Water in garnet of garnetite (metarodingite) and eclogite from the Erzgebirge and the Lepontine Alps     

Esther Schmädicke  Jürgen Gose 《Journal of Metamorphic Geology》2020,38(9):905-933

Little is known about water in nominally anhydrous minerals of orogenic garnet peridotite and enclosed metabasic rocks. This study is focused on peridotite-hosted eclogite and garnetite (metarodingite) from the Erzgebirge (EG), Germany, and the Lepontine Alps (LA), Switzerland. Newly discovered, peridotite-hosted eclogite in the Erzgebirge occurs in the same ultra-high pressure (UHP) unit as gneiss-hosted coesite eclogite, from which it is petrologically indistinguishable. Garnet is present in all mafic and ultramafic high pressure (HP) rocks providing for an ideal proxy to compare the H₂O content of the different rock types. Garnet composition is very similar in EG and LA samples and depends on the rock type. Garnet from garnetite, compared to eclogite, contains more CaO (garnetite: 10.5–16.5 wt%; eclogite: 5–11 wt%) and is also characterized by an anomalous REE distribution. In contrast, the infrared (IR) spectra of garnet from both rock types reveal the same OH absorption bands that are also identical to those of previously studied peridotitic garnet from the same locations. Two groups of IR bands, SW I (3,650 ± 10 cm⁻¹) and SW II (3,570–3,630 cm⁻¹) are ascribed to structural hydroxyl (colloquially ‘water’). A third, broad band is present in about half of the analysed garnet domains and related to molecular water (MW) in submicroscopic fluid inclusions. The primary content of structural H₂O, preserved in garnet domains without fluid inclusions (and MW bands), varies systematically—depending on both the location and the rock type. Garnet from EG rocks contains more water compared to LA samples, and garnet from garnetite (EG: 121–241 wt.ppm H₂O; LA: 23–46 wt.ppm) hosts more water than eclogitic garnet (EG: 84 wt.ppm; LA: 4–11 wt.ppm). Higher contents of structural water (SW) are observed in domains with molecular water, in which the SW II band (being not restricted to HP conditions) is simultaneously enhanced. This implies that fluid influx during decompression not only led to fluid inclusions but also favoured the uptake of secondary SW. The results signify that garnet from all EG and LA samples was originally H₂O-undersaturated. Combining the data from eclogite, garnetite and previously studied peridotite, H₂O and CaO are positively correlated, pointing to the same degree of H₂O-undersaturation at peak metamorphism in all rock types. This ubiquitous water-deficiency cannot be reconciled with the derivation of any of these rocks from the lowermost part of the mantle wedge that was in contact with the subducting plate. This agrees with the previously inferred abyssal origin for part of the rocks from the LA (Cima di Gagnone). A similar origin has to be invoked for the Erzgebirge UHP unit. We suggest that all mafic and ultramafic rocks of this unit not only shared the same metamorphic evolution but also a common protolith origin, most probably on the ocean floor. This inference is supported by the presence of peridotite-hosted garnetite, representing metamorphosed rodingite.  相似文献   

Evaluation of the removal of heavy metals in a natural wetland impacted by mining activities in Mexico     

Juan Miguel Gómez-Bernal  Esther Aurora Ruiz-Huerta  María Aurora Armienta-Hernández  Víctor Manuel Luna-Pabello 《Environmental Earth Sciences》2017,76(23):801

This research is focused on evaluating heavy metals (Cd, Cu, Fe, Mn, Pb, and Zn) uptake and removal by Eleocharis ovata, Cyperus manimae, Typha dominguensis, and Pteridium aquilinum in a natural wetland impacted by mining activities. We analyzed heavy metals content and distribution in native plants, soils, and water of a semipermanent natural wetland in Taxco de Alarcón, Guerrero, and we also determined the physicochemical characteristics of the water. Translocation factor (TF) and bioconcentration factor (BCF) were evaluated. Results showed that physical and chemical conditions are favorable for plants development. Correlation analysis showed a good and positive relation (0.95) between Cu and Pb in soils and plants. In the analyzed matrices: Zn (0.62–2.20 mg/L) exceeded the permissible limits in water, high concentrations of Pb and Zn (26.57–525.67 and 266.67–983.33 mg/kg, respectively) were detected in the studied soils, and Pb exceeded the normal range for E. ovata and P. aquilinum in the analyzed plants. Uptake of heavy metals in the tissues of different species was found in the following order: root > leaf. Data of TF and BCF showed that E. ovata is a tolerant plant with respect to heavy metals exposure since TF value was greater than 1. This study showed that E. ovata could be considered as a bioaccumulator of heavy metals in contaminated soils.  相似文献   

