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51.
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This work assessed both the fractionation and the seasonal mobility variations of Ga and In in systems impacted by acidic thermal waters. This was accomplished by performing thermodynamic calculations using the PHREEQC algorithm and by assessing the activity of acidophilic iron-oxidizing bacteria. The pH of the Kusatsu thermal waters in Gunma Prefecture, central Japan, is rapidly increased following the addition of a lime suspension. After an abrupt pH increase, under which conditions free ions of Ga and In and their complexes with Cl? and SO42? exist only in negligible quantities, the majority of dissolved Ga and In is removed by sorption onto suspended hydrous ferric oxides (HFOs). These HFOs are then transported to an artificial lake without significant sedimentation along the river. Subsequently, the suspended HFOs settle out and are added to sediments without significant fractionation between Ga and In. The Tamagawa thermal waters in Akita Prefecture, northeast Japan, are also treated with lime. However, complete neutralization requires mixing with some tributary streams, leading to a gradual downstream increase in pH. Dissolved Ga is, in general, sorbed by HFOs in upstream areas, leading to wide dispersal of Ga across the entire watershed. In comparison, In is transported to the lake inlet predominantly as a Cl? complex species without significant removal along the river, with the majority being precipitated in an artificial lake, where Cl? concentrations are too low to form stable complex species with In, and thus, dissolved In is sorbed by HFOs. As a result, In is effectively concentrated within downstream lakebed sediments, whereas Ga is dispersed along the river. Seasonal variations in Ga mobility within the Tamagawa field between snowmelt and low-flow seasons are primarily controlled by pH, because hydrolysis reactions of these metals, which are related to sorption reactions, tend to occur in the upstream regions in the snowmelt season. However, under warmer conditions, HFO formation preferably occurs due to the activity of acidophilic iron-oxidizing bacteria. Thus, under similar pH variations, dissolved Ga is more effectively removed by HFOs during warmer seasons. On the contrary, because HFOs are abundantly formed in low-flow season, even under colder conditions, before In hydrolysis reaction starts to occur, In mobility is less affected by water temperature and then bacterial activity.  相似文献   
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Journal of Seismology - Site response is a critical consideration when assessing earthquake hazards. Site characterization is key to understanding site effects as influenced by seismic site...  相似文献   
55.
Mamiko  Yoshida  Yuka  Yoshiuchi  Koichi  Hoyanagi 《Island Arc》2009,18(2):320-332
River floods influence sedimentary environments and ecosystems from the terrestrial to the deep-marine. This study documents the occurrence conditions of hyperpycnal flows generated by river floods and related organic-matter sedimentation for Holocene sediments of the Niigata Plain, Central Japan, based on detailed sedimentary facies, total sulfur and total organic carbon content, diatom assemblages and organic-matter composition. Holocene sediments of the Niigata Plain consist of sand, mud and gravel that were deposited in estuarine and fluvial systems during a sea-level rise (15 000–6800 years BP) and stillstand (after 6800 years BP) following the Last Glacial Maximum. Hyperpycnites are present in the upper part of the estuarine lagoon sediments. The depositional age is considered to be about 5000 years BP. The hyperpycnites comprise two successions of a top fining-up unit and a basal coarsening-up unit, and include abundant terrigenous organic matter and freshwater diatoms. A large volume of freshwater is inferred to have flowed into the lagoon during deposition of the upper part of the lagoon sediments. In consequence, hyperpycnal flows may have readily formed in the lagoon, because the halocline was weak. The hyperpycnal flows also produced a layer of concentrated terrigenous organic matter in the uppermost part of the hyperpycnites. The abundant organic matter on the estuarine floor is inferred to have produced anoxic bottom conditions owing to oxidative decomposition by benthic bacteria.  相似文献   
56.
Temporal and spatial variations of sea surface circulation in the South China Sea were revealed with use of altimetric data provided by TOPEX/POSEIDON from December 1992 to October 1997. The estimated distribution of sea surface dynamic heights from altimetric data coincide well with the results of observation by Soong et al. (1995) and Chu et al. (1998). The RMS variability of sea surface dynamic height, which is obtained after tidal correction based on Yanagi et al. (1997), is high in the central part of the South China Sea, the Gulf of Tongking, the Sunda Shelf and the Gulf of Thailand. The high RMS variability in the Gulf of Tongking, the Sunda Shelf and the Gulf of Thailand is due to set up and set down of sea water by the East Asian monsoon, which is northeasterly during winter and southwesterly during summer. Also, the high RMS variability in the central part of the South China Sea is due to the variations of basin-wide circulation. The circulations are dominant in the central part of the South China Sea during summer and winter, an anticyclonic circulation during summer and a cyclonic circulation during winter. It is suggested that these circulations are controlled by the East Asian monsoon. Hence, there is an interannual variability of the basin-wide circulation associated with the variation of the East Asian monsoon.  相似文献   
57.
