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1.
Garnet-rich rocks occur throughout the Proterozoic southern Curnamona Province, Australia, where they are, in places, spatially related to Broken Hill-type Pb-Zn-Ag deposits. Fine-scale bedding in these rocks, their conformable relationship with enclosing metasedimentary rocks, and their enrichment in Mn and Fe suggest that they are metamorphosed chemical precipitates. They formed on the floor of a 1.69?Ga continental rift basin from hydrothermal fluids mixed with seawater and detritus. Garnet in garnet-quartz and garnet-amphibole rocks is generally light rare earth element (LREE) depleted, and has flat heavy REE (HREE) enriched chondrite-normalized REE patterns, and negative Eu anomalies (Eu/Eu*?<?1). Garnet in garnet-rich rocks from the giant Broken Hill deposit has similar REE patterns and either positive (Eu/Eu*?>?1) or negative Eu anomalies. Manganese- and Mn-Ca-rich, Fe-poor garnets in garnetite, garnet-hedenbergite, and garnet-cummingtonite rocks at Broken Hill have Eu/Eu*?>?1, whereas garnet in Mn-poor, Fe-rich quartz garnetite and quartz-garnet-gahnite rocks from Broken Hill, and quartz garnetite from other locations have Eu/Eu*?<?1. The REE patterns of garnet and its host rock and interelement correlations among REEs and major element contents in garnet and its host rock indicate that the Eu anomaly in garnet reflects that of its host rock and is related to the major element composition of garnet and its host rock. The value of Eu/Eu* in garnet is related to its Mn, Fe, and Ca content and that of its host rock, and the distribution of REEs among garnet and accessory phases (e.g., feldspar). Positive Eu anomalies reflect high amounts of Eu that was preferentially incorporated into Mn- and Mn-Ca-rich oxides and carbonates in the protolith. In contrast, Eu/Eu*?<?1 indicates the preferential discrimination against Eu by Fe-rich, Mn-poor precursor minerals. Precursors to Mn-rich garnets at Broken Hill formed by precipitation from cooler and more oxidized hydrothermal fluids compared to those that formed precursors to Mn-poor, Fe-rich garnet at Broken Hill and the other locations. Garnet from the Broken Hill deposit is enriched in Zn (> 400?ppm), Cr (> 140?ppm), and Eu (up to 6?ppm and positive Eu anomalies), and depleted in Co, Ti, and Y compared to garnet in garnet-rich rocks from other localities. These values, as well as MnO contents ?>?15 wt. % and Eu/Eu*?>?1 are only found at the Broken Hill deposit and are good indicators of the presence of Broken Hill-type mineralization.  相似文献   

2.
Garnet and omphacite from ultrahigh-pressure eclogites from the Dabie orogen, eastern China were investigated by Micro-FTIR. The results show that all garnet and omphacite grains contain structural water occurring as hydroxyl (OH), with H2O contents varying from 14 to 1915 ppm (H2O wt) and from 105 to 695 ppm, respectively. Within the same sample, the water contents are either homogeneous at the grain scale or vary systematically from higher in the core to lower in the rim. Low water contents at crystal rims possibly result from hydroxyl exsolution after pressure decrease upon rock exhumation. The δD values of omphacites are between −108.4‰ and −114.2‰, and independent of water contents. Heterogeneous water contents of garnet occur at the centimeter scale and fluid mobility during UHP metamorphism was very limited. The estimated whole-rock water content based on mineral H2O contents is between 260 and 750 ppm, thereby implying that eclogitic rocks formed during continental subduction have the potential to recycle (at least) several hundreds ppm water to mantle depths. The preserved chemical differences likely indicate that the eclogitic rocks resided at mantle conditions for a limited time span, and imply that they were exhumed shortly after subduction. The water released during decompression might represent the early-stage retrograde fluid.  相似文献   

3.
Distribution of water among the main rock-forming nominally anhydrous minerals of mantle xenoliths of peridotitic and eclogitic parageneses from the Udachnaya kimberlite pipe, Yakutia, has been studied by IR spectroscopy. The spectra of all minerals exhibit vibrations attributed to hydroxyl structural defects. The content of H2O (ppm) in minerals of peridotites is as follows: 23–75 in olivine, 52–317 in orthopyroxene, 29–126 in clinopyroxene, and 0–95 in garnet. In eclogites, garnet contains up to 833 ppm H2O, and clinopyroxene, up to 1898 ppm (~ 0.19 wt.%). The obtained data and the results of previous studies of minerals of mantle xenoliths show wide variations in H2O contents both within different kimberlite provinces and within the Udachnaya kimberlite pipe. Judging from the volume ratios of mineral phases in the studied xenoliths, the water content varies over narrow ranges of values, 38–126 ppm. At the same time, the water content in the studied eclogite xenoliths is much higher and varies widely, 391–1112 ppm.  相似文献   

