Novel measurements of atmospheric iodine species by resonance fluorescence     

Catherine S. E. Bale  Trevor Ingham  Roisin Commane  Dwayne E. Heard  William J. Bloss 《Journal of Atmospheric Chemistry》2008,60(1):51-70

A field instrument has been developed for the purpose of measuring gas-phase atmospheric iodine species in the marine boundary layer. Vacuum UV resonance-fluorescence (RF), generated using a microwave discharge lamp, is employed to detect atomic iodine via the (5p⁴6s)–(5p⁵) transitions around 178–184 nm. The system can be operated in two modes; either to directly measure ambient iodine atoms, or to measure the total photolabile iodine loading of ambient air, through broadband visible photolysis of photolabile iodine-containing species, with subsequent RF detection of the iodine atoms released. In both cases the instrument allows for the in situ measurement of the species detected, which is advantageous for gathering information concerning their local sources and distribution. The instrument is calibrated through generation of a known concentration of iodine atoms from the photolysis of I₂ using a mercury pen-ray lamp. The instrument was deployed for the first time in August 2007 at Mace Head on the west coast of Ireland; initial results from this field trial are presented. Ambient iodine atoms were measured at levels up to 22 ± 4.8 ppt during the day, coinciding with the lowest tides, when Laminaria seaweed beds were exposed. The total photolabile iodine loading was also measured during several night-time and day-time periods and was found to correlate inversely with tidal height. Inferred I₂ concentrations based on these measurements indicate levels of several hundred ppt at the Mace Head site. These measurements represent the first direct observations of ambient iodine atoms and measurement of total photolabile iodine in the atmosphere.  相似文献   

The 2007 Bengkulu earthquake, its rupture model and implications for seismic hazard     

A. Ambikapathy  J. K. Catherine  V. K. Gahalaut  M. Narsaiah  A. Bansal  P. Mahesh 《Journal of Earth System Science》2010,119(4):553-560

The 12 September 2007 great Bengkulu earthquake (M _w 8.4) occurred on the west coast of Sumatra about 130 km SW of Bengkulu. The earthquake was followed by two strong aftershocks of M _w 7.9 and 7.0. We estimate coseismic offsets due to the mainshock, derived from near-field Global Positioning System (GPS) measurements from nine continuous SuGAr sites operated by the California Institute of Technology (Caltech) group. Using a forward modelling approach, we estimated slip distribution on the causative rupture of the 2007 Bengkulu earthquake and found two patches of large slip, one located north of the mainshock epicenter and the other, under the Pagai Islands. Both patches of large slip on the rupture occurred under the island belt and shallow water. Thus, despite its great magnitude, this earthquake did not generate a major tsunami. Further, we suggest that the occurrence of great earthquakes in the subduction zone on either side of the Siberut Island region, might have led to the increase in static stress in the region, where the last great earthquake occurred in 1797 and where there is evidence of strain accumulation.  相似文献   

Intense fracturing and fracture sealing induced by mineral growth in porous rocks     

Catherine Noiriel  François Renard  Mai-Linh Doan  Jean-Pierre Gratier 《Chemical Geology》2010,269(3-4):197-209

Mineral precipitation in the pores of a rock may exert a force, which is called crystallization pressure. This process has been studied experimentally and results bring a new look on the way fractures may develop and seal in natural systems. Cylindrical core samples of porous limestone and sandstone were left for several weeks in contact with an aqueous solution saturated with sodium chloride, at 30 or 45 °C, under axial normal stress in the range 0.02–0.26 MPa. The fluid was allowed to rise in the core samples by capillary forces, up to a controlled height where evaporation and precipitation occurred. The uniaxial deformation of the samples was measured using high-resolution displacement sensors. The samples were characterized using computed X-ray tomography, allowing therefore imaging in 3D the intensity and localization of the damage. Two kinds of damage could be observed. Firstly, small rock fragments were peeled from the sample surface. Secondly, and more interestingly, fracture networks developed, by nucleation of microcracks at the interface where evaporation occurred, and propagation to the free surface. Two families of fractures could be identified. A first set of sealed fracture parallel to the evaporation front is directly induced by crystallization pressure. A second fracture network, perpendicular to the evaporation front, accommodates the first set of fractures. An analytical model where fluid flow is coupled to evaporation, vapour transport, and localization of mineral precipitation explains the shape of this fracture network.  相似文献   

The DeKalb mounds of northeastern Illinois as archives of deglacial history and postglacial environments     

