Equilibrium and disequilibrium degassing of a phonolitic melt (Vesuvius AD 79 “white pumice”) simulated by decompression experiments     

Giada Iacono Marziano  Burkhard C. Schmidt  Daniela Dolfi 《Journal of Volcanology and Geothermal Research》2007

Equilibrium and disequilibrium degassing of a volatile phase from a magma of K-phonolitic composition was investigated to assess its behavior upon ascent. Decompression experiments were conducted in Ar-pressurized externally heated pressure vessels at superliquidus temperature (1050 °C), in the pressure range 10–200 MPa using pure water as fluid phase. All experiments were equilibrated at 200 MPa and then decompressed to lower pressures with rates varying from 0.0028 to 4.8 MPa/s. Isobaric saturation experiments were performed at the same temperature and at 900–950 °C to determine the equilibrium water solubility in the pressure range 30–250 MPa. The glasses obtained from decompression experiments were analyzed for their dissolved water content, vesicularity and bubble size distribution. All decompressed samples presented a first event of bubble nucleation at the capsule–melt interface. Homogeneous bubble nucleation in the melt only occurred in fast-decompressed experiments (4.8 and 1.7 MPa/s), for ΔP ≅ 100 MPa. For these decompression rates high water over-saturations were maintained until a rapid exsolution was triggered at ΔP > 150 MPa. For slower rates (0.0028, 0.024, 0.17 MPa/s) the degassing of the melt took place by diffusive growth of the bubbles nucleating at the capsule–melt interface. This process sensibly reduced water over-saturation in the melt, preventing homogeneous nucleation to occur. For decompression rates of 0.024 and 0.17 MPa/s low water over-saturations were attained in the melt, gradually declining toward equilibrium concentrations at low pressures. A near-equilibrium degassing path was observed for a decompression rate of 0.0028 MPa/s. Experimental data combined with natural pumice textures suggest that both homogeneous and heterogeneous bubble nucleations occurred in the phonolitic magma during the AD 79 Vesuvius plinian event. Homogeneous bubble nucleation probably occurred at a depth of ∼ 3 km, in response to a fast decompression of the magma during the ascent.  相似文献   

Phosphorus oxynitride PON, a silica analogue: structure and compression of the cristobalite-like phase; P –T phase diagram     

J. M. Léger  J. Haines  C. Chateau  G. Bocquillon  M. W. Schmidt  S. Hull  F. Gorelli  A. Lesauze  R. Marchand 《Physics and Chemistry of Minerals》2001,28(6):388-398

 The structure of the cristobalite-like polymorph of phosphorus oxynitride PON has been refined using neutron powder diffraction data. It is tetragonal, space group I&4macr;2d, Z=4. The four P–(O,N) distances are equal but the tetrahedron is compressed along c. In AX₂ or ABX₄ compounds, the tetragonal I&4macr;2d or I&4macr; structure is obtained when the average ratio of the cation to anion radius is below 1.186, whereas the tetragonal P4₁2₁2 or orthorhombic C222₁ structure is obtained at low temperatures for larger ratios. The cell parameters of this PON polymorph have been determined as a function of hydrostatic pressure by in situ angle dispersive X-ray powder diffraction in a diamond-anvil cell. Under truly hydrostatic pressure, a strong anisotropic behavior is observed with the c parameter being nearly incompressible. Very slight anisotropic stress strongly modifies the high-pressure behavior. According to the pressure-temperature conditions of treatment, three phases, cristobalite-, moganite-, and quartz-like, have been obtained by quenching experiments, and the P–T phase diagram of PON was derived. The high-pressure behavior of the α-quartz, moganite, and cristobalite-like polymorphs of PON and SiO₂ is discussed. Received: 7 August 2000 / Accepted: 21 January 2001  相似文献   

A novel ozone sensor for direct eddy flux measurements     

Hans Güsten  Günther Heinrich  Ralf W. H. Schmidt  Ulrich Schurath 《Journal of Atmospheric Chemistry》1992,14(1-4):73-84

A small, lightweight (1.5 kg) and fast-response ozone sensor for direct eddy flux measurements has been built. The basis for detection is the chemiluminescence of an organic dye adsorbed on dry silica gel in the reaction with ozone. The chemiluminescence is monitored with a cheap and small blue-sensitive photomultiplier. At a flow rate of 100 l min^-1 the ozone sensor has a 90% response time of significantly better than 0.1 s with a detection limit lower than 50 ppt at S/N=3. There are no interferences from other atmospheric trace gases like NO_x, H₂O₂ and PAN. Water vapour and SO₂ enhance the chemiluminescence efficiency of the ozone sensor. Since their response times are 22 seconds and 30 minutes, respectively, no correlation between rapid ozone fluctuations and those of these two trace gases is noticed by the ozone sensor when operating at a frequency of 10 Hz.The ozone sensor was tested for several weeks in continuous measurements of ozone fluxes and deposition velocities over different croplands using the eddy correlation technique. Good agreement was found between ozone dry deposition velocities derived from profile measurements and by eddy correlation.  相似文献   

