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31.
32.
Søren Jessen Flemming Larsen Dieke Postma Pham Hung Viet Nguyen Thi Ha Pham Quy Nhan Dang Duc Nhan Mai Thanh Duc Nguyen Thi Minh Hue Trieu Duc Huy Tran Thi Luu Dang Hoang Ha Rasmus Jakobsen 《Applied Geochemistry》2008
To study the geological control on groundwater As concentrations in Red River delta, depth-specific groundwater sampling and geophysical logging in 11 monitoring wells was conducted along a 45 km transect across the southern and central part of the delta, and the literature on the Red River delta’s Quaternary geological development was reviewed. The water samples (n = 30) were analyzed for As, major ions, Fe2+, H2S, NH4, CH4, δ18O and δD, and the geophysical log suite included natural gamma-ray, formation and fluid electrical conductivity. The SW part of the transect intersects deposits of grey estuarine clays and deltaic sands in a 15–20 km wide and 50–60 m deep Holocene incised valley. The NE part of the transect consists of 60–120 m of Pleistocene yellowish alluvial deposits underneath 10–30 m of estuarine clay overlain by a 10–20 m veneer of Holocene sediments. The distribution of δ18O-values (range −12.2‰ to −6.3‰) and hydraulic head in the sample wells indicate that the estuarine clay units divide the flow system into an upper Holocene aquifer and a lower Pleistocene aquifer. The groundwater samples were all anoxic, and contained Fe2+ (0.03–2.0 mM), Mn (0.7–320 μM), SO4 (<2.1 μM–0.75 mM), H2S (<0.1–7.0 μM), NH4 (0.03–4.4 mM), and CH4 (0.08–14.5 mM). Generally, higher concentrations of NH4 and CH4 and low concentrations of SO4 were found in the SW part of the transect, dominated by Holocene deposits, while the opposite was the case for the NE part of the transect. The distribution of the groundwater As concentration (<0.013–11.7 μM; median 0.12 μM (9 μg/L)) is related to the distribution of NH4, CH4 and SO4. Low concentrations of As (?0.32 μM) were found in the Pleistocene aquifer, while the highest As concentrations were found in the Holocene aquifer. PHREEQC-2 speciation calculations indicated that Fe2+ and H2S concentrations are controlled by equilibrium for disordered mackinawite and precipitation of siderite. An elevated groundwater salinity (Cl range 0.19–65.1 mM) was observed in both aquifers, and dominated in the deep aquifer. A negative correlation between aqueous As and an estimate of reduced SO4 was observed, indicating that Fe sulphide precipitation poses a secondary control on the groundwater As concentration. 相似文献
33.
34.
Bayesian estimation of reservoir properties—effects of uncertainty quantification of 4D seismic data
Kjersti Solberg Eikrem Geir Nævdal Morten Jakobsen Yan Chen 《Computational Geosciences》2016,20(6):1211-1229
This paper shows a history matching workflow with both production and 4D seismic data where the uncertainty of seismic data for history matching comes from Bayesian seismic waveform inversion. We use a synthetic model and perform two seismic surveys, one before start of production and the second after 1 year of production. From the first seismic survey, we estimate the contrast in slowness squared (with uncertainty) and use this estimate to generate an initial estimate of porosity and permeability fields. This ensemble is then updated using the second seismic survey (after inversion to contrasts) and production data with an iterative ensemble smoother. The impact on history matching results from using different uncertainty estimates for the seismic data is investigated. From the Bayesian seismic inversion, we get a covariance matrix for the uncertainty and we compare using the full covariance matrix with using only the diagonal. We also compare with using a simplified uncertainty estimate that does not come from the seismic inversion. The results indicate that it is important not to underestimate the noise in seismic data and that having information about the correlation in the error in seismic data can in some cases improve the results. 相似文献
35.
依据模型冰物理性质控制其力学性质的原则 ,利用能量平衡观点建立了冰内未冻结液体含量同制冰过程中的冰池温度、降温及升温时间、模型冰厚度 (喷雾时间×流量 )的理论关系 ,以其量纲表达式作为预测模型冰物理和力学参数的综合控制指标 ;通过系统测量酒精溶液冰点温度、冰池大厅气温、模型冰温度、冰内未冻液含量、冰密度、冰压缩强度、冰弯曲强度和冰变形模量 ,获得了不同冰点温度模型冰的物理和力学参数同该综合控制指标的实验关系 ;实现了用人为可控制因子定量控制模型冰物理和力学参数的目的 相似文献
36.
