Low temperature dynamics of molecular H2O in bassanite,gypsum and cordierite investigated by high resolution incoherent inelastic neutron scattering     

Björn Winkler  Bernard Hennion 《Physics and Chemistry of Minerals》1994,21(8):539-545

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The distribution of trace metals in the western North Atlantic off Nova Scotia     

J.M. Bewers  Bjørn Sundby  P.A. Yeats 《Geochimica et cosmochimica acta》1976,40(6):687-696

The distributions of Fe, Mn, Zn, Cu, Ni, Cd and Co have been determined in a section across the Scotian Shelf into the Atlantic Slope water. Significant differences in concentration exist for most of the trace metals between the four water masses in the section. Depletions of trace metal concentration in the highly productive Atlantic Slope water relative to the underlying Central Atlantic water are thought to be due to biological activity.The distributions of Fe and Mn are strongly related to the distribution of suspended particulate matter. The concentrations of Fe and Mn, extracted from the suspended matter on the Scotian Shelf, are considerably higher than those in the non-detrital fraction of the underlying sediments. This suggests that post-depositional changes cause the loss of both elements from the non-detrital fraction of the particles. Whereas Mn shows major nearshore increases in concentration related to continental runoff, nearshore Fe concentrations are largely controlled by particulate matter distribution. Continental runoff does not appear to have much influence upon the distributions of the other trace metals.  相似文献   

Trace element partitioning and melt structure: An experimental study at 1 atm pressure     

Bjørn O. Mysen  David Virgo 《Geochimica et cosmochimica acta》1980,44(12):1917-1930

Diopside-melt and forsterite-melt rare earth (REE) and Ni partition coefficients have been determined as a function of bulk compositions of the melt. Available Raman spectroscopic data have been used to determine the structures of the melts coexisting with diopside and forsterite. The compositional dependence of the partition coefficients is then related to the structural changes of the melt.The melts in all experiments have a ratio of nonbridging oxygens to tetrahedral cations ($\text{NBO}\text{T}$) between 1 and 0. The quenched melts consist of structural units that have, on the average, 2 (chain), 1 (sheet) and 0 (three-dimensional network) nonbridging oxygens per tetrahedral cation. The proportions of these structural units in the melts, as well as the overall $\text{NBO}\text{T}$, change as a function of the bulk composition of the melt.It has been found that Ce, Sm, Tm and Ni crystal-liquid partition coefficients ($\text{K}{}^{\mathrm{crystal?liq}}{}_{\mathrm{i}}\text{=}\text{C}{}^{\mathrm{crystal}}{}_{\mathrm{i}}\text{C}{}^{\mathrm{liq}}{}_{\mathrm{i}}$) decrease linearly with increasing $\text{NBO}\text{T}$. The values of the individual REE crystal-liquid trace element partition coefficients have different functional relations to $\text{NBO}\text{T}$, so that the degree of light REE enrichment of the melts would depend on their $\text{NBO}\text{T}$.The solution mechanisms of minor oxides such as CO₂, H₂O, TiO₂, P₂O₅ and Fe₂O₃ in silicate melts are known. These data have been recast as changes of $\text{NBO}\text{T}$ of the melts with regard to the type of oxide and its concentration in the melt. From such data the dependence of crystal-liquid partition coefficients on concentration and type of minor oxide in melt solution has been calculated.  相似文献   

Effect of an oil spill in Spitzbergen in 1978     

Bjørn Gulliksen  Jens Petter Taasen 《Marine pollution bulletin》1982,13(3):96-98

The oil content in the sediment and the marine life along the arctic shores of Van Mijenfjord, Spitzbergen, were investigated about two years after a spill from diesel storage tanks. High values of oil were recorded in the sediment along the shore near the tanks. The shore fauna is generally poor in these areas and the only biological effect detected was the disappearance of the amphipod Gammarus setosus from the surface layers.  相似文献   

Diagenesis in Mesozoic sandstones from Spitsbergen and the North Sea — A comparison     

Prof. Dr. K. BjØrlykke  Bergen A. ElvekhØI  A. O. Malm 《International Journal of Earth Sciences》1979,68(3):1152-1171

