Isolation of colloidal monomethyl mercury in natural waters using cross-flow ultrafiltration techniques   总被引：1，自引：0，他引：1  

Key-Young Choe  Gary A. Gill 《Marine Chemistry》2001,76(4):261

A series of experiments was conducted to evaluate the appropriateness of cross-flow ultrafiltration (CFUF) techniques for the determination of the phase speciation of monomethyl mercury (MeHg) in natural waters. Spiral-wound cartridge (Amicon S1Y1) and Miniplate (Amicon) were evaluated for their nominal molecular weight cut-offs of 1 and 10 kDa, respectively. The ultrafiltration behavior of standard macromolecules showed that the permeation of high molecular weight (HMW) organic macromolecules was not significant when a concentration factor (CF)>15 was used. The retention of low molecular weight (LMW) molecules was significant, especially at a low CF<5, suggesting that the use of a high CF (15) will minimize the retention of LMW molecules. Sorptive losses of MeHg in the solution phase to the 1 kDa membrane were negligible, but MeHg bound to HMW macromolecules was still retained (20%), even with a preconditioned membrane. The mass balance recovery of MeHg during ultrafiltration averaged 101±15% (n=7) and 105±14% (n=5) for the 1 and 10 kDa membranes, respectively. Sample storage over 24 h caused significant coagulation (47%) of the <10 kDa MeHg into the 10 kDa–0.45 μm colloidal or the particulate MeHg pool. The 1 kDa–0.45 μm colloidal MeHg in Galveston Bay and the Trinity River water samples accounted for 40–48% of the filter-passing MeHg, although the most abundant fraction (52–60%) of MeHg was the truly dissolved fraction (<1 kDa). The partition coefficient between the colloidal (1 kDa–0.45 μm) and truly dissolved MeHg (average log K_C=5.2) was higher than the partition coefficient based on particle/filter-passing (average log K_D=4.6) or particle/truly dissolved MeHg (average log K_P=4.8), suggesting that MeHg has stronger affinity for natural colloids than macroparticulate materials (>0.45 μm).  相似文献   

Dissolved trace element cycles in the San Francisco Bay estuary     

A.R. Flegal  G.J. Smith  G.A. Gill  S. Saudo-Wilhelmy  L.C.D. Anderson 《Marine Chemistry》1991,36(1-4)

Dissolved trace element (copper, nickel, cadmium, zinc, cobalt, and iron) concentrations were measured in surface water samples collected from 27 stations in the San Francisco Bay and Sacramento—San Joaquin Delta during April, August and December of 1989. The trace element distributions were relatively similar for all three sampling periods, and evidenced two distinct biogeochemical regimes within the estuarine system. The two regimes were comprised of relatively typical trace element gradients in the northern reach and anthropogenically perturbed gradients in the southern reach of the estuary. These dichotomous trace element distributions were consistent with previous reports on the distributions of nutrients and some other constituents within the estuary.In the northern reach, trace element and dissolved phosphate concentrations were non-conservative. Simple estuarine mixing models indicated substantial internal sources of dissolved copper (46–150%), nickel (250–500%) and cadmium (630–780%) relative to riverine inputs in April and August, and sizable internal sinks for dissolved cobalt (> 99%) and iron (> 70%) during the same periods. Dissolved zinc fluxes varied temporally, with a relatively large (135%) internal source in April and a relatively small (29%) internal sink in August.Concentrations of many trace elements (copper, nickel, cadmium, zinc, and cobalt) in the southern reach were anomalously high relative to concentrations at comparable salinities in the northern reach. Mass balance calculations indicated that those excesses were primarily due to anthropogenic inputs (waste-water discharges and urban runoff) and diagenetic remobilization from benthic sediments. The magnitude of these excesses was amplified by the long hydraulic residence time of dissolved constituents within the South Bay.The influence of other factors was evident throughout the system. Notably, upwelling appeared to elevate substantially dissolved cadmium concentrations at the mouth of the estuary and authigenic flocculation appeared to dominate the cycling of dissolved iron in both the northern and southern reaches of the system. Biological scavenging, geochemical scavenging and diagenic remobilization were also found to be important in different parts of the estuary. Additional complementary information is required to quantify accurately these processes.  相似文献   

The Harvest Experiment: Monitoring Jason-1 and TOPEX/POSEIDON from a California Offshore Platform     

Bruce J. Haines  Danan Dong  George H. Born  Stephen K. Gill 《Marine Geodesy》2003,26(3):239-259

We present calibration results from Jason-1 (2001-) and TOPEX/POSEIDON (1992-) overflights of a California offshore oil platform (Harvest). Data from Harvest indicate that current Jason-1 sea-surface height (SSH) measurements are high by 138 ± 18 mm. Excepting the bias, the high accuracy of the Jason-1 measurements is in evidence from the overflights. In orbit for over 10 years, the T/P measurement system is well calibrated, and the SSH bias is statistically indistinguishable from zero. Also reviewed are over 10 years of geodetic results from the Harvest experiment.  相似文献   

