Wind-Driven Dissolved Organic Matter Dynamics in a Chesapeake Bay Tidal Marsh-Estuary System     

J. Blake Clark  Wen Long  Maria Tzortziou  Patrick J. Neale  Raleigh R. Hood 《Estuaries and Coasts》2018,41(3):708-723

Controls on organic matter cycling across the tidal wetland-estuary interface have proved elusive, but high-resolution observations coupled with process-based modeling can be a powerful methodology to address shortcomings in either methodology alone. In this study, detailed observations and three-dimensional hydrodynamic modeling are used to examine biogeochemical exchanges in the marsh-estuary system of the Rhode River, MD, USA. Analysis of observations near the marsh in 2015 reveals a strong relationship between marsh creek salinity and dissolved organic matter fluorescence (fDOM), with wind velocity indirectly driving large amplitude variation of both salinity and fDOM at certain times of the year. Three-dimensional model results from the Finite Volume Community Ocean Model implemented for the wetland system with a new marsh grass drag module are consistent with observations, simulating sub-tidal variability of marsh creek salinity. The model results exhibit an interaction between wind-driven variation in surface elevation and flow velocity at the marsh creek, with northerly winds driving increased freshwater signal and discharge out of the modeled wetland during precipitation events. Wind setup of a water surface elevation gradient axially along the estuary drives the modeled local sub-tidal flow and thus salinity variability. On sub-tidal time scales (>36 h, <1 week), wind is important in mediating dissolved organic matter releases from the Kirkpatrick Marsh into the Rhode River.  相似文献   

Impact of drilling mud on chemistry and microbiology of an Upper Triassic groundwater after drilling and testing an exploration well for aquifer thermal energy storage in Berlin (Germany)     

Simona Regenspurg  Mashal Alawi  Guido Blöcher  Maria Börger  Stefan Kranz  Ben Norden  Ali Saadat  Traugott Scheytt  Lioba Virchow  Andrea Vieth-Hillebrand 《Environmental Earth Sciences》2018,77(13):516

After completion of an exploration well, sandstones of the Exter Formation were hydraulically tested to determine the hydraulic properties and to evaluate chemical and microbial processes caused by drilling and water production. The aim was to determine the suitability of the formation as a reservoir for aquifer thermal energy storage. The tests revealed a hydraulic conductivity of 1–2 E-5 m/s of the reservoir, resulting in a productivity index of 0.6–1 m³/h/bar. A hydraulic connection of the Exter Formation to the overlaying, artesian “Rupelbasissand” cannot be excluded. Water samples were collected for chemical and microbiological analyses. The water was similarly composed as sea water with a maximum salinity of 24.9 g/L, dominated by NaCl (15.6 g/L Cl and 7.8 g/L Na). Until the end of the tests, the water was affected by drilling mud as indicated by the high pH (8.9) and high bicarbonate concentration (359 mg/L) that both resulted from the impact of sodium carbonate (Na₂CO₃) additives. The high amount of dissolved organic matter (>?58 mg/L) and its molecular-weight distribution pattern indicated that residues of cellulose, an ingredient of the drilling mud, were still present at the end of the tests. Clear evidence of this contamination gave the measured uranine that was added as a tracer into the drilling mud. During fluid production, the microbial community structure and abundance changed and correlated with the content of drilling mud. Eight taxa of sulfate-reducing bacteria, key organisms in processes like bio-corrosion and bio-clogging, were identified. It can be assumed that their activity will be affected during usage of the reservoir.  相似文献   

Ecotoxicological evaluation of dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro State,Brazil) using bioassays with earthworms and collembolans     

Mariana Vezzone  Ricardo Cesar  Helena Polivanov  Aline Serrano  Danielle Siqueira  Leticia Abreu  Miriam Bianchi  Maria Elizabeth Correia  Zuleica Castilhos  Tácio de Campos 《Environmental Earth Sciences》2018,77(21):743

The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.  相似文献   

Spectral data source effect on crop state estimation by vegetation indices     

Maria Polinova  Thomas Jarmer  Anna Brook 《Environmental Earth Sciences》2018,77(22):752

