A Biogeochemical View of Estuarine Eutrophication: Seasonal and Spatial Trends and Correlations in the Delaware Estuary     

Jonathan H. Sharp  Kohei Yoshiyama  Alexander E. Parker  Matthew C. Schwartz  Susan E. Curless  Allison Y. Beauregard  Justin E. Ossolinski  Allen R. Davis 《Estuaries and Coasts》2009,32(6):1023-1043

The Delaware River and Bay Estuary is one of the major urbanized estuaries of the world. The 100-km long tidal river portion of the estuary suffered from major summer hypoxia in the past due to municipal and industrial inputs in the urban region; the estuary has seen remarkable water quality improvements from recent municipal sewage treatment upgrades. However, the estuary still has extremely high nutrient loading, which appears to not have much adverse impact. Since the biogeochemistry of the estuary has been relatively similar for the past two decades, our multiple year research database is used in this review paper to address broad spatial and seasonal patterns of conditions in the tidal river and 120 km long saline bay. Dissolved oxygen concentrations show impact from allochthonous urban inputs and meteorological forcing as well as biological influences. Nutrient concentrations, although high, do not stimulate excessive algal biomass due to light and multiple nutrient element limitations. Since the bay does not have strong persistent summer stratification, there is little potential for bottom water hypoxia. Elevated chlorophyll concentrations do not exert much influence on light attenuation since resuspended bottom inorganic sediments dominate the turbidity. Dissolved inorganic carbon and dissolved and particulate organic carbon distributions show significant variability from watershed inputs and lesser impact from urban inputs and biological processes. Ratios of dissolved and particulate carbon, nitrogen, and phosphorus help to understand watershed and urban inputs as well as autochthonous biological influences. Owing to the relatively simple geometry of the system and localized anthropogenic inputs as well as a broad spatial and seasonal database, it is possible to develop these biogeochemical trends and correlations for the Delaware Estuary. We suggest that this biogeochemical perspective allows a revised evaluation of estuarine eutrophication that should have generic value for understanding other estuarine and coastal waters.  相似文献   

On the occurrence,trace element geochemistry,and crystallization history of zircon from in situ ocean lithosphere   总被引：10，自引：2，他引：8  

Craig B. Grimes  Barbara E. John  Michael J. Cheadle  Frank K. Mazdab  Joseph L. Wooden  Susan Swapp  Joshua J. Schwartz 《Contributions to Mineralogy and Petrology》2009,158(6):757-783

We characterize the textural and geochemical features of ocean crustal zircon recovered from plagiogranite, evolved gabbro, and metamorphosed ultramafic host-rocks collected along present-day slow and ultraslow spreading mid-ocean ridges (MORs). The geochemistry of 267 zircon grains was measured by sensitive high-resolution ion microprobe-reverse geometry at the USGS-Stanford Ion Microprobe facility. Three types of zircon are recognized based on texture and geochemistry. Most ocean crustal zircons resemble young magmatic zircon from other crustal settings, occurring as pristine, colorless euhedral (Type 1) or subhedral to anhedral (Type 2) grains. In these grains, Hf and most trace elements vary systematically with Ti, typically becoming enriched with falling Ti-in-zircon temperature. Ti-in-zircon temperatures range from 1,040 to 660°C (corrected for a _TiO2 ≈ 0.7, a _SiO2 ≈ 1.0, pressure ≈ 2 kbar); intra-sample variation is typically ~60–150°C. Decreasing Ti correlates with enrichment in Hf to ~2 wt%, while additional Hf-enrichment occurs at relatively constant temperature. Trends between Ti and U, Y, REE, and Eu/Eu* exhibit a similar inflection, which may denote the onset of eutectic crystallization; the inflection is well-defined by zircons from plagiogranite and implies solidus temperatures of ~680–740°C. A third type of zircon is defined as being porous and colored with chaotic CL zoning, and occurs in ~25% of rock samples studied. These features, along with high measured La, Cl, S, Ca, and Fe, and low (Sm/La)_N ratios are suggestive of interaction with aqueous fluids. Non-porous, luminescent CL overgrowth rims on porous grains record uniform temperatures averaging 615 ± 26°C (2SD, n = 7), implying zircon formation below the wet-granite solidus and under water-saturated conditions. Zircon geochemistry reflects, in part, source region; elevated HREE coupled with low U concentrations allow effective discrimination of ~80% of zircon formed at modern MORs from zircon in continental crust. The geochemistry and textural observations reported here serve as an important database for comparison with detrital, xenocrystic, and metamorphosed mafic rock-hosted zircon populations to evaluate provenance.  相似文献   

