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41.
Maar lake Laguna Potrok Aike is located north of the Strait of Magellan (south‐eastern Patagonia). Seismic reflection profiles revealed a highly dynamic palaeoclimate history. Dunes were identified in the eastern part of the lake at approximately 30 to 80 m below the lake floor, overlying older lacustrine strata, and suggest that the region experienced dry conditions probably combined with strong westerly winds. It is quite likely that this can be linked to a major dust event recorded in the Antarctic ice cores during Marine Isotope Stage 4. The dunes are overlain by a series of palaeo‐shorelines indicating a stepwise water‐level evolution of a new lake established after this dry period, and thus a change towards wetter conditions. After the initial, rapid and stepwise lake‐level rise, the basin became deeper and wider, and sediments deposited on the lake shoulder at approximately 33 m below present‐day lake level point towards a long period of lake‐level highstand between roughly 53·5 ka cal. bp and 30 ka cal. bp with a maximum lake level some 200 m higher than the desiccation horizon. This highstand was then followed by a regressional phase of uncertain age, although it must have happened some time between approximately 30 ka cal. bp and 6750 yrs cal. bp . Dryer conditions during the Mid‐Holocene are evidenced by a dropping lake level, resulting in a basin‐wide erosional unconformity on the lake shoulder. A second stepwise transgression between ca 5·8 to 5·4 ka cal. bp and ca 4·7 to 4 ka cal. bp with palaeo‐shorelines deposited on the lake shoulder unconformity again indicates a change towards wetter conditions.  相似文献   
42.
Multi-scale geophysical studies were conducted in the central Skellefte district (CSD) in order to delineate the geometry of the upper crust (down to maximum ~ 4.5 km depth) for prospecting volcanic massive sulphide (VMS) mineralization. These geophysical investigations include potential field, resistivity/induced polarization (IP), reflection seismic and magnetotelluric (MT) data which were collected between 2009 and 2010. The interpretations were divided in two scales: (i) shallow (~ 1.5 km) and (ii) deep (~4.5 km). Physical properties of the rocks, including density, magnetic susceptibility, resistivity and chargeability, were also used to improve interpretations. The study result delineates the geometry of the upper crust in the CSD and new models were suggested based on new and joint geophysical interpretation which can benefit VMS prospecting in the area. The result also indicates that a strongly conductive zone detected by resistivity/IP data may have been missed using other geophysical data.  相似文献   
43.
This paper examines the processes by which the generic adaptive capacity of a system is translated into adaptation to climate change, what form it takes, and what factors facilitate or restrain such processes. This is done by an in-depth analysis of climate change adaptation in the Water supply and Wastewater (WW) sector of the Stockholm region. Observed adaptations are categorized in terms of building adaptive capacity and implementing adaptive decisions, and these measures are analyzed using a model of the adaptation process based on organizational learning theories. In particular, the concept of an organization’s actual adaptation space is defined and used as a means to understand the adaptation options that different WW organizations can pursue, as well as why such options might be pursued. The paper finds that most adaptation measures in the WW sector of the Stockholm region are aimed at building the adaptive capacity of the sector. It also finds that the extent to which adaptation measures can be pursued by the WW organizations is determined principally by how able the organization is to justify the additional resources required for adaptation. The analysis shows that there are two main routes to address this: use of climate knowledge to argue that adaptation is needed, and reference to rules and regulations to show that it is required.  相似文献   
44.
The dissolution and surface complexation of a non-stoichiometric hydroxyapatite (Ca8.4(HPO4)1.6(PO4)4.4(OH)0.4), (HAP) was studied in the pH range 3.5-10.5, at 25 °C in 0.1 M Na(Cl). The results from well-equilibrated batch experiments, potentiometric titrations, and zeta-potential measurements were combined with information provided by Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) spectroscopy and X-ray Photoelectron Spectroscopy (XPS). The information from the analyses was used to design an equilibration model that takes into account dissolution, surface potential, solution and surface complexation, as well as possible phase transformations. The results from the XPS measurements clearly show that the surface of the mineral has a different composition than the bulk and that the Ca/P ratio of the surface layer is 1.4 ± 0.1. This ratio was also found in solution in the batches equilibrated at low pH where the dominating reaction is dissolution. In the batches equilibrated at near neutral pH values, however, the Ca/P ratio in solution attains values as high as 25, which is due to re-adsorption of phosphate ions to the HAP surface. The total concentration of protons as well as the total concentration of dissolved calcium and phosphate in solution were used to calculate a model for the dissolution and surface complexation of HAP. The constant capacitance model was applied in designing the following surface complexation model:
  相似文献   
45.
