Fitness-for-Purpose of Reference Material Reference Values in Relation to Traceability of Measurement, as Illustrated by USGS BCR-1, NIST SRM 610 and IAEA NBS28   总被引：1，自引：0，他引：1  

Jean S. Kane 《Geostandards and Geoanalytical Research》2002,26(1):7-29

As in all fields of sample analysis, reference materials play a large role in supporting measurements in the geosciences. While a rather large number of materials are in distribution (> 380), not all are equally effective or fit-for-purpose in supporting laboratory data quality and thereby assuring the desired comparability of measurements between laboratories. Equally important, reference values that are not fit-for-purpose cannot be used effectively to establish traceability links between laboratory measurements and national and international standards. The needed fitness-for-purpose is not achieved for reference values either when more than one reference value has been proposed and a consensus does not exist among users as to which should be used by all, or when reference value uncertainties are too large in comparison to those of routine laboratory measurements. The focus of this review will be, first to outline the current reality, and second to suggest ways in which certifications of RMs can be improved to provide reference values that are universally accepted and more fit-for-purpose in general laboratory use. The discussion will be illustrated largely by current uses of USGS BCR-1, NIST SRM 610 and IAEA NBS28, as these three materials are those for which the largest body of newly published data exists, according to recent bibliographies of the geoanalytical literature published annually in Geostandards Newsletter: The Journal of Geostandards and Geoanalysis.  相似文献   

Use of Chemotaxonomy To Study the Influence of Benzalkonium Chloride on Bacterial Populations in Biodegradation Testing     

Klaus Kümmerer  Ali Al‐Ahmad  Almut Henninger 《洁净——土壤、空气、水》2002,30(4):171-178

Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days).  相似文献   

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period     

Jean‐Jacques Macaire  Saïda Bellemlih  Christian Di‐Giovanni  Patrick De Luca  Lionel Visset  Jacques Bernard 《地球表面变化过程与地形》2002,27(9):991-1009

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

La « Mission d'Andalousie », expédition géologique de l'Académie des sciences de Paris à la suite du grand séisme de 1884The ‘Mission d'Andalousie’, a geological expedition of the French Academy of Sciences,following the great Andalusian earthquake of 1884     

Jean Bonnin  Michel Durand-Delga  André Michard 《Comptes Rendus Geoscience》2002,334(10):795-808

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塔巴庙地区上古生界砂岩成岩作用特征及其储集性分析   总被引：12，自引：3，他引：12  

雷开强  孔繁征  张哨楠  李秀华 《矿物岩石》2003,23(3):92-96

鄂尔多斯盆地北部塔巴庙地区上古生界发育一套低孔低渗致密砂岩储层，储集空间以溶蚀微孔、蜂窝状溶孔和高岭石晶间隙为主，孔喉以细——微细为主。成岩作用决定了砂岩内部储集空间特征和储集性能，主要表现在较强的压实作用和胶结作用使砂岩的原生孔隙很少得到保存；较弱的溶蚀作用和强的蚀变作用使砂岩储集空间以微孔、超微孔为主，具有孔径小喉道细的特征，这是砂岩储集物性特别是渗透率偏低的直接原因。  相似文献   

Asymmetric one‐storey elastic systems with non‐linear viscous and viscoelastic dampers: Simplified analysis and supplemental damping system design     

Wen‐Hsiung Lin  Anil K. Chopra 《地震工程与结构动力学》2003,32(4):579-596

Investigated is the accuracy in estimating the response of asymmetric one‐storey systems with non‐linear viscoelastic (VE) dampers by analysing the corresponding linear viscous system wherein all non‐linear VE dampers are replaced by their energy‐equivalent linear viscous dampers. The response of the corresponding linear viscous system is determined by response history analysis (RHA) and by response spectrum analysis (RSA) extended for non‐classically damped systems. The flexible and stiff edge deformations and plan rotation of the corresponding linear viscous system determined by the extended RSA procedure is shown to be sufficiently accurate for design applications with errors generally between 10 and 20%. Although similar accuracy is also shown for the ‘pseudo‐velocity’ of non‐linear VE dampers, the peak force of the non‐linear VE damper cannot be estimated directly from the peak damper force of the corresponding linear viscous system. A simple correction for damper force is proposed and shown to be accurate (with errors not exceeding 15%). For practical applications, an iterative linear analysis procedure is developed for determining the amplitude‐ and frequency‐dependent supplemental damping properties of the corresponding linear viscous system and for estimating the response of asymmetric one‐storey systems with non‐linear VE dampers from the earthquake design (or response) spectrum. Finally, a procedure is developed for designing non‐linear supplemental damping systems that satisfy given design criteria for a given design spectrum. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Inelastic displacement ratios for evaluation of existing structures     