Automated calibration applied to watershed‐scale flow simulations     

Zhongbo Yu  Franklin W. Schwartz 《水文研究》1999,13(2):191-209

Complexity in simulating the hydrological response in large watersheds over long times has prompted a significant need for procedures for automatic calibration. Such a procedure is implemented in the basin‐scale hydrological model (BSHM), a physically based distributed parameter watershed model. BSHM simulates the most important basin‐scale hydrological processes, such as overland flow, groundwater flow and stream–aquifer interaction in watersheds. Here, the emphasis is on estimating the groundwater parameters with water levels in wells and groundwater baseflows selected as the calibration targets. The best set of parameters is selected from within plausible ranges of parameters by adjusting the values of hydraulic conductivity, storativity, groundwater recharge and stream bed permeability. The baseflow is determined from stream flow hydrographs by using an empirical scheme validated using a chemical approach to hydrograph separation. Field studies determined that the specific conductance for components of the composite hydrograph were sufficiently unique to make the chemical approach feasible. The method was applied to the Big Darby Creek Watershed, Ohio. The parameter set selected for the groundwater system provides a good fit with the estimated baseflow and observed water well data. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Relationships between physical‐geochemical soil properties and erodibility of streambanks among different physiographic provinces of Tennessee,USA          下载免费PDF全文

Badal Mahalder  John S. Schwartz  Angelica M. Palomino  Jon Zirkle 《地球表面变化过程与地形》2018,43(2):401-416

Erosion of cohesive soils in fluvial environments is dependent on physical, geochemical and biological properties, which govern inter‐particle attraction forces and control detachment rates from stream beds and banks. Most erosion rate models are based on the excess shear stress equation where the soil erodibility coefficient (k_d) is multiplied by the difference between the boundary hydraulic shear stress (τ_b) and the soil critical shear stress (τ_c). Both k_d and τ_c are a function of soil properties and must be obtained through in situ field or laboratory testing. Many studies have generated predictive relationships for k_d and τ_c derived from various soil properties. These studies typically were conducted in watersheds within a single physiographic region with a common surficial geology and/or investigated a limited number of soil properties, particularly geochemical properties. With widely reported differences in relationships between τ_c and soil properties, this study investigated differences in predictive relationships for τ_c among different physiographic provinces in Tennessee, USA. Erodibility parameters were determined in the field using a mini‐jet test device. Among these provinces, statistically four unique clusters were identified from a dataset of 128 observations and these data clusters were used to develop predictive models for τ_c to identify dominant properties governing erosion. In these clusters, 16 significant physical and geochemical soil properties were identified for τ_c prediction. Among these soil properties, water content and passing #200 sieve (percentage soil less than 75 μm) were the dominant controlling parameters to predict τ_c in addition to clay percentage (< 2 μm), bulk density, and soil pore water chemistry. This study suggests that unique relationships exist for physiographic provinces that are likely due to soil physical‐geochemical processes associated with surficial geology that determine minerology of the cohesive soil. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Evaluating the spatial distribution of water balance in a small watershed,Pennsylvania     

Zhongbo Yu  W. J. Gburek  F. W. Schwartz 《水文研究》2000,14(5):941-956

A conceptual water‐balance model was modified from a point application to be distributed for evaluating the spatial distribution of watershed water balance based on daily precipitation, temperature and other hydrological parameters. The model was calibrated by comparing simulated daily variation in soil moisture with field observed data and results of another model that simulates the vertical soil moisture flow by numerically solving Richards' equation. The impacts of soil and land use on the hydrological components of the water balance, such as evapotranspiration, soil moisture deficit, runoff and subsurface drainage, were evaluated with the calibrated model in this study. Given the same meteorological conditions and land use, the soil moisture deficit, evapotranspiration and surface runoff increase, and subsurface drainage decreases, as the available water capacity of soil increases. Among various land uses, alfalfa produced high soil moisture deficit and evapotranspiration and lower surface runoff and subsurface drainage, whereas soybeans produced an opposite trend. The simulated distribution of various hydrological components shows the combined effect of soil and land use. Simulated hydrological components compare well with observed data. The study demonstrated that the distributed water balance approach is efficient and has advantages over the use of single average value of hydrological variables and the application at a single point in the traditional practice. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

Gamma-Ray Line Observations of the 2000 July 14 Flare and SEP Impact on the Earth     

Share  G.H.  Murphy  R.J.  Tylka  A.J.  Schwartz  R.A.  Yoshimori  M.  Suga  K.  Nakayama  S.  Takeda  H. 《Solar physics》2001,204(1-2):41-53

The HXS and GRS detectors on Yohkoh observed the 14 July 2000, X5.7 flare, beginning at ∼ 10:20 UT, ∼ 4 min before the peak in soft X-rays. The hard X-rays and γ-rays peaked ∼ 3 min later at ∼ 10:27 UT. Solar γ-ray emission lasted until ∼ 10:40 UT. Impact of high-energy ions at the Sun is revealed by the γ-ray lines from neutron capture, annihilation radiation and de-excitation that are visible above the bremsstrahlung continuum. From measurement of these lines we find that the flare-averaged spectrum of accelerated protons is consistent with a power law ge10 MeV with index 3.14±0.15 and flux 1.1×10³² protons MeV⁻¹ at 10 MeV. We estimate that there were ∼1.5×10³⁰ erg in accelerated ions if the power law extended without a break down to 1 MeV; this is about 1% of the energy in electrons > 20 keV from measurements of the hard X-rays. We find no evidence for spectral hardening in the hard X-rays that has been suggested as a predictor for the occurrence of solar energetic particle (SEP) events. This was the third largest proton event above 10 MeV since 1976. The GRS and HXS also observed γ-ray lines and continuum produced by the impact of SEP on the Earth's atmosphere beginning about 13 UT on 14 July. These measurements show that the SEP spectrum softened considerably over the next 24 hours. We compare these measurements with proton measurements in space.  相似文献   

