Chlorinated compounds and polybrominated diphenyl ethers (PBDEs) in mussels (Mytilus galloprovincialis) collected from Apulia Region coasts     

Santina Giandomenico  Lucia Spada  Cristina Annicchiarico  Giorgio Assennato  Nicola Cardellicchio  Nicola Ungaro  Antonella Di Leo 《Marine pollution bulletin》2013

This project was carried out to assess the levels and spatial distribution of organochlorine compounds in the coastal marine environment, using mussels as bioindicators to evaluate the coastal water quality. Levels of polychlorobiphenils (PCB), chlorinated pesticides (DDT isomers, HCH isomers, Aldrin, Dieldrin, alfa-Endosulfan, Hexachlorobenzene, Pentachlorobenzene) and polybrominated diphenyl ethers (PBDEs) were determined in tissues from mussels (Mytilus galloprovincialis) collected along the Apulia Region coasts (Mediterranean Sea). Results indicate that contamination by organochlorine compounds is higher in mussels sampled in the Ionian Sea than in those from the Adriatic Sea, with PCB levels up to seven times higher in mussels from Ionian than from the Adriatic Sea. Although PCB levels were above the maximum values indicated by both European Community (EC) and National regulation in several sample sites, the PCB concentrations were particularly high in some stations, suggesting that these locations require a much specific attention. Conversely, results on the mussel contamination by PBDEs highlight their ubiquitous environmental distribution, and underline the need to establish the maximum level for these compounds in foodstuff, according to European Regulations.  相似文献   

PCBs in Central Vietnam coastal lagoons: levels and trends in dynamic environments     

Giuliani S  Piazza R  Bellucci LG  Cu NH  Vecchiato M  Romano S  Mugnai C  Nhon DH  Frignani M 《Marine pollution bulletin》2011,62(5):1013-1024

PCBs were analysed in surficial sediments and selected sediment cores collected between 2002 and 2008 in Central Vietnam coastal lagoons. The aim was to determine contamination levels and trends, and to evaluate the effects of anthropogenic pressures and natural events. Samples were mostly fine-grained with low total PCB concentrations (0.367-44.7 μg kg⁻¹). Atmospheric transport and post depositional processes modify to some degree the fingerprint of PCB inputs to the environment favouring the predominance of 3, 4 and 5 chlorinated congeners. The similarity of congener distributions in contemporary surficial samples also suggests the presence of a unique source over the entire study area, probably connected to mobilisation and long range transports from land-based stocks. The removal of consistent sediment layers is hypothesised based on repeated samplings of the same area. Natural meteorological events (such as typhoons) are suspected to be responsible for these sediment losses.  相似文献   

Mineralogy, composition and PGM of chromitites from Pefki, Pindos ophiolite complex (NW Greece): evidence for progressively elevated fAs conditions in the upper mantle sequence     

Argirios Kapsiotis  Tassos A. Grammatikopoulos  Basilios Tsikouras  Konstantin Hatzipanagiotou  Federica Zaccarini  Giorgio Garuti 《Mineralogy and Petrology》2011,101(1-2):129-150

The Pindos ophiolite complex, located in the northwestern part of continental Greece, hosts various chromite deposits of both metallurgical (high-Cr) and refractory (high-Al) type. The Pefki chromitites are banded and sub-concordant to the surrounding serpentinized dunites. The Cr# [Cr/(Cr?+?Al)] of magnesiochromite varies between 0.75 and 0.79. The total PGE grade ranges from 105.9 up to 300.0?ppb. IPGE are higher than PPGE, typical of mantle hosted ophiolitic chromitites. The PGM assemblage in chromitites comprises anduoite, ruarsite, laurite, irarsite, sperrylite, hollingworthite, Os-Ru-Ir alloys including osmium and rutheniridosmine, Ru-bearing oxides, braggite, paolovite, platarsite, cooperite, vysotskite, and palladodymite. Iridarsenite and omeiite were also observed as exsolutions in other PGM. Rare electrum and native Ag are recovered in concentrates. This PGM assemblage is of great petrogenetic importance because it is significantly different from that commonly observed in podiform mantle-hosted and banded crustal-hosted ophiolitic chromitites. PGE chalcogenides of As and S are primary, and possibly crystallized directly from a progressively enriched in As boninitic melt before or during magnesiochromite precipitation. The presence of Ru-bearing oxides implies simultaneous desulfurization and dearsenication processes. Chemically zoned laurite and composite paolovite-electrum intergrowths are indicative of the relatively high mobility of certain PGE at low temperatures under locally oxidizing conditions. The PGM assemblage and chemistry, in conjunction with geological and petrologic data of the studied chromitites, indicate that it is characteristic of chromitites found within or close to the petrologic Moho. Furthermore, the strikingly different PGM assemblages between the high-Cr chromitites within the Pindos massif is suggestive of non-homogeneous group of ores.  相似文献   