Arbitrary amplitude dust–ion acoustic solitary structures in electronegative plasma     

Ripin Kohli  N. S. Saini  T. S. Gill 《Astrophysics and Space Science》2018,363(9):193

In the present study existence domains of large amplitude dust–ion acoustic (DIA) solitary structures are analyzed in an unmagnetized and collisionless, electronegative plasma containing inertial positive and negative ions, inertialess superthermal electrons with two different temperatures and negatively charged stationary dust. Using the Sagdeev pseudopotential technique, the energy-balance equation has been derived and the critical values (lower and upper limits) of the Mach number are also determined. The effect of different physical parameters has been analyzed for the formation of these nonlinear structures. Also the critical values of different physical parameters have been determined to establish parametric regimes for the existence of positive/negative potential DIA solitary structures.  相似文献   

Grassroots innovations in community energy: The role of intermediaries in niche development     

Tom Hargreaves  Sabine Hielscher  Gill Seyfang  Adrian Smith 《Global Environmental Change》2013,23(5):868-880

Community energy projects are attracting increasing attention as potential sources of innovation to support sustainable energy transitions. Research into ‘grassroots innovations’ like community energy often recognises the difficulties they face in simply surviving let alone in growing or seeding wider change. Strategic niche management theory is potentially helpful here as it highlights the important roles played by ‘intermediary actors’ in consolidating, growing and diffusing novel innovations. This paper presents the first in-depth analysis of intermediary work in the UK community energy sector. New empirical evidence was gathered through interviews with 15 community energy intermediaries and a content analysis of 113 intermediary-produced case studies about community energy projects. Analysis finds intermediaries adopting a variety of methods to try and diffuse generic lessons about context-specific projects, but that trying to coordinate support for local projects that exist amidst very different social and political circumstances is challenging. This is exacerbated by the challenges of building a coherent institutional infrastructure for a sector where aims and approaches diverge, and where underlying resources are uncertain and inconsistent. Applications of relatively simple, growth-oriented approaches like strategic niche management to grassroots innovations need to be reformulated to better recognise their diverse and conflicted realities on the ground.  相似文献   

Climate change and hydrology at the prairie margin: Historic and prospective future flows of Canada's Red Deer and other Rocky Mountain rivers          下载免费PDF全文

Laurens J. Philipsen  Karen M. Gill  Anita Shepherd  Stewart B. Rood 《水文研究》2018,32(17):2669-2684

The South Saskatchewan River Basin of southern Alberta drains the transboundary central Rocky Mountains region and provides the focus for irrigation agriculture in Canada. Following extensive development, two tributaries, the Oldman and Bow rivers, were closed for further water allocations, whereas the Red Deer River (RDR) remains open. The RDR basin is at the northern limit of the North American Great Plains and may be suitable for agricultural expansion with a warming climate. To consider irrigation development and ecological impacts, it is important to understand the regional hydrologic consequences of climate change. To analyse historic trends that could extend into the future, we developed century‐long discharge records for the RDR, by coordinating data across hydrometric gauges, estimating annual flows from seasonal records, and undertaking flow naturalization to compensate for river regulation. Analyses indicated some coordination with the Pacific decadal oscillation and slight decline in summer and annual flows from 1912 to 2016 (?0.13%/year, Sen's slope). Another forecasting approach involved regional downscaling from the global circulation models, CGCMI‐A, ECHAM4, HadCM3, and NCAR‐CCM3. These projected slight flow decreases from the mountain headwaters versus increases from the foothills and boreal regions, resulting in a slight increase in overall river flows (+0.1%/year). Prior projections from these and other global circulation models ranged from slight decrease to slight increase, and the average projection of ?0.05%/year approached the empirical trend. Assessments of other rivers draining the central and northern Rocky Mountains revealed a geographic transition in flow patterns over the past century. Flows from the rivers in Southern Alberta declined (around ?0.15%/year), in contrast to increasing flows in north‐eastern British Columbia and the Yukon. The RDR watershed approaches this transition, and this study thus revealed regional differentiation in the hydrological consequences from climate change.  相似文献   

GAUGE: the GrAnd Unification and Gravity Explorer     

G. Amelino-Camelia  K. Aplin  M. Arndt  J. D. Barrow  R. J. Bingham  C. Borde  P. Bouyer  M. Caldwell  A. M. Cruise  T. Damour  P. D’Arrigo  H. Dittus  W. Ertmer  B. Foulon  P. Gill  G. D. Hammond  J. Hough  C. Jentsch  U. Johann  P. Jetzer  H. Klein  A. Lambrecht  B. Lamine  C. Lämmerzahl  N. Lockerbie  F. Loeffler  J. T. Mendonca  J. Mester  W.-T. Ni  C. Pegrum  A. Peters  E. Rasel  S. Reynaud  D. Shaul  T. J. Sumner  S. Theil  C. Torrie  P. Touboul  C. Trenkel  S. Vitale  W. Vodel  C. Wang  H. Ward  A. Woodgate 《Experimental Astronomy》2009,23(2):549-572

