Development of Cu and Zn Isotope MC-ICP-MS Measurements: Application to Suspended Particulate Matter and Sediments from the Scheldt Estuary   总被引：1，自引：0，他引：1  

Jérôme C.J. Petit  Jeroen de Jong  Lei Chou  Nadine Mattielli 《Geostandards and Geoanalytical Research》2008,32(2):149-166

The present study evaluates several critical issues related to precision and accuracy of Cu and Zn isotopic measurements with application to estuarine particulate materials. Calibration of reference materials (such as the IRMM 3702 Zn) against the JMC Zn and NIST Cu reference materials were performed in wet and/or dry plasma modes (Aridus I and DSN‐100) on a Nu Plasma MC‐ICP‐MS. Different mass bias correction methods were compared. More than 100 analyses of certified reference materials suggested that the sample‐calibrator bracketing correction and the empirical external normalisation methods provide the most reliable corrections, with long term external precisions of 0.06 and 0.07‰ (2SD), respectively. Investigation of the effect of variable analyte to spike concentration ratios on Zn and Cu isotopic determinations indicated that the accuracy of Cu measurements in dry plasma is very sensitive to the relative Cu and Zn concentrations, with deviations of δ⁶⁵Cu from ?0.4‰ (Cu/Zn = 4) to +0.4‰ (Cu/Zn = 0.2). A quantitative assessment (with instrumental mass bias corrections) of spectral and non‐spectral interferences (Ti, Cr, Co, Fe, Ca, Mg, Na) was performed. Titanium and Cr were the most severe interfering constituents, contributing to inaccuracies of ?5.1‰ and +0.60‰ on δ^68/64Zn, respectively (for 500 μg l^?1 Cu and Zn standard solutions spiked with 1000 μg l^?1 of Ti or Cr). Preliminary isotopic results were obtained on contrasting sediment matrices from the Scheldt estuary. Significant isotopic fractionation of zinc (from 0.21‰ to 1.13‰ for δ⁶⁶Zn) and copper (from ?0.38‰ to 0.23‰ for δ⁶⁵Cu), suggest a control by physical mixing of continental and marine water masses, characterized by distinct Cu and Zn isotopic signatures. These results provide a stepping‐stone to further evaluate the use of Cu and Zn isotopes as biogeochemical tracers in estuarine environments.  相似文献   

Experimental Study on the Wake Meandering Within a Scale Model Wind Farm Subject to a Wind-Tunnel Flow Simulating an Atmospheric Boundary Layer     

Nicolas Coudou  Sophia Buckingham  Laurent Bricteux  Jeroen van Beeck 《Boundary-Layer Meteorology》2018,167(1):77-98

The phenomenon of meandering of the wind-turbine wake comprises the motion of the wake as a whole in both horizontal and vertical directions as it is advected downstream. The oscillatory motion of the wake is a crucial factor in wind farms, because it increases the fatigue loads, and, in particular, the yaw loads on downstream turbines. To address this phenomenon, experimental investigations are carried out in a wind-tunnel flow simulating an atmospheric boundary layer with the Coriolis effect neglected. A \(3 \times 3\) scaled wind farm composed of three-bladed rotating wind-turbine models is subject to a neutral boundary layer over a slightly-rough surface, i.e. corresponding to offshore conditions. Particle-image-velocimetry measurements are performed in a horizontal plane at hub height in the wakes of the three wind turbines occupying the wind-farm centreline. These measurements allow determination of the wake centrelines, with spectral analysis indicating the characteristic wavelength of the wake-meandering phenomenon. In addition, measurements with hot-wire anemometry are performed along a vertical line in the wakes of the same wind turbines, with both techniques revealing the presence of wake meandering behind all three turbines. The spectral analysis performed with the spatial and temporal signals obtained from these two measurement techniques indicates a Strouhal number of \(\approx 0.20 - 0.22\) based on the characteristic wake-meandering frequency, the rotor diameter and the flow speed at hub height.  相似文献   

Improved collection of rooftop micrometeorites through optimized extraction methods: The Budel collection     

