to identify petrographically due to the abundance of secondary minerals such as quartz, chlorite, muscovite, cordierite, andalusite, phlogopite, pyrite and talc, combined with variably schistose fabrics. Application of immobile-element methods to 600 recent whole-rock chemical analyses has, however, allowed the original rock types to be identified and correlated. Rhyolite X lies immediately north of the A-ore, while andesitic to dacitic to rhyodacitic rocks make up the 100–150 m interval between the A-ore and B-ore, and massive rhyolite A lies immediately south of the B-ore. The felsic rocks are mostly of calc-alkaline affinity, excluding rhyolite X, which is transitional. The mine porphyry, which lies north of the A-ore and forms the marginal phase of the synvolcanic Viterliden Intrusive Complex, is compositionally similar to dacite and rhyodacite. Mass changes calculated for all rock types indicate that most of the volcanic rocks in the mine area are strongly depleted in Na and Ca, and have gained variable amounts of Mg and Fe, whereas Si changes range from negative to positive. Gains in Fe and changes in Si are largest within 5–10 m of the massive sulfide lenses. Cordierite-bearing schists of andesitic to felsic compositions that lie between massive sulfide lenses A and B are not as altered. The Einarsson Zone commonly shows large gains in Fe and Mg, while Si shows large gains to large losses. Immobile-element ratios indicate that very different secondary assemblages in the mine, e.g. andalusite–quartz–muscovite and cordierite–chlorite–talc, can be produced from the same precursor volcanic unit, e.g., rhyolite. Conversely, the same secondary mineral assemblage can be produced from different rocks, e.g. weakly altered andesite and strongly altered rhyolite. The common presence of cordierite + andalusite in the mine area, without anthophyllite, is unusual in the alteration systems of volcanic-hosted massive sulfide deposits, and is proposed to have formed by the metamorphic reaction of the synvolcanic alteration minerals kaolinite and chlorite to produce cordierite. Where kaolinite was in excess of chlorite, andalusite was also formed. We propose that highly acidic alteration fluids locally produced high-Al minerals such as kaolinite that either overprinted, or occurred in place of, a more typical sericite–chlorite–quartz alteration assemblage that otherwise formed near the massive sulfide lenses. Application of lithogeochemical methods to the altered, deformed and metamorphosed Kristineberg rocks has identified specific volcanic contacts with massive sulfide potential, and quantified the effects of synvolcanic hydrothermal alteration. Such an approach can increase the effectiveness of mineral exploration in metamorphosed terrains.  相似文献   

Alteration induced changes of magnetic fabric as exemplified by dykes of the Koolau volcanic range     

David Krása  Emilio Herrero-Bervera 《Earth and Planetary Science Letters》2005,240(2):445-453

We studied 93 samples from 8 basaltic dykes of the Koolau volcanic range on the island of Oahu,Hawaii,USA,to determine the influence of hydrothermal alteration on the magnetic fabric as determined by anisotropy of magnetic susceptibility (AMS) measurements. Rock magnetic as well as microscopic investigations show that only ≈25% of the samples have retained their original magnetomineralogical composition of unaltered Ti-poor titanomagnetite. The remaining samples have undergone hydrothermal alteration which transformed the primary magnetic phase into a granular intergrowth of titanomagnetite, titanomaghemite and hematite. In both sample groups,this magnetic phase occurs in coarse (tens of microns),irregularly shaped particles as well as interstitial clusters of smaller (< 5 μm) grains. Our investigations show that hydrothermal alteration does change the bulk susceptibility and the degree of anisotropy but not the directions of principal axes of the AMS ellipsoid which are predominantly corresponding to normal magnetic fabric. The stability of AMS directions, regardless of the degree of alteration, points towards the model of distribution anisotropy as the controlling factor for the observed magnetic fabric.  相似文献   

Inversion of titanomaghemite in oceanic basalt during heating     

David Krása  Jürgen Matzka 《Physics of the Earth and Planetary Interiors》2007,160(2):169-179

We studied the change of magnetic behaviour upon laboratory heating of altered mid-ocean ridge basalt (MORB) samples in the age range of 16-35 Ma to determine the influence of titanomaghemite inversion on the thermal demagnetisation of natural remanent magnetisation (NRM) of these basalts. MORB samples were heated to successively higher temperatures and at the same time the temperature dependence of either saturation magnetisation or NRM was monitored continuously. After each heating step, hysteresis loops and remanent magnetisation curves between 10 K and room temperature were measured. With this procedure, it is shown that the dominant magnetic remanence carrier in our MORB samples is cation deficient titanomaghemite. Moreover, it is demonstrated that the titanomaghemite is gradually changing to a Ti-poor titanomagnetite as the final inversion product. During inversion, both the Curie temperature as well as the maximum unblocking temperature of the NRM are gradually increasing. We show that the paradox of unblocking temperatures above the Curie temperatures often observed for altered MORBs is an artefact of this gradual, heating induced inversion process.  相似文献