The GAUGE (GrAnd Unification and Gravity Explorer) mission proposes to use a drag-free spacecraft platform onto which a number of experiments are attached. They are designed to address a number of key issues at the interface between gravity and unification with the other forces of nature. The equivalence principle is to be probed with both a high-precision test using classical macroscopic test bodies, and, to lower precision, using microscopic test bodies via cold-atom interferometry. These two equivalence principle tests will explore string-dilaton theories and the effect of space–time fluctuations respectively. The macroscopic test bodies will also be used for intermediate-range inverse-square law and an axion-like spin-coupling search. The microscopic test bodies offer the prospect of extending the range of tests to also include short-range inverse-square law and spin-coupling measurements as well as looking for evidence of quantum decoherence due to space–time fluctuations at the Planck scale.  相似文献   

Impact of Land Surface Heterogeneity on Mesoscale Atmospheric Dispersion   总被引：1，自引：1，他引：0  

Yuling Wu  Udaysankar S. Nair  Roger A. PielkeSr.  Richard T. McNider  Sundar A. Christopher  Valentine G. Anantharaj 《Boundary-Layer Meteorology》2009,133(3):367-389

Prior numerical modelling studies show that atmospheric dispersion is sensitive to surface heterogeneities, but past studies do not consider the impact of a realistic distribution of surface heterogeneities on mesoscale atmospheric dispersion. While these focussed on dispersion in the convective boundary layer, the present work also considers dispersion in the nocturnal boundary layer and above. Using a Lagrangian particle dispersion model (LPDM) coupled to the Eulerian Regional Atmospheric Modeling System (RAMS), the impact of topographic, vegetation, and soil moisture heterogeneities on daytime and nighttime atmospheric dispersion is examined. In addition, the sensitivity to the use of Moderate Resolution Imaging Spectroradiometer (MODIS)-derived spatial distributions of vegetation characteristics on atmospheric dispersion is also studied. The impact of vegetation and terrain heterogeneities on atmospheric dispersion is strongly modulated by soil moisture, with the nature of dispersion switching from non-Gaussian to near-Gaussian behaviour for wetter soils (fraction of saturation soil moisture content exceeding 40%). For drier soil moisture conditions, vegetation heterogeneity produces differential heating and the formation of mesoscale circulation patterns that are primarily responsible for non-Gaussian dispersion patterns. Nighttime dispersion is very sensitive to topographic, vegetation, soil moisture, and soil type heterogeneity and is distinctly non-Gaussian for heterogeneous land-surface conditions. Sensitivity studies show that soil type and vegetation heterogeneities have the most dramatic impact on atmospheric dispersion. To provide more skilful dispersion calculations, we recommend the utilisation of satellite-derived vegetation characteristics coupled with data assimilation techniques that constrain soil-vegetation-atmosphere transfer (SVAT) models to generate realistic spatial distributions of surface energy fluxes.  相似文献   

Bushfire and everyday life: Examining the awareness-action ‘gap’ in changing rural landscapes   总被引：1，自引：0，他引：1  

Christine Eriksen  Nicholas Gill 《Geoforum》2010,41(5):814-825

In this paper we use the notion of ‘everyday life’ to critically examine an apparent ‘gap’ between bushfire risk awareness and preparedness amongst diverse landholders in rural landscapes affected by amenity-led in-migration in southeast Australia. Landholders were found to bring their own agency to bushfire preparedness in the relationships between everyday procedures, dilemmas, and tradeoffs. Consequently, regardless of landholders’ awareness levels, attitudes towards bushfire and natural resource management influence if, how, and to what extent landowners prepare for bushfires. We argue that not only is the ‘gap’ complex but also paradoxical in that it is both evident in, and constituted by, landholder attitudes and action and simultaneously dissolved in their practices and decision-making in everyday life. Three dilemmas of everyday life in particular were found to underpin these attitudes: costs (in terms of monetary and time values), gender roles, and priorities. Using a mixed-methods research approach, this simultaneous cultural construction and material nature of bushfire in everyday life is mapped out through landholders’ narratives and actions that embody living with fire on the land. The place of bushfire in landholders’ everyday life has direct relevance to recent international discussions of the vulnerability of the growing number of people living in bushfire-prone rural-urban interface areas.  相似文献   

Andesites: Orogenic andesites and related rocks: R. S. Thorpe (editor). Wiley,New York, 1982. 724 p., $144.50.     

J.B. Gill 《Geochimica et cosmochimica acta》1982,46(12):2688-2689

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