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The main purpose of this study was to investigate the ability of sand/granular activated charcoal mixture medium to treat urban wastewater effluents. Several laboratory experiments were conducted to determine the best combination ratio of sand/activated charcoal which would allow the optimum water purification. A comparative study was undertaken to evaluate the effect of the addition of activated charcoal on infiltration-percolation efficiency. Experiments demonstrated that fortifying sand medium with granular activated charcoal improved the pollutants removal efficiencies. Results showed that a combination ratio of 3:1 (by volume) of sand and granular activated charcoal gave the best depuration efficiency regarding organic matter, nitrogen and orthophosphorous. The mean removal rates of COD, NH4–N and PO4–P were 83.29, 95.85 and 65.21%, respectively. Furthermore, experiments demonstrated that a mixture of sand/activated charcoal in a 3:1 ratio resulted in the optimum oxidation capacity.  相似文献   
23.
RbSr (λRb = 1.39 × 10?11yr?1) and U-Pb (λ 238 = 1.54 × 10?10yr?1, λ235 = 9.72 × 10?10yr?1) measurements were undertaken in the Sudbury area, Sudbury, Ontario to determine the ages of the Sudbury Nickel Irruptive, Superior Province granites north of Sudbury, Sudbury Breccia and subsequent metamorphism. The Sudbury Nickel Irruptive norite whole rock Rb-Sr data yield an age of 1883 ± 136Myr (I.R. = 0.7071 ± 0.0005; all results quoted at 2π level) while the Nickel Irruptive micropegmatite Rb-Sr system has been disturbed and does not yield an isochron. A plagioclase-whole rock pair from the norite near the norite-micropegmatite transition yields an age of 1866 Myr, which when taken in conjunction with field (Stevenson and Colgrove, 1968) and geochemical (Naldrettet al., 1970, 1972) data does not support the conclusion of gibbins and McNurr (1972) that the micropegmatite is a later intrusion rather than a differentiate of the magma which produced the norite. Rb-Sr studies of the Superior Province granites north of Sudbury yield an age of 2698 ± 162 Myr (I.R. = 0.7019 ± 0.0012). U-Pb zircon studies of these granites and granitic clasts within the Sudbury Breccia yield an age of 2.71 ± 0.05 Byr and suggest the breccia granitic clasts were derived from the Superior Province granites. The granitic rocks ~150 km north of Sudbury have been undisturbed for ~ 2.6 Byr based on Rb-Sr mineral studies, whereas the granites and Sudbury Breccia within ~ 15 km of the Nickel Irruptive, as well as the Sudbury norite at the perimeter of the Irruptive have been disturbed by the Penokean Orogeny 1.7–1.75 Byr ago. The Penokean event appears to have overprinted isotopic evidence of the Sudbury impact event at least in the area studied.  相似文献   
24.
The Pirkoh and Drazinda formations in the Sulaiman Range, central Pakistan, yielded assemblages of (early) Bartonian orthophragminids, characterized predominantly by discocyclinids with a significant number of species probably endemic to Indian Subcontinent. The rarity of Asterocyclina and the absence of Orbitoclypeus and Nemkovella are noteworthy. Ten species of Discocyclina Gümbel and two species of Asterocyclina Gümbel, referable to the Shallow Benthics Zone (SBZ) 17 are described for the first time from Pakistan. The discocyclinids, i.e. Discocyclina praeomphalus, D. sulaimanensis, D. kutchensis, along with the new taxa established here, D. zindapirensis sp. nov., D. rakhinalaensis sp. nov., and D. pseudodispansa sp. nov., seem to be confined to the Indo-Pakistani region (Eastern Tethys). The Discocyclina dispansa, D. discus, D. nandori, and D. augustae lineages known from Western Tethys are also common in the Indian Subcontinent, as are asterocyclinids, such as Asterocyclina sireli and A. stellata. The upper part of the Drazinda Formation (‘Pellatispira beds’), referable to latest Bartonian and/or the early Priabonian, is poor in orthophragminids and is characterized by the occurrence of reticulate Nummulites, Heterostegina, Pellatispira and Silvestriella. The records of ‘Lepidocyclina of Caribbean affinity’ with large embryons from the Eocene of the Indian Subcontinent correspond to misidentified Discocyclina discus.  相似文献   
25.