Geology and ore deposits of the Urals     

Evgeny V. Pushkarev  Oskar A. R. Thalhammer  Giorgio Garuti 《Mineralogy and Petrology》2013,107(1):1-2

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Presence and origin of polycyclic aromatic hydrocarbon in sediments of nine coastal lagoons in central Vietnam     

Giuliani S  Sprovieri M  Frignani M  Cu NH  Mugnai C  Bellucci LG  Albertazzi S  Romano S  Feo ML  Marsella E  Nhon DH 《Marine pollution bulletin》2008,56(8):1504-1512

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Seismic behavior of single‐story asymmetric‐plan buildings under uniaxial excitation     

Andrea Lucchini  Giorgio Monti  Sashi Kunnath 《地震工程与结构动力学》2009,38(9):1053-1070

The critical parameters that influence the nonlinear seismic response of asymmetric‐plan buildings are identified by evaluating the effects of different asymmetries that may characterize the structure of a building as well as exploring the influence of the ground motion features. First, the main findings reported in the literature on both the linear and nonlinear dynamic response of asymmetric‐plan buildings are presented. The common findings and the conflicting conclusions reached in different investigations are pointed out. Then, the results of comprehensive nonlinear dynamic analyses performed for evaluating the seismic response of systems characterized by different strength and stiffness configurations, representative of a large class of asymmetric‐plan buildings, are reported. Findings from the study indicate that the building response changes when moving from the linear to the nonlinear range, so that the seismic behavior of asymmetric‐plan buildings, apart from the source of asymmetry, can be always classified as irregular. Additionally, it was observed that as the seismic demands cause amplification of system nonlinearity with increasing earthquake intensity, the maximum displacement demand in the different resisting elements tends to be reached with the same deformed configuration of the system. The resultant of the seismic forces producing such a maximum demand is located at the center of resistance and corresponds to the collapse mechanism of the system that provides the maximum lateral strength in the exciting direction of the seismic action. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Late Quaternary deformation on the island on Pantelleria: New constraints for the recent tectonic evolution of the Sicily Channel Rift (southern Italy)     

Stefano Catalano  Giorgio De Guidi  Gianni Lanzafame  Carmelo Monaco  Luigi Tortorici   《Journal of Geodynamics》2009,48(2):75-82

Structural observations carried out on the volcanic Island of Pantelleria show that the tectonic setting is dominated by NNE trending normal faults and by NW-striking right-lateral strike-slip faults with normal component of motion controlled by a ≈N 100°E oriented extension. This mode of deformation also controls the development of the eruptive fissures, dykes and eruptive centres along NNE–SSW belts that may thus represent the surface response to crustal cracking with associated magma intrusions. Magmatic intrusions are also responsible for the impressive vertical deformations that affect during the Late Quaternary the south-eastern segment of the island and producing a large dome within the Pantelleria caldera complex. The results of the structural analysis carried out on the Island of Pantelleria also improves the general knowledge on the Late Quaternary tectonics of the entire Sicily Channel. ESE–WNW directed extension, responsible for both the tectonic and volcano-tectonic features of the Pantelleria Island, also characterizes, at a greater scale, the entire channel as shown by available geodetic and seismological data. This mode of extension reactivates the older NW–SE trending fault segments bounding the tectonic troughs of the Channel as right-lateral strike-slip faults and produces new NNE trending pure extensional features (normal faulting and cracking) that preferentially develop at the tip of the major strike-slip fault zones. We thus relate the Late Quaternary volcanism of the Pelagian Block magmatism to dilatational strain on the NNE-striking extensional features that develop on the pre-existing stretched area and propagate throughout the entire continental crust linking the already up-welled mantle with the surface.  相似文献   

Time dependence of negative buoyancy and the subduction of continental lithosphere   总被引：1，自引：0，他引：1  

Giorgio Ranalli  Rita Pellegrini  Sergio D&#x;Offizi 《Journal of Geodynamics》2000,30(5)