Mesozoic and Tertiary sandstones on Spitsbergen are generally tight and well cemented while Mesozoic and Tertiary sandstones from the North Sea include highly porous reservoir rocks.It is concluded that one of the most important controlling mechanisms for preservation of porosity is the build up of high pore pressures which effectively reduce pressure solution at grain contacts and the incidence of quartz overgrowth.High pore pressures are most commonly developed in onlapping sedimentary sequences with an effective shale seal like in the North Sea.Extensive diagenetic growth of kaolinite at the expence of clastic feldspar, which is commonly observed, requires a large flux of low salinity water. The most probable mechanism is fresh ground water drive through sandstones which have served as aquifers. During the late stages of burial (1–3 kms) the diagenetic reactions must have taken place within an isochemical semi-closed system. Calculations show that porewater expelled from compacting shales is insufficient to cause significant changes in the bulk chemistry of thick sandstones. Microprobe analyses carried out on Jurassic sandstones from the Statfjord field show that there are a continuous series of transitions from clastic mica to illite and kaolinite as indicated by a gradual loss of potassium. Evidence is presented to show that silica cementation is retarded in the presence of clastic mica while carbonate and feldspar cementation is favoured in this local high pH environment between sheets of mica. Electron probe analyses show that diagenetic feldspar overgrowths are pure potassium feldspar with a composition significantly different from that of clastic feldspar. During late diagenesis the porewater was most probably near equilibrium with the reactive phases.

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Zusammenfassung Die mesozoischen und tertiären Sandsteine von Spitzbergen sind im allgemeinen gut zementiert, während die gleichalten Sandsteine aus der Nordsee hochporöse Speichergesteine umfassen.Man erkennt, daß die Erhaltung der Porosität auf einen hohen Porenwasserdruck zurückzuführen ist. Dadurch wird Drucklösung an Kornkontakten sowie Weiterwachsen von Quarz verhindert.Hoher Porendruck entsteht gewöhnlich da, wo überlappende Sedimentserien mit einer Abdichtung durch Schiefer vorliegen—wie in der Nordsee.Ausgedehntes diagenetisches Wachstum von Kaolinit auf Kosten klastischer Feldspäte erfordert einen hohen Durchfluß von niedrigsalinem Wasser. Der wahrscheinlichste Mechanismus ist in einem Grundwasserstrom zu suchen, der durch die Sandsteine fließt, die als Wasserleiter dienen. Während der späten Stadien der Absenkung (1–3 km) müssen diese diagenetischen Reaktionen in einem halbgeschlossenem isochemischen System abgelaufen sein. Berechnungen aus Porenwasser, das von Schiefern gewonnen wurde, zeigen, daß dieses nicht ausreicht, bedeutende änderungen in der Gesamtchemie mächtiger Sandsteine zu bewirken.Mikrosondenanalysen, die an jurassischen Sandsteinen aus dem Statfjord-Feld vorgenommen wurden, zeigen, daß hier eine kontinuierliche Serie von übergängen aus klastischem Glimmer nach Illit und Kaolinit vorliegt. Eine stufenweise Abnahme von Kalium deutet dies an. Quarz-Zementation tritt zurück bei Anwesenheit von klastischem Glimmer, während Karbonat- und Feldspat-Zementation unter den Bedingungen eines hohen pH-Wertes zwischen den Glimmer-Blättern bevorzugt erscheint. Mikrosondenanalysen zeigen, daß der diagenetisch aufgewachsene Feldspat ein reiner Kali-Feldspat ist, der sich beträchtlich von den klastischen Feldspäten unterscheidet. Während der späten Diagenese stand das Porenwasser nahezu im Gleichgewicht mit den reagierenden Phasen.

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Résumé Les grès mésozoÏques et tertiaires du Spitzberg sont en général bien cimentés, tandis que les grès de mÊme âge de la Mer du Nord comprennent des roches-réservoirs très poreuses. On en conclut que l'un des plus importants mécanismes régissant le maintien de la porosité est la mise en jeu de fortes pressions dans les pores de la roche, ce qui effectievement réduit la dissolution par la voie de la pression s'exerÇant au contact des grains et l'intervention de la croissance des grains de quartz.De fortes pressions dans les pores sont le plus couramment développées dans les séquences sédimentaires isolées par un recouvrement argileux, comme dans la Mer du Nord.La croissance diagénétique à grande échélle de la kaolinite aux dépens du feldspath détritique, communément observée, requiert une grande circulation d'eau à faible salinité. Le mécanisme le plus probable est celui de la circulation d'eau douce dans des grès aquifères. Durant les derniers stades de l'enfouissement (1–3 km) les réactions diagénétiques se sont produites dans un système isochimique à moitié fermé. Des calculs montrent que l'eau poreuse chassée des argilites à la suite de leur compaction est insuffisante pour causer des changements de quelqu'importance dans la composition chimique des grès en masses épaisses. Des analyses à la microsonde sur des grès jurassiques de la région du Statfjord montrent qu'il existe une gamme continue de transitions depuis le mica détritique jusqu'à l'illite et la kaolinite, ainsi qu'il ressort de la perte graduelle du potassium. La preuve est donnée que la cimentation par la silice est retardée par la présence de mica détritique, tandis que la cimentation par le carbonate et par le feldspath est favorisée dans ce milieu restreint à pH élevé entre lamelles de mica. Des analyses électroniques montrent que les accroissements diagénétiques de feldspath sont faits de feldspath potassique pur d'une composition notablement différente de celle del feldspath détritique. A la fin de la diagénèse l'eau intersticielle était très probablement proche de l'équilibre avec les phases réagissantes.

