A temperature-induced reversible transformation between paratacamite and herbertsmithite     

Mark D. Welch  Matthew J. Sciberras  Peter A. Williams  Peter Leverett  Jochen Schlüter  Thomas Malcherek 《Physics and Chemistry of Minerals》2014,41(1):33-48

The crystal chemistry of paratacamite has been re-evaluated by studying a crystal from the holotype specimen BM86958 of composition Cu_3.71Zn_0.29(OH)₆Cl₂ using single-crystal X-ray diffraction at 100, 200, 300, 353, 393 and 423 K. At 300 K paratacamite has space group $R\bar{3}$ with unit-cell parameters a 13.644 and c 14.035 Å and exhibits a pronounced subcell, a′ = ½a and c′ = c, analogous to that of the closely related mineral herbertsmithite, Cu₃Zn(OH)₆Cl₂. Between 353 and 393 K, paratacamite undergoes a reversible phase transformation to the herbertsmithite-like substructure, space group $R\bar{3}m$ , unit-cell parameters a 6.839 and c 14.072 Å (393 K). The transformation is characterised by a gradual reduction in intensity of superlattice reflections, which are absent at 393 and 443 K. On cooling from 443 to 300 K at ~10 K min^?1, the superlattice reflections reappear and the refined structures ( $R\bar{3}$ ) of the initial and recovered 300 K states are almost identical. The complete reversibility of the transformation establishes that paratacamite of composition Cu_3.71Zn_0.29(OH)₆Cl₂ is thermodynamically stable at ambient temperatures. The nature of the rhombic distortion of the M(2)O₆ octahedron is discussed by considering two possibilities that are dependent upon the nature of cation substitution in the interlayer sites.  相似文献   

The cosmic microwave background and the ionization history of the Universe     

Antony Lewis  Jochen Weller †  Richard Battye 《Monthly notices of the Royal Astronomical Society》2006,373(2):561-570

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Zircon geochronology and geochemistry to constrain the youngest eruption events and magma evolution of the Mid-Miocene ignimbrite flare-up in the Pannonian Basin,eastern central Europe     

Réka?LukácsEmail author  Szabolcs?Harangi  Olivier?Bachmann  Marcel?Guillong  Martin?Dani?ík  Yannick?Buret  Albrecht?von?Quadt  István?Dunkl  László?Fodor  Jakub?Sliwinski  Ildikó?Soós  János?Szepesi 《Contributions to Mineralogy and Petrology》2015,170(5-6):52

A silicic ignimbrite flare-up episode occurred in the Pannonian Basin during the Miocene, coeval with the syn-extensional period in the region. It produced important correlation horizons in the regional stratigraphy; however, they lacked precise and accurate geochronology. Here, we used U–Pb (LA-ICP-MS and ID-TIMS) and (U–Th)/He dating of zircons to determine the eruption ages of the youngest stage of this volcanic activity and constrain the longevity of the magma storage in crustal reservoirs. Reliability of the U–Pb data is supported by (U–Th)/He zircon dating and magnetostratigraphic constraints. We distinguish four eruptive phases from 15.9 ± 0.3 to 14.1 ± 0.3 Ma, each of which possibly includes multiple eruptive events. Among these, at least two large volume eruptions (>10 km³) occurred at 14.8 ± 0.3 Ma (Demjén ignimbrite) and 14.1 ± 0.3 Ma (Harsány ignimbrite). The in situ U–Pb zircon dating shows wide age ranges (up to 700 kyr) in most of the crystal-poor pyroclastic units, containing few to no xenocrysts, which implies efficient recycling of antecrysts. We propose that long-lived silicic magma reservoirs, mostly kept as high-crystallinity mushes, have existed in the Pannonian Basin during the 16–14 Ma period. Small but significant differences in zircon, bulk rock and glass shard composition among units suggest the presence of spatially separated reservoirs, sometimes existing contemporaneously. Our results also better constrain the time frame of the main tectonic events that occurred in the Northern Pannonian Basin: We refined the upper temporal boundary (15 Ma) of the youngest counterclockwise block rotation and the beginning of a new deformation phase, which structurally characterized the onset of the youngest volcanic and sedimentary phase.  相似文献   

