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61.
North-West Europe yields few traces of early human occupation, in particular for the Acheulean. In this context, the Somme Valley in northern France offers a route to Britain during various Pleistocene low sea levels, and has provided numerous evidence of Lower Palaeolithic human occupation through fieldwork initiated during the 19th century. These localities are associated with the original definition in the 1930s by the French prehistorian Abbé Henri Breuil of the ‘Abbevillien’ (Abbevillian facies), based on lithic pieces including crudely made bifaces recovered in particular in some famous key localities of Abbeville, Carpentier, Léon and Moulin Quignon quarries. The history of the term and its definition subsequently gave rise to debates concerning the chronocultural framework of Palaeolithic assemblages among the scientific community of prehistorians over time, from Jacques Boucher de Perthes, Gabriel de Mortillet, Geoffroy d'Ault du Mesnil, Victor Commont, Henri Breuil and François Bordes. New investigations at these three localities, all associated with the High Terrace of the Somme system, pushed back the age of the expansion of the Acheulean both in northern France and in Western Europe to c. 670–650 000 years. They imply that early hominins were able to settle in North-West Europe during both climatic temperate and cold phases. Our work, including new excavations and associated field observations of the three Abbeville localities involved at the onset of the controversy, allows a re-examination of the Abbevillian and contributes to the discussion of the history of Prehistoric Science and the Earliest ‘Acheuleans’ in North-West Europe.  相似文献   
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Despite the importance of tropical ecosystems for climate regulation, biodiversity, water and nutrient cycles, only a few Critical Zone Observatories (CZOs) are located in the tropics. Among these, most are in humid climates, while very few data exist for semi-arid and sub-humid climates, due to the difficulty of estimating hydro-geochemical balances in catchments with ephemeral streams. We contribute to fill this gap by presenting a meteorological and hydro-geochemical dataset acquired at the Mule Hole catchment (4.1 km2), a pristine dry deciduous forest located in a biosphere reserve in south India. The dataset consists of time series of variables related to (i) meteorology, including rainfall, air temperature, relative humidity, wind speed and direction, and global radiation, (ii) hydrology, including water level and discharge at the catchment outlet, (iii) hydrogeology, including manual (monthly) and/or automated (from 15 min to hourly) groundwater levels in nine piezometers and (iv) geochemistry, including suspended sediment content in the stream and chemical composition of rainfall (event based), groundwater (monthly sampling) and stream water (storm events, 15 min to hourly frequency with an automatic sampler). The time series extend from 2003 to 2019. Measurement errors are minimized by frequent calibration of sensors and quality checks, both in the field and in the laboratory. Despite these precautions, several data gaps exist, due to occasional access restriction to the site and instrument destruction by wildlife. Results show that large seasonal and interannual variations of climatic conditions were reflected in the large variations of stream flow and groundwater recharge, as well as in water chemical composition. Notably, they reveal a long-term evolution of groundwater storage, suggesting hydrogeological cycles on a decadal scale. This dataset, alone or in combination with other data, has already allowed to better understand water and element cycling in tropical dry forests, and the role of forest diversity on biogeochemical cycles. As tropical ecosystems are underrepresented by Critical Zone Observatories, we expect this data note to be valuable for the global scientific community.  相似文献   
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The dissolution rates of natural fluorapatite (FAP), Ca10(PO4)6F2, were measured at 25 °C in mixed-flow reactors as a function of pH from 3.0 to 11.7, and aqueous calcium, phosphorus, and fluoride concentration. After an initial preferential Ca and/or F release, stoichiometric Ca, P, and F release was observed. Measured FAP dissolution rates decrease with increasing pH at 3 ? pH ? 7, FAP dissolution rates are pH independent at 7 ? pH ? 10, and FAP dissolution rates again decrease with increasing pH at pH ? 10. Measured FAP dissolution rates are independent of aqueous Ca, P, and F concentration at pH ≈ 3 and pH ≈ 10.Apatite dissolution appears to be initiated by the relatively rapid removal from the near surface of F and the Ca located in the M1 sites, via proton for Ca exchange reactions. Dissolution rates are controlled by the destruction of this F and Ca depleted surface layer. The destruction of this layer is facilitated by the adsorption/penetration of protons into the surface at acidic conditions, and by surface hydration at neutral and basic conditions. Taking into account these two parallel mechanisms, measured fluorapatite forward dissolution rates can be accurately described using
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The European Venus Explorer (EVE) mission described in this paper was proposed in December 2010 to ESA as an ‘M-class’ mission under the Cosmic Vision programme. It consists of a single balloon platform floating in the middle of the main convective cloud layer of Venus at an altitude of 55?km, where temperatures and pressures are benign (~25°C and ~0.5 bar). The balloon float lifetime would be at least 10 Earth days, long enough to guarantee at least one full circumnavigation of the planet. This offers an ideal platform for the two main science goals of the mission: study of the current climate through detailed characterization of cloud-level atmosphere, and investigation of the formation and evolution of Venus, through careful measurement of noble gas isotopic abundances. These investigations would provide key data for comparative planetology of terrestrial planets in our solar system and beyond.  相似文献   
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Résumé

Depuis plus d’un siècle, l’origine autochtone ou allochtone des formations résiduelles à silex (en abrégé RS : résidus à silex) par rapport aux craies a fait l’objet de multiples discussions. Pour répondre à ce problème, un bilan d’altération entre ces deux formations a été effectué. Il repose sur une connaissance précise des âges des craies-mères des RS et sur des comparaisons granulométrique et chimique entre craie et RS. Ces comparaisons s’appuient sur les quantités de silex contenues dans les craies et les RS, sachant que les silex sont reconnus comme autochtones et que leur degré de dissolution est calculé. Les résultats apportent des informations sur l’évolution crétacée du Bassin anglo-parisien, avec la mise en évidence de la craie du Maastrichtien dans le bassin de Paris et la reconstitution des épaisseurs de craie dissoutes. De plus, ils indiquent que la stratigraphie des craies est conservée dans les profils de RS. Ils montrent également que les silex, éléments autochtones des RS, sont faiblement altérés. Les matrices des RS sont, quant à elles, en grande partie allochtones, notamment dans les dix mètres supérieurs de la formation. L’allochtonie diminue avec la profondeur, avec des RS pouvant être considérés comme des résidus d’altération de la craie au sens strict à partir de 20 mètres de profondeur. © Elsevier, Paris  相似文献   
67.
