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101.
102.
Abstract— Puerto Lápice is a new eucrite fall (Castilla‐La Mancha, Spain, 10 May 2007). In this paper, we report its detailed petrography, magnetic characterization, mineral and bulk chemistry, oxygen and noble gas isotope systematics, and radionuclide data. Study of four thin sections from two different specimens reveal that the meteorite is brecciated in nature, and it contains basaltic and granulitic clasts, as well as recrystallized impact melt and breccia fragments. Shock veins are ubiquitous and show evidence of at least three different shock events. Bulk chemical analyses suggest that Puerto Lápice belongs to the main group of basaltic eucrites, although it has a significantly higher Cr content. Oxygen isotopes also confirm that the meteorite is a normal member of the HED suite. Noble gas abundances show typical patterns, with dominant cosmogenic and radiogenic contributions, and indicate an average exposure age of 19 ± 2 Ma, and a Pu‐fission Xe age well within typical eucrite values. Cosmogenic radionuclides suggest a preatmospheric size of about 20–30 cm in diameter.  相似文献   
103.
The long-term stability of biogenic uraninite with respect to oxidative dissolution is pivotal to the success of in situ bioreduction strategies for the subsurface remediation of uranium legacies. Batch and flow-through dissolution experiments were conducted along with spectroscopic analyses to compare biogenic uraninite nanoparticles obtained from Shewanella oneidensis MR-1 and chemogenic UO2.00 with respect to their equilibrium solubility, dissolution mechanisms, and dissolution kinetics in water of varied oxygen and carbonate concentrations. Both materials exhibited a similar intrinsic solubility of ∼10−8 M under reducing conditions. The two materials had comparable dissolution rates under anoxic as well as oxidizing conditions, consistent with structural bulk homology of biogenic and stoichiometric uraninite. Carbonate reversibly promoted uraninite dissolution under both moderately oxidizing and reducing conditions, and the biogenic material yielded higher surface area-normalized dissolution rates than the chemogenic. This difference is in accordance with the higher proportion of U(V) detected on the biogenic uraninite surface by means of X-ray photoelectron spectroscopy. Reasonable sources of a stable U(V)-bearing intermediate phase are discussed. The observed increase of the dissolution rates can be explained by carbonate complexation of U(V) facilitating the detachment of U(V) from the uraninite surface. The fraction of surface-associated U(VI) increased with dissolved oxygen concentration. Simultaneously, X-ray absorption spectra showed conversion of the bulk from UO2.0 to UO2+x. In equilibrium with air, combined spectroscopic results support the formation of a near-surface layer of approximate composition UO2.25 (U4O9) coated by an outer layer of U(VI). This result is in accordance with flow-through dissolution experiments that indicate control of the dissolution rate of surface-oxidized uraninite by the solubility of metaschoepite under the tested conditions. Although U(V) has been observed in electrochemical studies on the dissolution of spent nuclear fuel, this is the first investigation that demonstrates the formation of a stable U(V) intermediate phase on the surface of submicron-sized uraninite particles suspended in aqueous solutions.  相似文献   
104.
Within a wave-exposed mangrove forest, novel field observations are presented, comparing millimeter-scale turbulent water velocity fluctuations with contemporaneous subtidal bed elevation changes. High-resolution velocity and bed level measurements were collected from the unvegetated mudflat, at the mangrove forest fringe, and within the forest interior over multiple tidal cycles (flood–ebb) during a 2-week period. Measurements demonstrated that the spatial variability in vegetation density is a control on sediment transport at sub-meter scales. Scour around single and dense clusters of pneumatophores was predicted by a standard hydraulic engineering equation for wave-induced scour around regular cylinders, when the cylinder diameter in the equations was replaced with the representative diameter of the dense pneumatophore clusters. Waves were dissipated as they propagated into the forest, but dissipation at infragravity periods (> 30 s) was observed to be less than dissipation at shorter periods (< 30 s), consistent with the predictions of a simple model. Cross-wavelet analysis revealed that infragravity-frequency fluctuations in the bed level were occasionally coherent with velocity, possibly indicating scour upstream of dense pneumatophore patches when infragravity waves reinforced tidal currents. Consequently, infragravity waves were a likely driver of sediment transport within the mangrove forest. Near-bed turbulent kinetic energy, estimated from the turbulent dissipation rate, was also correlated with bed level changes. Specifically, within the mangrove forest and over the unvegetated mudflat, high-energy events were associated with erosion or near-zero bed level change, whereas low-energy events were associated with accretion. In contrast, no single relationship between bed level changes and mean current velocity was applicable across both vegetated and unvegetated regions. These observations support the theory that sediment mobilization scales with turbulent energy, rather than mean velocity, a distinction that becomes important when vegetation controls the development of turbulence.  相似文献   
105.