Spectral vegetation indices (VIs) are a well-known and widely used method for crop state estimation. The ability to monitor crop state by such indices is an important tool for agricultural management. Even though differences in imagery and point-based spectroscopy are obvious, their impact on crop state estimation by VIs is not well-studied. The aim of this study was to assess the performance level of the selected VIs calculated from spaceborne multispectral imagery and point-based field spectroscopy in application to crop state estimation. For this purpose, irrigated chickpea field was monitored by RapidEye satellite mission and additional measurements by field spectrometer were obtained. Estimated VIs average and coefficient of variation from each observation were compared with physical crop measurements: leaf water content, LAI and chlorophyll level. The results indicate that indices calculated from spaceborne spectral images regardless of the claimed response commonly react on phenology of the irrigated chickpea. This feature makes spaceborne spectral imagery an appropriate data source for monitoring crop development, crop water needs and yield prediction. VIs calculated from field spectrometer were sensitive for estimating pigment concentration and photosynthesis rate. Yet, a hypersensitivity of field spectral measures might lead to a very high variability (up to 69%) of the calculated values. Consequently, the high spatial variability of field spectral measurements depreciates the estimation agricultural field state by average mean only. Nevertheless, the spatial variability might have certain behavior trend, e.g., a significant increase in the active growth or stress and can be an independent feature for field state assessment.  相似文献   

Composition of barian mica in multiphase solid inclusions from orogenic garnet peridotites as evidence of mantle metasomatism in a subduction zone setting     

Renata??opjakováEmail authorView author&#;s OrcID profile  Jana?Kotková 《Contributions to Mineralogy and Petrology》2018,173(12):106

Multiphase solid inclusions in minerals formed at ultra-high-pressure (UHP) provide evidence for the presence of fluids during deep subduction. This study focuses on barian mica, which is a common phase in multiphase solid inclusions enclosed in garnet from mantle-derived UHP garnet peridotites in the Saxothuringian basement of the northern Bohemian Massif. The documented compositional variability and substitution trends provide constraints on crystallization medium of the barian mica and allow making inferences on its source. Barian mica in the multiphase solid inclusions belongs to trioctahedral micas and represents a solid solution of phlogopite KMg₃(Si₃Al)O₁₀(OH)₂, kinoshitalite BaMg₃(Al₂Si₂)O₁₀(OH)₂ and ferrokinoshitalite BaFe₃(Al₂Si₂)O₁₀(OH)₂. In addition to Ba (0.24–0.67 apfu), mica is significantly enriched in Mg (X_Mg ~ 0.85 to 0.95), Cr (0.03–0.43 apfu) and Cl (0.04–0.34 apfu). The substitution vector involving Ba in the I-site which describes the observed chemical variability can be expressed as BaFe^IVAlClK_?1Mg_?1Si_?1(OH)_?1. A minor amount of Cr and ^VIAl enters octahedral sites following a substitution vector ^VI(Cr,Al)₂□^VI(Mg,Fe)_?3 towards chromphyllite and muscovite. As demonstrated by variable Ba and Cl contents positively correlating with Fe, barian mica composition is partly controlled by its crystal structure. Textural evidence shows that barian mica, together with other minerals in multiphase solid inclusions, crystallized from fluids trapped during garnet growth. The unusual chemical composition of mica reflects the mixing of two distinct sources: (1) an internal source, i.e. the host peridotite and its garnet, providing Mg, Fe, Al, Cr, and (2) an external source, represented by crustal-derived subduction-zone fluids supplying Ba, K and Cl. At UHP–UHT conditions recorded by the associated diamond-bearing metasediments (c. 1100 °C and 4.5 GPa) located above the second critical point in the pelitic system, the produced subduction-zone fluids transporting the elements into the overlying mantle wedge had a solute-rich composition with properties of a hydrous melt. The occurrence of barian mica with a specific chemistry in barium-poor mantle rocks demonstrates the importance of its thorough chemical characterization.  相似文献   

Hydrologic models coupled with 2D hydrodynamic model for high-resolution urban flood simulation     

de Arruda Gomes  Mayara Maria  de Melo Verçosa  Lívia Fragoso  Cirilo  José Almir 《Natural Hazards》2021,108(3):3121-3157

