Experimental hydrothermal alteration of a martian analog basalt: Implications for martian meteorites     

Leslie L. BAKER  Deborah J. AGENBROAD  Scott A. WOOD 《Meteoritics & planetary science》2000,35(1):31-38

Abstract— A number of martian meteorite samples contain secondary alteration minerals such as Ca‐Mg‐Fe carbonates, Fe oxides, and clay minerals. These mineral assemblages hint at hydrothermal processes occurring in the martian crust, but the alteration conditions are poorly constrained. This study presents the results of experiments that examined the alteration of a high‐Fe basalt by CO₂‐saturated aqueous fluids at 23 and 75 °C and by mixed H₂O‐CO₂ vapors at 200 and 400 °C and water‐rock ratios of 1:1 and 1:10. Results indicate that observable alteration of the basalt takes place after runs of only seven days. This alteration includes mobilization of silica into phases such as opal‐CT and quartz, as well as the formation of carbonates, oxides, and at some conditions, zeolites and hydrous silicates. The degree of alteration increases with run temperature and, in high‐temperature vapor experiments, with increasing water content of the vapor. The degree of alteration and the mineralogy observed in the martian meteorites suggests that none of these samples were exposed to aqueous fluids for long periods of time. Nakhla and Lafayette probably interacted with water for relatively brief periods of time; if so, silica may have been leached from the parent rocks by the altering fluids. Allan Hills 84001 shows possible evidence for very limited interaction with an aqueous fluid, but the overall slight degree of alteration described for this meteorite strongly suggests that it never interacted extensively or at high temperature with any water‐bearing fluid. Elephant Moraine A79001 may not have been altered by aqueous fluids at all. The results of this study best support models wherein the meteorite parent rocks were wetted intermittently or for brief periods of time rather than models that invoke long‐term reaction with large volumes of water. Our experiments studied alteration of a high‐Fe basalt by dilute, CO₂‐saturated, aqueous solutions at 23 and 75 °C and by mixed H₂O‐CO₂ vapors at 200 and 400 °C. The results suggest that alteration of the parent rock takes place even after very short reaction times of seven days. All experiments produced carbonate minerals, including calcite, and in some cases, magnesite, siderite, and ankerite. A free silica phase, either opal, quartz, or hydrated silica, formed in most experiments. More altered experiments also contained minerals such as zeolites and hydrous phyllosilicates. Clay minerals were not observed to form in any experiments. In aqueous fluids, higher temperature corresponded with a higher degree of alteration, whereas changing fluid composition had no observable effect. In high‐temperature vapors, the degree of alteration was controlled by temperature and the proportion of H₂O to CO₂, with water‐rock ratio also playing a role in transport of silica. Application of these results to martian meteorites that contain secondary alteration minerals suggests that none of the martian rocks underwent extensive interaction with aqueous fluids. Nakhla and Lafayette contain clay minerals, which suggests that they interacted with water to some extent, possibly at elevated temperatures. Although ALH84001 shows possible evidence of very limited interaction with aqueous fluids, EETA79001 does not. These results support models for the alteration of these meteorites that do not invoke long‐term interaction with water or reaction with large volumes of water. Except for some models for alteration of ALH84001, this conclusion agrees with most of the literature on alteration of martian meteorites.  相似文献   

The Environment Act 1995 and quiet enjoyment: implications for countryside recreation in the national parks of England and Wales, UK   总被引：1，自引：0，他引：1  

Deborah J. Pearlman  Janet Dickinson  Linda Miller  Jerry Pearlman† 《Area》1999,31(1):59-66

Summary National parks in England and Wales have traditionally been seen as places of quiet, less hurried recreation. The phrase 'quiet enjoyment' was adopted to represent this notion, and this paper traces the policy-making process involved in attempting to conserve this view. The debate during the enactment of the Environment Act 1995 brought the use and meaning of the phrase to prominence; amongst other issues, the use of the phrase in tenancy law precluded its use in legislation. The loss of the phrase 'quiet enjoyment' could have prolonged effects on the way in which national parks are used for recreational purposes.  相似文献   

