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51.
Political Cartography: From Bertin to Brexit 总被引:1,自引:1,他引:0
Alexander Kent 《The Cartographic journal》2013,50(3):199-201
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53.
Hilary A. Dugan Tom Gleeson Scott F. Lamoureux Kent Novakowski 《Environmental Earth Sciences》2012,66(5):1385-1392
In the High Arctic, groundwater fluxes are limited by the presence of continuous permafrost, although it has been hypothesized that there may be localized groundwater flow and hydraulic connectivity beneath large lakes, due to the presence of taliks, or large regions of unfrozen ground. However, due to the logistical difficulty of employing seepage meters and piezometers in deep, ice-covered lakes, relatively little is known about groundwater discharge to polar lakes. One method of assessing groundwater discharge is through the use of geochemical tracers. We conducted a pilot study to quantify groundwater discharge into a High Arctic lake using dissolved radon gas as a geochemical tracer. Lake water was collected in 15 L polyvinyl chloride (PVC) bags with minimal atmospheric interaction from a 25-m deep lake near Shellabear Point, Melville Island, Northwest Territories, Canada. Sample bags were aerated through a closed water loop for 60 min to allow sufficient radon to equilibrate in a coupled air circuit. Radon in air concentrations were measured on a Durridge RAD7 portable alpha spectrometer. The field trial in a remote setting and separate tests with groundwater samples collected from a temperate site demonstrate the utility of the methodology. The limited results suggest that radon levels in the lower water column are elevated above background levels following nival melt in the surrounding watershed. Although these results are insufficient to quantify groundwater discharge, the results suggest subsurface flow may exist, and further study is warranted. 相似文献
54.
Liang-Saw Wen Peter H. Santschi Kent W. Warnken William Davison Hao Zhang Hsiu-Ping Li Kuo-Tung Jiann 《Estuarine, Coastal and Shelf Science》2011
It is generally assumed that estuarine mixing is continuous for metals from terrestrial sources, gradually decreasing towards the open ocean endmember. Here we show that, chemical reactivity, determined by ion exchange method, and molecular weight distributions, obtained using cross-flow ultrafiltration, of dissolved Cd, Cu, and Ni in the surface waters of the Gulf of Mexico varied systematically across the estuarine mixing zone of the Mississippi River. Most size or chemical affinity fractions of dissolved metals (<0.4 μm) were linearly related to salinity (10.8–36.6), suggesting that the distribution of these elements was mainly controlled by continuous mixing processes. Dissolved concentrations across the salinity gradient ranged for Cd: 87–187 pM; Cu: 1.4–18.3 nM; and Ni: 2.6–18.8 nM, with highest values near the Mississippi river mouth, and lowest concentrations in a warm core ring in the Gulf of Mexico. Dissolved Cd was mostly present as a truly dissolved (<10 kDa, 97 ± 1%) and cationic fraction (Chelex-100 extractable, 94 ± 4%). A novel observation across the estuarine mixing zone was that colloidal metal concentrations were identical to either inert (for Cu, Ni) or AMPG-labile anionic (Cu, Cd) fractions. The difference in behavior between Cu and the other two metals might indicate differences in the biopolymeric nature of the metal–organic chelates. In particular, the anionic-organic Cd fractions accounted for just 3 ± 1%, on average. However, for Cu, it was 24 ± 4%, and for Ni, it was 9 ± 6%. The fractions of the total dissolved metal fractions that were “inert” averaged 31 ± 10% for Cu and 29 ± 12% for Ni. Small but noticeable amounts (6 ± 3%) of dissolved inert Cd fractions were also present. Apparent non-local transport processes, likely associated with cross-shelf sediment resuspension processes, could have been responsible for the relatively high concentrations of ‘inert’ and ‘anionic’ metal fractions in high salinity coastal waters, and accounting for the persistence of metals bound to humic substances in the Gulf of Mexico. 相似文献
55.