The time evolution of negative buoyancy of a subducting slab is modelled from the beginning of subduction under various kinematic conditions (dip angle and subduction velocity). The calculations take into account the thermal and density effects of the variations of the thermophysical parameters with temperature and pressure, and of phase transitions. The magnitude of the negative buoyancy increases during subduction of oceanic lithosphere, up to values in the (2–4) × 10¹³ N m⁻¹ range when the tip of the slab reaches a depth of 600–700 km. If continental material arrives at the trench and is subducted, the downward buoyancy decreases by an amount proportional to the volume of the subducted continental crust. Assuming that subduction stops when the buoyancy becomes zero, and that delamination of the continental crust or slab breakoff do not occur, the maximum downdip length of the subductable continental crust is estimated as a function of the dip angle, subduction velocity and geometry of the margin. In most cases, subduction of continental material down to depths of 100–250 km is possible, and continental subduction can continue for times up to 10–15 Ma if the velocity is low. These estimates are not significantly affected by the hypothetical occurrence of a metastable olivine wedge within the slab, and could be lower bounds if the lower continental crust is mafic and transforms to eclogite.  相似文献   

The mafic-ultramafic complex near Finero (Ivrea-Verbano Zone), II. Geochronology and isotope geochemistry   总被引：1，自引：0，他引：1  

Meihua Lu  Albrecht W. Hofmann  Maurizio Mazzucchelli  Giorgio Rivalenti 《Chemical Geology》1997,140(3-4):223-235

Whole-rock Nd and Sr isotopic compositions of the mafic-ultramafic complex near Finero demonstrate that the magma was derived from a depleted, perhaps MORB-type mantle reservoir. The Sm-Nd data for the Amphibole Peridotite unit can be interpreted as an isochron with an apparent age of 533 ± 20 Ma, which is consistent with a ²⁰⁷Pb/²⁰⁶Pb evaporation age of 549 ± 12 Ma of a single zircon grain from the Internal Gabbro unit. However, the interpretation of these apparent ages remains open to question. We therefore retain the alternative hypotheses that the intrusion occurred either about 533 or 270 Ma ago, the latter being the most likely age of emplacement of the much larger magma body near Balmuccia (Val Sesia). The implication of the older emplacement age (if correct) would be that the igneous complex may be related to the numerous amphibolite units, which are intercalated with the metapelites of the overlying Kinzigite Formation, and together with them may constitute an accretionary complex. In this case, the mafic-ultramafic complex itself might also be part of such an accretionary complex (as has been proposed for the Balmuccia peridotite).

Internal Sm-Nd isochrons involving grt, cpx, plag and amph from the Internal Gabbro unit yield concordant ages of 231 ± 23, 226 ± 7, 223 ± 10, 214 ± 17, and 203 ± 13 Ma. These results confirm published evidence for a separate, regional heating event about 215 ± 15 Ma ago.

Initial _Nd(533) values average +6.3 ± 0.4 for six samples of the Amphibole Peridotite unit and +6.0 ± 1.2 for ten samples of the External Gabbro unit. ⁸⁷Sr/⁸⁶Sr ratios require little or no age correction and range from 0.7026 to 0.7047 (with two outliers at 0.7053 and 0.7071). Strong correlations between ⁸⁷Sr/⁸⁶Sr and K₂O and weaker correlations between initial _Nd and K₂O imply a comparatively minor (≤ 10%) contamination of the External Gabbro magma by crustal material and a later alteration by a crustal or seawater-derived fluid. These results contrast sharply with the isotopic composition (negative _Nd and high ⁸⁷Sr/⁸⁶Sr values) of the associated mantle rocks, the Phlogopite Peridotite unit, which has been pervasively metasomatized by crustal fluids. This type of metasomatism and its isotopic signature are never seen in the magmatic complex. This evidence rules out any direct genetic relationship between the igneous complex and the mantle peridotite. The crust-mantle interaction is the opposite of that seen at Balmuccia, where the mantle peridotite is essentially ‘pristine’ and the magmatic body has been extensively contaminated by assimilation of crustal rocks.  相似文献   

K-Ar datability of altered rocks: variability of excess Ar in hydrothermal minerals     

Igor M Villa  Giorgio Taddeucci 《Bulletin of Volcanology》1991,54(1):84-86

⁴⁰Ar/³⁹ Ar stepwise heating on one hydrothermal anhydrite and two partly hydrothermalized feldspars from a borehole in Vulcano volcano show that the initial trapped Ar does not have a constant isotopic composition. The constant ⁴⁰Ar/³⁶Ar ratio of the anhydrite, 306±3, is not a well-defined endmember for the two feldspars, which record a variety of fluid compositions. As the system is young (<100 ka), radiogenic Ar is much less than excess Ar.  相似文献