The H. J. Andrews Experimental Forest (HJA) encompasses the 6400 ha Lookout Creek watershed in western Oregon, USA. Hydrologic, chemistry and precipitation data have been collected, curated, and archived for up to 70 years. The HJA was established in 1948 to study the effects of harvest of old-growth conifer forest and logging-road construction on water quality, quantity and vegetation succession. Over time, research questions have expanded to include terrestrial and aquatic species, communities and ecosystem dynamics. There are nine small experimental watersheds and 10 gaging stations in the HJA, including both reference and experimentally treated watersheds. Gaged watershed areas range from 8.5 to 6242 ha. All gaging stations record stage height, water conductivity, water temperature and above-stream air temperature. At nine of the gage sites, flow-proportional water samples are collected and composited over 3-week intervals for chemical analysis. Analysis of stream and precipitation chemistry began in 1968. Analytes include dissolved and particulate species of nitrogen and phosphorus, dissolved organic carbon, pH, specific conductance, suspended sediment, alkalinity, and major cations and anions. Supporting climate measurements began in the 1950s in association with the first small watershed experiments. Over time, and following the initiation of the Long Term Ecological Research (LTER) grant in 1980, infrastructure expanded to include a set of benchmark and secondary meteorological stations located in clearings spanning the elevation range within the Lookout Creek watershed, as well as a large number of forest understory temperature stations. Extensive metadata on sensor configurations, changes in methods over time, sensor accuracy and precision, and data quality control flags are associated with the HJA data.  相似文献   
106.
ABSTRACT

Urban greening is a buzz term in urban policy and research settings in Australia and elsewhere. In a context of settler colonial urbanism, like Australia, a first fact becomes clear: urban greening is always being practiced on unceded Indigenous lands. Recognising this requires some honest reckoning with how this latest urban policy response perpetuates dispossessory settler-colonial structures. In this paper, we listen to the place-based ontologies of the peoples and lands from where we write to inform understanding the city as an always already Indigenous place – a sovereign Aboriginal City. In so doing, the paper tries to practice a way of creating more truthful and response-able urban knowledge practices. We analyse three distinct areas of scholarly research that are present in the contemporary literature: urban greening and green infrastructure; urban political ecology; and more-than-human cities. When placed in relationship of learning with the sovereign Aboriginal City, our analysis finds that these scholarly domains of urban greening work to re-organise colonial power relations. The paper considers what work the practice and scholarship of ‘urban greening’ might need to do in order to become response-able and learn to learn with Indigenous sovereignties and ontologies.  相似文献   
107.
The bulk chlorine concentrations and isotopic compositions of a suite of non‐carbonaceous (NC) and carbonaceous (CC) iron meteorites were measured using gas source mass spectrometry. The δ37Cl values of magmatic irons range from ?7.2 to 18.0‰ versus standard mean ocean chloride and are unrelated to their chlorine concentrations, which range from 0.3 to 161 ppm. Nonmagmatic IAB irons are comparatively Cl‐rich containing >161 ppm with δ37Cl values ranging from ?6.1 to ?3.2‰. The anomalously high and low δ37Cl values are inconsistent with a terrestrial source, and as Cl contents in magmatic irons are largely consistent with derivation from a chondrite‐like silicate complement, we suggest that Cl is indigenous to iron meteorites. Two NC irons, Cape York and Gibeon, have high cooling rates with anomalously high δ37Cl values of 13.4 and 18.0‰. We interpret these high isotopic compositions to result from Cl degassing during the disruption of their parent bodies, consistent with their low volatile contents (Ga, Ge, Ag). As no relevant mechanisms in iron meteorite parent bodies are expected to decrease δ37Cl values, whereas volatilization is known to increase δ37Cl values by the preferential loss of light isotopes, we interpret the low isotope values of <?5‰ and down to ?7.2‰ to most closely represent the primordial isotopic composition of Cl in the solar nebula. Similar conclusions have been derived from low δ37Cl values down to ?6, and ?3.8‰ measured in Martian and Vestan meteorites, respectively. These low δ37Cl values are in contrast to those of chondrites which average around 0‰ previously explained by the incorporation of isotopically heavy HCl clathrate into chondrite parent bodies. The poor retention of low δ37Cl values in many differentiated planetary materials suggest that extensive devolatilization occurred during planet formation, which can explain Earth's high δ37Cl value by the loss of approximately 60% of the initial Cl content.  相似文献   
108.
