Effect of NAPL Source Morphology on Mass Transfer in the Vadose Zone          下载免费PDF全文

Benjamin G. Petri  Radek Fučík  Tissa H. Illangasekare  Kathleen M. Smits  John A. Christ  Toshihiro Sakaki  Carolyn C. Sauck 《Ground water》2015,53(5):685-698

The generation of vapor‐phase contaminant plumes within the vadose zone is of interest for contaminated site management. Therefore, it is important to understand vapor sources such as non‐aqueous‐phase liquids (NAPLs) and processes that govern their volatilization. The distribution of NAPL, gas, and water phases within a source zone is expected to influence the rate of volatilization. However, the effect of this distribution morphology on volatilization has not been thoroughly quantified. Because field quantification of NAPL volatilization is often infeasible, a controlled laboratory experiment was conducted in a two‐dimensional tank (28 cm × 15.5 cm × 2.5 cm) with water‐wet sandy media and an emplaced trichloroethylene (TCE) source. The source was emplaced in two configurations to represent morphologies encountered in field settings: (1) NAPL pools directly exposed to the air phase and (2) NAPLs trapped in water‐saturated zones that were occluded from the air phase. Airflow was passed through the tank and effluent concentrations of TCE were quantified. Models were used to analyze results, which indicated that mass transfer from directly exposed NAPL was fast and controlled by advective‐dispersive‐diffusive transport in the gas phase. However, sources occluded by pore water showed strong rate limitations and slower effective mass transfer. This difference is explained by diffusional resistance within the aqueous phase. Results demonstrate that vapor generation rates from a NAPL source will be influenced by the soil water content distribution within the source. The implications of the NAPL morphology on volatilization in the context of a dynamic water table or climate are discussed.  相似文献   

Measurement of the radius of Mercury by radio occultation during the MESSENGER flybys     

Mark E. Perry  Daniel S. Kahan  Olivier S. Barnouin  Carolyn M. Ernst  Sean C. Solomon  Maria T. Zuber  David E. Smith  Roger J. Phillips  Dipak K. Srinivasan  Jürgen Oberst  Sami W. Asmar 《Planetary and Space Science》2011,59(15):1925-1931

The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft completed three flybys of Mercury in 2008–2009. During the first and third of those flybys, MESSENGER passed behind the planet from the perspective of Earth, occulting the radio-frequency (RF) transmissions. The occultation start and end times, recovered with 0.1 s accuracy or better by fitting edge-diffraction patterns to the RF power history, are used to estimate Mercury's radius at the tangent point of the RF path. To relate the measured radius to the planet shape, we evaluate local topography using images to identify the high-elevation feature that defines the RF path or using altimeter data to quantify surface roughness. Radius measurements are accurate to 150 m, and uncertainty in the average radius of the surrounding terrain, after adjustments are made from the local high at the tangent point of the RF path, is 350 m. The results are consistent with Mercury's equatorial shape as inferred from observations by the Mercury Laser Altimeter and ground-based radar. The three independent estimates of radius from occultation events collectively yield a mean radius for Mercury of 2439.2±0.5 km.  相似文献   

New distribution records of 2 Boeckella species in New Zealand (note)     

Carolyn W. Burns 《新西兰海洋与淡水研究杂志》2013,47(2)

The freshwater calanoid copepods Boeckella triarticulata and B. hamata were found in ponds near Napier. These are the first records of B. triarticulata in the North Island, New Zealand and of B. hamata in the east coast, North Island.  相似文献   

Synoptic surveys of lakes Rotorua and Rotoiti     

G. R. Fish  M. A. Chapman 《新西兰海洋与淡水研究杂志》2013,47(4):571-584

Surface and bottom water samples were collected from 39 widely spaced stations in Lake Rotorua in February 1967 and from 12 stations in Lake Rotoiti in March 1967. In Lake Rotorua, data obtained from these samples showed that small horizontal differences existed between the southern and northern parts of the lake probably related to the higher inflow of plant nutrients at the southern end and to the prevailing southerly wind concentrating phytoplankton populations at the northern end. Lake Rotoiti, which differed from Lake Rotorua in being thermally stratified, showed no important horizontal differences, Vigorous mixing in the strata probably being accomplished by deep seiches except in the shallow western basin of the lake, where the inflow from Lake Rotorua occurs. Serial vertical hauls for a zooplankton survey of Lake Rotoiti were taken from three stations in March 1967. The distribution of zooplankton was complex because diurnal vertical migrations of the animals were combined with horizontal movement of the water layers.  相似文献   