Development and skill assessment of a real-time hydrologic-hydrodynamic-wave modeling system for Lake Champlain flood forecasting     

Titze  Daniel  Beletsky  Dmitry  Feyen  Jesse  Saunders  William  Mason  Lacey  Kessler  James  Chu  Philip  Lee  Deborah 《Ocean Dynamics》2023,73(5):231-248

Ocean Dynamics - In response to record-breaking flooding on Lake Champlain in 2011, the International Joint Commission launched a 5-year study to explore solutions to flooding in the binational...  相似文献   

Evaluation of liquefaction potential in an intermountain Quaternary lacustrine basin (Fucino basin,central Italy)     

Paolo Boncio  Sara Amoroso  Giovanna Vessia  Marco Francescone  Mauro Nardone  Paola Monaco  Daniela Famiani  Deborah Di Naccio  Alessia Mercuri  Maria Rosaria Manuel  Fabrizio Galadini  Giuliano Milana 《Bulletin of Earthquake Engineering》2018,16(1):91-111

In this study, we analyse the susceptibility to liquefaction of the Pozzone site, which is located on the northern side of the Fucino lacustrine basin in central Italy. In 1915, this region was struck by a M 7.0 earthquake, which produced widespread coseismic surface effects that were interpreted to be liquefaction-related. However, the interpretation of these phenomena at the Pozzone site is not straightforward. Furthermore, the site is characterized by an abundance of fine-grained sediments, which are not typically found in liquefiable soils. Therefore, in this study, we perform a number of detailed stratigraphic and geotechnical investigations (including continuous-coring borehole, CPTu, SDMT, SPT, and geotechnical laboratory tests) to better interpret these 1915 phenomena and to evaluate the liquefaction potential of a lacustrine environment dominated by fine-grained sedimentation. The upper 18.5 m of the stratigraphic succession comprises fine-grained sediments, including four strata of coarser sediments formed by interbedded layers of sand, silty sand and sandy silt. These strata, which are interpreted to represent the frontal lobes of an alluvial fan system within a lacustrine succession, are highly susceptible to liquefaction. We also find evidence of paleo-liquefaction, dated between 12.1–10.8 and 9.43–9.13 kyrs ago, occurring at depths of 2.1–2.3 m. These data, along with the aforementioned geotechnical analyses, indicate that this site would indeed be liquefiable in a 1915-like earthquake. Although we found a broad agreement among CPTu, DMT and shear wave velocity “simplified procedures” in detecting the liquefaction potential of the Pozzone soil, our results suggest that the use and comparison of different in situ techniques are highly recommended for reliable estimates of the cyclic liquefaction resistance in lacustrine sites characterized by high content of fine-grained soils. In geologic environments similar to the one analysed in this work, where it is difficult to detect liquefiable layers, one can identify sites that are susceptible to liquefaction only by using detailed stratigraphic reconstructions, in situ characterization, and laboratory analyses. This has implications for basic (Level 1) seismic microzonation mapping, which typically relies on the use of empirical evaluations based on geologic maps and pre-existing sub-surface data (i.e., age and type of deposits, prevailing grain size, with particular attention paid to clean sands, and depth of the water table).  相似文献   

Key structural parameters affecting earthquake ground motion in 2D and 3D sedimentary structures     

Peter Moczo  Jozef Kristek  Pierre-Yves Bard  Svetlana Stripajová  Fabrice Hollender  Zuzana Chovanová  Miriam Kristeková  Deborah Sicilia 《Bulletin of Earthquake Engineering》2018,16(6):2421-2450

