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51.
New 40Ar/39Ar and 14C ages have been found for the Albano multiple maar pyroclastic units and underlying paleosols to document the most recent explosive activity in the Colli Albani Volcanic District (CAVD) near Rome, Italy, consisting of seven eruptions (Albano 1 = oldest). Both dating methodologies have been applied on several proximal units and on four mid-distal fall/surge deposits, the latter correlated, according to two current different views, to either the Albano or the Campi di Annibale hydromagmatic center. The 40Ar/39Ar ages on leucite phenocrysts from the mid-distal units yielded ages of ca. 72 ka, 73 ka, 41 ka and 36 ka BP, which are indistinguishable from the previously determined 40Ar/39Ar ages of the proximal Albano units 1, 2, 5 and 7, thus confirming their stratigraphic correspondence.  相似文献   
52.
During the ML = 5.6 and 5.8 earthquakes occurredin central Italy on 26 September 1997 the historiccentre of Nocera Umbra, lying on top of a 120 m highhill, was diffusely damaged (VII-VIII degrees of MCSintensity). Some recently built houses in the modernpart of the town suffered an even higher level ofdamage. A temporary seismic array was deployed toinvestigate a possible correlation between localamplifications of ground motion in this area and theobserved pattern of damage. After a geologic andmacroseismic survey, eight sites were selected asrepresentative of different local conditions, such astopographic irregularities, sharp hard-to-softlithology transitions, alluvium-filled valleys, andboth undisturbed and deformed rocks.Horizontal-to-vertical spectral ratios for bothmicrotremor and earthquake recordings, as well asspectral ratios referred to undisturbed rock sites,were used to quantify local variations of groundmotion. In spite of the diffuse damage in the historiccentre of Nocera Umbra, a small amplification isobserved at the stations on the hill's top. Thissuggests that the higher vulnerability of the ancientbuildings mainly accounts for the diffuse damage inthat part of the town. In the frequency band ofengineering interest (1 to 10 Hz) the largestamplifications of ground motion are found at softsites: in the Topino river valley, where many episodesof severe structural damage occurred, spectralamplification is significant over a broad frequencyband ranging from 2 Hz to more than 20 Hz. Inparticular, in the central part of the valley highamplification (> 4) is found from 3 to 10 Hz,reaching a maximum of 20 around 4 Hz. At the edge ofthe valley, close to the soil-to-rock transition,amplification is as large as 10 in a frequency bandranging from 4 to more than 20 Hz. A significantamplification (by a factor of 10 around 10 Hz) isobserved also at one of the rock sites, possibly dueto the presence of a cataclastic zone related to theactivity of a regional fault that altered themechanical properties of the rock.  相似文献   
53.
We found extensive evidence that the vertical ground accelerations produced during the largest shock (M = 6.0) of the 1997 Umbria-Marche earthquake sequence exceeded 1g in two areas close to the heavily-damaged villages of Annifo and Colle Croce. This evidence comes from the striking observation of thousands of freshly fractured and broken rocks and stones in these areas. Some of the broken stones lie isolated on soft detritic soil while others had been previously piled up, probably a long time agoto clear the fields for farming. The freshness of the cuts and fractures and the consistency of the observations for thousands of rocks and stones in these areas indicate that these rocks were thrown upwards during the earthquake, with breakage occurring at the time of impact. Ground motion calculations consistent with the static deformation inferred from GPS and interferometry data, show that the broken stones and rocks are found in the zone where the strongest shaking took place during the earthquake and that most of the shaking there was vertical.  相似文献   
54.
Linking the deformation history of mylonitized continental rocks to the progress of devolatilization reactions that trigger reaction softening is critical for the understanding of crustal scale processes. We have analysed the field geometries and microstructures of deformed rocks within the southern Hercynian belt in Calabria, as well as modelled the pressure–temperature–deformation (P–T–d) trajectory of a main ductile shear zone that tectonically coupled the deeper crustal Mammola Paragneiss Unit with the upper crustal Stilo–Pazzano Phyllite Unit. P–T modelling of the mylonitic Mammola Paragneiss Unit was performed through calculation of phase equilibrium diagrams with the software thermocalc in the MnNCKFMASHTO model system. The prograde P–T–d trajectory is based on the zoning profiles of garnet porphyroblasts and their mineral inclusions, primarily barroisite and epidote. P–T modelling shows that peak metamorphic conditions of ~0.9 GPa and 585°C were reached during a Dn-1 under-thrusting event. The following exhumation during the Dn mylonitic event, and contact metamorphism during Dn+1 and Dn+2 folding events, have also been modelled because they are essential to restore the previous tectono-metamorphic history. The exhumation trajectory was modelled down to 0.3 GPa with temperatures of 440–460°C, under fluid-deficient conditions, as well as the final late Carboniferous contact metamorphism up to Tmax of 680–720°C. The prograde path shows clear evidence for thermal buffering during garnet growth at the expense of chlorite, with a heating-dominated stage after chlorite breakdown. Subsequently, a rheological change associated with epidote breakdown (i.e. reaction softening) occurred, highlighted by a net steepening of the P/T trajectory towards the pressure peak. On the basis of the barroisite inclusions within garnet porphyroblasts as well as the ‘hairpin’ shape of the reconstructed P–T–d path (before contact metamorphism), we infer that the unusual low T/P gradient for the Hercynian crust exposed in the Mammola Paragneiss Unit records its involvement in the Palaeotethys–Gondwana subduction beneath Laurussia during Dn-1 under-thrusting. We present a new palaeotectonic interpretation along the southern Hercynian belt in Calabria during the Upper Mississippian–Lower Pennsylvanian, that is consistent with previous geochronology studies.  相似文献   
55.
