Isotope dilution sector-field inductively coupled plasma mass spectrometry combined with extraction chromatography for rapid determination of 241Am in marine sediment samples: A case study in Sagami Bay, Japan     

Jian Zheng  Masatoshi Yamada 《Journal of Oceanography》2008,64(4):541-550

²⁴¹Am is a useful tracer for understanding biogeochemical processes in the marine environment. ²⁴¹Am also poses a potential radiation threat to human health due to the continuous increase of its concentration in the global environment. We report a rapid analytical method for determining ²⁴¹Am in marine sediments using isotope dilution sector-field inductively coupled plasma mass spectrometry (SF-ICP-MS) combined with a high-efficiency sample introduction system (APEX-Q). A selective CaF₂ co-precipitation procedure followed by TRU extraction chromatography was employed to effectively remove the major sediment matrix and to pre-concentrate ²⁴¹Am. We achieved an extremely low detection limit of 0.32 fg/g or 0.041 mBq/g (for 1 gram sediment), which is better than that of alpha spectrometry, and it allowed the accurate determination of ²⁴¹Am in low-level marine sediment samples. The accuracy and precision of the developed analytical method was evaluated using a laboratory prepared Am isotope standard solution and Ocean Sediment reference material (IAEA-368). The results were satisfactory. For sediment samples, overall chemical recoveries varied from 60–90%. The developed method was applied to the study of ²⁴¹Am depth distribution in Sagami Bay, Japan, where we observed different depth profiles between ²⁴¹Am activity and ^239+240Pu activity.  相似文献   

Improving the prospects for detecting extrasolar planets in gravitational microlensing events in 2002     

I. A.Bond  F.Abe  R. J.Dodd  J. B.Hearnshaw  P. M.Kilmartin  K.Masuda  Y.Matsubara  Y.Muraki  S.Noda  O. K. L.Petterson  N. J.Rattenbury  M.Reid  To.Saito  Y.Saito  T.Sako  J.Skuljan  D. J.Sullivan  T.Sumi  S.Wilkinson  R.Yamada  T.Yanagisawa  P. C. M.Yock 《Monthly notices of the Royal Astronomical Society》2002,331(2):L19-L23

Gravitational microlensing events of high magnification have been shown to be promising targets for detecting extrasolar planets. However, only a few events of high magnification have been found using conventional survey techniques. Here we demonstrate that high-magnification events can be readily found in microlensing surveys using a strategy that combines high-frequency sampling of target fields with on-line difference imaging analysis. We present 10 microlensing events with peak magnifications greater than 40 that were detected in real-time towards the Galactic bulge during 2001 by the Microlensing Observations in Astrophysics (MOA) project. We show that Earth-mass planets can be detected in future events such as these through intensive follow-up observations around the event peaks. We report this result with urgency as a similar number of such events are expected in 2002.  相似文献   

P–V–T equation of state of Mn3Al2Si3O12 spessartine garnet     

Steeve Gréaux  Akihiro Yamada 《Physics and Chemistry of Minerals》2014,41(2):141-149

The thermoelastic parameters of synthetic Mn₃Al₂Si₃O₁₂ spessartine garnet were examined in situ at high pressure up to 13 GPa and high temperature up to 1,100 K, by synchrotron radiation energy dispersive X-ray diffraction within a DIA-type multi-anvil press apparatus. The analysis of room temperature data yielded K ₀ = 172 ± 4 GPa and K ₀ ^′  = 5.0 ± 0.9 when V _0,300 is fixed to 1,564.96 Å³. Fitting of P–V–T data by means of the high-temperature third-order Birch–Murnaghan EoS gives the thermoelastic parameters: K ₀ = 171 ± 4 GPa, K ₀ ^′  = 5.3 ± 0.8, (?K _0,T /?T) _P  = ?0.049 ± 0.007 GPa K^?1, a ₀ = 1.59 ± 0.33 × 10^?5 K^?1 and b ₀ = 2.91 ± 0.69 × 10^?8 K^?2 (e.g., α _0,300 = 2.46 ± 0.54 × 10^?5 K^?1). Comparison with thermoelastic properties of other garnet end-members indicated that the compression mechanism of spessartine might be the same as almandine and pyrope but differs from that of grossular. On the other hand, at high temperature, spessartine softens substantially faster than pyrope and grossular. Such softening, which is also reported for almandine, emphasize the importance of the cation in the dodecahedral site on the thermoelastic properties of aluminosilicate garnet.  相似文献   