J. Roberge P. J. Wallace A. J. R. Kent 《Contributions to Mineralogy and Petrology》2013,165(2):237-257
To investigate the origin of compositional zonation in the Bishop Tuff magma body, we have analyzed trace elements in the matrix glass of pumice clasts and in quartz-hosted melt inclusions. Our results show contrasting patterns for quartz in different parts of the Bishop Tuff. In all samples from the early part of the eruption, trace element compositions of matrix glasses are similar to but slightly more evolved than quartz-hosted melt inclusions. This indicates a cogenetic relationship between quartz crystals and their surrounding matrix glass, consistent with in situ crystallization. The range of incompatible element concentrations in melt inclusions and matrix glass from single pumice clasts requires 16–20 wt% in situ crystallization. This is greater than the actual crystal content of the pumices (<15 % crystals). In contrast to the pattern for the early pumices, pyroclastic flow samples from the middle part of the eruption show contrasting trends: In some clasts, the matrix is more evolved than the inclusions, whereas in other clasts, the matrix is less evolved. In the late Bishop Tuff, all crystal-rich samples have matrix glasses that are less evolved than the melt inclusions. Trace element abundances indicate that the cores of quartz in the late Bishop Tuff crystallized from more differentiated rhyolitic magma that was similar in many ways, yet distinct from the early-erupted Bishop Tuff. Our results are compatible with a model of secular incremental zoning (Hildreth and Wilson in Compositional zoning of the Bishop Tuff. J Petrol 48(5):951–999, 2007), in which melt batches from underlying crystal mush rise to various levels in a growing magma body according to their buoyancy. Early- and middle-erupted quartz crystallized from highly evolved rhyolitic melt, but then some parts of the middle-erupted magma were invaded by less differentiated rhyolite such that the matrix melt at the time of eruption was less evolved than the melt inclusions. A similar process occurred but to a greater extent in magma that erupted to form the late Bishop Tuff. In addition, there was a final, major magma mixing event in the late magma that formed Ti-rich rims on quartz and Ba-rich rims on sanidine, trapped less evolved rhyolitic melt inclusions, and resulted in dark and swirly crystal-poor pumice that is a rare type throughout much of the Bishop Tuff. 相似文献
56.
Oceanic arcs are commonly cited as primary building blocks of continents, yet modern oceanic arcs are mostly subducted. Also, lithosphere buoyancy considerations show that oceanic arcs (even those with a felsic component) should readily subduct. With the exception of the Arabian–Nubian orogen, terranes in post-Archean accretionary orogens comprise < 10% of accreted oceanic arcs, whereas continental arcs compose 40–80% of these orogens. Nd and Hf isotopic data suggest that accretionary orogens include 40–65% juvenile crustal components, with most of these (> 50%) produced in continental arcs.Felsic igneous rocks in oceanic arcs are depleted in incompatible elements compared to average continental crust and to felsic igneous rocks from continental arcs. They have lower Th/Yb, Nb/Yb, Sr/Y and La/Yb ratios, reflecting shallow mantle sources in which garnet did not exist in the restite during melting. The bottom line of these geochemical differences is that post-Archean continental crust does not begin life in oceanic arcs. On the other hand, the remarkable similarity of incompatible element distributions in granitoids and felsic volcanics from continental arcs is consistent with continental crust being produced in continental arcs.During the Archean, however, oceanic arcs may have been thicker due to higher degrees of melting in the mantle, and oceanic lithosphere would be more buoyant. These arcs may have accreted to each other and to oceanic plateaus, a process that eventually led to the production of Archean continental crust. After the Archean, oceanic crust was thinner due to cooling of the mantle and less melt production at ocean ridges, hence, oceanic lithosphere is more subductable. Widespread propagation of plate tectonics in the late Archean may have led not only to rapid production of continental crust, but to a change in the primary site of production of continental crust, from accreted oceanic arcs and oceanic plateaus in the Archean to primarily continental arcs thereafter. 相似文献
57.
58.