In the northeastern corner of Sicily (Peloritani Mountains) thin bodies of hercynian crystalline basement, covered by Meso-Cenozoic veneers of sedimentary rocks, represent the highest and innermost Africa-vergent group of thrust units of the Sicilian Belt. The Peloritani tectonic edifice consists of a set of prevalently middle- to high-grade crystalline rocks (so-called Fondachelli Unit, Mandanici Unit and Aspromonte Unit) and thrusts over a thin tectonic wedge made of prevalently Mesozoic to Tertiary sedimentary covers overlying pre-Triassic low-grade metamorphic rocks (Longi-Taormina Unit). The tectonic bodies of the Peloritani thrust system are overlain by thick clastic sequences of late Oligoceneearly Miocene age (the so-called Stilo-Capo d'Orlando Formation). Previous work has pointed out the 'molassic' character of these clastic sequences, which postdate the main deformation phase of the Peloritani belt, started during Oligocene time. New structural data on the crystalline and sedimentary terrains, sedimentological analysis of the outcropping Oligo-Miocene foreland clastic deposits and their geometric relationships with the substrate, make it possible to recognize the syn-tectonic character and the timing of deformation of these basin-fill deposits, which are expressed by prograding clastic fans in the active margin of a foreland-foredeep system. This system has progressively been involved in the accretion of the Sicilian Belt and migration during the early Miocene towards the more external areas represented by the Sicilide sector. Seen in this light, three different lithological units have been distinguished to prdvide a framework for a review of the palaeotectonic significance of the overall Oligo-Miocene terrigenous covers of the Peloritani Thrust belt  相似文献   
56.
We present an overview of the seismogenic sources of northeastern Italy and western Slovenia, included in the last version of the Database of Individual Seismogenic Sources (DISS 3.0.2) and a new definition of the geometry of the Montello Source that will be included in the next release of the database. The seismogenic sources included in DISS are active faults capable of generating Mw > 5.5 earthquakes. We describe the method and the data used for their identification and characterization, discuss some implications for the seismic hazard and underline controversial points and open issues.In the Veneto–Friuli area (NE Italy), destructive earthquakes up to Mw 6.6 are generated by thrust faulting along N-dipping structures of the Eastern Southalpine Chain. Thrusting along the mountain front responds to about 2 mm/a of regional convergence, and it is associated with growing anticlines, tilted and uplifted Quaternary palaeolandsurfaces and forced drainage anomalies. In western Slovenia, dextral strike–slip faulting along the NW–SE trending structures of the Idrija Fault System dominates the seismic release. Activity and style of faulting are defined by recent earthquakes (e.g. the Ms 5.7, 1998 Bovec–Krn Mt. and the Mw 5.2, 2004 Kobarid earthquakes), while the related recent morphotectonic imprint is still a debated matter.We reinterpreted a large set of tectonic data and developed a segmentation model for the outermost Eastern Southalpine Chain thrust front. We also proposed the association of the four major shocks of the 1976 Friuli earthquake sequence with individual segments of three major thrust fronts. Although several sub-parallel active strike–slip strands exist in western Slovenia, we were able to positively identify only two segments of the Idrija Fault System. A comparison of the regional GPS velocity with long-term geological slip-rates of the seismogenic sources included in DISS shows that from a quarter to half of the deformation is absorbed along the external alignment of thrust faults in Veneto and western Friuli. The partitioning of the deformation in western Slovenia among the different strike–slip strands could not be quantified.  相似文献   
57.