New intermediate-resolution, normal-incidence seismic reflection profiles from Lake Tanganyika’s central basin capture dramatic evidence of base-level change during two intervals of the late Pleistocene. Four seismically-defined stratigraphic sequences (A–D) tied to radiocarbon-dated sediment cores provide a chronology for fluctuating environmental conditions along the Kalya Platform. Stacked, oblique clinoforms in Sequence C are interpreted as prograding siliciclastic deltas deposited during a major regression that shifted the paleo-lake shore ∼21 km towards the west prior to ∼106 ka. The topset-to-foreset transitions in these deltas suggest lake level was reduced by ∼435 m during the period of deposition. Mounded reflections in the overlying sequence are interpreted as the backstepping remnants of the delta system, deposited during the termination of the lowstand and the onset of transgressive conditions in the basin. The youngest depositional sequence reflects the onset of profundal sedimentation during the lake level highstand. High amplitude reflections and deeply incised channels suggest a short-lived desiccation event that reduced lake level by ∼260 m, interpreted as a product of Last Glacial Maximum (32–14 ka) aridity. Paleobathymetric maps constructed for the two interpreted regressions reveal that despite the positive lake-floor topography created by the Kavala Island Ridge Accommodation Zone, Lake Tanganyika remained a large, mostly connected water body throughout the late Pleistocene. The results of this analysis further imply that Lake Tanganyika is the most drought resistant water body in the East African tropics, and may have acted as a refuge for local and migrating fauna during periods of prolonged aridity.  相似文献   
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The surface chemistry of natural wollastonite, diopside, enstatite, forsterite, and albite in aqueous solutions was characterized using both electrokinetic techniques and surface titrations performed for 20 min in batch reactors. Titrations performed in such reactors allow determination of both proton consumption and metal release from the mineral surface as a function of pH. The compositions, based on aqueous solution analysis, of all investigated surfaces vary dramatically with solution pH. Ca and Mg are preferentially released from the surfaces of all investigated divalent metal silicates at pH less than ∼8.5-10 but preferentially retained relative to silica at higher pH. As such, the surfaces of these minerals are Si-rich and divalent metal poor except in strongly alkaline solutions. The preferential removal of divalent cations from these surfaces is coupled to proton consumption. The number of protons consumed by the preferential removal of each divalent cation is pH independent but depends on the identity of the mineral; ∼1.5 protons are consumed by the preferential removal of each Ca atom from wollastonite, ∼3 protons are consumed by the preferential removal of each Mg or Ca atom from diopside or enstatite, and ∼4 protons are consumed by the preferential removal of each Mg from forsterite. These observations are interpreted to stem from the creation of additional ‘internal’ adsorption sites by the preferential removal of divalent metal cations which can be coupled to the condensation of partially detached Si. Similarly, Na and Al are preferentially removed from the albite surface at 2 > pH > 11; mass balance calculations suggest that three protons are consumed by the preferential removal of each Al atom from this surface over this entire pH range. Electrokinetic measurements on fresh mineral powders yield an isoelectric point (pHIEP) 2.6, 4.4, 3.0, 4.5, and <1, for wollastonite, diopside, enstatite, forsterite, and albite, respectively, consistent with the predominance of SiO2 in the surface layer of all of these multi-oxide silicates at acidic pH. Taken together, these observations suggest fundamental differences between the surface chemistry of simple versus multi-oxide minerals including (1) a dependency of the number and identity of multi-oxide silicate surface sites on the aqueous solution composition, and (2) the dominant role of metal-proton exchange reactions on the reactivity of multi-oxide mineral surfaces including their dissolution rate variation with aqueous solution composition.  相似文献   
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