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1.
Liang-Saw Wen Peter H. Santschi Kent W. Warnken William Davison Hao Zhang Hsiu-Ping Li Kuo-Tung Jiann 《Estuarine, Coastal and Shelf Science》2011
It is generally assumed that estuarine mixing is continuous for metals from terrestrial sources, gradually decreasing towards the open ocean endmember. Here we show that, chemical reactivity, determined by ion exchange method, and molecular weight distributions, obtained using cross-flow ultrafiltration, of dissolved Cd, Cu, and Ni in the surface waters of the Gulf of Mexico varied systematically across the estuarine mixing zone of the Mississippi River. Most size or chemical affinity fractions of dissolved metals (<0.4 μm) were linearly related to salinity (10.8–36.6), suggesting that the distribution of these elements was mainly controlled by continuous mixing processes. Dissolved concentrations across the salinity gradient ranged for Cd: 87–187 pM; Cu: 1.4–18.3 nM; and Ni: 2.6–18.8 nM, with highest values near the Mississippi river mouth, and lowest concentrations in a warm core ring in the Gulf of Mexico. Dissolved Cd was mostly present as a truly dissolved (<10 kDa, 97 ± 1%) and cationic fraction (Chelex-100 extractable, 94 ± 4%). A novel observation across the estuarine mixing zone was that colloidal metal concentrations were identical to either inert (for Cu, Ni) or AMPG-labile anionic (Cu, Cd) fractions. The difference in behavior between Cu and the other two metals might indicate differences in the biopolymeric nature of the metal–organic chelates. In particular, the anionic-organic Cd fractions accounted for just 3 ± 1%, on average. However, for Cu, it was 24 ± 4%, and for Ni, it was 9 ± 6%. The fractions of the total dissolved metal fractions that were “inert” averaged 31 ± 10% for Cu and 29 ± 12% for Ni. Small but noticeable amounts (6 ± 3%) of dissolved inert Cd fractions were also present. Apparent non-local transport processes, likely associated with cross-shelf sediment resuspension processes, could have been responsible for the relatively high concentrations of ‘inert’ and ‘anionic’ metal fractions in high salinity coastal waters, and accounting for the persistence of metals bound to humic substances in the Gulf of Mexico. 相似文献
2.
Vertical profiles of dissolved and particulate Mn, Fe, Ni, Cu, Zn, Cd, Pb, and (234)Th were determined in the Hung-Tsai Trough off southwestern Taiwan during 19-23 November, 2004. Except in the case of Cd, the distribution coefficient (K(d)) of the trace elements showed a negative correlation with the suspended particle concentration. Based on the average K(d) values, the general sequence of particle affinities for the eight trace elements is, from highest to lowest, Fe>Mn≈Pb>Zn≈Th>Cd≈Cu≈Ni. The trace metal data was coupled with the particle removal flux estimated from (234)Th/(238)U disequilibrium to investigate metal removal by particle sinking from the euphotic layer. The residence time of trace elements with respect to particle removal from the euphotic layer was estimated. A negative correlation between the residence time and the distribution coefficient for the trace metals was found. 相似文献
3.
This paper is a continuation of previous research, which obtained a convenient solution for arbitrary surface fluxes before ponding. By means of Fourier Transformation this has been extended to derive analytical solutions of a linearized Richards' equation for arbitrary input fluxes after surface saturation. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
4.
Jiann‐Neng Fang Bing‐Sheng Yu Cheng‐Hong Chen David Teh‐Yu Wang Li‐Ping Tan 《Geoarchaeology》2011,26(2):245-268
Three coins of the Khotan horse, or Sino‐Kharosthi, style from Xinjiang province of China were recently obtained from a coin dealer. Because the archaeological context of these coins remains unknown, we conducted chemical and stylistic analyses to help determine their authenticity. Energy dispersive X‐ray (EDX) and wavelength dispersive X‐ray (WDX or microprobe) measurements indicate that they are red (pure) copper and bronze coins, with one coin containing 4.2% Ag. Metal content and the presence of secondary minerals formed through weathering indicate that these are authentic ancient coins that were buried in a dry environment. All three coins bear Chinese characters; one shows Kharosthi, and two display Brahmi, a popular language in Khotan from A.D. 260 to 282. This indicates that the Sino‐Brahmi coins were made slightly later than the Sino‐Kharosthi coins, which were made before A.D. 260. These specimens represent the first Sino‐Brahmi coin and 20‐zhu coin ever reported in the literature. © 2011 Wiley Periodicals, Inc. 相似文献
5.
Jiann‐Mou Chen 《水文研究》2008,22(26):5037-5047
Most methods developed to represent water flow phenomena in an unconfined aquifer with a fully penetrated pumping well are either numerical, such as the well‐known FEMWTER model, or experimental; analytical models of a partially penetrated pumping well are rare. This study employs the linearized Richards equation as the governing equation, with the aid of Fourier Integral Transformation, to obtain an analytical solution of the water content distribution in an unconfined aquifer with a partially penetrated pumping well. The results from this study could serve to substantiate in some sense results from numerical models. In addition, the theory developed herein can be modified to simulate a vacuum‐pressured pumping well since it is derived by considering, among others, the location and length of a well screen with fluxes. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
6.
Dissolved and particulate Mn and Fe in the nearshore waters were determined at 27 stations along the west coast of Taiwan during 19-23 November 2004. The latitudinal distributions of Mn and Fe were very similar; however, the concentration in the dissolved phase was lower, whereas that in the particulate phase was higher in the northern regime. The higher percentage of Fe than Mn that was associated with particles resulted in a two-order of magnitude higher particle-water partition coefficient for Fe, Kd(Fe), than that for Mn, Kd(Mn). The removal fluxes of Mn and Fe could be estimated by multiplying the particulate 234Th removal flux with the Mn/234Th and Fe/234Th ratios in suspended particles, which ranged from 0.1 to 3.8 mmol m−2 d−1 for Mn, and from 3.4 to 194.5 mmol m−2 d−1 for Fe. Residence times ranged from 1 to 20 days for Mn and Fe were estimated in the nearshore. 相似文献
7.