Natural Hazards - Floods are the most frequent natural disaster and pose a very challenging threat to many cities worldwide. Understanding the flood dynamic is essential for developing strategies...  相似文献   

Methodological challenges to confirmatory latent variable models of social vulnerability     

Goodman  Zachary T.  Stamatis  Caitlin A.  Stoler  Justin  Emrich  Christopher T.  Llabre  Maria M. 《Natural Hazards》2021,106(3):2731-2749

Natural Hazards - Socially vulnerable communities experience disproportionately negative outcomes following natural disasters and underscoring a need for well-validated measures to identify those...  相似文献   

Testing the consistency of Holocene and Last Glacial Maximum spatial correlations in temperature proxy records     

Maria Reschke  Igor Kröner  Thomas Laepple 《第四纪科学杂志》2021,36(1):20-28

Holocene temperature proxy records are commonly used in quantitative synthesis and model-data comparisons. However, comparing correlations between time series from records collected in proximity to one another with the expected correlations based on climate model simulations indicates either regional or noisy climate signals in Holocene temperature proxy records. In this study, we evaluate the consistency of spatial correlations present in Holocene proxy records with those found in data from the Last Glacial Maximum (LGM). Specifically, we predict correlations expected in LGM proxy records if the only difference to Holocene correlations would be due to more time uncertainty and more climate variability in the LGM. We compare this simple prediction to the actual correlation structure in the LGM proxy records. We found that time series data of ice-core stable isotope records and planktonic foraminifera Mg/Ca ratios were consistent between the Holocene and LGM periods, while time series of Uk'37 proxy records were not as we found no correlation between nearby LGM records. Our results support the finding of highly regional or noisy marine proxy records in the compilation analysed here and suggest the need for further studies on the role of climate proxies and the processes of climate signal recording and preservation.  相似文献   

A novel methodological approach for land subsidence prediction through data assimilation techniques     

Gazzola  Laura  Ferronato  Massimiliano  Frigo  Matteo  Janna  Carlo  Teatini  Pietro  Zoccarato  Claudia  Antonelli  Massimo  Corradi  Anna  Dacome  Maria Carolina  Mantica  Stefano 《Computational Geosciences》2021,25(5):1731-1750

Computational Geosciences - Anthropogenic land subsidence can be evaluated and predicted by numerical models, which are often built over deterministic analyses. However, uncertainties and...  相似文献   

What drives policy change for REDD+? A qualitative comparative analysis of the interplay between institutional and policy arena factors     

Kaisa Korhonen-Kurki  Maria Brockhaus  Jenniver Sehring  Monica Di Gregorio  Samuel Assembe-Mvondo  Andrea Babon 《Climate Policy》2019,19(3):315-328

Reducing Emissions from Deforestation and forest Degradation (REDD+) has emerged as a promising climate change mitigation mechanism in developing countries. In order to identify the enabling conditions for achieving progress in the implementation of an effective, efficient and equitable REDD+, this paper examines national policy settings in a comparative analysis across 13 countries with a focus on both institutional context and the actual setting of the policy arena. The evaluation of REDD+ revealed that countries across Africa, Asia and Latin America are showing some progress, but some face backlashes in realizing the necessary transformational change to tackle deforestation and forest degradation. A Qualitative Comparative Analysis (QCA) undertaken as part of the research project showed two enabling institutional configurations facilitating progress: (1) the presence of already initiated policy change; and (2) scarcity of forest resources combined with an absence of any effective forestry framework and policies. When these were analysed alongside policy arena conditions, the paper finds that the presence of powerful transformational coalitions combined with strong ownership and leadership, and performance-based funding, can both work as a strong incentive for achieving REDD+ goals.

Key policy insights

• The positive push of already existing policy change, or the negative stress of resource scarcity together with lack of effective policies, represents institutional conditions that can support REDD+ progress.

• Progress also requires the presence of powerful transformational coalitions and strong ownership and leadership. In the absence of these internal drivers, performance-based funding can work as a strong incentive.

• When comparing three assessments (2012, 2014, 2016) of REDD+ enabling conditions, some progress in establishing processes of change can be observed over time; however, the overall fluctuation in progress of most countries reveals the difficulty in changing the deforestation trajectory away from business as usual.

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