Five satellites of Neptune orbit under the synchronous zone. In this sense the Neptune's system is similar to that of Uranus (nine satellites) and differs from Jupiter (two) and Saturn (zero). The basic parameters describing the angular momentum within the Neptune's system and of its tidal evolution are estimated. The main character of the tidal dynamics is due to the retrograde Triton. The total tidal decrease in the spin angular momentum of Neptune is compared with those of Uranus, Jupiter and Saturn.  相似文献   
46.
Johnson, M. D. & Ståhl, Y. 2009: Stratigraphy, sedimentology, age and palaeoenvironment of marine varved clay in the Middle Swedish end‐moraine zone. Boreas, 10.1111/j.1502‐3885.2009.00124.x. ISSN 0300‐9483 Deglaciation of the Middle Swedish end‐moraine zone and age of the sediment in and between the moraines have been discussed for about a hundred years. The goal of this project was to determine the stratigraphy and age of the sediment in and between the moraines. Inter‐moraine flats are underlain by clay, 10–25 m thick, overlying thin sand and gravel or till on bedrock. The clay is overlain by a few metres of sand and gravel. Much of the clay beneath the flats consists of rhythmites that grade from grey to red and are 2–74 cm thick. Our interpretation of these rhythmites as being varves is supported by grain size and mineralogical and elemental variations. Foraminifera and ostracods show that the clay was deposited in an arctic marine environment, while radiocarbon dating of the microfossils indicates that the clay was deposited 12 150 cal. 14C years ago, during the Younger Dryas chronozone (YD). Most of the optical stimulated luminescence dates on the clay are much older, containing quartz sand that was insufficiently bleached. The stratigraphy indicates that the moraines are composed of YD clay pushed into ridge forms during ice‐front oscillations. It is not possible to determine how far north the Scandinavian Ice Sheet retreated prior to the YD advance. We neither support nor reject the suggestion that the ice margin retreated to the northern edge of Mt. Billingen during the Allerød, causing the Baltic Ice Lake to drain.  相似文献   
47.
Sorption of Ni(II) onto chlorite surfaces was studied as a function of pH (5–10), ionic strength (0.01–0.5 M) and Ni concentration (10−8–10−6 M) in an Ar atmosphere using batch sorption with radioactive 63Ni as tracer. Such studies are important since Ni(II) is one of the major activation products in spent nuclear fuel and sorption data on minerals such as chlorite are lacking. The sorption of Ni(II) onto chlorite was dependent on pH but not ionic strength, which indicates that the process primarily comprises sorption by surface complexation. The maximum sorption was at pH ∼ 8 (Kd = ∼10−3 cm3/g). Desorption studies over a period of 1–2 weeks involving replacement of the aqueous solution indicated a low degree of desorption. The acid–base properties of the chlorite mineral were determined by titration and described using a non-electrostatic surface complexation model in FITEQL. A 2-pK NEM model and three surface complexes, Chl_OHNi2+, Chl_OHNi(OH)+ and Chl_OHNi(OH)2, gave the best fit to the sorption results using FITEQL. The high Kd values and low degree of desorption observed indicate that under expected groundwater conditions, a large fraction of Ni(II) that is potentially leachable from spent nuclear fuel may be prevented from migrating by sorption onto chlorite surfaces.  相似文献   
48.