4.
By taking advantage of having depth profiles between contrasting lithologies from core samples of the Chinese Continental Scientific Drilling (CCSD) project, a combined study was carried out to examine changes in mineral H isotope, total water and hydroxyl contents in garnet and omphacite across the contacts between ultrahigh-pressure (UHP) eclogite and gneiss in the Sulu orogen, east-central China. The samples of interest were from two continuous core segments from the CCSD main hole at depths of 734.21-737.16 and 929.67-932.86 m, respectively. The results show δD values of −116‰ to  − 64‰ for garnet and −104‰ to −82‰ for omphacite, consistent with incorporation of meteoric water into protoliths of UHP metamorphic rocks by high-T alteration. Both equilibrium and disequilibrium H isotope fractionations were observed between garnet and omphacite, suggesting fluid-assisted H isotope exchange at local scales during amphibolite-facies retrogression. While bulk water analysis gave total H2O concentrations of 522-1584 ppm for garnet and 1170-20745 ppm for omphacite, structural hydroxyl analysis yielded H2O contents of 80-413 ppm for garnet and 228-412 ppm for omphacite. It appears that significant amounts of molecular H2O are present in the minerals, pointing to enhanced capacity of water storage in the UHP eclogite minerals. Hydrogen isotope variations in the transition between eclogite and gneiss show correlations with variations in their water contents. Petrographically, the degree of retrograde metamorphism generally increases with decreasing distance from the eclogite-gneiss boundary. Thus, retrograde metamorphism results in mineral reactions and H isotope variation. Because hydroxyl solubility in nominally anhydrous minerals decreases with dropping pressure, significant amounts of water are expected to be released from the minerals during decompression exhumation. Decompression exsolution of structural hydroxyl from 1 m3 volume of eclogite composed of only garnet and omphacite results in release of a quantitative estimate of 3.07-3.44 kg water that can form 140-156 kg amphibole during exhumation. Therefore, it is concluded that fluid for retrogression of the eclogites away from the eclogite-gneiss boundary was derived from the decompression exsolution of structural hydroxyl and molecular H2O in nominally anhydrous minerals. For the eclogites adjacent to gneiss, in contrast, the retrograde metamorphism was principally caused by aqueous fluid from the gneiss which is relatively rich in water. Consequently, both the origin and availability of metamorphic fluid during exhumation of deeply subducted continental crust are deciphered by this combined study focusing on the transitions and the retrograde processes between the felsic and mafic UHP rocks.  相似文献   

5.
Coesite is typically found as inclusions in rock‐forming or accessory minerals in ultrahigh‐pressure (UHP) metamorphic rocks. Thus, the survival of intergranular coesite in UHP eclogite at Yangkou Bay (Sulu belt, eastern China) is surprising and implies locally “dry” conditions throughout exhumation. The dominant structures in the eclogites at Yangkou are a strong D2 foliation associated with tight‐to‐isoclinal F2 folds that are overprinted by close‐to‐tight F3 folds. The coesite‐bearing eclogites occur as rootless intrafolial isoclinal F1 fold noses wrapped by a composite S1–S2 foliation in interlayered phengite‐bearing quartz‐rich schists. To evaluate controls on the survival of intergranular coesite, we determined the number density of intergranular coesite grains per cm2 in thin section in two samples of coesite eclogite (phengite absent) and three samples of phengite‐bearing coesite eclogite (2–3 vol.% phengite), and measured the amount of water in garnet and omphacite in these samples, and also in two samples of phengite‐bearing quartz eclogite (6–7 vol.% phengite, coesite absent). As coesite decreases in the mode, the amount of primary structural water stored in the whole rock, based on the nominally anhydrous minerals (NAMs), increases from 107/197 ppm H2O in the coesite eclogite to 157–253 ppm H2O in the phengite‐bearing coesite eclogite to 391/444 ppm H2O in the quartz eclogite. In addition, there is molecular water in the NAMs and modal water in phengite. If the primary concentrations reflect differences in water sequestered during the late prograde evolution, the amount of fluid stored in the NAMs at the metamorphic peak was higher outside of the F1 fold noses. During exhumation from UHP conditions, where NAMs became H2O saturated, dehydroxylation would have generated a free fluid phase. Interstitial fluid in a garnet–clinopyroxene matrix at UHP conditions has dihedral angles >60°, so at equilibrium fluid will be trapped in isolated pores. However, outside the F1 fold noses strong D2 deformation likely promoted interconnection of fluid and migration along the developing S2 foliation, enabling conversion of some or all of the intergranular coesite into quartz. By contrast, the eclogite forming the F1 fold noses behaved as independent rigid bodies within the composite S1–S2 foliation of the surrounding phengite‐bearing quartz‐rich schists. Primary structural water concentrations in the coesite eclogite are so low that H2O saturation of the NAMs is unlikely to have occurred. This inherited drier environment in the F1 fold noses was maintained during exhumation by deformation partitioning and strain localization in the schists, and the fold noses remained immune to grain‐scale fluid infiltration from outside allowing coesite to survive. The amount of inherited primary structural water and the effects of strain partitioning are important variables in the survival of coesite during exhumation of deeply subducted continental crust. Evidence of UHP metamorphism may be preserved in similar isolated structural settings in other collisional orogens.  相似文献   