In order to evaluate and further constrain models for volatile movement and vapor enrichment of magma stored at shallow levels, amphibole phenocrysts from 2004–2005 Mount St. Helens dacite were analyzed for major and selected trace elements (Li, Cu, Zn, Mn, and REE) and Li isotopes. Several recent studies have examined fluid-mobile trace element abundances in phencryst phases and melt inclusions as a means of tracking volatile movement within subvolcanic magmatic systems, and high Li contents in plagioclase phenocrysts from 1980 and 2004 Mount St. Helens dacites have been interpreted as evidence that shallow magma was fluxed by a Li-bearing vapor phase prior to eruption. 相似文献
59.
Bruce R. Bowman W. Kent Tobiska Michael J. Kendra 《Journal of Atmospheric and Solar》2008,70(11-12):1482-1496
The goal of this study was to characterize the thermospheric semiannual density response to solar heating during the last 35 years. Historical radar observational data have been processed with special orbit perturbations on 28 satellites with perigee heights ranging from 200 to 1100 km. Approximately 225,000 very accurate average daily density values at perigee have been obtained for all satellites using orbit energy dissipation rates. The semiannual variation has been found to be extremely variable from year to year. The magnitude of the maximum yearly difference, from the July minimum to the October maximum, is used to characterize the yearly semiannual variability. It has been found that this maximum difference can vary by as much as 100% from one year to the next. A high correlation has been found between this maximum difference and solar EUV data. The semiannual variation for each year has been characterized based on analyses of annual and semiannual cycles, using Fourier analysis, and equations have been developed to characterize this yearly variability. The use of new solar indices in the EUV and FUV wavelengths is shown to very accurately describe the semiannual July minimum phase shifting and the variations in the observed yearly semiannual amplitude. 相似文献
60.
Brenda Moraska Lafrancois Suzanne Magdalene D. Kent Johnson 《Journal of Paleolimnology》2009,41(4):603-622
Long-term water quality monitoring data from two riverine lakes in the Upper Mississippi River basin, Lakes St. Croix and
Pepin, were analyzed to compare the long-term average water quality conditions and land use distributions, water quality trends
and loads at lake inlets and outlets, trends from long-term versus short-term monitoring records, and the ability of paleolimnological
cores to accurately infer lake water quality conditions. During the 1976–2004 period, the long-term average concentrations
of nutrients, suspended solids, and chlorophyll-a were consistently lower at the Lake St. Croix inlet versus the Lake Pepin inlet, which drains a greater proportion of urban
and agricultural runoff. Despite these differences, nutrient trends were similar at the inlets to both lakes; reductions in
total phosphorus and ammonium concentrations were attributed to improvements in point source technologies, whereas increasing
nitrate concentrations were attributed to both point source changes and nonpoint source increases. Despite improvements in
several water quality variables, nitrate concentrations are increasing in both lakes, sediment trends indicate persistent
nonpoint source inputs to Lake Pepin, and current total phosphorus concentrations remain well above pre-1950s levels in both
lakes. Since urban development and agriculture are increasing in the Lake St. Croix and Lake Pepin Watersheds, continued point
source regulation and additional nonpoint source control efforts will be needed to further improve water quality in these
lakes. The 1976–2004 trends for most water quality variables were similar at inlet versus outlet sites on Lake St. Croix.
Trends at Lake Pepin inlet versus outlet sites were less similar, but data availability limited the comparison to the 1993–2003
period. While the truncated data record highlighted short-term trends in both lakes, the full data record was most useful
for exploring general patterns in water quality. Length of monitoring record affected our ability to detect trends at the
inlets to both lakes, and altered the magnitude of detected trends. During the two decades of the 1980s and 1990s, paleolimnological
estimates of retained phosphorus loads were similar to those estimated from recent water quality monitoring. These similarities
support the use of paleolimnological approaches to infer past water quality conditions in Lakes St. Croix and Pepin.
This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this
special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue. 相似文献