Movement of radiocaesium fallout released by the 2011 Fukushima nuclear accident     

Koji Minoura  Tsutomu Yamada  Shin-ichi Hirano  Shinji Sugihara 《Natural Hazards》2014,73(3):1843-1862

The moment magnitude (M _w) 9.0 Tohoku-Oki Earthquake occurred on March 11, 2011, generating an unusually large tsunami. The seismic shocks and tsunami inundation severely damaged the Fukushima Daiichi Nuclear Power Plant. Radionuclide emission due to reactor breakdown contaminated wide areas of Fukushima and its surroundings. Heavy rainfall causes runoff across surface soil, and fine soil particles are susceptible to uptake by the flowing water. The high radioactivity of grains suspended in floodwater indicates that radioactive fallout was streamed into rivers in particulate form and transported downstream under high-flow conditions. Here, we investigated the diachronic mode of ¹³⁴Cs and ¹³⁷Cs in central Fukushima, through which the contaminated air mass drifted and caused wet deposition of radionuclides. Stratigraphic measurements of radioactivity in sediment cores is the method employed in this study to determine the basin-wide movement of ¹³⁴Cs and ¹³⁷Cs, to evaluate the significance of the erosion–transportation–accumulation processes on natural decontamination in terrain characterized by steep slopes and high precipitation. Stratigraphic results illustrate the process of fluvial sediment discharge, and the massive deposition of radiocaesium suggests basin-wide movement of fallout during concentrated rainfall. Grain suspension in torrential currents is an important pathway for transportation of radionuclides from land to sea, and the appearance of hotspots on floodplains and the offshore sea floor is the consequence of erosion and transportation under seasonal heavy precipitation. Radioactive horizons occur in offshore sediment columns and thus radiocaesium discharged from the estuary will persist forever under the sea floor if no artificial disturbance occurs.  相似文献   

Occurrence of hydroxylated polychlorinated biphenyls in the brain of cetaceans stranded along the Japanese coast   总被引：1，自引：0，他引：1  

Kunisue T  Sakiyama T  Yamada TK  Takahashi S  Tanabe S 《Marine pollution bulletin》2007,54(7):963-973

Levels of hydroxylated polychlorinated biphenyls (OH-PCBs) and PCBs were measured in the brain of melon-headed whales (MW: Peponocephala electra), striped dolphins (SD: Stenella coeruleoalba) and finless porpoises (FP: Neophocaena phocaenoides) stranded along the Japanese coast during 2002-2003. Levels of OH-PCBs (including identified and unknown OH-P(5)CB, -H(6)CB, -H(7)CB and O(8)CB congeners) in the brain of MW, SD and FP were in the range of 20-290, 21-330 and 170-240pg/g wet wt., respectively. Observed OH-PCB levels were 2-3 orders of magnitude lower than PCBs in the same individuals. OH-PCBs/PCBs ratios in MW, SD and FP brain were lower than those in blood of humans and wildlife and in the brain of polar bears reported previously. OH-PCBs were also detected in maternal and fetal brain of SD (1 pair), suggesting transfer of OH-PCBs into the fetal brain of odontocete cetaceans. When fetus/dam concentration ratios of OH-PCB congeners detected in maternal and fetal brain were estimated, the values were higher than those of PCB congeners, implying that OH-PCBs in maternal blood could be more easily transferred into fetal brain via placenta than PCBs.  相似文献   

Study by MOA of extrasolar planets in gravitational microlensing events of high magnification     

I. A. Bond  N. J. Rattenbury  J. Skuljan  F. Abe  R. J. Dodd  J. B. Hearnshaw  M. Honda  J. Jugaku  P. M. Kilmartin  A. Marles  K. Masuda  Y. Matsubara  Y. Muraki  T. Nakamura  G. Nankivell  S. Noda  C. Noguchi  K. Ohnishi  M. Reid  To. Saito  H. Sato  M. Sekiguchi  D. J. Sullivan  T. Sumi  M. Takeuti  Y. Watase  S. Wilkinson  R. Yamada  T. Yanagisawa  P. C. M. Yock 《Monthly notices of the Royal Astronomical Society》2002,333(1):71-83