6.
Jadeite‐bearing kyanite eclogite has been discovered in the Iratsu body of the Sanbagawa belt, SW Japan. The jadeite + kyanite assemblage is stable at higher pressure–temperature (P–T) conditions or lower H2O activity [a(H2O)] than paragonite, although paragonite‐bearing eclogite is common in the Sanbagawa belt. The newly discovered eclogite is a massive metagabbro with the peak‐P assemblage garnet + omphacite + jadeite + kyanite + phengite + quartz + rutile. Impure jadeite is exclusively present as inclusions in garnet. The compositional gap between the coexisting omphacite (P2/n) and impure jadeite (C2/c) suggests relatively low metamorphic temperatures of 510–620 °C. Multi‐equilibrium thermobarometry for the assemblage garnet + omphacite + kyanite + phengite + quartz gives peak‐P conditions of ~2.5 GPa, 570 °C. Crystallization of jadeite in the metagabbro is attributed to Na‐ and Al‐rich effective bulk composition due to the persistence of relict Ca‐rich clinopyroxene at the peak‐P stage. By subtracting relict clinopyroxene from the whole‐rock composition, pseudosection modelling satisfactorily reproduces the observed jadeite‐bearing assemblage and mineral compositions at ~2.4–2.5 GPa, 570–610 °C and a(H2O) >0.6. The relatively high pressure conditions derived from the jadeite‐bearing kyanite eclogite are further supported by high residual pressures of quartz inclusions in garnet. The maximum depth of exhumation in the Sanbagawa belt (~80 km) suggests decoupling of the slab–mantle wedge interface at this depth.  相似文献   

7.
Coexisting garnet blueschist and eclogite from the Chinese South Tianshan high‐pressure (HP)–ultrahigh‐pressure (UHP) belt consist of similar mineral assemblages involving garnet, omphacite, glaucophane, epidote, phengite, rutile/sphene, quartz and hornblendic amphibole with or without paragonite. Eclogite assemblages generally contain omphacite >50 vol.% and a small amount of glaucophane (<5 vol.%), whereas blueschist assemblages have glaucophane over 30 vol.% with a small amount of omphacite which is even absent in the matrix. The coexisting blueschist and eclogite show dramatic differences in the bulk‐rock compositions with higher X(CaO) [=CaO/(CaO + MgO + FeOtotal + MnO + Na2O)] (0.33–0.48) and lower A/CNK [=Al2O3/(CaO + Na2O + K2O)] (0.35–0.56) in eclogite, but with lower X(CaO) (0.09–0.30) and higher A/CNK (0.65–1.28) in garnet blueschist. Garnet in both types of rocks has similar compositions and exhibits core–rim zoning with increasing grossular and pyrope contents. Petrographic observations and phase equilibria modelling with pseudosections calculated using thermocalc in the NCKMnFMASHO system for the coexisting garnet blueschist and eclogite samples suggest that the two rock types share similar P–T evolutional histories involving a decompression with heating from the Pmax to the Tmax stage and a post‐Tmax decompression with slightly cooling stage, and similar P–T conditions at the Tmax stage. The post‐Tmax decompression is responsible for lawsonite decomposition, which results in epidote growth, glaucophane increase and omphacite decrease in the blueschist, or in an overprinting of the eclogitic assemblage by a blueschist assemblage. Calculated P–X(CaO), P–A/CNK and P–X(CO2) pseudosections indicate that blueschist assemblages are favoured in rocks with lower X(CaO) (<0.28) and higher A/CNK (>0.75) or fluid composition with higher X(CO2) (>0.15), but eclogite assemblages preferentially occur in rocks with higher X(CaO) and lower A/CNK or fluid composition with lower X(CO2). Moreover, phase modelling suggests that the coexistence of blueschist and eclogite depends substantially on P–T conditions, which would commonly occur in medium temperatures of 500–590 °C under pressures of ~17–22 kbar. The modelling results are in good accordance with the measured bulk‐rock compositions and modelled temperature results of the coexisting garnet blueschist and eclogite from the South Tianshan HP–UHP belt.  相似文献   

8.
An olivine basalt, a tonalite (andesite), a granite (rhyolite), and a red clay (pelagic sediment) were reacted, with known quantities of water in sealed noble metal capsules, in a piston-cylinder apparatus at 30 kb pressure. For the pelagic sediment, with H2O+=7.8% and no additional water, the liquidus temperature is 1240°C, the primary phases are garnet and kyanite. The subsolidus phase assemblage is phengite mica+garnet+clinopyroxene+coesite+kyanite. With 5 wt.% water added, the liquidus temperatures and primary phases for the calc-alkaline rocks are 1280°-1180°-1080°, garnet+clinopyroxene, garnet, and quartz respectively. Garnet and clinopyroxene occur throughout the melting interval of the olivine tholeiite for all water contents. Garnet is joined by clinopyroxene 80° below the andesite plus 5% H2O liquidus, quartz is joined by clinopyroxene 180° below the rhyolite plus 5% H2O liquidus. The subsolidus phase assemblage is garnet+clinopyroxene+coesite+minor kyanite for all the calc-alkaline compositions. We conclude that calc-alkaline andesites and rhyolites are not equilibrium partial melting pruducts of subducted oceanic crust consisting of olivine tholeiite basalt and siliceous sediments. Partial melting in subduction zones produces broadly acid and intermediate liquids, but these liquids lie off the calc-alkaline basalt-andesite-rhyolite join and must undergo modification at lower pressures to produce calcalkaline magmas erupted in overlying island arcs.  相似文献   

