Implications of Quaternary volcanism at Cerro Tuzgle for crustal and mantle evolution of the Puna Plateau,Central Andes,Argentina     

Beatriz Coira  Suzanne Mahlburg Kay 《Contributions to Mineralogy and Petrology》1993,113(1):40-58

The high-K Tuzgle volcanic center, (24° S, 66.5° W) along with several small shoshonitic centers, developed along extensional Quaternary faults of the El Toro lineament on the east-central Puna plateau, 275 km east of the main front of the Andean Central Volcanic Zone (CVZ). These magmas formed by complex mixing processes in the mantle and thickened crust (>50 km) above a 200 km deep scismic zone. Tuzgle magmas are differentiated from shoshonitic series magmas by their more intraplate-like Ti group element characteristics, lower incompatible element concentrations, and lower ⁸⁷Sr/⁸⁶Sr ratios at a given Nd. Underlying Mio-Pliocene volcanic rocks erupted in a compressional stress regime and have back-arc like calc-alkaline chemical characteristics. The Tuzgle rocks can be divided into two sequences with different mantle precursors: a) an older, more voluminous rhyodacitic (ignimbrite) to mafic andestitic (56% to 71% SiO₂) sequence with La/Yb ratios <30, and b) a younger andesitic sequence with La/Yb ratios >35. La/Yb ratios are controlled by the mafic components: low ratios result from larger mantle melt percentages than high ratios. Shoshonitic series lavas (52% to 62% SiO₂) contain small percentage melts of more isotopically enriched arc-like mantle sources. Some young Tuzgle lavas have a shoshonitic-like component. Variable thermal conditions and complex stress system are required to produce the Tuzgle and shoshonitic series magmas in the same vicinity. These conditions are consistent with the underlying mantle being in transition from the thick mantle lithosphere which produced rare shoshonitic flows in the Altiplano to the thinner mantle lithosphere that produced back-are calc-alkaline and intraplate-type flows in the southern Puna. Substantial upper crustal type contamination in Tuzgle lavas is indicated by decreasing Nd (-2.5 to-6.7) with increasing ⁸⁷Sr/⁸⁶Sr (0.7063 to 0.7099) ratios and SiO₂ concentrations, and by negative Eu anomalies (Eu/Eu^* <0.78) in lavas that lack plagioclase phenocrysts. Trace element arguments indicate that the bulk contaminant was more silicic than the Tuzgle ignimbrite and left a residue with a high pressure mineralogy. Crustal shortening processes transported upper crustal contaminants to depths where melting occurred. These contaminants mixed with mafic magmas that were fractionating mafic phases at high pressure. Silicic melts formed at depth by these processes accumulated at a mid to upper crustal discontinuity (decollement). The Tuzgle ignimbrite erupted from this level when melting rates were highest. Subsequent lavas are mixtures of contaminated mafic magmas and ponded silicic melts. Feldspar and quartz phenocrysts in the lavas are phenocrysts from the ponded silicic magmas.  相似文献   

Using stable and radioactive isotopes for the investigation of contaminant metal mobilization in a metal mining district     

Michael Schubert  Karsten Osenbrück  Kay Knöller 《Applied Geochemistry》2008

Naturally occurring stable and radioactive isotopes were used as environmental tracers to investigate contaminant metal mobilization processes in a metal smelter dump mainly consisting of slag. Water emerging from the dump at a spring is heavily contaminated by metals. The smelter dump contains minor amounts of flue dust, a material which shows a high potential for metal mobilization. Nearby dumps mainly consist of low-grade ore. Concentration patterns of ²³⁸U, ²²⁶Ra and ²¹⁰Pb determined in sediment deposited close to the contaminated spring reveal the flue dust to be the major local metal source rather than the slag or the low-grade ore. Contamination pathways inside the dump were investigated using hydrological, chemical and isotopic data. Strong negative correlation between water discharge and metal concentration in the spring water suggests, besides short-term dilution of the metal concentration by direct rainwater runoff, distinct long-term dilution of the spring water by groundwater being discharged at a significantly increased rate as a result of heavy rains. δ¹⁸O and δD signatures of rain, local groundwater and spring water confirm the importance of groundwater derived from the local aquifer. Another hydrological component with importance for metal mobilization was found to be water that is recharged in the dump itself. Tritium analysis allowed an assessment of the probable residence time of that water component in the smelter dump. Since that water component seems to represent a major local contamination pathway the findings of the study are of substantial importance for site remediation planning. As a primary result it could be stated that covering the dump would not result in any noteworthy short-term improvement of the spring water quality. First significant effects would only be visible after 2–3 decades at the earliest.  相似文献   

The evolution of clusters in the CLEF cosmological simulation: X-ray structural and scaling properties     

Scott T. Kay  Antonio C. da Silva  Nabila Aghanim  Alain Blanchard  rew R. Liddle  Jean-Loup Puget  Rachida Sadat  Peter A. Thomas 《Monthly notices of the Royal Astronomical Society》2007,377(1):317-334

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The proposed solway firth barrages: A review of the geological and geotechnical aspects     