Guido Jonker  Roel van Elsas  Jeroen H. J. L. van der Lubbe  Wim van Westrenen 《Meteoritics & planetary science》2023,58(4):463-479

The scientific value of micrometeorites collected from deep-sea sediments or glacial deposits can be limited by poorly constrained accumulation times or severe alteration, coupled with a complex infrastructure of sampling expeditions. Collecting micrometeorites from rooftops has recently become a feasible alternative, but extraction methods have not been optimized or standardized to date. Here, we show that existing methods for the recovery of melted cosmic spherules (CSs) can be strongly improved by using a sequence of mineral separation techniques, including shape separation with an asymmetric vibrator and heavy liquid density separation with overflow centrifuges. We retrieved 1006 micrometeorites from the gutter of a barn in Budel, the Netherlands. Particle diameters are 80–515 μm, with the major mode at 130 μm and a slope exponent of −4.88. Differences in size distributions among various types of CSs indicate a multi-source influx, with CS textures controlled by their parent body's mineralogy and orbital parameters. Repeated sampling of the rooftop after accumulation times of 959 and 333 days allows for a time-integrated global mass flux estimate of 472 t year⁻¹. This estimate is notably higher than previous rooftop-based estimates but is still severely affected by micrometeorite loss from the gutter through drainage. The mass flux peaks at an equivalent particle diameter of ~200 μm. The Budel collection is the first rooftop collection to contain abundant vitreous micrometeorites and include the coarse-grained S-type CS class. Unmelted and I-type micrometeorites remain difficult to extract from rooftop samples. Vitreous micrometeorites display various stages of weathering, showing that severe alteration of glass can progress at a faster rate in populated regions than previously assumed. This study demonstrates that methodological adjustments can drastically increase the scientific potential of rooftop micrometeorite collections.  相似文献   

Global Triptych: a bottom-up approach for the differentiation of commitments under the Climate Convention     

Heleen Groenenberg  Kornelis Blok  Jeroen van der Sluijs 《Climate Policy》2013,13(2):153-175

Abstract

In the coming years the international debate on commitments for the second commitment period under the Kyoto Protocol will intensify. In this study, the Global Triptych approach is put forward as an input for international decision-making concerning the differentiation of commitments by 2020. It is a sector- and technology-oriented approach, and we calculated quantitative emission limitation objectives and global emissions starting from bottomup information on long-term reduction opportunities. Central to the calculations were long-term sustainability targets for the year 2050, formulated for (1) energy efficiency in the energy-intensive industry, (2) greenhouse gas intensity of electricity production, and (3) per capita emissions in the domestic sectors. Calculated emission limitation objectives for 13 world regions ranged from about ?30% to more than +200%. The ranking of world regions in the differentiation turned out to be independent of the levels chosen for the long-term sustainability targets. The objectives seem sufficient to maintain the long-term possibility of stabilizing atmospheric greenhouse gas concentrations at about 550 ppm CO₂-eq, but will require severe emission reductions. These may be relaxed to a certain degree if stabilization at 650 ppm CO₂-eq is aimed for. We conclude that the bottom-up character of the approach made it possible to examine important basic principles of the Climate Convention, including equity, the needs and circumstances of developing countries, cost-effectiveness and sustainable development.  相似文献   

Planktonic diatom communities in temperate South-Central Chilean lakes with a focus on Asterionella formosa and the genus Aulacoseira     

Van de Vyver  Evelien  Pinseel  Eveline  Verleyen  Elie  Vanormelingen  Pieter  Van Wichelen  Jeroen  de Jong  Rixt  Urrutia  Roberto  Vyverman  Wim 《Journal of Paleolimnology》2022,68(3):279-296

Journal of Paleolimnology - Paleolimnological records from temperate South-Central Chilean lakes revealed a recent and marked increase in the relative abundances of the key-planktonic diatom...  相似文献   

Flood disaster subcultures in The Netherlands: the parishes of Borgharen and Itteren     

Karen Engel  Georg Frerks  Lucia Velotti  Jeroen Warner  Bart Weijs 《Natural Hazards》2014,73(2):859-882