A search for extrasolar planets was carried out in three gravitational microlensing events of high magnification, MACHO  98–BLG–35  , MACHO  99–LMC–2  and OGLE  00–BUL–12  . Photometry was derived from observational images by the MOA and OGLE groups using an image subtraction technique. For MACHO  98–BLG–35  , additional photometry derived from the MPS and PLANET groups was included. Planetary modelling of the three events was carried out in a supercluster computing environment. The estimated probability for explaining the data on MACHO  98–BLG–35  without a planet is <1 per cent. The best planetary model has a planet of mass ∼(0.4–1.5)× M _Earth at a projected radius of either ∼1.5 or ∼2.3 au. We show how multiplanet models can be applied to the data. We calculate exclusion regions for the three events and find that Jupiter-mass planets can be excluded with projected radii from as wide as about 30 au to as close as around 0.5 au for MACHO  98–BLG–35  and OGLE  00–BUL–12  . For MACHO  99–LMC–2  , the exclusion region extends out to around 10 au and constitutes the first limit placed on a planetary companion to an extragalactic star. We derive a particularly high peak magnification of ∼160 for OGLE  00–BUL–12  . We discuss the detectability of planets with masses as low as Mercury in this and similar events.  相似文献   

Aeolian dust experiment on climate impact: An overview of Japan–China joint project ADEC   总被引：1，自引：1，他引：0  

M. Mikami  G.Y. Shi  I. Uno  S. Yabuki  Y. Iwasaka  M. Yasui  T. Aoki  T.Y. Tanaka  Y. Kurosaki  K. Masuda  A. Uchiyama  A. Matsuki  T. Sakai  T. Takemi  M. Nakawo  N. Seino  M. Ishizuka  S. Satake  K. Fujita  Y. Hara  K. Kai  S. Kanayama  M. Hayashi  M. Du  Y. Kanai  Y. Yamada  X.Y. Zhang  Z. Shen  H. Zhou  O. Abe  T. Nagai  Y. Tsutsumi  M. Chiba  J. Suzuki 《Global and Planetary Change》2006,52(1-4):142

The Aeolian Dust Experiment on Climate Impact (ADEC) was initiated in April 2000 as a joint five-year Japan–China project. The goal was to understand the impact of aeolian dust on climate via radiative forcing (RF). Field experiments and numerical simulations were conducted from the source regions in northwestern China to the downwind region in Japan in order to understand wind erosion processes temporal and spatial distribution of dust during their long-range transportation chemical, physical, and optical properties of dust and the direct effect of radiative forcing due to dust. For this, three intensive observation periods (IOP) were conducted from April 2002 to April 2004.The in situ and network observation results are summarized as follows: (1) In situ observations of the wind erosion process revealed that the vertical profile of moving sand has a clear size dependency with height and saltation flux and that threshold wind velocity is dependent on soil moisture. Results also demonstrated that saltation flux is strongly dependent on the parent soil size distribution of the desert surface. (2) Both lidar observations and model simulations revealed a multiple dust layer in East Asia. A numerical simulation of a chemical transport model, CFORS, illustrated the elevated dust layer from the Taklimakan Desert and the lower dust layer from the Gobi Desert. The global-scale dust model, MASINGAR, also simulated the dust layer in the middle to upper free troposphere in East Asia, which originated from North Africa and the Middle East during a dust storm in March 2003. Raman lidar observations at Tsukuba, Japan, found the ice cloud associated with the dust layer at an altitude of 6 to 9 km. Analysis from lidar and the radio-sonde observation suggested that the Asian dust acted as ice nuclei at the ice-saturated region. These results suggest the importance of dust's climate impact via the indirect effect of radiative forcing due to the activation of dust into ice nuclei. (3) Studies on the aerosol concentration indicated that size distributions of aerosols in downwind regions have bimodal peaks. One peak was in the submicron range and the other in the supermicron range. The main soluble components of the supermicron peak were Na⁺, Ca²⁺, NO₃⁻, and Cl⁻. In the downwind region in Japan, the dust, sea salt, and a mixture of the two were found to be dominant in coarse particles in the mixed boundary layer. (4) Observation of the optical properties of dust by sky-radiometer, particle shoot absorption photometer (PSAP), and Nephelometer indicated that unpolluted dust at source region has a weaker absorption than originally believed.A sensitivity experiment of direct RF by dust indicated that single scattering albedo is the most important of the optical properties of dust and that the sensitivity of instantaneous RF in the shortwave region at the top of the atmosphere to the refractive index strongly depends on surface albedo. A global scale dust model, MASINGAR, was used for evaluation of direct RF due to dust. The results indicated the global mean RF at the top and the bottom of the atmosphere were − 0.46 and − 2.13 W m^− 2 with cloud and were almost half of the RF with cloud-free condition.  相似文献   

