Chemical and textural equilibration of garnet during amphibolite facies metamorphism: The influence of coupled dissolution–reprecipitation          下载免费PDF全文

Tim J Dempster  Julie La Piazza  Andrew G Taylor  Nicolas Beaudoin  Peter Chung 《Journal of Metamorphic Geology》2017,35(9):1111-1130

Metamorphic equilibration requires chemical communication between minerals and may be inhibited through sluggish volume diffusion and or slow rates of dissolution in a fluid phase. Relatively slow diffusion and the perceived robust nature of chemical growth zoning may preclude garnet porphyroblasts from readily participating in low‐temperature amphibolite facies metamorphic reactions. Garnet is widely assumed to be a reactant in staurolite‐isograd reactions, and the evidence for this has been assessed in the Late Proterozoic Dalradian pelitic schists of the Scottish Highlands. The 3D imaging of garnet porphyroblasts in staurolite‐bearing schists reveals a good crystal shape and little evidence of marginal dissolution; however, there is also lack of evidence for the involvement of either chlorite or chloritoid in the reaction. Staurolite forms directly adjacent to the garnet, and its nucleation is strongly associated with deformation of the muscovite‐rich fabrics around the porphyroblasts. “Cloudy” fluid inclusion‐rich garnet forms in both marginal and internal parts of the garnet porphyroblast and is linked both to the production of staurolite and to the introduction of abundant quartz inclusions within the garnet. Such cloudy garnet typically has a Mg‐rich, Mn‐poor composition and is interpreted to have formed during a coupled dissolution–reprecipitation process, triggered by a local influx of fluid. All garnet in the muscovite‐bearing schists present in this area is potentially reactive, irrespective of the garnet composition, but very few of the schists contain staurolite. The staurolite‐producing reaction appears to be substantially overstepped during the relatively high‐pressure Barrovian regional metamorphism reflecting the limited permeability of the schists in peak metamorphic conditions. Fluid influx and hence reaction progress appear to be strongly controlled by subtle differences in deformation history. The remaining garnet fails to achieve chemical equilibrium during the reaction creating distinctive patchy compositional zoning. Such zoning in metamorphic garnet created during coupled dissolution–reprecipitation reactions may be difficult to recognize in higher grade pelites due to subsequent diffusive re‐equilibration. Fundamental assumptions about metamorphic processes are questioned by the lack of chemical equilibrium during this reaction and the restricted permeability of the regional metamorphic pelitic schists. In addition, the partial loss of prograde chemical and textural information from the garnet porphyroblasts cautions against their routine use as a reliable monitor of metamorphic history. However, the partial re‐equilibration of the porphyroblasts during coupled dissolution–reprecipitation opens possibilities of mapping reaction progress in garnet as a means of assessing fluid access during peak metamorphic conditions.  相似文献   

Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy          下载免费PDF全文

Luke Daly  Phil A. Bland  Svetlana Tessalina  David W. Saxey  Steven M. Reddy  Denis Fougerouse  William D.A. Rickard  Lucy V. Forman  Alexandre La Fontaine  Julie M. Cairney  Simon P. Ringer  Bruce F. Schaefer  Daniel Schwander 《Geostandards and Geoanalytical Research》2018,42(3):279-299

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.  相似文献   

Relict sand dredging for beach nourishment in the central Tyrrhenian Sea (Italy): effects on benthic assemblages     

Barbara La Porta  Monica Targusi  Loretta Lattanzi  Paola La Valle  Daniela Paganelli  & Luisa Nicoletti 《Marine Ecology》2009,30(S1):97-104

The aim of this study is to analyse the effects in space and time of relict sand-dredging activities on macrobenthic assemblages, in an area situated offshore Montalto di Castro (central Tyrrhenian Sea, Italy), and to analyse the recolonisation processes of macrobenthos in the dredged areas. The area in question is characterised by relict sand deposits (Holocenic paleo-beaches), used for beach nourishment along the Latium coast. The effects of sand extraction on benthic assemblages were investigated before, during and after three dredging operations. The sites analysed are located within the dredged areas (inside stations) and in neighbouring, not dredged, areas (outside stations). The results showed that the impact of sand extraction was confined to the dredged stations and to the areas in proximity to the dredged areas. During dredging activities, the structure of benthic assemblages within the impacted stations was characterised by low species richness and diversity. Both the direct removal of sediment and the re-suspension and consequent deposition of fine sediment affected benthic assemblages of the impacted stations. A few months after the dredgings, a recolonisation process was still observed at all the impacted stations. A gradual recolonisation process was observed at those stations affected by only one dredging, whereas a different recolonisation was observed at those stations affected by two dredgings over time. This study suggests that differences of re-colonisation processes of benthic assemblages are related to the intensity of dredging operations in terms of dredging frequency.  相似文献   

Strato-mesospheric ozone and IMF sector boundary     

Manuel Gil  Jan Laštovička  Reviever L. Křivský 《Studia Geophysica et Geodaetica》1989,33(1):101-103

Summary We find no effect of the interplanetary magnetic field(IMF) sector boundary crossing in ozone at altitudes ranging from the middle stratosphere(10 hPa) to the lower mesosphere(0.4 hPa) at middle latitudes(40°–60° N), based on winter data over the period of December 1979–December 1982.