The Great Belt, the Øresund and the Little Belt connect the central Baltic Sea and the Kattegat. A fixed station was moored in the contraction area in the Little Belt during the period 18–28 July 1995, measuring temperature, salinity and current in two levels, while discharge was measured by the RVDana. The composite Froude number calculated at the fixed station shows that the two layer flow through this area was most often supercritical. The discharges were satisfactorily related to the currents measured at the fixed station, and time-series of transports through the Little Belt were established. When compared to the transports through the Øresund the water transport ratio (Øresund:Little Belt) was found to be 4·4, while the salt transport ratio was found to be 3·0. The resistance of the Little Belt, when considering the differences in sea level from Gedser to Hornbæk, was 1839×10−12 s2 m−5. On the basis of water level and surface salinity measurements made during the period 1931–76, a net discharge of 2300 m3 s−1and a net salt transport of 36 tonnes s−1through the Little Belt from the central Baltic Sea were found. 相似文献
37.
Andrey A. Gurenko Kaj A. Hoernle Alexander V. Sobolev Folkmar Hauff Hans-Ulrich Schmincke 《Contributions to Mineralogy and Petrology》2010,159(5):689-702
The Canary Island primitive basaltic magmas are thought to be derived from an HIMU-type upwelling mantle containing isotopically
depleted (NMORB)-type component having interacted with an enriched (EM)-type component, the origin of which is still a subject
of debate. We studied the relationships between Ni, Mn and Ca concentrations in olivine phenocrysts (85.6–90.0 mol.% Fo, 1,722–3,915 ppm
Ni, 1,085–1,552 ppm Mn, 1,222–3,002 ppm Ca) from the most primitive subaerial and ODP Leg 157 high-silica (picritic to olivine
basaltic) lavas with their bulk rock Sr–Nd–Pb isotope compositions (87Sr/86Sr = 0.70315–0.70331, 143Nd/144Nd = 0.51288–0.51292, 206Pb/204Pb = 19.55–19.93, 207Pb/204Pb = 15.60–15.63, 208Pb/204Pb = 39.31–39.69). Our data point toward the presence of both a peridotitic and a pyroxenitic component in the magma source.
Using the model (Sobolev et al. in: Science 316:412–417, 2007) in which the reaction of Si-rich melts originated during partial
melting of eclogite (a high pressure product of subducted oceanic crust) with ambient peridotitic mantle forms olivine-free
reaction pyroxenite, we obtain an end member composition for peridotite with 87Sr/86Sr = 0.70337, 143Nd/144Nd = 0.51291, 206Pb/204Pb = 19.36, 207Pb/204Pb = 15.61 and 208Pb/204Pb = 39.07 (EM-type end member), and pyroxenite with 87Sr/86Sr = 0.70309, 143Nd/144Nd = 0.51289, 206Pb/204Pb = 20.03, 207Pb/204Pb = 15.62 and 208Pb/204Pb = 39.84 (HIMU-type end member). Mixing of melts from these end members in proportions ranging from 70% peridotite and 30%
pyroxenite to 28% peridotite and 72% pyroxenite derived melt fractions can generate the compositions of the most primitive
Gran Canaria shield stage lavas. Combining our results with those from the low-silica rocks from the western Canary Islands
(Gurenko et al. EPSL 277:514–524, 2009), at least four distinct components are required. We propose that they are (1) HIMU-type
pyroxenitic component (representing recycled ocean crust of intermediate age) from the plume center, (2) HIMU-type peridotitic
component (ancient recycled ocean crust stirred into the ambient mantle) from the plume margin, (3) depleted, MORB-type pyroxenitic
component (young recycled oceanic crust) in the upper mantle entrained by the plume, and (4) EM-type peridotitic component
from the asthenosphere or lithosphere above the plume center. 相似文献
38.