The crystal structure and chemical composition of a crystal of (Mg14?x Cr x )(Si5?x Cr x )O24 (x ≈ 0.30) anhydrous Phase B (Anh-B) synthesized in the model system MgCr2O4–Mg2SiO4 at 12 GPa and 1600 °C have been investigated. The compound was found to be orthorhombic, space group Pmcb, with lattice parameters a = 5.900(1), b = 14.218(2), c = 10.029(2) Å, V = 841.3(2) Å3 and Z = 2. The structure was refined to R 1 = 0.065 using 1492 independent reflections. Chromium was found to substitute for both Mg at the M3 site (with a mean bond distance of 2.145 Å) and Si at the octahedral Si1 site (mean bond distance: 1.856 Å), according to the reaction Mg2+ + Si4+ = 2Cr3+. Such substitutions cause a reduction in the volume of the M3 site and an increase in the volume of the Si-dominant octahedron with respect to the values typically observed for pure Anh-B and Fe2+-bearing Anh-B. Taking into account that Cr3+ is not expected to be Jahn–Teller active, it appears that both the Cr3+–for–Mg and Cr3+–for–Si substitutions in the Anh-B structure decrease the distortion of the octahedra. Electron microprobe analysis gave the Mg13.66(8)Si4.70(6)Cr0.62(4)O24 stoichiometry for the studied phase. The successful synthesis of this phase provides new information for the possible mineral assemblages occurring in the Earth’s deep upper mantle and shed new light on the so-called X discontinuity that has been observed at 275–345 km depth in several subcontinental and subduction zone environments.  相似文献   
58.
We studied the photoluminescence properties of a sample of SiO2-clathrate Melanophlogite, a crystalline microporous material which is found in nature as a rare mineral. Upon β irradiation, the material displays an intense light emission under near-UV illumination. We studied in detail this optical activity by steady-state and time-resolved photoluminescence measurements as a function of temperature. The spectroscopic properties we find can be ascribed to a population of quasi-free molecules trapped within each of the two different types of cage available in the structure of this clathrate, although the spectroscopic properties of the guest molecules are affected by their interactions with the host matrix. Based on the available data, we attribute the observed photoluminescence to trapped S2 molecules, emitting from their excited 3Σ u ? or 3Π u electronic states, depending on the cage they are trapped in and on temperature. Our results have an impact on the fundamental understanding of host–guest interactions characteristic of microporous systems such as clathrates. Indeed, the data highlight that even a relatively weak coupling between quasi-free S2 molecules and the two types of cages provided by the Melanophlogite host has a surprisingly complex influence on the optical properties of the guest.  相似文献   
59.
In the Maritime Alps (north‐west Italy – south‐east France), the Middle Triassic–lowermost Cretaceous platform carbonates of the Provençal Domain locally show an intense dolomitization. Dolomitized bodies, irregularly shaped and variable in size from some metres to hundreds of metres, are associated with tabular bodies of dolomite‐cemented breccias, cutting the bedding at a high angle, and networks of dolomite veins. Field and petrographic observations indicate that dolomitization was a polyphase process, in which episodes of hydrofracturing and host‐rock dissolution, related to episodic expulsion of overpressured fluids through faults and fracture systems, were associated with phases of host‐rock dolomitization and void cementation. Fluid inclusion analysis indicates that dolomitizing fluids were relatively hot (170 to 260°C). The case study represents an outstanding example of a fossil hydrothermal system, which significantly contributes to the knowledge of such dolomitization systems in continental margin settings. The unusually favourable stratigraphic framework allows precise constraint of the timing of dolomitization (earliest Cretaceous) and, consequently, direct evaluation of the burial setting of dolomitization which, for the upper part of the dolomitized succession, was very shallow or even close to the surface. The described large‐scale hydrothermal system was probably related to deep‐rooted faults, and provides indirect evidence of a significant earliest Cretaceous fault activity in this part of the Alpine Tethys European palaeomargin.  相似文献   
60.
The Corsica‐Sardinia block is a lithospheric fragment whose recent role in the geodynamics of the central‐Western Mediterranean basin is still enigmatic. The most recent regional structure in Sardinia is the Plio‐Pleistocene Campidano Basin, which is considered in a ‘post‐rift’ stage since the Middle Pleistocene. New structural and stratigraphic geological surveys along with luminescence ages provide evidence to support an ongoing tectonic activity since the Marine Isotopic Stage 7 (MIS7; ca. 220 ka) on the Sinis peninsula, the structural high that bounds the north‐western side of the Campidano Basin. In particular, this paper reveals for the first time the presence of N–S striking normal faults system offsetting late Pleistocene aeolianites (130 ± 12 ka; 82 ± 9 ka).  相似文献   
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