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41.
The short-lived thorium isotope 234Th (half-life 24.1 days) has been used as a tracer for a variety of transport processes in aquatic systems. Its use as a tracer of oceanic export via sinking particles has stimulated a rapidly increasing number of studies that require analyses of 234Th in both marine and freshwater systems. The original 234Th method is labor intensive. Thus, there has been a quest for simpler techniques that require smaller sample volumes. Here, we review current methodologies in the collection and analysis of 234Th from the water column, discuss their individual strengths and weaknesses, and provide an outlook on possible further improvements and future challenges. Also included in this review are recommendations on calibration procedures and the production of standard reference materials as well as a flow chart designed to help researchers find the most appropriate 234Th analytical technique for a specific aquatic regime and known sampling constraints.  相似文献   
42.
The Porto Alegre region, Southern Brazil, comprises a fractured aquifer system constituted by pre-Cambrian granitic and gneissic rocks, and a porous aquifer system formed by Cenozoic muddy–sandy to sandy sediments. A model is presented for the origin of the fluoride in the groundwater of the fractured aquifer system, based on ionic interrelations, a statistical analysis of physicochemical parameters and geochemical modeling. The fluoride is present at levels of up to 6.13 mg/L in groundwater and it arises due to the dissolution of secondary fluorite filling fractures in the granitic and gneissic rocks. The dissolution of fluorite occurs at the same time as calcite and dolomite solubilization. The statistical analysis identified three chemically distinct groups (named 1, 2 and 3) and two subgroups (1A and 1B) of groundwater in the fractured aquifer. The most significant differences between these groups are the different concentration ranges of fluoride, calcium, bicarbonate, magnesium, total dissolved solids and chloride and pH values, as well as the correlations between them. The compositional evolution of each groundwater group is governed mainly by how much high-salinity groundwater from the porous aquifer system is mixed with them and the different thermodynamic equilibrium conditions of calcite, dolomite and fluorite.  相似文献   
43.
The common mussel Mytilus galloprovincialis was selected as unique biomonitor species to implement a regional monitoring programme, the CIESM Mediterranean Mussel Watch (MMW), in the Mediterranean and Black Seas. As of today, and upon standardization of the methodological approach, the MMW Network has been able to quantify 137Cs levels in mussels from 60 coastal stations and to produce the first distribution map of this artificial radionuclide at the scale of the entire Mediterranean and Black Seas. While measured 137Cs levels were found to be very low (usually <1 Bq kg−1 wet wt) 137Cs activity concentrations in the Black Sea and North Aegean Sea were up to two orders of magnitude higher than those in the western Mediterranean Basin. Such effects, far from representing a threat to human populations or the environment, reflect a persistent signature of the Chernobyl fallout in this area.  相似文献   
44.
Based on a pseudo-static approach, finite difference (FDM) numerical analyses have been performed aimed at evaluating the seismic effects on the ultimate bearing capacity of shallow strip foundations. In the specialised literature, such seismic effects are usually divided in two components, namely, a structure inertia and a soil inertia, which can be either considered together, or separately addressed and then superposed. Both of these inertia effects are investigated in this work. The results of a comprehensive numerical study are presented in—and critically compared to—the wide framework of available analytical solutions proposed in the literature in the last 30 years. The good agreement found between the numerical and the analytical approaches is pointed out, thus providing further evidence of the reliability of some available and widespread solutions. The possibility of superposition of the two inertia effects is investigated. It is found that in some cases the soil inertia may play a significant role in the seismic capacity of the system, and that simple one-constant equations can be readily used in foundation design to estimate the reduction in bearing capacity (namely, factors e i , e k ) deriving from the two inertia effects.  相似文献   
45.
Adsorption is one of the most significant processes in the mobility of soluble pollutants in soils. The aim of this work is to characterize and evaluate the adsorption capacity of soils from Viamão District, Brazil. The studied ions were leadtotal, coppertotal, sulfate, phosphate, and potassium. The soils were mapped by remote sensing and characterized by granulometrical and mineralogical techniques. The adsorption tests were made by the contact of soil samples with aqueous solutions. The soils adsorption capacity presented the following trend: Pbtotal>Cutotal≈PO 4 3− >K+ ≈SO 4 2+ . Adsorption in the soils is strongly influenced by clay content. The adsorption of phosphate, copper, and lead was accentuated by the presence of organic matter. Phosphate adsorption was controlled by oxides and organic matter. Both potassium and sulfate showed insignificant adsorption in the studied soils.  相似文献   
46.
We present a regional surface waveform tomography of the Pacific upper mantle, obtained using an automated multimode surface waveform inversion technique on fundamental and higher mode Rayleigh waves, to constrain the   VSV   structure down to ∼400 km depth. We have improved on previous implementations of this technique by robustly accounting for the effects of uncertainties in earthquake source parameters in the tomographic inversion. We have furthermore improved path coverage in the South Pacific region by including Rayleigh wave observations from the French Polynesian Pacific Lithosphere and Upper Mantle Experiment deployment. This improvement has led to imaging of vertical low-velocity structures associated with hotspots within the South Pacific Super-Swell region. We have produced an age-dependent average cross-section for the Pacific Ocean lithosphere and found that the increase in   VSV   with age is broadly compatible with a half-space cooling model of oceanic lithosphere formation. We cannot confirm evidence for a Pacific-wide reheating event. Our synthetic tests show that detailed interpretation of average   VSV   trends across the Pacific Ocean may be misleading unless lateral resolution and amplitude recovery are uniform across the region, a condition that is difficult to achieve in such a large oceanic basin with current seismic stations.  相似文献   
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