9.
A continuous flow method, by a combination of thermal conversion elemental analyzer (TC/EA) with isotope ratio mass spectrometry (MS), is presented for determination of both H isotope composition and H2O concentration of garnet from eclogite. Together with biotite NBS-30, the garnet was tested by preheating mineral grains at different temperatures. Preheating at 90°C for 12 h was found to be capable of eliminating adsorption water on sample surface. This results in constant δD values and total H2O contents for the garnet, with weighted means of −93 ± 2‰ and 522 ± 11 ppm (wt), respectively. The garnet that was preheated at 350°C for 4 h also gave constant δD values of −86 ± 6‰ and H2O contents of 281 ± 13 ppm (wt). The latter result for the H2O contents agrees with the H2O contents 271 ± 58 ppm (wt) measured by Fourier transform infrared spectroscopy for quantitative analysis of structural hydroxyl in the same garnet. Stepwise-heating TC/EA-MS analyses for the garnet show that the molecular H2O are depleted in D relative to the structural OH and has higher mobility than the structural OH. Therefore, the TC/EA-MS method can be used not only for quantitative determination of both H isotope composition and H2O concentration of hydrous and anhydrous minerals, but also for the concentration of structural hydroxyl after high-T dehydration.  相似文献   

10.
Garnets in UHP eclogites from Bixiling in Dabieshan were investigated by Fourier transform infrared spectroscopy (FTIR). The results indicate that all garnets contain structural water that occurs as hydroxyl (OH−) and non-structural molecular water (H2O) possibly in the form of sub-microscopic fluid inclusions. The structural hydroxyl contents range from 92 to 1735 ppm (H2O wt.) and most are between 200 and 1000 ppm. Therefore, garnet in eclogite can recycle surface water into the mantle. Various water contents were observed among different samples of the same outcrop (∼150 m) and in different domains of the same sample (∼1 cm). This variability in structural H2O contents suggests that the mobility of fluids during UHP metamorphism was very limited, and that both subduction and exhumation processes of UHP rocks occurred in a short time interval.  相似文献   

11.
The Sanbagawa belt is one of the famous subduction‐related high‐pressure (HP) metamorphic belts in the world. However, spatial distributions of eclogite units in the belt have not yet satisfactorily established, except within the Besshi region, central Shikoku, southwest Japan because most eclogitic rocks were affected by lower pressure overprinting during exhumation. In order to better determine the areal distribution of the eclogite units and their metamorphic features, inclusion petrography of garnet porphyroblasts using a combination of electron probe microanalyser and Raman spectroscopy was applied to pelitic and mafic schists from the Asemi‐gawa region, central Shikoku. All pelitic schist samples are highly retrogressed, and include no index HP minerals such as jadeite, omphacite, paragonite, or glaucophane in the matrix. Garnet porphyroblasts in pelitic schists occur as subhedral or anhedral crystals, and show compositional zoning with irregular‐shaped inner segments and overgrown outer segments, the boundary of which is marked by discontinuous changes in spessartine. This feature suggests that a resorption process of the inner segment occurred prior to the formation of the outer segment, indicating discontinuous crystallization between the two segments. The inner segment of some composite‐zoned garnet grains displays Mn oscillations, implying infiltration of metamorphic fluid during the initial exhumation stage. Evidence for an early eclogite facies event was determined from mineral inclusions (e.g., jadeite, paragonite, glaucophane) in the garnet inner segments. Mafic schists include no index HP minerals in the matrix as with pelitic schists. Garnet grains in mafic schists show simple normal zoning, recording no discontinuous growth during crystal formation. There are no index HP mineral inclusions in the garnet, and thus no evidence suggesting eclogite facies conditions. Quartz inclusions in garnet of the pelitic and mafic schists show residual pressure values (?ω1) of >8.5 cm?1 and <8.5 cm?1 respectively. The combination of Raman geobarometry and conventional thermodynamic calculations gives peak P–T conditions of 1.6–2.1 GPa at 460–520°C for the pelitic schists. The ?ω1 values of quartz inclusions in mafic schists are converted to a metamorphic pressure of 1.2–1.4 GPa at 466–549°C based on Raman geothermometry results. These results indicate that a pressure gap definitely exists between the mafic schists and the almost adjacent pelitic schists, which have experienced a different metamorphic history. Furthermore, the peak P–T values of the Asemi‐gawa eclogite unit are compatible with those of Sanbagawa eclogite unit in the Besshi region of central Shikoku, suggesting that these eclogite units share a similar P–T trajectory. The Asemi‐gawa eclogite unit exists in a limited area and is composed of mostly pelitic schists. We infer that these abundant pelitic schists played a key role in buoyancy‐driven exhumation by reducing bulk rock density and strength.  相似文献   