Dynamic of Sea Water Interface using Hydrochemical Facies Evolution Diagram     

Elena Giménez-Forcada 《Ground water》2010,48(2):212-216

This paper analyzes the results of a theoretical simulation of sea water intrusion and its dynamics. The assignment of hydrochemical facies identifies whether the aquifer is in the phase of sea water intrusion or freshening, indicating the status of the aquifer in terms of the advance or regression of the saline front. A new multi-rectangular diagram is proposed that aids interpretation of these important processes through the representation and evolution of hydrochemical facies (hydrochemical facies evolution diagram, HFE-D). As an example, the HEF-D is applied to an alluvial aquifer in the Vinaroz-Peñíscola Plain (Spain), where Ca-Cl facies characterize the sea water intrusion phase, while Na-MixHCO₃/MixSO₄ facies characterize a freshening stage.  相似文献   

Understanding and managing the morphology of branches incising into sand-clay deposits in the Dutch Rhine Delta     

Kees SLOFF  Ary VAN SPIJK  Esther STOUTHAMER  Arjan SIEBEN 《国际泥沙研究》2013,28(2):127-138

In the Rhine-Meuse delta in the south-western part of the Netherlands,the morphology of the river branches is highly dependent on the erodibility of the subsoil.Erosion processes that were initiated after closure of the Haringvliet estuary branch by a dam(in 1970),caused a strong incision of several connecting branches.Due to the geological evolution of this area the lithology of the subsoil shows large variations in highly erodible sand and poorly erodible peat and clay layers.This study shows how the geological information can be used to create 3D maps of the erodibility of the sub-soil, and how this information can be used to schematize the sub-soil in computational models for morphological simulations.Local incisement of sand patches between areas with poorly erodible bed causes deep scour holes,hence increasing the risk on river-bank instability(flow slides) and damage to constructions such as groynes,quays,tunnels, and pipelines.Various types of mathematical models,ranging from 1D(SOBEK) to quasi-3D(Delft3D) have been applied to study the future development of the river bed and possible management options.The results of these approaches demonstrate that models require inclusion of a layer-bookkeeping approach for sub-soil schematization, non-uniform sediment fractions(sand-mud),tidal and river-discharge boundary conditions,and capacity-reduction transport modeling.For risk-reducing river management it has been shown how the development of the river bed can be addressed on a large scale and small scale.For instance,the use of sediment feeding and fixation of bed can be proposed for large-scale management,while monitoring and interventions at initiation of erosion can be proposed as response to small-scale developments that exceed predefined intervention levels.  相似文献   

Crustal structure and tectonic setting of the south central Andes from gravimetric analysis     

Cecilia Weidmann  Silvana Spagnotto  Orlando Álvarez  Marcos Sánchez  Federico Lince Klinger  Mario Giménez  Patricia Martínez 《Geofísica Internacional》2013,52(3):197-208

Based on terrestrial gravity data, in this paper we prepared a map of Bouguer anomalies, which was filtered to separate shallow and deep gravity sources. Based on a density model and gravimetric inversion techniques, the discontinuous crust-mantle boundary and the top of crystalline basement were modeled. Subsequently, the equivalent elastic thickness (Te) was evaluated, considering information from the crust-mantle discontinuity and topographic load, finding high Te values in the eastern Andean foothills and west of the Velasco range. These results are consistent with the positive isostatic and residual Bouguer anomaly values, which suggest the presence of high-density rocks in the mid-to upper crust. In addition, petrographic and geochemical analysis conducted in surface outcrops suggest a mantle origin.  相似文献   

Magnetic and structural study of the Eaux-Chaudes intrusion: understanding the Variscan deformation in the Western Axial Zone (Pyrenees)     

Esther Izquierdo-Llavall  Teresa Román-Berdiel  Antonio M. Casas  Belén Oliva-Urcia  Inmaculada Gil-Pe?a  Ruth Soto  Antonio Jabaloy 《International Journal of Earth Sciences》2012,101(7):1817-1834