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Experimental determination of rare earth element partitioning between hydrous silicate melt,amphibole and garnet peridotite minerals at upper mantle pressures and temperatures     

Bjørn O. Mysen 《Geochimica et cosmochimica acta》1978,42(8):1253-1263

Partition coefficients of Ce, Sm and Tm involving garnet peridotite minerals, amphibole and hydrous silicate melt have been determined experimentally in the temperature and pressure ranges 950–1075°C and 10–25 kbar.Only several parts per million to several tens of parts per million of rare earth element (REE) can dissolve in the minerals before the crystal-liquid partition coefficients begin to vary as a function of REE content. The concentration ranges of constant partition coefficient increase with increasing temperature and are also positively correlated with the magnitude of the crystal-liquid partition coefficients. The upper concentration limits of constant partition coefficient and the value of the crystal-liquid partition coefficient for REE decrease in the order garnet > clinopyroxene > amphibole > orthopyroxene > olivine.Partition coefficients may vary by at least an order of magnitude as a function of bulk composition of the liquid phase (e.g. changing from basaltic to andesitic). The approximate ranges of the values of the partition coefficients as a function of bulk liquid composition are as follows: where the values increase with increasing acidity of the melt.  相似文献   

Redox Chemistry in the Root Zone of a Salt Marsh Sediment in the Tagus Estuary,Portugal   总被引：5，自引：1，他引：4  

Bjørn Sundby  Carlos Vale  Miguel Caetano  George W. LutherIII 《Aquatic Geochemistry》2003,9(3):257-271

Measurements of O₂, Fe(II), Mn(II)and HS₅ in salt marshsediments in the Tagus Estuary, Portugal, made with a voltammetric microelectrode, reveal strong seasonal differences in pore water composition within the 20~cm deep root zone. In spring, oxygen was below detection limit except close to the sediment surface. Fe(II) was present below 5 cm in concentrations ranging from detection limit to 1700 M. In summer, oxygen was present in the pore water almost to the bottom of the root zone in concentrations ranging from detection limit to more than 100 M. The spatial variability was intense: O₂ concentrations as high as 78 M and as low as 25 M existed within 2~mm of each other. Fe(II) was below detection limit except towards the bottom of the root zone. In late fall, oxygen was found to 8 cm depth, but in concentrations lower than in summer, and Fe(II) was present below 9 cm. Mn(II) was found at levels declining from typical values of 200 M in spring to less than 20 M in late fall. With one exception, sulfide was below the detection limit in all measurements. During periods when dissolved Fe(II) is available in the pore water at the same time as ₂ is delivered by roots, iron-rich concretions can form on roots. These conditions, which lead to precipitation of iron oxide in the sediment adjacent to roots, exist in spring, when new roots infiltrate anoxic Fe(II) containing sediment. They do not exist in summer, when dissolved Fe(II) is unavailable, or in winter, when oxygen is unavailable. The seasonal redox pattern revealed by the pore water chemistry is driven by the annual cycle of growth and decay of roots.  相似文献   

Comments on “carbon cycling in a shallow turbid estuary of Southeast Texas: The use of plant pigment biomarkers and water quality parameters” by Bianchi, Baskaran, DeLord and Ravichandran,Estuaries 20:404–415     

Michael H. Flinn  Elizabeth Harris  Robert Cady  Christopher S. Johnson  Erla Björk Örnólfsdóttir  Lisa Campbell  Douglas C. Biggs 《Estuaries and Coasts》1998,21(4):837-838

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The dynamics of H2O in minerals     

Björn Winkler 《Physics and Chemistry of Minerals》1996,23(4-5):310-318

The application of infrared, proton nuclear magnetic resonance, and dielectric spectroscopy and incoherent neutron scattering for the elucidation of the dynamics of H₂O incorporated into minerals is reviewed. The examples given include beryl, cordierite, gypsum, bassanite, layer silicates and zeolites. It is demonstrated that for such structures static models may be inappropriate, and dynamic models have to be used to describe the role and behavior of the H₂O molecules.  相似文献   

Do tributary streams contribute significantly to the transport of faecal pellets in large rivers?     

Björn Malmqvist  Roger S. Wotton 《Aquatic Sciences - Research Across Boundaries》2002,64(2):156-162

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