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991.
992.
High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm−1 at ambient temperature for hydrous Mg-ringwoodite (γ-Mg2SiO4) up to 30 GPa. The main feature in the OH stretching region is an extremely broad band centred at 3,150 cm−1. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm−1 and an absorption plateau persist with a maximum wavenumber of 3,800 cm−1. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.  相似文献   
993.
Magma mingling: Tectonic and geodynamic implications   总被引:2,自引:0,他引:2  
An attempt is made to consider the tectonic and geodynamic implications of the mingling of mafic and felsic magmas, particularly, the relationships between mafic and felsic igneous rocks in composite dikes and plutons. Magma mingling develops in suprasubduction, intraplate, and collisional settings. The attributes typical of each type of mingling are discussed with special emphasis on the magma mingling of the collisional type, which is related to synmetamorphic shearing and may be regarded as a direct indicator of synorogenic collapse of collisional structural features. This phenomenon is exemplified in the Ol’khon collisional system in Siberia.  相似文献   
994.
Coastal fortifications in South East England have been continuously built and rebuilt over the centuries according to the ebb and flow of politics in Europe. This paper covers an extensive historical period from the influx of the Romans to the present day, detailing how landslides and coastal erosion have affected the numerous constructions along this stretch of coastline. Principal landslide-prone strata form extensive sections of this part of the coast with the tendency to be weak and highly susceptible to marine attack and cliff retreat. Fortifications have been built out of necessity in strategic positions without full consideration of the ground upon which they have been constructed. The continual construction of fortifications along this section of coastline constitutes an unparalleled archaeological record, but it is one that is under continuous threat from coastal erosion and landsliding.  相似文献   
995.
Hg mobilization from contaminated soils and mine wastes was the source of environmental contamination in the Valle del Azogue mining area. We researched solid-phase speciation and aqueous mobility of Hg through Scanning electron microscopy-energy dispersive X-ray spectroscopy and electron probe microanalysis analysis, solid-phase-Hg-thermo-desorption (SPTD) and laboratory column experiments. We found that in contaminated soils and mine wastes, the predominant Hg species was cinnabar (HgS), mainly formed from the weathering of Hg-rich pyrite, and metallic Hg (0) in the matrix, whereas in calcines and tailings the dominant species was metallic Hg (0). The mobilization of Hg in the aqueous phase seems to have originated from the dissolution of elemental Hg (0) present in soils and wastes, reaching concentrations of up to 67 μg l−1, and showing a higher long-term environmental potential risk, in addition to atmospheric emissions.  相似文献   
996.
The procedure for geotechnical site investigation is well established but little attention is currently given to investigating the potential of vegetation to assist with ground stability. This paper describes how routine investigation procedures may be adapted to consider the effects of the vegetation. It is recommended that the major part of the vegetation investigation is carried out, at relatively low cost, during the preliminary (desk) study phase of the investigation when there is maximum flexibility to take account of findings in the proposed design and construction. The techniques available for investigation of the effects of vegetation are reviewed and references provided for further consideration. As for general geotechnical investigation work, it is important that a balance of effort is maintained in the vegetation investigation between (a) site characterisation (defining and identifying the existing and proposed vegetation to suit the site and ground conditions), (b) testing (in-situ and laboratory testing of the vegetation and root systems to provide design parameters) and (c) modelling (to analyse the vegetation effects).  相似文献   
997.
江西彭山锡多金属矿田地质地球化学特征研究   总被引:1,自引:0,他引:1       下载免费PDF全文
彭山锡多金属矿田位于长江中下游的九瑞地区,是近年来发现的一个以富锡、铅、锌矿产为主的大型矿田。以黑云母二长花岗岩与二云母碱长化岗岩组成的彭山隐伏岩体为中心,各类金属矿床呈“晕圈式”分布。矿床的形成分为2个成矿期共7个阶段,通过对彭山岩体、典型矿床及围岩中的硫同位素、铅同位素、包裹体及稀土资料进行分析,反映出燕山晚期钙碱性花岗岩体的缦位与多金属矿床的形成有着密切的联系,岩浆活动为本区提供了大量的成矿物质。  相似文献   
998.
韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例,通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比,确定等比线斜率,探讨韧性变形对岩石体积和成分变异的影响。计算结果表明,在糜棱岩化过程中,糜棱岩化花岗岩体积亏损21%,花岗质糜棱岩体积亏损31%。质量平衡计算结果和等比线图表明,韧;陛剪切作用导致SiO2,流失量最大,A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失,显示出较强的活动性,MnO、P2O5、Sc位于等比线上或附近,表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的,不活动组分的变异是体.积亏损造成的。  相似文献   
999.
The combination of radiance from both clear and cloudy regions of sky within the instrument's field of view (FOV) adds significant uncertainty to retrievals of atmospheric state profiles and cloud microphysical properties from infrared spectroradiometers. In this letter, we use observations of radiance from both the 8-13 and 3-5 /spl mu/m bands to retrieve estimates of the cloud fraction in the instrument's FOV, as well as microphysical cloud properties, from high-spectral-resolution infrared radiometers. Cloud fraction derived from imagers as well as high-time-resolution observations show good agreement and high correlation with our derived cloud fraction values. This is shown for both ground-based and aircraft-based observations. We also demonstrate that the use of the additional information in the 3-5 /spl mu/m band extends the dynamic range and accuracy of microphysical properties that can be retrieved from infrared radiance data.  相似文献   
1000.
Hydro-ecological modelers often use spatial variation of soil information derived from conventional soil surveys in simulation of hydro-ecological processes over watersheds at mesoscale (10–100 km2). Conventional soil surveys are not designed to provide the same level of spatial detail as terrain and vegetation inputs derived from digital terrain analysis and remote sensing techniques. Soil property layers derived from conventional soil surveys are often incompatible with detailed terrain and remotely sensed data due to their difference in scales. The objective of this research is to examine the effect of scale incompatibility between soil information and the detailed digital terrain data and remotely sensed information by comparing simulations of watershed processes based on the conventional soil map and those simulations based on detailed soil information across different simulation scales. The detailed soil spatial information was derived using a GIS (geographical information system), expert knowledge, and fuzzy logic based predictive mapping approach (Soil Land Inference Model, SoLIM). The Regional Hydro-Ecological Simulation System (RHESSys) is used to simulate two watershed processes: net photosynthesis and stream flow. The difference between simulation based on the conventional soil map and that based on the detailed predictive soil map at a given simulation scale is perceived to be the effect of scale incompatibility between conventional soil data and the rest of the (more detailed) data layers at that scale. Two modeling approaches were taken in this study: the lumped parameter approach and the distributed parameter approach. The results over two small watersheds indicate that the effect does not necessarily always increase or decrease as the simulation scale becomes finer or coarser. For a given watershed there seems to be a fixed scale at which the effect is consistently low for the simulated processes with both the lumped parameter approach and the distributed parameter approach.  相似文献   
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