Neutral hydrogen surveys for high-redshift galaxy clusters and protoclusters     

Richard A. Battye  Rod D. Davies  Jochen Weller 《Monthly notices of the Royal Astronomical Society》2004,355(4):1339-1347

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小型激光天文动力学空间计划概念   总被引：1，自引：0，他引：1  

倪维斗  朱进  武向平  褚桂柏  杨彬  高健  关敏  汤健仁  周翊  张中豪  黄天衣  曲钦岳  易照华  李广宇  陶金河  吴岸明  罗俊  叶贤基  周泽兵  熊耀恒  毕少兰  须重明  吴雪君  唐孟希  包芸  李芳昱  黄珹  杨福民  叶叔华  张书练  张元仲  聂玉昕  陈光  Joergen Christensen-Dalsgaard  Hansjoerg Dittus  Yasunori Fujii  Claus Laemmerzahl  Jean Francois Mangin  Achim Peters  Albrecht Ruediger  Etienne Samain  Stephan Schiller 《天文研究与技术》2002,(3):123-136

小型激光天文动力学空间计划是 :使用在太阳轨道上无拖曳航天器和地面站以激光干涉和脉冲测距的方法 ,精确地探讨天文动力学 ,检测相对论与时空基本定律 ,改进探测引力波的灵敏度以及更准确地测定太阳、行星和小行星的参数。 1 969年开始的月球激光 (反射 )测距 ,对地球物理、参考坐标的选定、相对论的检验均有重要的贡献。 3 0年来 ,激光技术的长足进步 ,使现在正是适合于开始进行研究空间有源 (主动 )测距和光波空间通讯的时候。激光天文动力学的兴起是必然的趋势 ,其精确度将比现在提高 3到 6个数量级 ,将是天文动力学革命性的发展。小型激光天文动力学空间计划可以起到带头作用。它的关键技术有三 ,即 :弱光锁相、极精确无拖曳航天和高衰减日冕仪。弱光锁相已有长足的进步。对高衰减日冕仪的研究 ,也有了初步的方案。LISA空间计划将于 2 0 0 6年 8月发射SMART -2 ,研究测试极精确无拖曳航天。小型激光天文动力学空间计划的关键技术已日趋成熟。在第一届国际激光天文动力学研讨会 ( 2 0 0 1 ,9.1 3 -2 3 )中介绍了各相关学科背景及前沿研究 ,讨论了激光天文动力学空间计划科学目标及相关技术 ,并召开了两次小型激光天文动力学空间计划预研究筹备会 ,建立了和欧洲的合作关系。会后着手进行此项对基础  相似文献   

The Millennium Galaxy Catalogue: bulge–disc decomposition of 10 095 nearby galaxies     

Paul D. Allen  Simon P. Driver  Alister W. Graham  Ewan Cameron  Jochen Liske  Roberto De Propris 《Monthly notices of the Royal Astronomical Society》2006,371(1):2-18

We present near-infrared (NIR) adaptive optics-assisted spectroscopic observations of the  CO (Δμ= 2)  absorption bands towards the centre of the giant elliptical galaxy NGC 1399. The observations were made with NAOS-CONICA (on the European Southern Observatory's Very Large Telescope) and have a full width at half-maximum resolution of 0.15 arcsec (14 pc). Kinematic analysis of the observations reveals a decoupled core and strongly non-Gaussian line-of-sight velocity profiles in the central 0.2 arcsec (19 pc). NIR imaging also indicates an asymmetric elongation of the central isophotes in the same region.
We use spherical orbit-superposition models to interpret the kinematics, using a set of orthogonal 'eigen-velocity profiles' that allow us to fit models directly to spectra. The models require a central black hole of mass  1.2^+0.5_−0.6× 10⁹ M_⊙  , with a strongly tangentially biased orbit distribution in the inner 40 pc.  相似文献   