Insights into zooplankton‐cyanobacteria interactions derived from enclosure studies     

Carolyn W. Burns 《新西兰海洋与淡水研究杂志》2013,47(3):477-482

Few workers have used enclosures specifically to study interactions between zoo‐plankton and cyanobacteria. Differences among studies in enclosure size, nutrient level, plankton abundance and species composition, presence or absence of fish, and length of experiments make generalisations difficult. Zooplankton had no direct effect on the growth of ungrazed cyanobacteria (Anabaena flos‐aquae, Aphanizomenon flos‐aquae, large Microcystis colonies) in short‐term (<5 days) and long‐term (> 1 month) enclosure studies. When large cyanobacteria were abundant, some Daphnia spp. snowed reduced reproduction and development. When large grazers were abundant they suppressed the growth of edible, colonial cyanobacteria (Aphanizomenon elenkinii, small Microcystis colonies). By altering the ambient light and nutrient environment, large zooplankton may suppress cyanobacteria; evidence for the importance of grazers in promoting cyanobacterial dominance by removing competing phytoplankton species is equivocal. Zooplankton may suppress nitrogen fixation by cyanobacteria through ammonia excretion and may promote a change in dominance from diatoms to cyanobacteria through recycling phosphorus but not silicon.  相似文献   

Wind-driven diversion of summer river runoff preconditions the Laptev Sea coastal polynya hydrography: Evidence from summer-to-winter hydrographic records of 2007–2009     

Igor A. Dmitrenko  Sergey A. Kirillov  Thomas Krumpen  Mikhail Makhotin  E. Povl Abrahamsen  Sascha Willmes  Ekaterina Bloshkina  Jens A. Hölemann  Heidemarie Kassens  Carolyn Wegner 《Continental Shelf Research》2010

This paper examines the role of atmospheric forcing in modifying the pathways of riverine water on the Laptev Sea shelf, using summer-to-winter hydrographic surveys from 2007 to 2009. Over the two consecutive winter seasons of 2007–2008 and 2008–2009 in the area of the winter coastal polynya, our data clearly link winter surface salinity fields to the previous summer conditions, with substantially different winter salinity patterns preconditioned by summer atmospheric forcing. In the summer of 2007, dominant along-shore westerly winds in the cyclonic regime force the Lena River runoff to flow eastward. In contrast, in the summer of 2008, dominant along-shore easterly winds over the East Siberian Sea and on-shore northerly winds over the Laptev Sea in the anticyclonic regime lock the riverine water in the vicinity of the Lena Delta. Over the coastal polynya area in the southeastern Laptev Sea these patterns precondition a surface salinity difference of 8–16 psu between the winters of 2008 and 2009. Overall, this indicates a residence time of at least half a year for riverine water on the Laptev Sea shelf. Future climate change associated with an enhanced summer cyclonicity over the eastern Arctic may turn more riverine water eastward along the eastern Siberian coast, resulting in weaker vertical density stratification over the Laptev Sea shelf, with possible impact on the efficiency of vertical mixing and polynya dense water production.  相似文献   

Quantitative geomorphological analysis of drumlins in the Peterborough drumlin field,Ontario, Canada     

John C. Maclachlan  Carolyn H. Eyles 《Geografiska Annaler: Series A, Physical Geography》2013,95(2):125-144

Drumlins are enigmatic subglacial landforms that have been interpreted to form by a number of processes, including incremental accumulation of till, erosion of previously deposited sediment, catastrophic meltwater floods, and sediment deformation. However, relatively little is known about the controls on drumlin formation, such as spatially variable glacial processes or substrate characteristics, and how these controls may be identified from variations in drumlin morphology within a single drumlin field. This paper explores a computational method that allows identification of drumlins and extraction of their morphological characteristics from existing topographic digital data for a portion of the Peterborough drumlin field in Ontario, Canada. Spatial and non‐spatial analysis of the form and distribution of drumlins across the study area identifies drumlin characteristics such as size, elongation ratio, symmetry and long axis orientation and shows that drumlins are not randomly distributed across the region and their form characteristics have distinct regional trends. Kernel density analysis is used to identify the regional trends in drumlin characteristics. Factors that appear to influence the form and distribution of drumlins in the study area include sediment thickness, length of time beneath the ice, ice velocity and direction of ice movement. The distribution of particularly well developed asymmetric and elongate drumlins coincides with the location of a broad bedrock low and is interpreted to identify the former location of a fast‐flowing ice stream.  相似文献   