The plankton food web structure and trophodynamics in the neritic area of Sagami Bay were investigated from January 2003 to December 2005, based on abundance, biomass, production rate and nutritional requirements of pico- (0.2–2 μm), nano- (2–20 μm), micro- (20–200 μm) and mesoplankton (>200 μm: mainly copepods CI-CVI) at 0–10 m depth. The average carbon biomass of the total plankton community was higher in spring and summer (1.452 and 1.466 g C m−2, respectively) than in winter and autumn (0.676 and 0.686 g C m−2, respectively). The average values of primary production and of production rate and food requirement of heterotrophic organisms were higher in summer than in other seasons. During the study period the biomass, production rate and food requirement of small heterotrophs (i.e. bacteria: BA; heterotrophic nanoflagellates: HNF; microzooplankton: MZ) were much higher than those of copepod secondary (CSP) and tertiary producers (CTP), indicating that the microbial food web was the main route of carbon flow from phytoplankton (PP) to CSP and CTP, rather than the grazing food chain. In particular, during summer and autumn the biomass of pico- and nano-size PP plus BA was greater than that of micro-size PP, suggesting the high prevalence of the microbial food web (pico-/nanophytoplankton/BA-HNF/MZ-copepods). During winter and spring, the biomass of micro-size PP was greater than that of pico- and nano-size PP plus BA, suggesting that the indirect route (microphytoplankton-MZ-copepods) probably prevailed, while the microbial food web might be important.  相似文献   
58.
This paper presents a study of the usefulness of flood layers as a time marker in sediments and a report of a case study of Lake Kizaki in central Japan. A flood layer can be identified as a layer having a higher density, coarser grain size, lower TN content, and higher C/N ratio than those of the upper and lower horizons. It can also be characterized by a hyperpycnal sequence composed of a basal coarsening-upward unit and a top fining-upward unit. When flood layers can be correlated with heavy rains in meteorological records, detailed age markers are well established in the sediment. Five flood layers were identified in the surface sediment of Lake Kizaki, and they could be attributed to the historical heavy rainfalls that took place on July 12, 1995; September 28, 1983; August 25, 1974; September 26, 1959; and September 1, 1949 under the constraint of an age model. A precise age model is essential to clarify the environmental changes such as the pollutant history in detail.  相似文献   
59.
The Saga Plain is near Beppu–Shimabara graben, a region of potential active volcanism. In the graben, mantle He, which has a high 3He/4He ratio of 1.1 × 10−5, escapes easily from the underlying subduction zone. In groundwater of the Saga Plain, except in the Shiroishi district, this ratio gradually increased as the dissolved He content increased, to a maximum of 5 × 10−6. In central Shiroishi, however, the ratio reached a minimum of 8.7 × 10−7 with increasing dissolved He content, suggesting that groundwater in central Shiroishi has selectively accumulated radiogenic He, which has a very low ratio of 1 × 10−8, rather than reflecting the regional He, which is rich in mantle He. This can be explained if groundwater in Shiroishi has become mixed with fossil pore water drawn from impermeable marine clay aquitard layers. The withdrawal of pore water has also caused severe land subsidence in central Shiroishi.  相似文献   
60.
We investigated levels of the pollutant tributyltin (TBT) in blood of pufferfishes (six species), Japanese sea perch, red sea bream, Japanese common goby, Japanese flounder, rockfish, conger eel, and sea mullet collected off the coast of northern Kyushu, Japan. We found considerable levels of TBT (1.4-190 ng/mL) accumulated in the blood of these fish. Blood TBT concentrations were 1.3-22.5 times liver concentrations and 4.9-78 times muscle concentrations, except in conger eel and mullet. We detected TBT (16-111 ng/mL-blood) in the plasma of the fine-patterned puffer (Takifugupoecilonotus) year-round, without any apparent seasonal trend. These results suggest that fish inhabiting coastal areas of Kyushu, Japan, continue to be contaminated with TBT.  相似文献   
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