Linking ages to metamorphic stages in rocks that have experienced low‐ to medium‐grade metamorphism can be particularly tricky due to the rarity of index minerals and the preservation of mineral or compositional relicts. The timing of metamorphism and the Mesozoic exhumation of the metasedimentary units and crystalline basement that form the internal part of the Longmen Shan (eastern Tibet, Sichuan, China), are, for these reasons, still largely unconstrained, but crucial for understanding the regional tectonic evolution of eastern Tibet. In situ core‐rim 40Ar/39Ar biotite and U–Th/Pb allanite data show that amphibolite facies conditions (~10–11 kbar, 530°C to 6–7 kbar, 580°C) were reached at 210–180 Ma and that biotite records crystallization, rather than cooling, ages. These conditions are mainly recorded in the metasedimentary cover. The 40Ar/39Ar ages obtained from matrix muscovite that partially re‐equilibrated during the post peak‐P metamorphic history comprise a mixture of ages between that of early prograde muscovite relicts and the timing of late muscovite recrystallization at c. 140–120 Ma. This event marks a previously poorly documented greenschist facies metamorphic overprint. This latest stage is also recorded in the crystalline basement, and defines the timing of the greenschist overprint (7 ± 1 kbar, 370 ± 35°C). Numerical models of Ar diffusion show that the difference between 40Ar/39Ar biotite and muscovite ages cannot be explained by a slow and protracted cooling in an open system. The model and petrological results rather suggest that biotite and muscovite experienced different Ar retention and resetting histories. The Ar record in mica of the studied low‐ to medium‐grade rocks seems to be mainly controlled by dissolution–reprecipitation processes rather than by diffusive loss, and by different microstructural positions in the sample. Together, our data show that the metasedimentary cover was thickened and cooled independently from the basement prior to c. 140 Ma (with a relatively fast cooling at 4.5 ± 0.5°C/Ma between 185 and 140 Ma). Since the Lower Cretaceous, the metasedimentary cover and the crystalline basement experienced a coherent history during which both were partially exhumed. The Mesozoic history of the Eastern border of the Tibetan plateau is therefore complex and polyphase, and the basement was actively involved at least since the Early Cretaceous, changing our perspective on the contribution of the Cenozoic geology.  相似文献   
109.
110.
Tibetan Plateau vortices(TPVs) are mesoscale cyclones originating over the Tibetan Plateau(TP) during the extended summer season(April–September).Most TPVs stay on the TP,but a small number can move off the TP to the east.TPVs are known to be one of the main precipitation-bearing systems on the TP and moving-off TPVs have been associated with heavy precipitation and flooding downstream of the TP(e.g.,in Sichuan province or over the Yangtze River Valley).Identifying and tracking TPVs is difficult because of their comparatively small horizontal extent(400–800 km) and the limited availability of soundings over the TP,which in turn constitutes a challenge for short-term predictions of TPV-related impacts and for the climatological study of TPVs.In this study,(i) manual tracking(MT) results using radiosonde data from a network over and downstream of the TP are compared with(ii) results obtained by an automated tracking(AT) algorithm applied to ERA-Interim data.Ten MT-TPV cases are selected based on method(i) and matched to and compared with the corresponding AT-TPVs identified with method(ii).Conversely,ten AT-TPVs are selected and compared with the corresponding MT-TPVs.In general,the comparison shows good results in cases where the underlying data are in good agreement,but considerable differences are also seen in some cases and explained in terms of differences in the tracking methods,data availability/coverage and disagreement between sounding and ERA-Interim data.Recommendations are given for future efforts in TPV detection and tracking,including in an operational weather forecasting context.  相似文献   
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