J.A. Kay 《Engineering Geology》1969,3(4):265-306

The various barrages suggested for the Solway Firth are discussed. The specific geology of each of the proposed sites is reviewed and the inadequacy of present information emphasised. Geotechnical problems which might arise during and after construction of the barrages are summarized. The possible sources of various types of constructional materials are indicated. Finally, methods are suggested which would provide much of the information essential for an accurate assessment of the various proposals for the area.  相似文献   

Diurnal coastal-trapped waves on the eastern shelf of Sakhalin in the Sea of Okhotsk and their modification by sea ice     

Jun Ono  Kay I. Ohshima  Genta Mizuta  Yasushi Fukamachi  Masaaki Wakatsuchi 《Continental Shelf Research》2008

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Automatic correction and simplification of geological maps and cross-sections for numerical simulations     

Pierre Anquez  Jeanne Pellerin  Modeste Irakarama  Paul Cupillard  Bruno Lévy  Guillaume Caumon 《Comptes Rendus Geoscience》2019,351(1):48-58

Incorporating prior geological knowledge in geophysical process models often meets practical meshing challenges and raises the question of how much detail is to be included in the geometric model. We introduce a strategy to automatically repair and simplify geological maps, geological cross-sections and the associated meshes while preserving elementary consistency rules. To identify features breaking validity and/or the thin features potentially problematic when generating a mesh, we associate an exclusion zone with each model feature (horizon, fault). When these zones overlap, both the connectivity and the geometry of the geological layers are automatically modified. The output model enforces specific practical quality criteria on the model topology and geometry that facilitates the generation of a mesh with lower bounds on minimum angles and minimum local entity sizes. Our strategy is demonstrated on an invalid geological cross-section from a real-case study in the Lorraine coal basin. We further explore the impacts of the model modifications on wave propagation simulation. We show that the differences on the seismograms due to model simplifications are relatively small if the magnitude of simplifications is adapted to the physical problem parameters.  相似文献   

Direct observations of sea-ice thickness and brine rejection off Sakhalin in the Sea of Okhotsk     

Yasushi Fukamachi  Kunio Shirasawa  Anatoliy M. Polomoshnov  Kay I. Ohshima  Ervin Kalinin  Sohey Nihashi  Humfrey Melling  Genta Mizuta  Masaaki Wakatsuchi 《Continental Shelf Research》2009,29(11-12):1541-1548

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A toxicity identification evaluation of silty marine harbor sediments to characterize persistent and non-persistent constituents     

Stronkhorst J  Schot ME  Dubbeldam MC  Ho KT 《Marine pollution bulletin》2003,46(1):56-64

Sediment toxicity in silty marine harbor sediments is frequently dominated by ammonia or sulfide, leaving the adverse effects of persistent toxic substances unnoticed. To investigate the latter, we subjected interstitial water from three contaminated silty sediments to toxicity identification evaluation (TIE) phase I manipulations and tested for toxicity with four bioassays: the amphipod Corophium volutator (survival as an endpoint), the sea urchin Psammechinus miliaris (fertilization, embryo development) and the bacterium Vibrio fischeri (bioluminescence inhibition).The graduated pH manipulations identified the prominent toxicity of ammonia in the amphipod and sea urchin embryo tests, and also sulfide toxicity in the bacterium test. In two of the three samples tested with the amphipods, sea urchin embryos and bacteria, a small but significant reduction in interstitial water toxicity was achieved by removing persistent compounds through C(18) solid phase extraction. EDTA chelation resulted in a slight detoxification of the interstitial water for the amphipods and sea urchin embryos, but this was not related to any measured trace metals. Despite the presence of toxic levels of ammonia and sulfide in the harbor sediments, we established the adverse biological effects of persistent constituents by means of the TIE manipulations and in vivo interstitial water bioassays.  相似文献   

Incorporation and leaching of heavy metals in clay annealed with Pb, Cu and V     

Volker Karius  Petra Bruhns  Kay Hamer  Reinhard X. Fischer 《Environmental Geology》2001,41(3-4):297-304

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Tributyltin release from harbour sediments--modelling the influence of sedimentation, bio-irrigation and diffusion using data from Bremerhaven     

Hamer K  Karius V 《Marine pollution bulletin》2005,50(9):980-992

This study describes the potential release of TBT from harbour sediments based on model calculations for different sediment management scenarios applying a numerical one-dimensional FD-model. A conceptual model was developed focussing on the following processes involved in the transport of TBT: sorption equilibrium, diffusion, irrigation and sedimentation. Assuming TBT-concentration of 292 microg/kg in the sediment, the diffusive release of TBT from sediments into the bottom water was calculated to 7.4 x 10(-7)-6.9 x 10(-6)mol m(-2) after 1 year and 7.4 x 10(-6)-1.6 x 10(-4)mol m(-2) after 100 years. In these scenarios, neither sedimentation nor capping were considered. Assuming a sedimentation at a rate of 1cm/a, the polluted sediments will be covered with TBT-free suspended matter. A diffusive release of TBT will be prevented if no bio-irrigation takes place. Capping with a layer of sand of 50 cm thickness will decrease the diffusive release. If a reactive capping could be applied, the release of TBT into the bottom water would be stopped almost completely. The study shows that our model calculations enables us to compare different scenarios in sediment management based on available data. Additionally, it can provide information for risk assessment in the absence of data.  相似文献