12.
As is common in suture zones, widespread high‐pressure rocks in the Caribbean region reached eclogite facies conditions close to ultrahigh‐pressure metamorphism. Besides eclogite lenses, abundant metapelitic rocks in the Chuacús complex (Guatemala Suture Zone) also preserve evidence for high‐pressure metamorphism. A comprehensive petrological and geochronological study was undertaken to constrain the tectonometamorphic evolution of eclogite and associated metapelite from this area in central Guatemala. The integration of field and petrological data allows the reconstruction of a previously unknown segment of the prograde P–T path and shows that these contrasting rock types share a common high‐pressure evolution. An early stage of high‐pressure/low‐temperature metamorphism at 18–20 kbar and 530–580°C is indicated by garnet core compositions as well as the nature and composition of mineral inclusions in garnet, including kyanite–jadeite–paragonite in an eclogite, and chloritoid–paragonite–rutile in a pelitic schist. Peak high‐pressure conditions are constrained at 23–25 kbar and 620–690°C by combining mineral assemblages, isopleth thermobarometry and Zr‐in‐rutile thermometry. A garnet/whole‐rock Lu‐Hf date of 101.8 ± 3.1 Ma in the kyanite‐bearing eclogite indicates the timing of final garnet growth at eclogite facies conditions, while a Lu‐Hf date of 95.5 ± 2.1 Ma in the pelitic schist reflects the average age of garnet growth spanning from an early eclogite facies evolution to a final amphibolite facies stage. Concordant U‐Pb LA‐ICP‐MS zircon data from the pelitic schist, in contrast, yield a mean age of 74.0 ± 0.5 Ma, which is equivalent to a U‐Pb monazite lower‐intercept age of 73.6 ± 2.0 Ma in the same sample, and comparable within errors with a less precise U‐Pb lower‐intercept age of 80 ± 13 Ma obtained in post‐eclogitic titanite from the kyanite‐bearing eclogite. These U‐Pb metamorphic ages are interpreted as dating an amphibolite facies overprint. Protolith U‐Pb zircon ages of 167.1 ± 4.2 Ma and 424.6 ± 5.0 Ma from two eclogite samples reveal that mafic precursors in the Chuacús complex originated in multiple tectonotemporal settings from the Silurian to Jurassic. The integration of petrological and geochronological data suggests that subduction of the continental margin of the North American plate (Chuacús complex) beneath the Greater Antilles arc occurred during an Albian‐Cenomanian pre‐collisional stage, and that a subsequent Campanian collisional stage is probably responsible of the amphibolite facies overprint and late syncollisional exhumation.  相似文献   

13.
Garnet-bearing ultramafic rocks (GBU) enclosed in high-grade gneisses are known from several parts of the Bohemian Massif. One of these is the high-pressure(HP)-unit 1 in the Erzgebirge Crystalline Complex, which is the subject of the present study. Hitherto, two different models have been put forward to explain the stabilisation of garnet in mantle-derived ultramafic rocks from the Bohemian Massif and their emplacement into the crust. (1) Garnetiferous assemblages were formed in the ultramafics before they came in contact with their crustal host rocks. (2) Garnet was formed in the ultramafics at the expense of spinel due to cooling caused by their tectonic emplacement in the crust. The PT-evolution revealed by the investigated GBU from the Erzgebirge Crystalline Complex, however, requires a third model. The reconstruction of the PT-paths for the Erzgebirge GBU is based on both conventional thermobarometry and phase relations. Thermodynamic calculations allowed the construction of a PT-phase diagram for the system Na2O-CaO-MgO-Al2O3-SiO2-H2O, which is the first quantitative petrogenetic grid in this model system relevant to ultramafic HP-rocks. The grid shows the uni-, di-, and tri-variant assemblages stable in peridotitic rocks at different PT-conditions, providing a tool to constrain PT-paths from the succession of mineral assemblages observed in a rock. The PT-path obtained for the Erzgebirge GBU suggests that the garnet-bearing assemblages formed by HP-metamorphism of spinel peridotite which was emplaced into the crust prior to or during the HP-compressional stage. This model is supported by peak PT-conditions around 900?°C and 30–35 kbar recorded by the ultramafic rocks, which are very similar to those attained in the eclogites sensu stricto which occur in the same tectonic unit (HP-unit 1) and for which an in situ metamorphism has been inferred (Schmädicke et al. 1992). On the other hand, the other two high-pressure units in the Erzgebirge, HP-units 2 and 3, which also contain eclogites sensu stricto but lack peridotites, record lower peak PT-conditions of 650–750?°C/24–26 kbar and 600–650?°C/20–24 kbar, respectively. Postulating an in situ HP-metamorphism for the garnet peridotites as result of continental collision during the Variscan orogeny, a crustal thickness of 90–110 km would be required. A comparison of the distribution of eclogites sensu stricto and mantle-derived rocks from the Bohemian Massif together with their reported PT-conditions reveals a correlation between peak PT-conditions in eclogites sensu stricto and the prevailing assemblages in the ultramafic rocks in the same unit. Furthermore, the Erzgebirge Crystalline Complex and the Snieznik Complex on one hand as well?as the Granulitgebirge and the Sowie Góry on the other hand are thought to be genetically linked. The garnet peridotites from the Granulitgebirge, the Sowie Góry and the Gföhl unit seem to have experienced peak PT-conditions not recorded by their country rocks with non-eclogitic basic interlayers, inferring a formation of?HP-assemblages in the ultramafics prior to their emplacement into the crust.  相似文献   

