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71.
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Clusters of elevated methane concentrations in aquifers overlying the Barnett Shale play have been the focus of recent national attention as they relate to impacts of hydraulic fracturing. The objective of this study was to assess the spatial extent of high dissolved methane previously observed on the western edge of the play (Parker County) and to evaluate its most likely source. A total of 509 well water samples from 12 counties (14,500 km2) were analyzed for methane, major ions, and carbon isotopes. Most samples were collected from the regional Trinity Aquifer and show only low levels of dissolved methane (85% of 457 unique locations <0.1 mg/L). Methane, when present is primarily thermogenic (δ13C 10th and 90th percentiles of ?57.54 and ?39.00‰ and C1/C2+C3 ratio 10th, 50th, and 90th percentiles of 5, 15, and 42). High methane concentrations (>20 mg/L) are limited to a few spatial clusters. The Parker County cluster area includes historical vertical oil and gas wells producing from relatively shallow formations and recent horizontal wells producing from the Barnett Shale (depth of ~1500 m). Lack of correlation with distance to Barnett Shale horizontal wells, with distance to conventional wells, and with well density suggests a natural origin of the dissolved methane. Known commercial very shallow gas accumulations (<200 m in places) and historical instances of water wells reaching gas pockets point to the underlying Strawn Group of Paleozoic age as the main natural source of the dissolved gas.  相似文献   
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The recognized ecological importance of Posidonia oceanica, the most important seagrass of the Mediterranean Sea, makes it crucial to assess the state of health of its meadows, discriminating natural from anthropogenic impacts. In this paper, the hydrodynamic conditions at the upper limit of P. oceanica meadows along the Ligurian coast (NW Mediterranean Sea) were investigated. A relationship between the distance of the upper limit of the meadow from the shoreline and the morphodynamic domain of the beach (i.e. distinctive types of beach produced by the topography, wave climate and sediment composition) was found. A zonation of the state of the shallow portions of the meadows down the submerged beach profile was identified. Zone a, from the shoreline to the breaking limit, is naturally critical for the development of the meadow. Zone b, from the breaking limit to the closure depth, is subjected to natural and human impacts. Zone c, below the closure depth, is little influenced by coastal dynamics. This study quantifies for the first time how much the status of the shallow portions of P. oceanica meadows is dependent on coastal dynamics, which is important for their proper management.  相似文献   
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Nitrate is considered the nutrient that limits new primary production in the southeastern Bering Sea shelf. Nitrate regenerated through biological nitrification has the potential to significantly support primary production as well. Here we use measurements of the specific rate of water column nitrification in a 1-D ecosystem model to quantify the resupply of nitrate from nitrification in the middle shelf of the southeastern Bering Sea. Model sensitivity studies reveal nitrification rate is an important control on the dominant phytoplankton functional type, and the amount of nitrate in su mer bottom waters and in the winter water column. Evaluation of nitrification using the model supports the hypothesis that increases in late-summer nitrate concentrations observed in the southeastern Bering Sea bottom waters are due to nitrification. Model results for nitrate replenishment exceed previously estimated rates of 20-30% based on observations. The results of this study indicate that nitrification, potentially the source of up to - 38% of the springtime water column nitrate, could support - 24% of the annual primary production.  相似文献   
77.
Soil water content is a key variable for biogeochemical and atmospheric coupled processes. Its small‐scale heterogeneity impacts the partitioning of precipitation (e.g., deep percolation or transpiration) by triggering threshold processes and connecting flow paths. Forest hydrologists frequently hypothesized that throughfall and stemflow patterns induce soil water content heterogeneity, yet experimental validation is limited. Here, we pursued a pattern‐oriented approach to explore the relationship between net precipitation and soil water content. Both were measured in independent high‐resolution stratified random designs on a 1‐ha temperate mixed beech forest plot in Germany. We recorded throughfall (350 locations) and stemflow (65 trees) for 16 precipitation events in 2015. Soil water content was measured continuously in topsoil and subsoil (210 profiles). Soil wetting was only weakly related to net precipitation patterns. The precipitation‐induced pattern quickly dissipates and returns to a basic pattern, which is temporally stable. Instead, soil hydraulic properties (by the proxy of field capacity) were significantly correlated with this stable soil water content pattern, indicating that soil structure more than net precipitation drives soil water content heterogeneity. Also, both field capacity and soil water content were lower in the immediate vicinity of tree stems compared to further away at all times, including winter, despite stemflow occurrence. Thus, soil structure varies systematically according to vegetation in our site. We conclude that enhanced macroporosity increases gravity‐driven flow in stem proximal areas. Therefore, although soil water content patterns are little affected by net precipitation, the resulting soil water fluxes may strongly be affected. Specifically, this may further enhance the channelling of stemflow to greater depth and beyond the rooting zone.  相似文献   
78.
