Background concentrations of photochemically active trace constituents in the stratosphere and upper troposphere     

Kaplan  Lewis D. 《Pure and Applied Geophysics》1973,106(1):1341-1345

Summary High resolution absorption spectroscopy can be used for obtaining very small background concentrations or very low upper limits of trace constituents, particularly from measurements inQ-branches of fundamental vibration-rotation bands. As examples, the results of a search for NH₃ and SO₂ in the Vermande and Dionne Mont-Louis solar spectra will be reported. The relative concentration of NH₃ is very much lower above the Pyrenees than the generally accepted minimum background concentrations near sea-level.  相似文献   

Metal/silicate fractionation in the solar system     

John S. Lewis 《Earth and Planetary Science Letters》1972

Fractionation between the metal and silicate components of objects in the inner solar system has long been recognized as a necessity in order to explain the observed density variations of the terrestrial planets and the H-group, L-group dichotomy of the ordinary chondrites. This paper discusses the densities of the terrestrial planets in light of current physical and chemical models of processes in the solar nebula. It is shown that the observed density trends in the inner solar system need not be the result of special fractionation processes, and that the densities of the planets may be direct results of simultaneous application of both physical and chemical restraints on the structure of the nebula, most notably the variation of temperature with heliocentric distance. The density of Mercury is easily attributed to accretion at temperatures so high that MgSiO₃ is only partially retained but Fe metal is condensed. The densities of the other terrestrial planets are shown to be due to different degrees of retention of S, O and H as FeS, FeO and hydrous silicates produced in chemical equilibrium between condensates and solar-composition gases. It is proposed that Mercury and Venus Have cores of Fe⁰, Earth has a core of Fe⁰ containing substantial amounts of FeS, and Mars has a quite small core of FeS with more FeO in its mantle than in Earth's. Geophysical and geochemical consequences of these conclusions are discussed.  相似文献   

An analysis of various time-stepping schemes for initial value problems     

O. C. Zienkiewicz  R. W. Lewis 《地震工程与结构动力学》1972,1(4):407-408

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Volatile element chemistry in the solar nebula: Na,K, F,Cl, Br,and P     

Bruce Fegley  John S. Lewis 《Icarus》1980,41(3):439-455

The results of the most extensive set to date of thermodynamic calculations of the equilibrium chemistry of several hundred compounds of the elements Na, K, F, Cl, Br, and P in a solar composition system are reported. The calculations are carried out over a wide range of temperatures and pressures and along an adiabat in the primitive solar nebula. Two extreme models of accretion are investigated. In one extreme complete chemical equilibrium between condensates and gases is maintained because the time scale for accretion is long compared to the time scale for cooling or dissipation of the nebula. Condensates formed in this homogeneous accretion model include several phases such as whitlockite, alkali feldspars, and apatite minerals which are found in chondrites. In the other extreme complete isolation of newly formed condensates from prior condensates and gases occurs due to a time scale for accretion that is short relative to the time required for nebular cooling or dissipation. The condensates produced in this heterogeneous accretion model include alkali sulfides, ammonium halides, and ammonium phosphates. None of these phases are found in chondrites. Available observations of the Na, K, F, Cl, Br, and P elemental abundances in the terrestrial planets are found to be compatible with the predictions of the homogeneous accretion model.  相似文献   

Thermal precursors in satellite images of the 1999 eruption of Shishaldin Volcano     

Jonathan Dehn  Kenneson G. Dean  Kevin Engle  Pavel Izbekov 《Bulletin of Volcanology》2002,64(8):525-534

Shishaldin Volcano, Unimak Island Alaska, began showing signs of thermal unrest in satellite images on 9 February 1999. A thermal anomaly and small steam plume were detected at the summit of the volcano in short-wave thermal infrared AVHRR (advanced very high resolution radiometer) satellite data. This was followed by over 2 months of changes in the observed thermal character of the volcano. Initially, the thermal anomaly was only visible when the satellite passed nearly directly over the volcano, suggesting a hot source deep in the central crater obscured from more oblique satellite passes. The "zenith angle" needed to see the anomaly increased with time, presumably as the thermal source rose within the conduit. Based on this change, an ascent rate of ca. 14 m per day for the thermal source was estimated, until it reached the summit on around 21 March. It is thought that Strombolian activity began around this time. The precursory activity culminated in a sub-Plinian eruption on 19 April, ejecting ash to over 45,000 ft. (13,700 m). The thermal energy output through the precursory period was calculated based on geometric constraints unique to Shishaldin. These calculations show fluctuations that can be tied to changes in the eruptive character inferred from seismic records and later geologic studies. The remote location of this volcano made satellite images a necessary observation tool for this eruption. To date, this is the longest thermal precursory activity preceding a sub-Plinian eruption recorded by satellite images in the region. This type of thermal monitoring of remote volcanoes is central in the efforts of the Alaska Volcano Observatory to provide timely warnings of volcanic eruption, and mitigate their associated hazards to air-traffic and local residents.  相似文献   

Meteorites, meteors and comets     

Jonathan Shanklin 《Astronomy& Geophysics》2003,44(5):5.31-5.32

There are many areas in which professional and amateur co-operation brings benefits to both. Speakers at the RAS-BAA Pro-am discussion meeting on 10 May explored observational work on some of the debris in the solar system. The meeting concluded with a lecture given in memory of the noted amateur astronomer George Alcock. Jonathan Shanklin reports.  相似文献   

Potassium Doppler-resonance lidar for the study of the mesosphere and lower thermosphere at the Arecibo Observatory     