Kui Xiang Kjersti Solberg Eikrem Morten Jakobsen Geir Nvdal 《Geophysical Prospecting》2022,70(1):3-18
We have derived a convergent scattering series solution for the frequency-domain wave equation in acoustic media with variable density and velocity. The convergent scattering series solution is based on the homotopy analysis of a vectorial integral equation of the Lippmann–Schwinger type. By using the Green's function and partial integration, we have derived the vectorial integral equation of the Lippmann–Schwinger type that involves the pressure gradient field as well as the pressure field from the wave equation. The vectorial Lippmann–Schwinger equation can in principle be solved via matrix inversion, but the computational cost of matrix inversion scales like , where is the number of grid blocks. The computational cost can be significantly reduced if one solves the vectorial Lippmann–Schwinger equation iteratively. A simple iterative solution is the Born series, but it is only convergent when the scattering potential is sufficiently small. In this study, we have used the so-called homotopy analysis method to derive an iterative solution for the vectorial Lippmann–Schwinger equation which can be made convergent even in strongly scattering media. The computational cost of our convergent scattering series scales as . Our algorithm, which is based on the homotopy analysis method, involves a convergence control operator that we select using hierarchical matrices. We use a three-layer model and a resampled version of the SEG/EAGE salt model to show the performance of the developed convergent scattering series. 相似文献
39.
Immiscible silicate liquid partition coefficients: implications for crystal-melt element partitioning and basalt petrogenesis 总被引:2,自引:1,他引:2
Ilya V. Veksler Alexander M. Dorfman Leonid V. Danyushevsky Jakob K. Jakobsen Donald B. Dingwell 《Contributions to Mineralogy and Petrology》2006,152(6):685-702
This study investigates partitioning of elements between immiscible aluminosilicate and borosilicate liquids using three synthetic mixtures doped with 32 trace elements. In order to get a good spatial separation of immiscible liquids, we employed a high-temperature centrifuge. Experiments were performed at 1,050–1,150°C, 1 atm, in sealed Fe and Pt containers. Quenched products were analysed by electron microprobe and LA ICP-MS. Nernst partition coefficients (D’s) between the Fe-rich and Si-rich aluminosilicate immiscible liquids are the highest for Zn (3.3) and Fe (2.6) and the lowest for Rb and K (0.4–0.5). The plots of D values against ionic potential Z/r in all the compositions show a convex upward trend, which is typical also for element partitioning between immiscible silicate and salt melts. The results bear upon the speciation and structural position of elements in multicomponent silicate liquids. The ferrobasalt–rhyolite liquid immiscibility is observed in evolved basaltic magmas, and may play an important role in large gabbroic intrusions, such as Skaergaard, and during the generation of unusual lavas, such as ferropicrites. 相似文献
40.
The acoustic signature of fluid flow in complex porous media 总被引:2,自引:0,他引:2
Effective medium approximations for the frequency-dependent and complex-valued effective stiffness tensors of cracked/porous rocks with multiple solid constituents are developed on the basis of the T-matrix approach (based on integral equation methods for quasi-static composites), the elastic–viscoelastic correspondence principle, and a unified treatment of the local and global flow mechanisms, which is consistent with the principle of fluid mass conservation. The main advantage of using the T-matrix approach, rather than the first-order approach of Eshelby or the second-order approach of Hudson, is that it produces physically plausible results even when the volume concentrations of inclusions or cavities are no longer small. The new formulae, which operates with an arbitrary homogeneous (anisotropic) reference medium and contains terms of all order in the volume concentrations of solid particles and communicating cavities, take explicitly account of inclusion shape and spatial distribution independently. We show analytically that an expansion of the T-matrix formulae to first order in the volume concentration of cavities (in agreement with the dilute estimate of Eshelby) has the correct dependence on the properties of the saturating fluid, in the sense that it is consistent with the Brown–Korringa relation, when the frequency is sufficiently low. We present numerical results for the (anisotropic) effective viscoelastic properties of a cracked permeable medium with finite storage porosity, indicating that the complete T-matrix formulae (including the higher-order terms) are generally consistent with the Brown–Korringa relation, at least if we assume the spatial distribution of cavities to be the same for all cavity pairs. We have found an efficient way to treat statistical correlations in the shapes and orientations of the communicating cavities, and also obtained a reasonable match between theoretical predictions (based on a dual porosity model for quartz–clay mixtures, involving relatively flat clay-related pores and more rounded quartz-related pores) and laboratory results for the ultrasonic velocity and attenuation spectra of a suite of typical reservoir rocks. 相似文献