The present study provides new magnetic and microstructural data for the Eaux-Chaudes granodioritic massif (Western Axial Zone, Pyrenees) and contributes to the understanding of its geometry, internal structure and emplacement mechanism. Moreover, the geological cross-sections and field data allow to reconstruct the evolution of the whole area from Variscan to Alpine times and to integrate the emplacement of the igneous body in the context of the Variscan orogeny. The Eaux-Chaudes pluton (301?±?9?Ma) is mainly composed by granodiorite, describing a normal compositional zoning and an approximately concentric arrangement that is consistent with the zonation of the low-field magnetic susceptibility. Magnetic foliation is subhorizontal in the inner part of the intrusion and becomes parallel to the petrographical contacts along pluton margins, roughly describing the geometry of the intrusion. Magnetic lineations are dominantly subhorizontal, with E–W to ENE–WSW directional maximum. The general parallelism between Variscan structures of the host rock and the geometry and magmatic fabric of the intrusion reveals a late syn-Variscan emplacement. The tectonic regime registered during magma emplacement is in agreement with an N–S shortening and an E–W stretching direction, consistent with the transpressive regime deduced for other Pyrenean intrusions. Alpine overprint produced a slight tilting in the southern part of the intrusion, but it can be considered that the original Variscan structure is basically unchanged.  相似文献   

Text, talk, things, and the subpolitics of performing place   总被引：1，自引：0，他引：1  

Marleen Buizer  Esther Turnhout 《Geoforum》2011,42(5):530-538

This article tells the story of how a group of Dutch and Belgian citizens organized themselves to promote an area that they valued, to put it on the map, to raise awareness about its qualities, and to protect it from urban and industrial development. Our theoretical perspective focuses on the performative and political aspects of this place-making process and the discursive and material practices involved. We connect this to Beck’s concept of subpolitics.Our findings show how the group performed this place not only through text and talk - giving the area a name, using their knowledge and expertise to raise awareness about its values, lobbying and cooperating with decision-makers -, but also through things - installing art objects and information signs that articulate certain characteristics and values of the area. Our findings demonstrate the struggles involved in these performances. The group involved multiple perspectives on what the important values and characteristics of the area are and on what strategies would work best in trying to influence decision-making and protect the area. However, the use of expertise as the main strategy to gain influence excluded the more critical and activist strategies and privileging archaeological and historical values and characteristics came at the expense of attention on agricultural and natural values.Our findings make clear that performing place cannot be taken to be homogeneous and that it inevitably involves multiple perspectives and demands. The struggles, power relations and dynamics of inclusion and exclusion that this multiplicity implicates reveal a form of sub-politics that involves both politicization and depoliticization. Also, it is a form of subpolitics that is more diverse and ambiguous than Beck’s conceptualization presupposes by its emphasis on the role of outsiders as a homogeneous group.  相似文献   

A Burst with Double Radio Spectrum Observed up to 212 GHz     

C. G. Giménez de Castro  G. D. Cristiani  P. J. A. Simões  C. H. Mandrini  E. Correia  P. Kaufmann 《Solar physics》2013,284(2):541-558

We study a solar flare that occurred on 10 September 2002, in active region NOAA 10105, starting around 14:52 UT and lasting approximately 5 minutes in the radio range. The event was classified as M2.9 in X-rays and 1N in Hα. Solar Submillimeter Telescope observations, in addition to microwave data, give a good spectral coverage between 1.415 and 212 GHz. We combine these data with ultraviolet images, hard and soft X-ray observations, and full-disk magnetograms. Images obtained from Ramaty High Energy Solar Spectroscopic Imager data are used to identify the locations of X-ray sources at different energies, and to determine the X-ray spectrum, while ultraviolet images allow us to characterize the coronal flaring region. The magnetic field evolution of the active region is analyzed using Michelson Doppler Imager magnetograms. The burst is detected at all available radio frequencies. X-ray images (between 12 keV and 300 keV) reveal two compact sources. In the 212 GHz data, which are used to estimate the radio-source position, a single compact source is seen, displaced by 25″ from one of the hard X-ray footpoints. We model the radio spectra using two homogeneous sources, and we combine this analysis with that of hard X-rays to understand the dynamics of the accelerated particles. Relativistic particles, observed at radio wavelengths above 50 GHz, have an electron index evolving with the typical soft–hard–soft behavior.  相似文献   