B. Brandon Curry  Michael E. Konen  Catherine H. Yansa  Helena Alexanderson 《Quaternary Research》2010,74(1):82-90

The “type” DeKalb mounds of northeastern Illinois, USA (42.0°N, −88.7°W), are formed of basal sand and gravel overlain by rhythmically bedded fines, and weathered sand and gravel. Generally from 2 to 7 m thick, the fines include abundant fossils of ostracodes and uncommon leaves and stems of tundra plants. Rare chironomid head capsules, pillclam shells, and aquatic plant macrofossils also have been observed.Radiocarbon ages on the tundra plant fossils from the “type” region range from 20,420 to 18,560 cal yr BP. Comparison of radiocarbon ages of terrestrial plants from type area ice-walled lake plains and adjacent kettle basins indicate that the topographic inversion to ice-free conditions occurred from 18,560 and 16,650 cal yr BP. Outside the “type” area, the oldest reliable age of tundra plant fossils in DeKalb mound sediment is 21,680 cal yr BP; the mound occurs on the northern arm of the Ransom Moraine (−88.5436°W, 41.5028°N). The youngest age, 16,250 cal yr BP, is associated with a mound on the Deerfield Moraine (−87.9102°W, 42.4260°N) located about 9 km east of Lake Michigan. The chronology of individual successions indicates the lakes persisted on the periglacial landscape for about 300 to 1500 yr.  相似文献   

Virtual moralities: The mainstreaming of Fairtrade in Kenyan tea fields     

Catherine S. Dolan 《Geoforum》2010,41(1):33-43

Fairtrade was founded to alleviate poverty and economic injustice through a market-based form of solidarity exchange. Yet with the increasing participation of transnational food corporations in Fairtrade sourcing, new questions are emerging on the extent to which the model offers an alternative to the inimical tendencies of neoliberalism. Drawing on a qualitative research project of Kenyan Fairtrade tea, this paper examines how the process of corporate mainstreaming influences the structure and outcomes of Fairtrade, and specifically the challenges it poses for the realization of Fairtrade’s development aspirations. It argues firstly that whilst tea producers have experienced tangible benefits from Fairtrade’s social premium, these development ‘gifts’ have been conferred through processes marked less by collaboration and consent than by patronage and exclusion. These contradictions are often glossed by the symbolic force of Fairtrade’s key tenets - empowerment, participation, and justice - which simultaneously serve to neutralize critique and mystify the functions that Fairtrade performs for the political economy of development and neoliberalism. Second, building on recent critiques of corporate social responsibility, the paper explores how certain neoliberal rationalities are emboldened through Fairtrade, as a process of mainstreaming installs new metrics of governance (standards, certification, participation) that are at once moral and technocratic, voluntary and coercive, and inclusionary and marginalizing. The paper concludes that these technologies have divested exchange of mutuality, as the totemic features of neoliberal regulation - standards, procedures and protocols - increasingly render north south partnerships ever more virtual and depoliticized.  相似文献   

Continuous monitoring of comet Holmes from before the 2007 Outburst     

Ehab E. El-Houssieny  Robert J. Nemiroff  Timothy E. Pickering 《Astrophysics and Space Science》2010,330(1):19-22

The outburst and subsequent brightness evolution of comet 17P/Holmes has been observed using the MMT Observatory’s All-Sky Camera (Pickering 2006) on Mt. Hopkins near Tucson, Arizona, USA. The comet was picked up at the limiting visual magnitude of 5.5 on October 24.38 and tracked by the camera continuously until sunrise four hours later. During this time the comet brightened to visual magnitude 3.5. Comet Holmes was next observed just after sunset on October 25.23 at visual magnitude 2.5, where it remained approximately constant over the next three days. The comet then began to dim slowly and was followed into the early months of 2008 with periods of dense time coverage.  相似文献   

First insights into the structure and environmental setting of cold-seep communities in the Marmara Sea     

Bénédicte Ritt  Jozée Sarrazin  Jean-Claude Caprais  Philippe Noël  Olivier Gauthier  Catherine Pierre  Pierre Henry  Daniel Desbruyères 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(9):1120-1136