This study focuses on the composition, abundance and distribution of ichthyoplankton in the inner shelf area off Bahía Blanca Estuary on the SW Atlantic Ocean during late spring. Eggs and larvae of Brevoortia aurea, Engraulis anchoita, Parona signata, Sciaenidae spp. – such as Cynoscion guatucupa and Micropogonias furnieri –, and Odontesthes argentinensis were found. Species richness was low probably as a result of season and shallow depths. Ichthyoplankton abundance reached values close to 10 000 per 10 m−3 (eggs) and 4000 per 10 m−3 (larvae) and displayed a spatial distribution pattern with maximum abundance values restricted to a band parallel to the coast. Differences between egg and larval patterns, probably derived from a different displacement and hydrodynamic behavior, were observed. Egg and larvae distribution patterns were found related with spawning areas and to directly depend on salinity and mesozooplankton. The larvae distribution pattern, in particular, was found to inversely depend on particulate organic carbon. In addition, the geographic location of egg and larvae maxima strongly coincided with a saline front reported for this area in springtime, thus suggesting a direct relationship with it.  相似文献   
79.
Flows of different hierarchy, which travel through limestone, schist, sandstone and ultra-basic rocks, with ages from the Paleocene to the Jurassic, at Sierra del Rosario, Pinar del Río, Cuba, were characterized. The waters were sampled from 1984 until 2004 and the data were statistically processed by means of chemical equilibrium and physico-chemical models, under a flow system view of interpretation. Results demonstrate that the physico-chemical properties of the water are controlled by water–rock interaction resulting from residence time since rainwater infiltrate and the path it follows to the discharge zone and the type of aquifer material the different groundwater flows are in contact with. Geochemical indices allow the definition of the different types of flow (local, intermediate, regional) to be characterized, permitting a further definition of the different flow systems and rock type involved, as well as its use for water supply and medical use. The main geochemical processes which control the chemical composition acquisitions mode are: congruent dissolution of calcite, dolomite, and halite; incongruent dissolution of plagioclase and microcline minerals; pyrite oxidation, sulphate reduction, and silica dissolution at the surface or silica precipitation at deep saturation and circulation zones.  相似文献   
80.
Water is one of the major environmental factors limiting plant growth and survival in the Mediterranean region. Quercus suber L. woodlands occupy vast areas in the Iberian Peninsula, frequently under shallow water table conditions. The relative magnitude of soil and groundwater uptake to supply transpiration is not easy to evaluate under these circumstances. We recently developed a conceptual framework for the functioning of the root system in Q. suber that simulates well tree transpiration, based on two types of root behaviour: shallow connected and deep connected. Although this significantly improved knowledge on the functional traits of Mediterranean Q. suber, the approach has the limitation of requiring root sap flow data, which are seldom available. In this work, we present alternative methodologies to assess if trees are connected to groundwater and to estimate the soil and groundwater contributions to tree transpiration. We provide evidence on the tree unrestricted access to groundwater solely based on meteorological, stem sap flow and leaf water potential data. Using a soil mass balance approach, we estimated the yearly soil and groundwater contributions to tree transpiration: 69.7% and 30.3%, respectively. Groundwater uptake became dominant in the dry summer: 73.2% of tree transpiration. Results reproduce extremely well those derived from root modelling. Because of its simplicity both in formulation and data requirements, our approach is potentially liable to be adapted to other groundwater‐dependent Mediterranean oak sites, where interactions between land use and water resources may be relevant. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
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