14.
Mantle xenoliths brought to the surface by kimberlite magmas along the south-western margin of the Kaapvaal craton in South Africa can be subdivided into eclogites sensu stricto, kyanite eclogites and orthopyroxene eclogites, all containing omphacite, and garnet clinopyroxenites and garnet websterites characterised by diopside. Texturally, chemically (major elements) and thermally, we observe an evolution from garnet websterites (TEG = 742–781 °C) towards garnet clinopyroxenites (TEG = 715–830 °C) and to eclogites (TEG = 707–1056 °C, mean value of 913 °C). Pressures calculated for orthopyroxene-bearing samples suggest upper mantle conditions of equilibration (P = 16–33 kb for the garnet websterites, 18 kb for a garnet clinopyroxenite and 23 kb for an opx-bearing eclogite). The overall geochemical similarity between the two groups of xenoliths (omphacite-bearing and diopside-bearing) as well as the similar trace element patterns of clinopyroxenes and garnet suggest a common origin for these rocks. Recently acquired oxygen isotope data on garnet (δ18Ognt = 5.25–6.78 ‰ for eclogites, δ18Ognt = 5.24–7.03 ‰ for garnet clinopyroxenites) yield values ranging from typical mantle values to other interpreted as resulting from low-temperature alteration or precursors sea-floor basalts and associated rocks. These rocks could then represent former magmatic oceanic rocks that crystallised from a same parental magma as plagioclase free diopside-bearing and plagioclase-bearing crustal rocks. During subduction, these oceanic rock protoliths equilibrated at mantle depth, with the plagioclase-bearing rocks converting to omphacite and garnet-bearing lithologies (eclogites sensu largo), whereas the plagioclase-free diopside-bearing rocks converted to diopside and garnet-bearing lithologies (garnet websterites and garnet clinopyroxenites).  相似文献   

15.
Garnet granulite facies mid‐to lower crust in Fiordland, New Zealand, provides evidence for pulsed intrusion and deformation occurring in the mid‐to lower crust of magmatic arcs. 238U‐206Pb zircon ages constrain emplacement of the ～595 km2 Malaspina Pluton to 116–114 Ma. Nine Sm‐Nd garnet ages (multi‐point garnet‐rock isochrons) ranging from 115.6 ± 2.6 to 110.6 ± 2.0 Ma indicate that garnet granulite facies metamorphism was synchronous or near synchronous throughout the pluton. Hence, partial melting and garnet granulite facies metamorphism lasted <5 Ma and began within 5 Ma of pluton emplacement. Garnet granulite facies L‐S tectonites in the eastern part of the Malaspina Pluton record the onset of extensional strain and arc collapse. An Sm‐Nd garnet age and thermobarometric results for these rocks directly below the amphibolite facies Doubtful Sound shear zone provide the oldest known age for extension in Fiordland at ≥112.8 ± 2.2 Ma at ～920 °C and 14–15 kbar. Narrow high Ca rims in garnet from some of these suprasolidus rocks could reflect a ≤ 1.5 kbar pressure increase, but may be largely a result of temperature decrease based on the Ca content of garnet predicted from pseudosections. At peak metamorphic conditions >900 °C, garnet contained ～4000 ppm Ti; subsequently, rutile inclusions grew during declining temperature with limited pressure change. Garnet granulite metamorphism of the Malaspina Pluton is c. 10 Ma younger than similar metamorphism of the Pembroke Granulite in northern Fiordland; therefore, high‐P metamorphism and partial melting must have been diachronous for this >3000 km² area of mid‐to‐lower crust. Thus, two or more pulses of intrusion shortly followed by garnet granulite metamorphism and extensional strain occurred from north to south along the axis of the lower crustal root of the Cretaceous Gondwana arc.  相似文献   