Unusual exsolution phenomena in omphacite and partial replacement of phengite by phlogopite + kyanite in an eclogite from the Erzgebirge   总被引：4，自引：0，他引：4  

Esther Schmädicke  Wolfgang Friedrich Müller 《Contributions to Mineralogy and Petrology》2000,139(6):629-642

In the Erzgebirge Crystalline Complex, eclogites occur in three different high pressure (HP) units (1, 2 and 3) recording contrasting pressure (P)–temperature (T) conditions. Eclogites from HP-unit 1 experienced peak metamorphic conditions in the coesite stability field at about 33 kbar/850 °C. Commonly, these eclogites from HP-unit 1 are all very similar, with an eclogitic peak assemblage of omphacite–garnet–coesite–K-feldspar, rarely accompanied by kyanite, and omphacites systematically deviating from a stoichiometric composition. In contrast, an eclogite recently found near Blumenau, is mineralogically and geochemically different from the typical eclogites of HP-unit 1. This unusual eclogite reveals the eclogitic equilibrium assemblage omphacite–garnet–coesite–phengite–phlogopite–kyanite, and yields metamorphic peak conditions of 870 °C and >29 kbar. There is clear textural evidence of the formation of phlogopite and kyanite under partial consumption of phengite and garnet. Moreover, the omphacite is stoichiometric and contains abundant exsolution lamellae, the thickest of which were identified as quartz by the electron microprobe. The finer lamellae were studied by transmission electron microscopy (TEM). Oligoclase was identified as an exsolution phase. Other lamellae proved to consist of K-white mica, also interpreted as exsolution. Prior to exsolution, the omphacite composition must have been cation-deficient, as that of the other, common HP-unit 1 eclogites. These non-stoichiometric compositions are ascribed to partial substitution by the Ca-Eskola pyroxene component, which calculates to an average of 8 mol% for omphacite in HP-unit 1 eclogites. According to experiments, this substitution becomes significant at P > 30 kbar. Exsolution of K-white mica may indicate hydroxyl defects in the original omphacite, also favoured by high pressure. Oligoclase and K-white mica exsolution from Ca-Eskola-rich clinopyroxene has not previously been reported. The omphacite has a disordered C2/c structure; and in just one case very small (a few tens of nanometres) antiphase domains, resulting from the C2/c to P2/n transformation, are present. These features may indicate a brief thermal history and rapid tectonic processes. Received: 4 January 1999 / Accepted: 20 April 2000  相似文献   

Spectral Trends of Solar Bursts at Sub-THz Frequencies     

L. O. T. Fernandes  P. Kaufmann  E. Correia  C. G. Giménez de Castro  A. S. Kudaka  A. Marun  P. Pereyra  J.-P. Raulin  A. B. M. Valio 《Solar physics》2017,292(1):21

Previous sub-THz studies were derived from single-event observations. We here analyze for the first time spectral trends for a larger collection of sub-THz bursts. The collection consists of a set of 16 moderate to small impulsive solar radio bursts observed at 0.2 and 0.4 THz by the Solar Submillimeter-wave Telescope (SST) in 2012?–?2014 at El Leoncito, in the Argentinean Andes. The peak burst spectra included data from new solar patrol radio telescopes (45 and 90 GHz), and were completed with microwave data obtained by the Radio Solar Telescope Network, when available. We critically evaluate errors and uncertainties in sub-THz flux estimates caused by calibration techniques and the corrections for atmospheric transmission, and introduce a new method to obtain a uniform flux scale criterion for all events. The sub-THz bursts were searched during reported GOES soft X-ray events of class C or larger, for periods common to SST observations. Seven out of 16 events exhibit spectral maxima in the range 5?–?40 GHz with fluxes decaying at sub-THz frequencies (three of them associated to GOES class X, and four to class M). Nine out of 16 events exhibited the sub-THz spectral component. In five of these events, the sub-THz emission fluxes increased with a separate frequency from that of the microwave spectral component (two classified as X and three as M), and four events have only been detected at sub-THz frequencies (three classified as M and one as C). The results suggest that the THz component might be present throughout, with the minimum turnover frequency increasing as a function of the energy of the emitting electrons. The peculiar nature of many sub-THz burst events requires further investigations of bursts that are examined from SST observations alone to better understand these phenomena.  相似文献