Physical and chemical characteristics of intertidal sediments and their relationships with bacteria and cyanobacteria were analyzed at four stations at Pereque Beach. Granulometric analysis showed that Pereque beach has sediment that is classified as sand. The lowest value of the sediment C/N rates (6.08), mainly due to a higher concentration of organic nitrogen, was found at the northern part of Pereque Beach, where organic matter of marine source was more prominent. In this area, density (9.6x10(6)cells cm(-3)), biomass (1992.04ngC cm(-3)) and activity of bacteria were higher than at the southern end. In contrast, cyanobacteria density varied from 2.0 to 4.0x10(5)cells cm(-3), with biomass and total chlorophyll a of the sediment being higher at the southern part, where there are water input from Pereque River and higher organic matter of continental origin. The variability in the microbial population is discussed in the light of the sediment granulometry, organic matter quality, fresh water inflow and pollution.  相似文献   
49.
Abstract— The Lockne and Tvären craters formed in the Late Ordovician Baltoscandian epicontinental sea. Both craters demonstrate similarities concerning near‐synchronous age, target seabed, and succeeding resurge deposits; however, the water depths at the impact sites and the sizes of the craters were not alike. The post‐impact sedimentary succession of carbonates, i.e., the Dalby Limestone, deposited on top of the resurge sediments in the two craters, is nevertheless similar. At least three main facies of the Dalby Limestone were established in the Lockne crater, depending on sea‐floor topography, location with respect to the crater, and local water currents. The dominating nodular argillaceous facies, showing low values of inorganic carbon (IC), was distributed foremost in the deeper and quiet areas of the crater floor and depressions. At the crater rim, consisting of crushed crystalline basement ejecta, a rim facies with a reef‐like fauna was established, most certainly due to topographical highs and substrate‐derived nutrients. Between these facies are occurrences of a relatively thick‐bedded calcilutite rich in cephalopods (cephalopod facies). In Tvären, the lower part of the succession consists of an analogous argillaceous facies, also showing similar low IC values as in Lockne, followed by calcareous mudstones with an increase of IC. Occasionally biocalcarenites with a distinctive fauna occur in the Tvären succession, probably originating as detritus from a facies developed on the rim. They are evident as peaks in IC and lows in organic carbon (Corg). The fauna in these biocalcarenites corresponds very well with those of erratic boulders derived from Tvären; moreover, they correspond to the rim facies of Lockne except for the inclusion of photosynthesizing algae, indicating shallower water at Tvären than Lockne. Consequently, we suggest equivalent distribution patterns for the carbonates of the Dalby Limestone in Lockne and Tvären.  相似文献   
50.
The new mineral agricolaite, a potassium uranyl carbonate with ideal formula K4(UO2)(CO3)3, occurs in vugs of ankerite gangue in gneisses in the abandoned Giftkiesstollen adit at Jáchymov, Czech Republic. The name is after Georgius Agricola (1494?C1555), German scholar and scientist. Agricolaite occurs as isolated equant irregular translucent grains to 0.3?mm with yellow color, pale yellow streak, and vitreous luster. It is brittle with uneven fracture and displays neither cleavage nor parting. Agricolaite is non-fluorescent. Mohs hardness is ~4. It is associated with aragonite, brochantite, posnjakite, malachite, rutherfordine, and ??pseudo-voglite??. Experimental density is higher than 3.3?g.cm?3, Dcalc is 3.531?g.?cm?3. The mineral is monoclinic, space group C2/c, with a 10.2380(2), b 9.1930(2), c 12.2110(3) ?, ?? 95.108(2)°, V 1144.71(4) ?3, Z?=?4. The strongest lines in the powder X-ray diffraction pattern are d(I)(hkl): 6.061(55)(002), 5.087(57)(200), 3.740(100)(202), 3.393(43)(113), 2.281(52)(402). Average composition based on ten electron microprobe analyses corresponds to (in wt.%) UO3 48.53, K2O 31.49, CO2(calc) 22.04 which gives the empirical formula K3.98(UO2)1.01(CO3)3.00. The crystal structure was solved from single-crystal X-ray diffraction data and refined to R 1?=?0.0184 on the basis of the 1,308 unique reflections with F o?>?4??F o. The structure of agricolaite is identical to that of synthetic K4(UO2)(CO3)3 and consists of separate UO2(CO3)3 groups organized into layers parallel to (100) and two crystallographically non-equivalent sites occupied by K+ cations. Both the mineral and its name were approved by the IMA-CNMNC.  相似文献   
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