Groundwater is the most appropriate and widely used source of drinking water,which is increasingly threatened by pollution from industrial and agricultural activities.To check the severity of the problem,156 groundwater samples were collected from various depths(60-110 ft) of 52 different localities in Faisalabad city,the third largest metropolis in Pakistan,and analyzed for the metals(Zn,Cu,Cd,Ni,Pb,Mn and Fe) concentration in 2009.Quantification was done by using Flame Atomic Absorption Spectrophotometer technique and the results were compared with WHO standards for drinking water quality.Results showed that the levels of Cu,Mn and Fe were below the WHO standards while the concentrations of Zn,Cd,Ni and Pb were above the recommended levels of safe drinking water.Correlation analysis among the occurrence of these heavy metals revealed a highly significant and positive correlation of Mn with Zn and Fe.A significant and positive correlation of Cd was also found with Cu and groundwater depth showing that there is strong association between Cu-Cd pair and that the Cd concentration varies with depth of groundwater in the study area.Regional patterns of heavy metals occurrence were mapped using Geographical Information System(GIS) for the identification and demarcation of risk areas.The concentration maps may be used by policymakers of the city to mitigate groundwater pollution.  相似文献   
26.
Like tree rings, high‐resolution soil sampling of low‐permeability (low‐k) zones can be used to evaluate the style of source history at contaminated sites (i.e., historical pattern of concentration and composition vs. time since releases occurred at the interface with the low‐k zone). This is valuable for the development of conceptual site model (CSM) and can serve as an important line of evidence supporting monitored natural attenuation (MNA) as a long‐term remedy. Source histories were successfully reconstructed at two sites at Naval Air Station Jacksonville using a simple one‐dimensional (1D) model. The plume arrival time and historical composition were reconstructed from the time initial releases that were suspected to occur decades earlier. At the first site (Building 106), the source reconstructions showed relatively constant source concentrations, but significant attenuation over time in the downgradient plume in the transmissive zone, suggesting MNA may not be an appropriate remedy if source control is a requirement, but attenuation processes are clearly helping to maintain plume stability and reduce risk. At the second site (Building 780), source concentrations in the transmissive zone showed an approximately a one order of magnitude over time, but apparently less attenuation in the downgradient plume. The source reconstruction method appeared to reflect site remediation efforts (excavation, soil vapor extraction) implemented in the 1990s. Finally, a detailed analysis using molecular biological tools, carbon isotopes, and by‐products suggests that most degradation activity is associated with high‐k zones but not with low‐k zones at these source areas. Overall, the source reconstruction methodology provided insight into historical concentration trends not obtainable otherwise given the limited long‐term monitoring data.  相似文献   
27.
Paleozoic rocks in the Wadi El Sahu area are affected by many major faults in different directions. A reverse fault trending NE-SW is exposed for about 300 m of its length as it cuts through the Abu Hamata and Adedia formations on the south side of Wadi El Sahu. A secondary ascending hydrothermal solution carrying heavy metals and radioactive minerals passed through the fault plain and the surrounding fractures, forming mineralized and radioactive zone. The mineralized zone thickness ranges from 60 cm to 200 cm along the fault plain. These rocks were analyzed radiometrically using a portable gamma-ray spectrometer, chemically by employing ICP-ES and ICP-MS, as well as mineralogically by both binocular and Environmental Scanning Electron microscope. Gold content was also determined by fire assay. REE and U contents reached up to 2682 and 1216 ppm, respectively. Mineralogical investigations indicated the presence of uraninite, torbernite, autunite, sklodowskite, kasolite as uranium minerals, thorite as a thorium mineral, monazite, allanite and xenotime as REE-bearing minerals, zircon and columbite as accessory minerals, gold and nickel as precious and base metals, in addition to cassiterite, chalcopyrite, chalcocite and chrysocolla. High REE and U contents are attributed to the circulation of epigenetic U and REE-bearing hydrothermal solutions along the fault plain and its surrounding fractures. Hydrothermal alteration processes could then be confirmed by the presence of the M-type tetrad effect in the REE-patterns of the ferruginous sandstone. The non-chondritic ratio of Nb/Ta, Zr/Hf and Y/Ho in the studied sandstone may be attributed to the tetrad effect. The Ce and Eu anomaly with unusual REE-patterns was represented by the presence of conjugated M-W tetrad effects, indicating either the dual effect of hydrothermal solutions or groundwater with seawater. The results clarify that the tetrad-effects could be used as evidence for the environment of deposition and as an indication for gold mineralization.  相似文献   
28.