Evaluating the impact of data quantity, distribution and algorithm selection on the accuracy of 3D subsurface models using synthetic grid models of varying complexity     

Kelsey E. MacCormack  Jason J. Brodeur  Carolyn H. Eyles 《Journal of Geographical Systems》2013,15(1):71-88

Testing the accuracy of 3D modelling algorithms used for geological applications is extremely difficult as model results cannot be easily validated. This paper presents a new approach to evaluate the effectiveness of common interpolation algorithms used in 3D subsurface modelling, utilizing four synthetic grids to represent subsurface environments of varying geological complexity. The four grids are modelled with Inverse Distance Weighting and Ordinary Kriging, using data extracted from the synthetic grids in different spatial distribution patterns (regular, random, clustered and sparse), and with different numbers of data points (100, 256, 676 and 1,600). Utilizing synthetic grids for this evaluation allows quantitative statistical assessment of the accuracy of both interpolation algorithms in a variety of sampling conditions. Data distribution proved to be an important factor; as in many geological situations, relatively small numbers of randomly distributed data points can generate more accurate 3D models than larger amounts of clustered data. This study provides insight for optimizing the quantity and distribution of data required to accurately and cost-effectively interpolate subsurface units of varying complexity.  相似文献   

Paleowind velocity and paleocurrents of pluvial Lake Manly,Death Valley,USA     

Jeffrey R. Knott  Joanna M. Fantozzi  Kelly M. Ferguson  Summer E. Keller  Khadija Nadimi  Carolyn A. Rath  Jennifer M. Tarnowski  Michelle L. Vitale 《Quaternary Research》2012,78(2):363-372

Pluvial lake deposits are found throughout western North America and are frequently used to reconstruct regional paleoclimate. In Death Valley, California, USA, we apply the beach particle technique (BPT) of Adams (2003), Sedimentology, 50, 565–577 and Adams (2004), Sedimentology, 51, 671–673 to Lake Manly deposits at the Beatty Junction Bar Complex (BJBC), Desolation Canyon, and Manly Terraces and calculate paleowind velocities of 14–27 m/s. These wind velocities are within the range of present-day wind velocities recorded in the surrounding area. Sedimentary structures and clast provenance at Desolation Canyon and the Manly Terraces indicate sediment transport from north to south. Lake level, based on the elevation of constructional features, indicates that the hill west of the BJBC was an island and that the BJBC spits formed during simple lake regression. The data are consistent with the hypothesis that the present wind regime (velocity and direction) formed the pluvial Lake Manly features.  相似文献   

A geomorphological mapping approach for the assessment of seabed geohazards and risk     

Gayle Hough  Jennifer Green  Paul Fish  Andy Mills  Roger Moore 《Marine Geophysical Researches》2011,32(1-2):151-162

Exploration and development of offshore hydrocarbon resources has advanced into remote deepwater regions over the last decade and poses significant technical challenges for the design and installation of wells and facilities at extreme water depths. Seafloor and shallow subsurface processes and conditions in these areas are complex and generally poorly understood, and the geohazards to development are larger scale and fundamentally different to those encountered onshore; consequently the geohazard risk to deepwater development projects is potentially significant and requires careful evaluation and mitigation during the front-end planning and engineering design stages of projects. There are no established industry standards or methods for the assessment of geohazards and engineering-quality geophysical data at the scale of development. The paper describes an integrated and systematic map-based approach for the assessment and mitigation of seabed geohazards and risk to proposed deepwater development. The approach employs a multi-disciplinary team working with engineering-quality field calibrated data to accurately map and assess seafloor ground conditions and ensure that development proposals are not exposed to intolerable geohazard risk. The approach taken is very similar to the practice of establishing geological models for land-based engineering projects, in which the complete geological history of the site is used to characterise and predict the performance of the ground. Such an approach is routine for major projects on land but so far does not seem to be common practice in the offshore industry. The paper illustrates the seafloor geomophological mapping approach developed. The products are being used to optimise development layouts to avoid geohazards where possible and to support site-specific engineering design of facilities based on a detailed understanding of the potential geohazard loadings and associated risk.  相似文献