Jonathan S. Friedman  Craig A. Tepley  Shikha Raizada  Qihou H. Zhou  Jonas Hedin  Rubn Delgado 《Journal of Atmospheric and Solar》2003,65(16-18):1411-1424

We have developed a lidar to study the temperature structure of the nighttime mesopause region over the Arecibo Observatory (18.35°N, 66.75°W) by measuring the lineshape of the fluorescence spectrum of atomic potassium that is deposited in the mesosphere and lower thermosphere (MLT) by meteors. To demonstrate how the potassium lidar can enhance MLT studies at Arecibo, we show recent results for: (1) comparisons with airglow temperature measurements; (2) simultaneous operations with stratospheric and mesospheric temperature profiling by Rayleigh lidar; (3) simultaneous observations of K, Ca⁺, and E-region electron density profiles; and (4) occurrences of sporadic K layers, and relationships to sporadic E layers.  相似文献   

Comparison of Measured Ozone Production Efficiencies in the Marine Boundary Layer at Two European Coastal Sites under Different Pollution Regimes     

A. R. Rickard  G. Salisbury  P. S. Monks  A. C. Lewis  S. Baugitte  B. J. Bandy  K. C. Clemitshaw  S. A. Penkett 《Journal of Atmospheric Chemistry》2002,43(2):107-134

Ozone production efficiencies (E_N), which can be defined as the netnumber of ozone molecules produced per molecule of NO_xoxidised, have been calculated from measurements taken during three intensive field campaigns (one in the spring, EASE 96, and two in the summer, EASE 97 and TIGER 95), at two European coastal sites (Mace Head, Ireland (EASE) and Weybourne, Norfolk (TIGER)) impacted by polluted air masses originating from both the U.K. and continental Europe, as well as relatively clean oceanic air masses from the Arctic and Atlantic. From a detailed wind sector analysis of the EASE 96 and 97 data it is clear that two general types of pollution regime were encountered at Mace Head. The calculated ozone production efficiency in clean oceanic air masses was approximately 65, which contrasted to more polluted air, from the U.K. and the continental European plume, where the efficiency decreased to between 4 and 6. The latter values of E_Nagree well with literature measurements conducted downwind of various urban centres in the U.S. and Europe, which are summarised in a wide-ranging review table. The E_N value calculated for clean oceanic air is effectivelyan upper limit, owing to the relatively rapid deposition of HNO₃ tothe ocean. Consideration of the variation of E_N with NO_x forthe three campaigns suggests that ozone production efficiency is relatively insensitive to both geographical location and season. The measuredE_N values are also compared with values derived from steady-state expressions. An observed anti-correlation between E_N and measured ozone tendencyis briefly discussed.  相似文献   

Holocene geomagnetic secular variation recorded by volcanic deposits at Mount St. Helens,Washington     

Jonathan T. Hagstrum  Richard P. Hoblitt  Cynthia A. Gardner  Thomas E. Gray 《Bulletin of Volcanology》2002,63(8):545-556

A compilation of paleomagnetic data from volcanic deposits of Mount St. Helens is presented in this report. The database is used to determine signature paleomagnetic directions of products from its Holocene eruptive events, to assign sampled units to their proper eruptive period, and to begin the assembly of a much larger database of paleomagnetic directions from Holocene volcanic rocks in western North America. The paleomagnetic results from Mount St. Helens are mostly of high quality, and generally agree with the division of its volcanic deposits into eruptive episodes based on previous geologic mapping and radiocarbon dates. The Muddy River andesite's paleomagnetic direction, however, indicates that it is more likely part of the Pine Creek eruptive period rather than the Castle Creek period. In addition, the Two-Fingers andesite flow is more likely part of the Middle Kalama eruptive period and not part of the Goat Rocks period. The paleomagnetic data from Mount St. Helens and Mount Hood document variation in the geomagnetic field's pole position over the last ~2,500 years. A distinct feature of the new paleosecular variation (PSV) record, similar to the Fish Lake record (Oregon), indicates a sudden change from rapid clockwise movement of the pole about the Earth's spin axis to relatively slow counterclockwise movement at ~800 to 900 years B.P.  相似文献   

Lacustrine shore platforms at Lake Waikaremoana,North Island,New Zealand     

Jonathan C. Allan  Wayne J. Stephenson  Robert M. Kirk  Anna Taylor 《地球表面变化过程与地形》2002,27(2):207-220

This paper examines the morphology and processes governing the development of shore platforms at Lake Waikaremoana, North Island, New Zealand. Shore platforms at Lake Waikaremoana are recent features, and were formed when a new sequence of shoreline development was initiated, due to lowering of the lake by 5 m in 1946 for hydroelectric power development. Three predominant platform morphologies were identified around the lake. These include gently sloping platforms (c.1·5 to 3·9°), ramp platforms (c.6·8 to 9·2°), and concave ramp platforms (c.7·9 to 12°). Platform widths ranged from 11 to 31 m, with the gently sloping platforms characterized by the widest morphologies. Erosion rates were estimated using perched sandstone boulders and were found to range from 3·4 to 12·5 mm a^?1, with a mean erosion rate of 5·9 mm a^?1. Higher rates of erosion were identified at lower platform elevations, due to a greater frequency of wetting and drying cycles coincident with storm waves, while lower erosion rates were identified at higher elevations. Field evidence suggests that shore platforms at Lake Waikaremoana were likely initiated and continue to develop as a result of subaerial wetting and drying cycles. Waves, coincident with fluctuating lake levels, play an important role by removing the weathered material from the platforms, and appear to control the width of the platforms. A conceptual model of platform development is presented, and analogies are drawn between this model, and the formation of shore platforms in oceanic environments. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献