Alluvial valleys generate strong effects on earthquake ground motion (EGM). These effects are rarely accounted for even in site-specific studies because of (a) the cost of the required geophysical surveys to constrain the site model, (b) lack of data for empirical prediction, and (c) poor knowledge of the key controlling parameters. We performed 3D, 2D and 1D simulations for six typical sedimentary valleys of various width and depth, and for a variety of modifications of these 6 “nominal models” to investigate sensitivity of EGM characteristics to impedance contrast, attenuation, velocity gradient and geometry. We calculated amplification factors, and 2D/1D and 3D/2D aggravation factors for 10 EGM characteristics, using a representative set of recorded accelerograms to account for input motion variability. The largest values of the amplification and aggravation factors are found for the Arias intensity and cumulative absolute velocity, the lowest for the root-mean-square acceleration. The aggravation factors are largest for the vertical component. For each model, at least one EGM characteristic exhibits a significant 2D/1D aggravation factor, while all EGM characteristics exhibit significant 2D/1D aggravation factor on the vertical component. For all investigated sites, there is always an area in the valley for which 1D estimates are not sufficient. 2D estimates are insufficient at several sites. The key structural parameters are the shape ratio and overall geometry of the sediment-bedrock interface, impedance contrast at the sediment-bedrock interface, and attenuation in sediments. The amplification factors may largely exceed the values that are usually considered in GMPEs between soft soils and rock sites.  相似文献   

Geomorphic and hydraulic unit richness and complexity in a coastal plain river          下载免费PDF全文

Jonathan D. Phillips 《地球表面变化过程与地形》2017,42(15):2623-2639

Geomorphic and hydraulic units in river channels are closely linked to geodiversity and habitats, and thus to biodiversity. In a ~ 200 km reach of the lower Sabine River, in the northern Gulf of Mexico Coastal Plain, 72 different hydraulic units (HU) were identified in six geomorphic zones or river styles. Richness–area relationships indicate a linear or logarithmic increase of HUs, as opposed to the less steep power functions generally found in biogeographic species–area curves or in soil richness–area analyses. Different results are obtained when starting from the upstream or downstream end of the study area, indicating the importance of directionality in such analyses. These results show that HUs (and related habitats and biotopes) are both richer and more variable than a repeated sequence of units. The number of HUs inundated increases linearly with flow stage categories, indicating the importance of high within‐bank flows in maintaining and activating HUs. Aggregated HUs (AHUs) associated with similar geomorphic units are highly connected, both with respect to patterns of spatial adjacency and potential connectivity at similar flow levels. Spectral graph theory metrics applied to a graph representation of spatial adjacency shows a highly complex network with a high potential for rapid propagation of changes—and even more so for a graph based on flow connectivity. The flow connectivity graph shows far higher synchronization as indicated by algebraic connectivity. Thus suggests more rapid and coherent changes for processes driven by river flow, as opposed to phenomena driven by other factors between flow events. These findings have important implications for understanding relationships between geodiversity and habitat diversity, managing habitat and biodiversity, and linking the latter to instream flows. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Development of a unified oil droplet size distribution model with application to surface breaking waves and subsea blowout releases considering dispersant effects     

Zhengkai Li  Malcolm Spaulding  Deborah French McCay  Deborah Crowley  James R. Payne 《Marine pollution bulletin》2017,114(1):247-257

An oil droplet size model was developed for a variety of turbulent conditions based on non-dimensional analysis of disruptive and restorative forces, which is applicable to oil droplet formation under both surface breaking-wave and subsurface-blowout conditions, with or without dispersant application. This new model was calibrated and successfully validated with droplet size data obtained from controlled laboratory studies of dispersant-treated and non-treated oil in subsea dispersant tank tests and field surveys, including the Deep Spill experimental release and the Deepwater Horizon blowout oil spill. This model is an advancement over prior models, as it explicitly addresses the effects of the dispersed phase viscosity, resulting from dispersant application and constrains the maximum stable droplet size based on Rayleigh-Taylor instability that is invoked for a release from a large aperture.  相似文献   

Rock slope failure in a recently deglaciated permafrost rock wall at Piz Kesch (Eastern Swiss Alps), February 2014          下载免费PDF全文