16.
In the Chinese southwestern Tianshan (U)HP belt, former lawsonite presence has been predicted for many (U)HP metamorphic eclogites, but only a very few lawsonite grains have been found so far. We discovered armoured lawsonite relicts included in quartz, which, on its part, is enclosed in porphyroblastic garnet in an epidote eclogite H711‐14 and a paragonite eclogite H711‐29. H711‐14 is mainly composed of garnet, omphacite, epidote and titanite, with minor quartz, paragonite and secondary barroisite and glaucophane. Coarse‐grained titanite occasionally occurs in millimetre‐wide veins in equilibrium with epidote and omphacite, and relict rutile is only preserved as inclusions in matrix titanite and garnet. H711‐29 shows the mineral assemblage of garnet, omphacite, glaucophane, paragonite, quartz, dolomite, rutile and minor epidote. Dolomite and rutile are commonly rimed by secondary calcite and titanite respectively. Porphyroblastic garnet in both eclogites is compositionally zoned and exhibits an inclusion‐rich core overgrown by an inclusion‐poor rim. Phase equilibria modelling predicts that garnet cores formed at the P‐peak (490–505 °C and 23–25.5 kbar) and coexisted with the lawsonite eclogite facies assemblage of omphacite + glaucophane + lawsonite + quartz. Garnet rims (550–570 °C and ~20 kbar) grew subsequently during a post‐peak epidote eclogite facies metamorphism and coexisted with omphacite + quartz ± glaucophane ± epidote ± paragonite. The results confirm the former presence of a cold subduction zone environment in the Chinese southwestern Tianshan. The P–T evolution of the eclogites is characterized by a clockwise P–T path with a heating stage during early exhumation (thermal relaxation). The preservation of lawsonite in these eclogites is attributed to isolation from the matrix by quartz and rigid garnet, which should be considered as a new type of lawsonite preservation in eclogites. The complete rutile–titanite transition in H711‐14 took place in the epidote eclogite facies stage in the presence of an extremely CO2‐poor fluid with X(CO2) [CO2/(CO2 + H2O) in the fluid] <<0.008. In contrast, the incomplete rutile–titanite transition in H711‐29 may have occurred after the epidote eclogite facies stage and the presence of dolomite reflects a higher X(CO2) (>0.01) in the coexisting fluid at the epidote eclogite facies stage.  相似文献   

17.
Eclogites within exhumed continental collision zones indicate regional burial to depths of at least 60 km, and often more than 100 km in the coesite‐stable, ultra‐high pressure (UHP) eclogite facies. Garnet, omphacitic pyroxene, high‐Si mica, kyanite ± coesite should grow at the expense of low‐P minerals in most felsic compositions, if equilibrium obtained at these conditions. The quartzofeldspathic rocks that comprise the bulk of eclogite facies terranes, however, contain mainly amphibolite facies, plagioclase‐bearing assemblages. To what extent these lower‐P minerals persisted metastably during (U)HP metamorphism, or whether they grew afterwards, reflects closely upon crustal parameters such as density, strength and seismic character. The Nordfjord area in western Norway offers a detailed view into a large crustal section that was subducted into the eclogite facies. The degree of transformation in typical pelite, paragneiss, granitic and granodioritic gneiss was assessed by modelling the equilibrium assemblage, comparing it with existing parageneses in these rocks and using U/Th–Pb zircon geochronology from laser ablation ICPMS to establish the history of mineral growth. U–Pb dates define a period of zircon recrystallization and new growth accompanying burial and metamorphism lasting from 430 to 400 Ma. Eclogite facies mafic rock (~2 vol.% of crust) is the most transformed composition and records the ambient peak conditions. Rare garnet‐bearing pelitic rocks (<10 vol.% of crust) preserve a mostly prograde mineral evolution to near‐peak conditions; REE concentrations in zircon indicate that garnet was present after 425 Ma and feldspar broke down after 410 Ma. Felsic gneiss – by far the most abundant rock type – is dominated by quartz + biotite + feldspar, but minor zoisite/epidote, phengitic white mica, garnet and rutile point to a prograde HP overprint. Relict textures indicate that much of the microstructural framework of plagioclase, K‐feldspar, and perhaps biotite, persisted through at least 25 Ma of burial, and ultimately UHP metamorphism. The signature reaction of the eclogite facies in felsic rocks – jadeite/omphacite growth from plagioclase – cannot be deduced from the presence of pyroxene or its breakdown products. We conclude that prograde dehydration in orthogneiss leads to fluid absent conditions, impeding equilibration beyond ~high‐P amphibolite facies.  相似文献   