Radio emission of galactic clusters at 1.4 GHz and 2.7 GHz     

R. Schwartz 《Astrophysics and Space Science》1971,14(2):286-300

41 galactic clusters containing stars with spectral types from O5 to B9 have been observed at frequencies of 1.4 GHz and 2.7 GHz. Only clusters with spectral types earlier than B1 show thermal radio emission. Emission measure, mean electron density, and mass ofHii gas have been computed from the observed data, and a comparison between the radio flux and H- and H-flux densities has been made. The ratio of hydrogen mass and total stellar mass of the clusters and the gas to dust ratio are given.  相似文献   

The 1986 Kermadec earthquake and its relation to plate segmentation     

Heidi Houston  Helen Anderson  Susan L. Beck  Jiajun Zhang  Susan Schwartz 《Pure and Applied Geophysics》1993,140(2):331-364

To evaluate the tectonic significance of the October 20, 1986 Kermadec earthquake (M _w =7.7), we performed a comprehensive analysis of source parameters using surface waves, body waves, and relocated aftershocks. Amplitude and phase spectra from up to 93 Rayleigh waves were inverted for centroid time, depth, and moment tensor in a two-step algorithm. In some of the inversions, the time function was parameterized to include information from the body-wave time function. The resulting source parameters were stable with respect to variations in the velocity and attenuation models assumed, the parameterization of the time function, and the set of Rayleigh waves included. The surface wave focal mechanism derived (=275°, =61°, =156°) is an oblique-compressional mechanism that is not easy to interpret in terms of subduction tectonics. A seismic moment of 4.5×10²⁰ N-m, a centroid depth of 45±5 km, and a centroid time of 13±3 s were obtained. Directivity was not resolvable from the surface waves. The short source duration is in significant contrast to many large earthquakes.We performed a simultaneous inversion ofP andSH body waves for focal mechanism and time function. The focal mechanism agreed roughly with the surface wave mechanism. Multiple focal mechanisms remain a possibility, but could not be resolved. The body waves indicate a short duration of slip (15 to 20 s), with secondary moment release 60s later. Seismically radiated energy was computed from the body-wave source spectrum. The stress drop computed from the seismic energy is about 30 bars. Sixty aftershocks that occurred within three months of the mainshock were relocated using the method of Joint Hypocentral Determination (JHD). Most of the aftershocks have underthrusting focal mechanisms and appear to represent triggered slip on the main thrust interface. The depth, relatively high stress drop, short duration of slip, and paucity of true aftershocks are consistent with intraplate faulting within the downgoing plate. Although it is not clear on which nodal plane slip occurred, several factors favor the roughly E-W trending plane. The event occurred near a major segmentation in the downgoing plate at depth, near a bend in the trench, and near a right-lateral offset of the volcanic are by 80 km along an E-W direction. Also, all events in the region from 1977 to 1991 with CMT focal mechanisms similar to that of the Mainshock occurred near the mainshock epicenter, rather than forming an elongate zone parallel to the trench as did the aftershock activity. We interpret this event as part of the process of segmentation or tearing of the subducting slab. This segmentation appears to be related to the subduction of the Louisville Ridge, which may act as an obstacle to subduction through its buoyancy.  相似文献   

Coring artifacts and contaminant inventories in lake sediment     

M. Stephenson  J. Klaverkamp  M. Motycka  C. Baron  W. Schwartz 《Journal of Paleolimnology》1996,15(1):99-106

Sediments of Lake 382, Experimental Lakes Area, Canada, were sampled at six sites using a 5-cm Wildco KB core sampler (KB), a similar device incorporating a ball check valve (BC), and a 0.2 m by 1.2 m flat-faced aluminum freeze core sampler (FC). Cores were sectioned at 1-cm intervals to a depth of 15 cm. Contaminant (²¹⁰Pb and ¹³⁷Cs) concentrations (Bq g^-1) were measured by gamma spectroscopy, and inventories (Bq cm^-2) were calculated following standard methods. Sediments collected using FC, BC and KB had similar contaminant concentrations, however, cores collected by FC and BC had lower estimated inventories than KB cores. Differences between estimates appear to be caused by differences in the water content (WC) of core material. Laboratory studies confirm that FC sediments have higher WC than tube-cored sediment. We hypothesize that ice crystal formation increases the WC of freeze cores, resulting in lower contaminant inventories. Loss of surficial sediment caused by a bow wave may have a similar effect on BC samples. We conclude that KB core gear is appropriate for sampling sediments to measure contaminant concentrations and inventories in recently deposited sediments.  相似文献   

A note on the Jewish population of the USSR from the 1989 census data     

Schwartz L 《Soviet geography》1991,32(6):433-435

This note provides additional, more detailed information on the composition and spatial distribution of the Jewish population of the USSR in 1989. It supplements the author's previous study on the nationality distribution in the USSR.  相似文献