Marcia Phillips  Andrea Wolter  Rachel Lüthi  Florian Amann  Robert Kenner  Yves Bühler 《地球表面变化过程与地形》2017,42(3):426-438

In February 2014, a rock pillar with a volume of around 150 000  m³ collapsed at Piz Kesch in the Eastern Swiss Alps. A reconstruction of the conditions prior to the event and of the event itself is presented on the basis of different sources of data. The methods applied include photogrammetry, terrestrial laser scanning, structural geological analysis, examination of meteorological data, carbon‐14 (¹⁴C) dating of organic material in permafrost ice from a tension crack and numerical modelling of likely modes of failure. Despite a complete lack of in situ measurements in the rock wall prior to the event and of direct observations during the event, the available data allow the determination of the approximate timing of the event as well as the structural predisposition, the probable mode of failure and the timescale of several millennia involved in the triggering of the failure of the rock pillar. The interdisciplinary analysis of this event contributes towards understanding the complex interaction of processes involved in large rock slope failures currently occurring in warming mountain permafrost regions. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Soil redistribution and pedologic transformations in coastal plain croplands     

Jonathan D. Phillips  Heather Golden  Karen Cappiella  Bain Andrews  Tamara Middleton  David Downer  Deonna Kelli  Lee Padrick 《地球表面变化过程与地形》1999,24(1):23-39

In agricultural basins of the southeastern coastal plain there are typically large disparities between upland soil erosion and sediment delivered to streams. This suggests that colluvial storage and redistribution of eroded soil within croplands is occurring, and/or that processes other than fluvial erosion are at work. This study used soil morphology and stratigraphy as an indicator of erosion and deposition processes in a watershed at Littlefield, North Carolina. Soil stratigraphy and morphology reflect the ways in which mass fluxes associated with cultivation transform the local soils. Fluvial, aeolian and tillage processes were all found to be active in the redistribution of soil. The soil transformations are of five general types. First, erosion and compaction in the cultivated area as a whole result in the thinning of Arenic and Grossarenic Paleudults and Paleaquults to form Arenic, Typic and Aquic Paleudults and Paleaquults. Second, redistribution of surficial material within the fields results in transitions between Arenic and Typic or Aquic subgroups as loamy sand A and E horizons are truncated or accreted. Third, aeolian deposition at forested field boundaries leads to the formation of compound soils with podzolized features. Fourth, sandy rill fan deposits at slope bases create cumulic soils distinct from the loamy sands of the source area or the darker, finer terrace soils buried by the fan deposits. Finally, tillage and fluvial deposition in upland depressions results in the gradual burial of Rains (poorly drained Typic Paleaquults) soils. Results confirm the importance of upland sediment storage and redistribution, and the role of tillage and aeolian processes as well as fluvial processes in the region. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Post‐tectonic clastic dykes in the Dalradian of Scotland and Ireland: implications for delayed lithification and deformation of sediments     

C. A. Phillips  G. I. Alsop 《Geological Journal》2000,35(2):99-110

Structures associated with soft‐sediment deformation are preserved in the Neoproterozoic Dalradian Supergroup of SW Scotland and NW Ireland. Clastic dykes display a range of age relationships to regional Caledonian D₁ folds and fabrics from pre‐tectonic to hitherto unrecognized post‐tectonic. Evidence for the post‐D₁ timing of some dykes includes the emplacement of centimetre‐scale injections along regional S₁ cleavage, the disorientation and transport of cleaved wall‐rock clasts within larger dykes, and clastic dykes which markedly cross‐cut and transect F₁ fold hinges and axial planes. Collectively, these observations are compatible with the earliest regional (D₁) structures deforming a sequence which contained locally overpressured and unlithified pockets of sediment. These critical relationships indicate that overpressured pockets of unlithified sediment were possibly retained within the Dalradian for significant periods of time spanning at least 120 Ma given existing isotopic constraints. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献