This paper reports the results of cyclic loading tests performed on four specimens consisting of reinforced concrete frames with brick infill walls. The brick infill is pre‐laid, followed by the cast in‐place RC columns and beams. Test parameters include the height‐to‐length ratio of the brick infill wall and the mortar compressive strength. Test results reveal that the in‐plane lateral strength of brick infill wall is related to the fracture path. The fracture path for brick infill walls with large height‐to‐length ratios includes bed joints, cross joints, and vertical splitting of bricks. As a result, the lateral strength of this type of brick infill wall is larger. In comparison, the fracture path for brick infill walls with small height‐to‐length ratios only passes through joints, which is the reason why they have lower lateral strength. Mortar with higher strength improves the lateral strength of brick infill wall. In addition to presenting experimental observations in detail, this paper compares the test results with those obtained from existing methods for assessment of seismic resistance. Comments and recommendations are offered with respect to the capabilities of the assessment methods in predicting stiffness, strength, and ultimate deformation capacity of brick infill walls. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
8.
Lacustrine sedimentological and geochemical records for the last 170 years of climate and environmental changes in southeastern China 
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下载免费PDF全文 Kandasamy Selvaraj Bao Zhi Lin Jiann‐Yuh Lou Wei Lan Xia Xiang Tong Huang Chen‐Tung A. Chen 《Boreas: An International Journal of Quaternary Research》2016,45(1):165-179
Reconstruction of modern climate and environmental changes in east Asia using inland natural climate archives can provide valuable insights on decadal–multidecadal climate and environmental patterns that are probably related to both natural and anthropogenic forcing. Here we investigated an 89‐cm‐long sediment core (TH1) from Tian Lake, southeastern China, for sedimentological, physical and geochemical parameters in order to understand climate and environmental changes for the latest two centuries. 137Cs‐ and 210Pb‐based age models show that the fine sand–coarse silt‐dominated core contains ~170 years (c. AD 1842–2011) of continuous sedimentation. Sediments with fine sands, low MS values, high water content, high TOC content and a high C:N ratio from c. AD 1842 to 1897 suggest intense hydrological conditions and strong runoff in the catchment, probably because of a humid climate. From AD 1897 to 1990, sediments with very fine sand and coarse silt, high MS values, low water content and unchanged TOC and C:N ratios indicate normal hydrological conditions and in‐lake algae‐derived organic matter. During this interval, the chemical weathering indicators show stronger weathering conditions compared with sediments deposited during AD 1842–1897, supporting the dominance of weathered surface soil input in the earlier interval and physical erosion dominance in the later period, respectively. Since AD 1990, the continuous decrease of geochemical proxies suggests human‐interacted Earth surface processes in the catchment of Tian Lake. A PCA revealed four dominant geochemical controlling factors – detrital input, trophic status, grain size and early diagenesis –, accounting for 26, 20, 18 and 16% of total variance, respectively. This study for the first time provides lacustrine geochemical evidence for the most recent two centuries of climate and environmental changes in coastal southeastern China, a region that is currently undergoing an inversion of critical zone, i.e. an overturning of its soil profile, owing to swift modernization. 相似文献
9.
Water samples from eight major Texas rivers were collected at different times during 1997–1998 to determine the dissolved and particulate trace metal concentrations, expected to show differences in climate patterns, river discharge and other hydrochemical conditions, and human activities along the different rivers. Specifically, two eastern Texas rivers (Sabine, Neches) lie in a region with high vegetation, flat topography, and high rainfall rates, while four Central Texas rivers (Trinity, Brazos, Colorado, and San Antonio) flow through large population centers. Relatively high dissolved organic carbon (DOC) concentrations in the eastern Texas rivers and lower pH led to higher Fe and Mn concentrations in river waters. The rivers that flow through large population centers showed elevated trace metal (e.g., Cd, Pb, Zn) concentrations partly due to anthropogenically produced organic ligands such as ethylenediaminetetraacetic acid (EDTA) present in these rivers. Trace metal levels were reduced below dams/reservoirs along several Texas rivers. Statistical analysis revealed four major factors (suspended particulate matter [SPM], EDTA, pH, and DOC) that can explain most of the observed variability of trace metal concentrations in these rivers. SPM concentrations directly controlled particulate metal contents. Variation in pH correlated with changes of dissolved Co, Fe, Mn, and Ni, and particulate Mn concentrations, while DOC concentrations were significantly related to dissolved Fe concentrations. Most importantly, it was found that, more than pH, EDTA concentrations exerted a major control on dissolved concentrations of Cd and Zn, and, to a lesser extent, Cu, Ni, and Pb. 相似文献
10.
The analysis of infiltration of 2D trickle irrigation under multiple‐line sources, governed by the celebrated Richards equation, is performed, aiming at determining the efficiency of trickle irrigation so as to reduce the water demand. A closed‐form solution is explicitly obtained by utilizing the Fourier integral transformation, and this serves as a means to compute the distribution of volumetric water content during trickle irrigation. Results for the infiltration of 2D trickle irrigation under single line and multiple‐line sources are presented, which illustrate the distribution of infiltration water that diffuses into the soil, and make it possible to calculate the period of time required for trickle irrigation for different plants. The results can be applied to verify complicated solutions from other numerical models. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献