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51.
Masayuki  Ehiro  Satoru  Kojima  Tadashi  Sato  Talat  Ahmad  Tomoyuki  Ohtani 《Island Arc》2007,16(1):124-132
Abstract   Callovian (late Middle Jurassic) ammonoids Macrocephalites and Jeanneticeras were recovered from the Shyok suture zone, northeast of Chang La Pass, Ladakh, northwest India. They are the first reliable Jurassic fossils and the oldest chronologic data from the Shyok suture zone. The ammonoid-bearing Jurassic strata, newly defined as the Tsoltak Formation, consist largely of terrigenous mudstone with thin sandstone beds and were probably a part of the continental basement to the Cretaceous Ladakh Arc.  相似文献   
52.
Histological examination of gonads as well as chemical analysis of organotin compounds in tissues of the giant abalone, Haliotis madaka, was conducted to evaluate continuing endocrine disruption in abalone populations in Japan. Abalone specimens were collected from two different areas, Tsushima as a reference site and Jogashima as a site representative of declining abalone populations where serious organotin contamination had been observed, each month from January 1998 to March 1999. Scores were given to the development stages of reproductive cells in the ovary and testis. The degree of sexual maturation was evaluated by calculating the mean value of a histogram of these scores for the reproductive cells of each abalone. The temporal variations in degree of sexual maturation showed that female and male abalone from Tsushima matured synchronously, while those from Jogashima did not, which were similar to results of the previous study during September 1995–November 1996. Approximately 19% of the female abalone from Jogashima were masculinized with an ovo-testis, which was also similar to the result of the previous study. The masculinization of female abalone is reported to be induced by tributyltin (TBT) and triphenyltin (TPhT) from antifouling paints. Concentrations of the sum of butyltins (TBT, dibutyltin (DBT) and monobutyltin (MBT): ΣBTs) and the sum of phenyltins (TPhT, diphenyltin (DPhT) and monophenyltin (MPhT): ΣPhTs) in the muscle of abalone from Jogashima (n = 73) of 7.8 ± 9.0 ng/g wet wt. and 4.5 ± 6.8 ng/g wet wt., respectively, were significantly higher than those from Tsushima (n = 87) of 4.7 ± 4.9 ng/g wet wt. and 0.8 ± 1.7 ng/g wet wt., respectively (p < 0.05 for ΣBTs; p < 0.001 for ΣPhTs), although concentrations of TBT and TPhT in the muscle of abalone from Jogashima (n = 73) of 2.2 ± 2.5 ng/g wet wt. and 5.8 ± 5.1 ng/g wet wt., respectively, were insignificantly and significantly higher than those from Tsushima (n = 87) of 0.4 ± 0.6 ng/g wet wt. and 0.5 ± 0.9 ng/g wet wt., respectively, (p > 0.05 for TBT; p < 0.001 for TPhT). Thus, endocrine disruption as well as contamination by organotins in the giant abalone from Jogashima is still persisting.  相似文献   
53.
Molybdenum is an economically important subproduct of North Chilean porphyry‐type deposits, and thus spatial and temporal distribution of molybdenite as the primary Mo‐bearing mineral in the Escondida and Escondida Norte deposits were characterized using several mineralogical and chemical techniques and the Re‐Os dating method. Molybdenum is distributed extensively in the two deposits, and high molybdenum concentrations (>500 ppm) are recognized particularly in the chlorite‐sericite transitional zone between the potassic and sericitic zones. Two modes of occurrence of molybdenite are observed in the Escondida deposit: aggregates with Cu‐Fe‐sulfide minerals in fine veinlets (sulfide‐veinlet type), and monomineralic microveinlets associated with NE‐trending faults. The former and the latter yielded ages of 36.1 ± 0.2 Ma and 35.2 ± 0.2 Ma, respectively. Re‐Os dating of Escondida Norte molybdenites also show two distinct episodes, at 37.7 ± 0.3 Ma and a younger episode at 36.6 ± 0.2 Ma. These data indicate that the Escondida Norte is older than the main Escondida deposit. The Re‐Os age data combined with those of the porphyry emplacement suggest that the molybdenite mineralization in the Escondida district occurred as several short episodic pulses during the late‐magmatic to hydrothermal transition, and that the Cu‐Mo deposits were formed in a variable overall period spanning 1 to 5 m.y.  相似文献   
54.