Astrovirtel—From Archival Research to the Astrophysical Virtual Observatory     

R. Albrecht  R. Albrecht  P. Benvenuti  P. Benvenuti  F. Pierfederici 《Astrophysics and Space Science》2004,290(3-4):431-438

Given the high cost of modern astronomical observing facilities it is evident that efforts must be made to optimally exploit the data in order to maximize the return on investment. This concept was first implemented on a large scale for the Hubble Space Telescope, and has since been taken over for other space borne and large ground-based facilities. The European HST Science Data Archive is located at the European Southern Observatory (ESO). It has been extended to include data from ESO telescopes and instruments, especially the Very Large Telescope (VLT) and Wide Field Imager (WFI). It was thus natural to design the archive such that queries could be extended across its full content, regardless of the origin of the data. This constituted a first step toward a virtual observatory. The Astrovirtel program, first established in 1999–2000 with funding provided by the European Commission, makes it possible for scientists to use this facility for their investigations. At the same time it allowed us to establish science requirements for archive cross queries, and to define capabilities required for VO's. Recently the European Commission decided to provide the funding for the implementation of the Astrophysical Virtual Observatory (AVO). This will include several European observatories and scientific organizations. It is being developed in close coordination with the US National Virtual Observatory.  相似文献   

Preliminary evaluation of the occurrence of herbicides and PAHs in the Wet Tropics region of the Great Barrier Reef, Australia, using passive samplers   总被引：2，自引：0，他引：2  

Shaw M  Müller JF 《Marine pollution bulletin》2005,51(8-12):876-881

The proximity of the Great Barrier Reef (GBR) Marine Park to areas of intensive agriculture and increasing urbanisation places the park under potential threat of contamination by land-based pollutants. Passive samplers were deployed at inshore reef and river mouth sites in the Wet Tropics region of the GBR during a dry and a wet season to measure levels of land-based organic pollutants in this environment. Two types of passive sampling devices were deployed: (i) a polar sampler, which can be used to monitor polar herbicides and (ii) semipermeable membrane devices (SPMDs) which sequester more hydrophobic compounds (e.g. PAHs, chlorpyrifos). Herbicides (diuron, simazine, atrazine, hexazinone and/or flumeturon) were detected at low concentrations (ng L⁻¹) at all sites sampled and in both seasons. Chlorpyrifos was not detected while PAHs were present in SPMDs at levels below limits of detection. The results show that the GBR environment does contain low levels of organic pollutants and that passive sampling provides a sensitive monitoring tool for measuring waterborne organic pollutants.  相似文献   

Utilization of the European Hubble Space Telescope Science Data archive     

R. Albrecht  B. Pirenne 《Astrophysics and Space Science》1995,228(1-2):379-383

The Hubble Space Telescope (HST) is a very complex astronomical observing facility, producing data with unique calibration and analysis requirements. The data are collected in Science Data Archives which are available through computer networks world wide. This paper describes the approaches and technologies which are being used at the Space Telescope European Coordinating Facility (ST-ECF) to enable users in different institutions to efficiently work with HST data.  相似文献   

Estimating reliability and resolution of probability forecasts through decomposition of the empirical score     

Jochen Br?cker 《Climate Dynamics》2012,39(3-4):655-667

Proper scoring rules provide a useful means to evaluate probabilistic forecasts. Independent from scoring rules, it has been argued that reliability and resolution are desirable forecast attributes. The mathematical expectation value of the score allows for a decomposition into reliability and resolution related terms, demonstrating a relationship between scoring rules and reliability/resolution. A similar decomposition holds for the empirical (i.e. sample average) score over an archive of forecast–observation pairs. This empirical decomposition though provides a too optimistic estimate of the potential score (i.e. the optimum score which could be obtained through recalibration), showing that a forecast assessment based solely on the empirical resolution and reliability terms will be misleading. The differences between the theoretical and empirical decomposition are investigated, and specific recommendations are given how to obtain better estimators of reliability and resolution in the case of the Brier and Ignorance scoring rule.  相似文献