The Hinode (Solar-B) Mission: An Overview     

T. Kosugi  K. Matsuzaki  T. Sakao  T. Shimizu  Y. Sone  S. Tachikawa  T. Hashimoto  K. Minesugi  A. Ohnishi  T. Yamada  S. Tsuneta  H. Hara  K. Ichimoto  Y. Suematsu  M. Shimojo  T. Watanabe  S. Shimada  J. M. Davis  L. D. Hill  J. K. Owens  A. M. Title  J. L. Culhane  L. K. Harra  G. A. Doschek  L. Golub 《Solar physics》2007,243(1):3-17

The Hinode satellite (formerly Solar-B) of the Japan Aerospace Exploration Agency’s Institute of Space and Astronautical Science (ISAS/JAXA) was successfully launched in September 2006. As the successor to the Yohkoh mission, it aims to understand how magnetic energy gets transferred from the photosphere to the upper atmosphere and results in explosive energy releases. Hinode is an observatory style mission, with all the instruments being designed and built to work together to address the science aims. There are three instruments onboard: the Solar Optical Telescope (SOT), the EUV Imaging Spectrometer (EIS), and the X-Ray Telescope (XRT). This paper provides an overview of the mission, detailing the satellite, the scientific payload, and operations. It will conclude with discussions on how the international science community can participate in the analysis of the mission data. T. Kosugi deceased 26 November 2006.  相似文献   

Statistical Analysis of Ground Motions Estimated on the Basis of a Recipe for Strong-motion Prediction: Approach to Quantitative Evaluation of Average and Standard Deviation of Ground Motion Distribution     

Masayuki Yamada  Shigeki Senna  Hiroyuki Fujiwara 《Pure and Applied Geophysics》2011,168(1-2):141-153

For seismic hazard assessment, we study the variabilities of predicted ground motion on the basis of a ??recipe for predicting strong ground motion?? and propose approximations to evaluate spatial distributions of the standard deviation for PGV, R1.0, R2.0, and R5.0 in the estimated ground motions. For strong-motion prediction, we use a finite difference method for a long period range (>1.0?s). To estimate variabilities, a Monte Carlo simulation is used and we adopt the Latin Hypercube Sampling (LHS) technique to reduce computations. In this article, we consider only aleatory variabilities in source parameters among all possible variabilities, such as those in the source parameters, the propagation characteristics and site characteristics. Model sources are assumed for dip-slip fault and strike-slip fault, and the variabilities are considered for parameters such as asperity location, rupture starting point, average asperity slip contrast, stress drop and rupture velocity. On the target site, 100 instances of PGV, R1.0, R2.0 and R5.0 data are obtained for 100 sets of parameters and an average and a standard deviation of the log normal distribution, corresponding to the variability for ground motion estimation, are statistically analyzed. For all target sites uniformly distributed in the area around the faults, the average and the standard deviation are statistically analyzed and spread to spatial maps. It is found that the spatial distributions of standard deviation values for both the dip-slip and strike-slip faults are not uniform. Approximations are attempted to develop a quantitative evaluation for spatial distributions of the standard deviation of the log normal distribution for PGV, R1.0, R2.0, and R5.0. The spatial distributions by these approximations are considered to almost reconstruct the characteristics, which are statistically analyzed by the finite difference method.  相似文献   

Contribution of abiogenic and biogenic particles to trace-metal composition of phytoplankton assemblages in seawater of Shimizu Port, Japan     

Masahiro Sakata  Masaki Yamada  Satoshi Mitsunobu  Yasuhiro Senga 《Journal of Oceanography》2012,68(5):807-813

The contribution of abiogenic and biogenic particles to trace-metal (As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sb, Ti, V, and Zn) composition was investigated for phytoplankton (primarily diatoms) collected in Shimizu Port, a coastal seawater region. Except for Cd, the trace metals occurred predominantly in lithogenic or nonlithogenic abiogenic particles associated with plankton. In contrast, it is likely that Cd in seawater is taken up intracellularly, and not adsorbed extracellularly by phytoplankton. The lower P-normalized quotas of Cd in Shimizu Port than in offshore regions may be because plankton are dominated by diatoms.  相似文献