Jorge Ruiz‐García  Eduardo Miranda 《地震工程与结构动力学》2003,32(8):1237-1258

Results of a detailed statistical study of constant relative strength inelastic displacement ratios to estimate maximum lateral inelastic displacement demands on existing structures from maximum lateral elastic displacement demands are presented. These ratios were computed for single‐degree‐of‐freedom systems with different levels of lateral strength normalized to the strength required to remain elastic when subjected to a relatively large ensemble of recorded earthquake ground motions. Three groups of soil conditions with shear wave velocities higher than 180m/s are considered. The influence of period of vibration, level of lateral yielding strength, site conditions, earthquake magnitude, distance to the source, and strain‐hardening ratio are evaluated and discussed. Mean inelastic displacement ratios and those associated with various percentiles are presented. A special emphasis is given to the dispersion of these ratios. It is concluded that distance to the source has a negligible influence on constant relative strength inelastic displacement ratios. However, for periods smaller than 1s earthquake magnitude and soil conditions have a moderate influence on these ratios. Strain hardening decreases maximum inelastic displacement at a fairly constant rate depending on the level of relative strength for periods of vibration longer than about 1.0s while it decreases maximum inelastic displacement non‐linearly as the period of vibration shortens and as the relative‐strength ratio increases for periods of vibration shorter than 1.0s. Finally, results from non‐linear regression analyses are presented that provide a simplified expression to be used to approximate mean inelastic displacement ratios during the evaluation of existing structures built on firm sites. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

鲁东官山榴辉岩与围岩接触关系的新发现及其对年代学的启示   总被引：14，自引：2，他引：14       下载免费PDF全文

宋明春  金振民  王来明  张希道  李远友 《地质学报》2003,77(2):238-244

鲁东官山榴辉岩呈透镜状包于变质含霓石碱性花岗岩中,榴辉岩的片麻理与主岩片麻理总体呈交切关系,局部可见变质含霓石碱性花岗岩呈细小岩枝状脉贯入榴辉岩中。变质含霓石碱性花岗岩锆石U-Pb法下交点年龄为231±25 Ma,上交点年龄为818±66 Ma。发现了闪长玢岩脉斜切式侵入榴辉岩及变质含霓石碱性花岗岩的接触关系,且闪长玢岩脉中有榴辉岩捕虏体,这种现象指示:闪长玢岩侵位时榴辉岩已折返至地壳较浅部位。研究表明,榴辉岩与变质含霓石碱性花岗岩共同经历了新元古代的超高压变质作用,但变质作用发生时含霓石碱性花岗岩可能处于熔融状态,榴辉岩是其中的固相包体。  相似文献   

Landslide susceptibility analysis using GIS and artificial neural network     

Saro Lee  Joo‐Hyung Ryu  Kyungduck Min  Joong‐Sun Won 《地球表面变化过程与地形》2003,28(12):1361-1376

The purpose of this study is to develop landslide susceptibility analysis techniques using an arti?cial neural network and to apply the newly developed techniques to the study area of Yongin in Korea. Landslide locations were identi?ed in the study area from interpretation of aerial photographs, ?eld survey data, and a spatial database of the topography, soil type and timber cover. The landslide‐related factors (slope, curvature, soil texture, soil drainage, soil effective thickness, timber age, and timber diameter) were extracted from the spatial database. Using those factors, landslide susceptibility was analysed by arti?cial neural network methods. The landslide susceptibility index was calculated by the back‐propagation method, which is a type of arti?cial neural network method, and the susceptibility map was made with a geographic information system (GIS) program. The results of the landslide susceptibility analysis were veri?ed using landslide location data. The validation results showed satisfactory agreement between the susceptibility map and the existing data on landslide location. A GIS was used to ef?ciently analyse the vast amount of data, and an arti?cial neural network to be an effective tool to maintain precision and accuracy. The results can be used to reduce hazards associated with landslides and to plan land use and construction. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

A procedure for evaluating seismic energy demand of framed structures     

Chung‐Che Chou  Chia‐Ming Uang 《地震工程与结构动力学》2003,32(2):229-244

Energy serves as an alternative index to response quantities like force or displacement to include the duration‐related seismic damage effect. A procedure to evaluate the absorbed energy in a multistorey frame from energy spectra was developed. For low‐ to medium‐rise frames, it required a static pushover analysis of the structure to determine the modal yield force and ductility factor of an equivalent single‐degree‐of‐freedom system for the first two modes. The energy spectra were then used to determine the energy contribution of each mode. A procedure was also developed to distribute the energy along the frame height based on energy shapes. This study showed that the second‐mode response in some cases needs to be considered to reflect the energy (or damage) concentration in the upper floors. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献