A brackish-water cold seep on the North Anatolian Fault (NAF) in the Marmara Sea was investigated with the Nautile submersible during the MarNaut cruise in 2007. This active zone has already been surveyed and revealed evidence of active seeping on the seafloor, such as bubble emissions, patches of reduced sediments, microbial mats and authigenic carbonate crusts. MarNaut was the first opportunity to sample benthic communities in the three most common microhabitats (bioturbated and reduced sediments, carbonate crust) and to examine their relationships with environmental conditions. To do so, faunal communities were sampled and chemical measurements were taken close to the organisms. According to diversity indices, the bioturbated microhabitat exhibited the highest taxonomic diversity and evenness despite a lower number of samples. Conversely, the reduced sediment microhabitat exhibited the lowest taxonomic diversity and evenness. The carbonate crust microhabitat was intermediate although it had the highest biomass. Multivariate analyses showed that (1) fauna were relatively similar within a single microhabitat; (2) faunal community structure varied greatly between the different microhabitats; (3) there was a link between faunal distribution and the type of substratum; and (4) chemical gradients (i.e. methane, oxygen and probably sulphides) may influence faunal distribution. The estimated fluid flow velocity (0.4–0.8 m/yr) confirmed the presence of fluid emission and provided evidence of seawater convection in the two soft-sediment microhabitats. Our results suggest that the reduced sediments may represent a harsher environment with high upward fluid flow, which restrains seawater from penetrating the sediments and inhibits sulphide production, whereas bioturbated sediments can be viewed as a bio-irrigated system with sulphide production occurring at greater depths. Therefore, the environmental conditions in reduced sediments appear to prevent the colonization of symbiont-bearing fauna, such as vesicomyid bivalves, which are more often found in bioturbated sediments. Fluid flow appears to control sulphide availability, which in turn influences the horizontal and vertical distribution patterns of fauna at small spatial scales as observed at other seep sites.  相似文献   

Perceptions of risk and adaptation: Coffee producers,market shocks,and extreme weather in Central America and Mexico     

Catherine M. Tucker  Hallie Eakin  Edwin J. Castellanos 《Global Environmental Change》2010,20(1):23-32

This article explores the role of risk perception in adaptation to stress through comparative case studies of coffee farmers’ responses to climatic and non-climatic stressors. We hypothesized that farmers associating these changes with high risk would be more likely to make adaptations than those who saw the events as part of normal variation. Nevertheless, we found that farmers who associated events with high risk were not more likely to engage in specific adaptations. Adaptive responses were more clearly associated with access to land than perception of risk, suggesting that adaptation is more a function of exogenous constraints on decision making than perception.  相似文献   

Thermal Convection in Finite Prandtl Number Fluids at High Rayleigh Number     

Catherine A. Hier  Stephen Y. Bergeron  David A. Yuen  Erik O. Sevre  John M. Boggs 《Visual Geosciences》2001,6(3):1-4

  相似文献   

Metasomatic hydrous fluids in amphibole peridotites from Zabargad Island (Red Sea)     

Pierre Agrinier  Catherine Mvel  Delphine Bosch  Marc Javoy 《Earth and Planetary Science Letters》1993,120(3-4):187-205

Combining textural, petrological, chemical and isotopic (Sr, H and O) data for amphiboles and whole rocks from the Zabargad peridotite diapir allows three different events to be distinguished. During each event, which can be related to a specific tectonic process of the rifting of the Red Sea, hydrous fluids produced amphiboles.

The first and the second generations of amphiboles have characteristics consistent with the involvement of mantle-derived hydrous fluids. The first generation consists of scarce Ti-pargasites which crystallized from small amounts of fluid at temperatures of around 900–1000°C. Their growth was linked to magma percolation in the peridotites before their deformation during diapiric uplift. The second generation consists of Cr-pargasites which crystallized locally (and abundantly) during reaction between the peridotites and a sodium/potassium-bearing hydrous fluid at temperatures of around 700–800°C. These amphiboles grew synchronously with the diapiric uplift. The hydrous fluids probably originated in the sub-continental mantle and were released during the diapiric uplift of the peridotites.

The third generation consists of amphiboles (pargasitic hornblende, hornblende sensu lato and tremolite) which are localized in shear zones and veins. They crystallized at temperatures estimated between 700°C and 450°C, again from a sodium/potassium-bearing hydrous fluid. However, this fluid is extraneous to the peridotites, as shown by the Sr, H and O isotope compositions which suggest seawater penetration either during or after the final emplacement of the peridotite diapir.

Although the peridotite diapir was emplaced in granulitic gneisses of the pan-African deep continental crust, no evidence was found for a contribution of hydrous continental fluids in the production of the amphiboles present in the peridotite bodies of Zabargad Island.  相似文献