Understanding the effects of contaminants that can diffuse into low-permeability (“low-k”) zones is crucial for effective groundwater remedial decision-making. Because low-k zones can serve as low-level sources of contamination to more transmissive zones over time, an accurate evaluation of the impacts of matrix diffusion at contaminated sites is vital. This study compared numerical groundwater flow and transport simulations using MODFLOW/RT3D at a hypothetical site using three cases, each with increasing discretization of the vertical 10-m thick domain: (1) a coarse multilayer heterogeneous grid based on one layer for each of four different hydrogeological units, (2) a “low-resolution” discretization approach where the low-k units were divided into several sublayers giving the model 10 layers, and (3) a “high-resolution” numerical model with 199 layers that are a few centimeters thick. When comparing the results of each case, significant differences were observed between the discretizations used, even though all other model input data were identical. The conventional grid models (Cases 1 and 2) appeared to underestimate groundwater plume concentrations by a factor ranging from 1.1 to 36 when compared to the high-resolution grid model (Case 3), and underestimated predicted cleanup times by more than a factor of 10 for some of the hypothetical sampling points in the modeling domain. These results validate the implication of Chapman et al. (2012), that conventional vertical discretization of numerical groundwater flow and transport models at contaminated sites (with layers that are greater than 1 m thick) can lead to significant errors when compared to more accurate high-resolution vertical discretization schemes (layers that are centimeters thick).  相似文献   
29.
Abstract

Runoff and soil erosion are known to cause a degradation in soil and water quality. Six natural runoff plots (three 10 m long and three 30 m long) were established on 6% uniform slope area for the study of P and N losses associated with runoff and soil erosion in northern Iraq. The soil at the site belongs to the Calciorthid suborder which dominates in the low rainfall zone of northern Iraq. Runoff, erosion, and associated P and N losses, were recorded from these plots for three rainfall seasons. Results illustrated that eroded sediment is always rich in available P and inorganic N compared to the original soil. Concentrations of soluble P and soluble N in runoff illustrated significant variability both between storms and between seasons. Both sediment-bound P and soluble P were significantly correlated with the ratio of runoff to rainfall.  相似文献   
30.
Managing risks from extreme events will be a crucial component of climate change adaptation. In this study, we demonstrate an approach to assess future risks and quantify the benefits of adaptation options at a city-scale, with application to flood risk in Mumbai. In 2005, Mumbai experienced unprecedented flooding, causing direct economic damages estimated at almost two billion USD and 500 fatalities. Our findings suggest that by the 2080s, in a SRES A2 scenario, an ??upper bound?? climate scenario could see the likelihood of a 2005-like event more than double. We estimate that total losses (direct plus indirect) associated with a 1-in-100 year event could triple compared with current situation (to $690?C$1,890 million USD), due to climate change alone. Continued rapid urbanisation could further increase the risk level. The analysis also demonstrates that adaptation could significantly reduce future losses; for example, estimates suggest that by improving the drainage system in Mumbai, losses associated with a 1-in-100 year flood event today could be reduced by as much as 70%.,We show that assessing the indirect costs of extreme events is an important component of an adaptation assessment, both in ensuring the analysis captures the full economic benefits of adaptation and also identifying options that can help to manage indirect risks of disasters. For example, we show that by extending insurance to 100% penetration, the indirect effects of flooding could be almost halved. We conclude that, while this study explores only the upper-bound climate scenario, the risk-assessment core demonstrated in this study could form an important quantitative tool in developing city-scale adaptation strategies. We provide a discussion of sources of uncertainty and risk-based tools could be linked with decision-making approaches to inform adaptation plans that are robust to climate change.  相似文献   
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