The Netherlands knows a persistent threat of flooding. To adapt to this dangerous reality, the Dutch have cultivated what disaster research literature has labeled ‘disaster subcultures’ or a set of cultural (tangible and intangible) tools to deal with the recurrent hazard. While there is abundant attention for the way the Dutch ‘coastal’ and ‘low-lying’ communities deal with the recurrent threat of (coastal) flooding, less is known about the way the Dutch ‘high-lands’ deal with the yearly threat of (fluvial) flooding. This article presents the findings of an explorative research endeavor (2011–2013) aimed at discerning if the disaster subculture concept has contemporary relevance in the Netherlands, particularly with respect to flooding, and if so, whether applying this lens would reveal more about the nature of existing disaster subcultures. Because less is known about the Dutch ‘high-lands,’ we chose to look into the existence and attributes of disaster subcultures in the parishes Borgharen and Itteren, which experience a systematic threat of flooding. Our findings suggest that the disaster subculture lens is valuable as it enables the empirical appreciation of disaster subcultures, even in a small country like the Netherlands, and it unveiled elements of these neighboring parishes’ flood reality that otherwise might have gone unnoticed and that seem central to understanding these two parishes’ levels of vulnerability and resilience. It is our contention that the concept ‘disaster subculture’ makes a greater understanding possible of the cultural context from which vulnerability and resilience to specific and recurrent threats emerge.  相似文献   

Introduction to the spectral element method for three-dimensional seismic wave propagation   总被引：28，自引：0，他引：28  

Dimitri Komatitsch  & Jeroen Tromp 《Geophysical Journal International》1999,139(3):806-822

  相似文献   

Sulfur and iron speciation in surface sediments along the northwestern margin of the Black Sea   总被引：4，自引：0，他引：4  

Jeroen W. M. Wijsman  Jack J. Middelburg  Peter M. J. Herman  Michael E. Bttcher  Carlo H. R. Heip 《Marine Chemistry》2001,74(4)

The speciation of sedimentary sulfur (pyrite, acid volatile sulfides (AVS), S⁰, H₂S, and sulfate) was analyzed in surface sediments recovered at different water depths from the northwestern margin of the Black Sea. Additionally, dissolved and dithionite-extractable iron were quantified, and the sulfur isotope ratios in pyrite were measured. Sulfur and iron cycling in surface sediments of the northwestern part of the Black Sea is largely influenced by (1) organic matter supply to the sediment, (2) availability of reactive iron compounds and (3) oxygen concentrations in the bottom waters. Biologically active, accumulating sediments just in front of the river deltas were characterized by high AVS contents and a fast depletion of sulfate concentration with depth, most likely due to high sulfate reduction rates (SRR). The δ³⁴S values of pyrite in these sediments were relatively heavy (−8‰ to −21‰ vs. V-CDT). On the central shelf, where benthic mineralization rates are lower, re-oxidation processes may become more important and result in pyrite extremely depleted in δ³⁴S (−39‰ to −46‰ vs. V-CDT). A high variability in δ³⁴S values of pyrite in sediments from the shelf-edge (−6‰ to −46‰ vs. V-CDT) reflects characteristic fluctuations in the oxygen concentrations of bottom waters or varying sediment accumulation rates. During periods of oxic conditions or low sediment accumulation rates, re-oxidation processes became important resulting in low AVS concentrations and light δ³⁴S values. Anoxic conditions in the bottom waters overlying shelf-edge sediments or periods of high accumulation rates are reflected in enhanced AVS contents and heavier sulfur isotope values. The sulfur and iron contents and the light and uniform pyrite isotopic composition (−37‰ to −39‰ vs. V-CDT) of sediments in the permanently anoxic deep sea (1494 m water depth) reflect the formation of pyrite in the upper part of the sulfidic water column and the anoxic surface sediment. The present study demonstrates that pyrite, which is extremely depleted in ³⁴S, can be found in the Black Sea surface sediments that are positioned both above and below the chemocline, despite differences in biogeochemical and microbial controlling factors.  相似文献