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Резюме Мы не нaшлu нuкaко о эффекma nересеченuя секmорноŭ рaнuцы межnлaнеmно о мa нumно о nоля в озоне в облaсmu высоm меж?rt;у сре?rt;неŭ сmрamосфероŭ(10 Пa) u нuжнеŭ мезосфероŭ(0,4 Пa) нa сре?rt;нuх шuроmaх(40°–60° с.ш.), nрuменяя зuмнuе ?rt;aнные зa nерuо?rt; ?rt;екaбрь 1979 – ?rt;екaбрь 1982 .

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Trends in planetary wave activity in the upper middle atmosphere inferred from the nighttime LF radio wave absorption measurements     

Jan Laštovička 《Studia Geophysica et Geodaetica》1994,38(2):206-212

Summary The nighttime LF radio wave absorption in the lower ionosphere measured at two frequencies in central Europe over 1963–1985 is used to infer planetary wave activity and its long-term trend in the upper middle atmosphere (∼90–100 km). The observed positive trend is roughly consistent with results based on daytime absorption. Nighttime results are less pronounced and less statistically significant probably due to perturbing effects of geomagnetic activity. The observed trends, which are probably of anthropogenic origin, are together with the daytime results [3,4] the first evidence of long-term trends in planetary wave activity in the upper middle atmosphere.  相似文献   

Comments on “Monte Vulture Volcano (Basilicata,Italy): an analysis of morphology and volcaniclastic facies” by J. E. Guest,A. M. Duncan and D. K. Chester     

Luigi La Volpe  Claudia Principe 《Bulletin of Volcanology》1991,53(3):222-227

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Effects of the IMF pro- and anti-sectors in the winter midlatitude ionosphere     

Jan Laštovička  Reviewer L. Křívský 《Studia Geophysica et Geodaetica》1985,29(1):101-104

Summary On the basis of the 1966–73 data, the effect of the difference between pro- and anti-sectors of the IMF is found to be negligible in the winter midlatitude (Central Europe) ionosphere contrary to the dominant effect of this difference in the high-latitude ionosphere found earlier.

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a ¶rt;a a 1966–73. u¶rt;m u m amu ¶rt; pro- u anti- mau . na a u ¶rt;um (¶rt; na) u, , a naa a, naum um u.

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Some possibilities of predicting radio wave absorption in the lower ionosphere     

Josef Boška  Jan Laštovička  Reviewer L. Křivský 《Studia Geophysica et Geodaetica》1986,30(1):87-92

Summary An attempt is made to show possible ways of predicting radio wave absorption in the midlatitude lower ionosphere using relations between absorption and the intensity of solar ionizing radiation and/or common solar activity indices, and between absorption and f₀F2.

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aa mu nuau nu a¶rt;u ¶rt;um u u a mu ¶rt; nu u umum uuu uu (uu uu u¶rt;au amumu) u ¶rt; nu u f₀F2.

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Effects of the imf sector structure in the midlatitude troposphere and stratosphere     

Jan Laštovička  Reviewer F. Pechala 《Studia Geophysica et Geodaetica》1986,30(4):394-403

Summary The data on geopotential heights and temperatures at 7 pressure levels between 1000-10 hPa above Berlin(52.5 °N, 13.4 °E) are analysed for the winters of 1963–1973. No demonstrable effect of the interplanetary magnetic field sector boundary crossing (IMF SBC) is found in the lower and middle stratosphere, but there is a demonstrable effect in the middle troposphere at the 500 hPa level. This effect is less important than the IMF SBC effect in the tropospheric vorticity area index and seems to be of a different type.

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auum ¶rt;a nnmua m u mnam a 7 nm ¶rt;au ¶rt; 1000-10 a a¶rt; u(52,5 °.., 13,4 °.¶rt;.) ¶rt; u 1963–1973. ua ¶rt;aam m nu mau nam aum n( ) ¶rt;a amu u u ¶rt; mam, ma m a¶rt; ¶rt; mn a 500 a. mm m a, m u¶rt; na¶rt;u aumu am, u am m ¶rt; muna.

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Understanding the inelastic seismic behaviour of asymmetric-plan buildings     

Juan C. La De Llera  Anil K. Chopra 《地震工程与结构动力学》1995,24(4):549-572

Studied in this paper is the inelastic seismic behaviour of asymmetric-plan buildings using the histories of base shear and torque. The first step in understanding this behaviour is to construct the base shear and torque surface (BST) for the building, which represents all combinations of shear and torque that applied statically lead to collapse of the structure. Several factors controlling the shape of this surface, such as strength eccentricity and bidirectional ground motion, are identified. Also, their effects on the building responses are studied considering several structural configurations. The results obtained show that the BST surface, in conjunction with the base-shear and torque histories, provides a useful conceptual framework for understanding the behaviour of asymmetric systems. Furthermore, using these surfaces, relevant aspects of the behaviour and design of such buildings become apparent even before dynamic analysis of the structure.  相似文献