18.
To evaluate the role of garnet and amphibole fractionation at conditions relevant for the crystallization of magmas in the roots of island arcs, a series of experiments were performed on a synthetic andesite at conditions ranging from 0.8 to 1.2 GPa, 800–1,000°C and variable H2O contents. At water undersaturated conditions and fO2 established around QFM, garnet has a wide stability field. At 1.2 GPa garnet + amphibole are the high-temperature liquidus phases followed by plagioclase at lower temperature. Clinopyroxene reaches its maximal stability at H2O-contents ≤9 wt% at 950°C and is replaced by amphibole at lower temperature. The slopes of the plagioclase-in boundaries are moderately negative in space. At 0.8 GPa, garnet is stable at magmatic H2O contents exceeding 8 wt% and is replaced by spinel at decreasing dissolved H2O. The liquids formed by crystallization evolve through continuous silica increase from andesite to dacite and rhyolite for the 1.2 GPa series, but show substantial enrichment in FeO/MgO for the 0.8 GPa series related to the contrasting roles of garnet and amphibole in fractionating Fe–Mg in derivative liquids. Our experiments indicate that the stability of igneous garnet increases with increasing dissolved H2O in silicate liquids and is thus likely to affect trace element compositions of H2O-rich derivative arc volcanic rocks by fractionation. Garnet-controlled trace element ratios cannot be used as a proxy for ‘slab melting’, or dehydration melting in the deep arc. Garnet fractionation, either in the deep crust via formation of garnet gabbros, or in the upper mantle via formation of garnet pyroxenites remains an important alternative, despite the rare occurrence of magmatic garnet in volcanic rocks.  相似文献   

19.
A garnet-bearing tonalitic porphyry from the Achiq Kol area, northeast Tibetan Plateau has been dated by SHRIMP U-Pb zircon techniques and gives a Late Triassic age of 213 ± 3 Ma. The porphyry contains phenocrysts of Ca-rich, Mn-poor garnet (CaO > 5 wt%; MnO < 3 wt%), Al-rich hornblende (Al2O3 ~ 15.9 wt%), plagioclase and quartz, and pressure estimates for hornblende enclosing the garnet phenocrysts yield values of 8–10 kbar, indicating a minimum pressure for the garnet. The rock has SiO2 of 60–63 wt%, low MgO (<2.0 wt%), K2O (<1.3 wt%), but high Al2O3 (>17 wt%) contents, and is metaluminous to slightly peraluminous (ACNK = 0.89–1.05). The rock samples are enriched in LILE and LREE but depleted in Nb and Ti, showing typical features of subduction-related magmas. The relatively high Sr/Y (~38) ratios and low HREE (Yb < 0.8 ppm) contents suggest that garnet is a residual phase, while suppressed crystallization of plagioclase and lack of negative Eu anomalies indicate a high water fugacity in the magma. Nd–Sr isotope compositions of the rock (εNdT = −1.38 to −2.33; 87Sr/86Sri = 0.7065–0.7067) suggest that both mantle- and crust-derived materials were involved in the petrogenesis, which is consistent with the reverse compositional zoning of plagioclase, interpreted to indicate magma mixing. Both garnet phenocrysts and their ilmenite inclusions contain low MgO contents which, in combination with the oxygen isotope composition of garnet separates (+6.23‰), suggests that these minerals formed in a lower crust-derived felsic melt probably in the MASH zone. Although the rock samples are similar to adakitic rocks in many aspects, their moderate Sr contents (<260 ppm) and La/Yb ratios (mostly 16–21) are significantly lower than those of adakitic rocks. Because of high partition coefficients for Sr and LREE, fractionation of apatite at an early stage in the evolution of the magma may have effectively decreased both Sr and LREE in the residual melt. It is suggested that extensive crystallization of apatite as an early phase may prevent some arc magmas from evolving into adakitic rocks even under high water fugacity.  相似文献   

20.
We studied high-grade metamorphic rocks of the El Cristo hill area of the Tandilia belt. Mineral analyses and thermodynamic calculations were carried out for two adjacent rock samples: an amphibole–biotite gneiss and a garnet–biotite-bearing migmatite. Peritectic garnets in the migmatite show core compositions of pyr4.5(gro + andr)10spes6alm79.5 changing to pyr3.5(gro + andr)17spes6alm73.5 at their thin rims. Garnet compositions in the gneiss are pyr6.5(gro + andr)26spes12alm55.5 and pyr4.5(gro + andr)34spes12alm49.5 for core and rim, respectively. A P–T path was constructed by calculating pseudosections in the 11-component system Si–Ti–Al–Fe–Mn–Mg–Ca–Na–K–O–H and contouring them by isopleths for garnet components using the PERPLE_X software package. Supra-solidus crystallization of garnet cores in the migmatite began at 5.8 kbar and 660 °C. Garnet rims equilibrated at 7.0 kbar and 640 °C compatible with garnet cores in the amphibole–biotite gneiss (7.6 kbar and 660 °C). The further chemical development of garnet in this rock points to P–T conditions of 11.6 kbar and 620 °C and 12.2 kbar and 595 °C (outermost garnet rim). At this high-pressure stage Ca-amphibole was not stable. Most biotite formed during exhumation whereas the high-pressure accessory minerals, titanite and epidote, persisted. According to the obtained anti-clockwise P–T path the originally partly melted material was tectonically transported from ∼22 km (middle crust) to ∼40 km (lower crust) depths reaching a geothermal gradient as low as 15 °C km−1. This transport probably occurred along a major suture zone, which was active during the Paleoproterozoic (2.25–2.10 Ga), before a terminating collision of terranes near the SW boundary of the Rio de la Plata craton.  相似文献   

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