Modes of occurrence of Au‐ and Ag‐bearing phases and their relation with associated hypogene ore minerals were examined with the objective to elucidate Au‐Ag distribution at the Esperanza porphyry deposit in the Eocene Centinela copper belt, using ore‐microscope modal analysis, semi‐quantitative analyses by automated mineralogy, electron probe microanalysis, and secondary ion mass spectrometer. The Esperanza hypogene mineralization is characterized by early‐stage chalcopyrite‐rich veinlets in the potassic alteration zone and later polymetallic stage with tennantite and galena in the chlorite‐sericitic alteration zone. Only the early‐stage chalcopyrite contains fine‐grained electrum (Au68Ag32 ‐ Au81Ag19) and hessite (Ag2Te), and thus yields positive correlations in Cu vs. Au and Cu vs. Ag grades that are clearly recognized in the hypogene sulfide zone. The early‐stage chalcopyrite grains frequently exhibit polysynthetic twinning suggestive of inversion from intermediate solid solution. These features suggest that the fine‐grained electrum and hessite are products exsolved in the cooling process with the intermediate solid solution to chalcopyrite inversion. In contrast, tennantite and galena of the later‐stage mineralization contain no detectable Ag, and it is thus proposed that the early‐stage inverted chalcopyrite is the principal storage of economically important precious metals.  相似文献   
55.
The paleolimnology of two lakes which were isolated as a result of the crustal uplift during the late Holocene along the Soya Coast, Lützow-Holm Bay, East Antarctica were studied. The focus was on temporal variations in the biogeochemical composition of sediment cores recovered from Lake Skallen at Skallen and Lake Oyako at Skarvsnes. Both sets of lake sediments record environmental changes associated with a transition from marine to lacustrine settings, as indicated by analyses of C and N contents, nitrogen isotopic compositions (δ15N), and major element concentrations. Changes in the dominant primary producers during the marine–lacustrine transition (marine diatom to cyanobacteria) at L. Skallen was clearly revealed by biogenic opal-A, diatom assemblages, and molecular signature from denaturing gradient gel electrophoresis (DGGE) with 16S ribosomal RNA (rRNA) gene analysis. Radiocarbon dating of acid-insoluble organic C suggested that the environmental transition from marine to fresh water occurred at 2940 ± 100 cal yr BP at L. Skallen and 1060 ± 90 cal yr BP at L. Oyako. Based on these data, a mean crustal uplift rate of 3.2 mm yr−1 is inferred for the history of marine–lacustrine transition via brackish conditions. The geological setting causing glacio-isostatic uplift was the primary factor in controlling the transition event in sedimentary and biological facies.  相似文献   
56.
A statistical analysis of two consecutive sequences of observations on radiolarian abundances in the western North Pacific, by methods appropriate to data on the simplex (i.e., compositional data), show that although the overall graphical presentations of the frequencies appear similar, there are substantial differences in the earlier part of each of the series. The results of the multivariate analyses are used for identifying those species that contribute most to the analysis. A brief guide to the mathematical properties of compositional data is given.  相似文献   
57.
58.
The concentrations of Cu, Ni and Cd were determined in Funka Bay during a spring phytoplankton bloom, consisting of diatoms. Just after the bloom, both dissolved Cd and nutrients were removed in the euphotic zone. However, the removal ratio of Cd to phosphate was very different from that in seawater. The removal of Cd took place at a Cd/phosphate ratio of 0.07×10−3, which was lower than in seawater before the bloom (0.25×10−3), leading to an increase in this ratio in seawater exceeding 0.7×10−3 at the end of the bloom. Elevated concentrations of Cd and phosphate were observed in the deeper layer after the bloom due to the decomposition of detrital materials produced in the bloom. The ratio of Cd/phosphate in the regeneration step was 0.24×10−3 which was different from the removal ratio of 0.07×10−3. These observations suggest that the high Cd/phosphate ratio in the regeneration would reflect a relatively high regeneration rate of Cd than that of phosphate. No significant decrease in Cu and Ni concentrations was observed during the development of the bloom, suggesting that biological removal of these metals was not so significant during the spring bloom. The concentrations of Cd, Cu and silicate in surface waters increased after the bloom with decreasing salinity due to the influence of a spring thaw.  相似文献   
59.
Journal of Oceanology and Limnology -  相似文献   
60.
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