The Holocene paleohydrology and climatic history of the northern great sandy desert - fitzroy trough: With special reference to the history of the northwest Australian monsoon     

Karl-Heinz Wyrwoll  Jennifer Hopwood  N. L. McKenzie 《Climatic change》1992,22(1):47-65

The Holocene history of the northwest Australian monsoon is considered in the light of new stratigraphic findings from the southern margin of the monsoon regime. A discussion of the present-day climatology of northwestern Australia and synoptic controls on precipitation in the areas at the southern margin of the monsoon regime is given as background information for the interpretation of stratigraphic findings from swamp and alluvial sequences. The stratigraphic findings point to little change in the intensity of the northwest Australian monsoon since ca. 6.5 ka. A more tentative inference drawn from the field evidence is that the monsoon activity may well have been reduced in this region during the Early Holocene; during this time insolation levels were also reduced. The possible relationship of the northwest Australian monsoon to insolation levels is explored. It is clear that monsoon behavior cannot be accounted for as a simple linear response of monsoon intensity to variations in insolation. Possible controls are discussed with particular emphasis on the plausibility of changes in the damping of convective motions providing the mechanism. Gill's model of heat-induced circulation is used to provide some evidence in favour of this conjecture.  相似文献   

Schwermetalle in der Nordsee: Ergebnisse der ZISCH-Großaufnahme vom 2.5 bis 13.6.1986     

Dr. Michael Haarich  Pr. Diether Schmidt 《Ocean Dynamics》1993,45(3):137-201

  相似文献   

Zur Deckentektonik des Hochbalkans     

Dr. Klaus Schmidt 《International Journal of Earth Sciences》1960,50(1):416-424

Zusammenfassung Im Botewgebiet der Stara Planina (Hochbalkan) liegt inmitten paläozoischer, mesozoischer und tertiärer Schichten ein 30 km langer und 12 km breiter Granitkomplex, der als autochthone Einheit, aber auch als Deckscholle gedeutet worden ist. Die Deckennatur des Komplexes wird durch die großtektonischen Verhältnisse eindeutig belegt. Der Bewegungsplan besitzt meridionale Symmetrie, die tektonischen Haupttransporte erfolgten von S nach N. Groß- und Kleingefüge entsprechen einander. Das Liegende der Decke besitzt keine einheitliche Prägung. Diskordante Lagerungsverhältnisse lassen variszische, kimmerische, kretazische, laramische und pyrenäische Bewegungen erkennen.  相似文献   

A meteorological 80-m tower near Rotterdam     

P. J. Rijkoort  F. H. Schmidt  C. A. Velds  J. Wieringa 《Boundary-Layer Meteorology》1970,1(1):5-17

Construction, observation site and instrumentation are described of an 80-m meteorological observation tower, erected in Vlaardingen, The Netherlands, for studies in connection with air pollution problems along the Nieuwe Waterweg. From measurements made regularly in the period April 1967–April 1968 summaries are given of wind profile parameters and gustiness averages. Case histories are presented of an air pollution episode lasting several days, and of an hourly average wind direction difference of 120 ° over 70 m.  相似文献   

Anticyclonic and cyclonic eddies near the Somali Coast     

Dr. Karl-Heinz Szekielda 《Ocean Dynamics》1971,24(1):26-29

  相似文献   

Electrostatic Force in Blowing Snow     

D. S. Schmidt  R. A. Schmidt  J. D. Dent 《Boundary-Layer Meteorology》1999,93(1):29-45

Separation of electrostatic charge during the transport of particles by wind adds a force to the gravitational and fluid forces that determine trajectories of particles moving by saltation. Evaluating this electrostatic force requires the electric field strength very near the saltation surface, and charge-to-mass ratios for the moving particles. Field mill readings 4 cm above the surface in a moderate blizzard showed electric field strength as high as +30 kV m^-1. Another experiment gave charge-to-mass ratios of individual saltation particles in low-level drifting that ranged between +72 C kg^-1 and -208 C kg^-1. From these measurements, we estimated electrostatic forces as large as the gravitational force on some saltating particles. Including forces of this magnitude in the equations of motion significantly alters predicted saltation trajectories from those for uncharged particles. Predictions appear reasonable that for some saltating particles, the electrostatic force prevents new surface impacts. These results should help improve models of energy transfer in the planetary boundary layer during blizzards and sandstorms.  相似文献   

Modellrechnungen für die freigesetzte Energie bei der Oxydation organischen Materials im Seewasser     

Karl-Heinz Szekielda 《Ocean Dynamics》1967,20(6):265-269

  相似文献