Primodial retention of carbon by the terrestrial planets     

John S. Lewis  Stephen S. Barshay  Barbara Noyes 《Icarus》1979,37(1):190-206

Chemical equilibrium calculations on the stability of pure and dissolved graphite and cohenite (Fe₃C), several other carbides, and several carbonates have been carried out for a system with solar elemental abundances over a very wide range of temperature and pressure. The calculated abundances of condensed carbon compounds are similar to the observed inventories on Earth and Venus, but fully 10 times smaller than the minimum carbon abundance found in ordinary chondrites. The total carbon content of most iron meteorites is compatible with their origin as a cooling FeNiCSP solution which was saturated with dissolved carbon at the solidus, such as would be produced by melting an ordinary chondrite, not by direct condensation from or equilibrium with the primitive solar nebula. It is argued that the carbon content of Mars need not be appreciably greater than that of the Earth. Material with even lower formation temperatures than Mars, such as the primitive material in the asteroid belt, may retain substantially more carbon as disequilibrium polymeric organic matter, possibly by the Fischer-Tropsch mechanism favored by Anders. Carbonates are not found as equilibrium products in a solar-composition system, and are probably secondary alteration products. CaCO₃ might, however, persist in a solar-composition gas at temperatures below 460°K and pressures below 10^?6.6 bar. The most stable condensed carbon compounds are found to be graphite, Fe₃C, and possibly TiC, all in solid solution in the metal phase.  相似文献   

Thermodynamics of selected trace elements in the Jovian atmosphere     

Bruce Fegley  John S. Lewis 《Icarus》1979,38(2):166-179

The thermochemistry of several hundred compounds of twelve selected trace elements (Ge, Se, Ga, As, Te, Pb, Sn, Cd, Sb, Tl, In, and Bi) has been investigated for solar composition material along a Jupiter adiabat. The results indicate that AsF₃, InBr, TlI, and SbS, in addition to CO, PH₃, GeH₄, AsH₃, H₂Se, HCl, HF, and H₃BO₃ proposed by Barshay and Lewis (1978), may be potential chemical tracers of atmospheric dynamics. The reported observations of GeH₄ is interpreted on the basis of new calculations as implying rapid vertical transport from levels where T ? 800°K. Upper limits are also set on the abundances of many gaseous compounds of the elements investigated.  相似文献   

Mass-radius relationships and constraints on the composition of Pluto,II     

Mark J. Lupo  John S. Lewis 《Icarus》1980,44(1):41-42

A new estimate of Pluto's mass within the range of possible masses considered in an earlier work has enabled us to refine our model of Pluto's interior.  相似文献   

Numerical simulation of the final stages of terrestrial planet formation     

Larry P. Cox  John S. Lewis 《Icarus》1980,44(3):706-721

Three representative numerical simulations of the growth of the terrestrial planets by accretion of large protoplanets are presented. The mass and relative-velocity distributions of the bodies in these simulations are free to evolve simultaneously in response to close gravitational encounters and occasional collisions between bodies. The collisions between bodies, therefore, arise in a natural way and the assumption of expressions for the relative velocity distribution and the gravitational collision cross section is unnecessary. These simulations indicate that the growth of bodies with final masses approaching those of Venus and the Earth is possible, at least for the case of a two-dimensional system. Simulations assuming an initial uniform distribution of orbital eccentricities on the interval from 0 to e_max are found to produce final states containing too many bodies with masses which are too small when e_max < 0.10, while simulations with e_max > 0.20 result in too many catastrophic collisions between bodies thus preventing rapid accretion of planetary-size bodies. The e_max = 0.15 simulation ends with a state surprisingly similar to that of the present terrestrial planets and, therefore, provides a rough estimate of the range of radial sampling to be expected for the terrestrial planets.  相似文献   

Stable isotope (O and C) and pollen trends in eastern Lake Erie,evidence for a locally-induced climatic reversal of Younger Dryas age in the Great Lakes basin     

C F M Lewis  T W Anderson 《Climate Dynamics》1992,6(3-4):241-250

A cool period from about 11000 to 10 500 BP (11 to 10.5 ka) is recognized in pollen records from the southern Great Lakes area by the return of Picea and Abies dominance and by the persistence of herbs. The area of cooling appears centred on the Upper Great Lakes. A high-resolution record (ca. 9 mm/y) from a borehole in eastern Lake Erie reveals, in the same time interval, this pollen anomaly, isotope evidence of meltwater presence (a — 3 per mil shift in ¹⁸O and a +1.1 per mil shift in ¹³C), increased sand, and reduced detrital calcite content, all suggesting concurrent cooling of Lake Erie. The onset of cooling is mainly attributed to the effect of enhanced meltwater inflow on the relatively large upstream Main Lake Algonquin during the first eastward discharge of glacial Lake Agassiz. Termination of the cooling coincides with drainage of Lake Algonquin, and is attributed to loss of its cooling effectiveness associated with a substantial reduction in its surface area. It is hypothesized that the cold extra inflow effectively prolonged the seasonal presence of lake ice and the period of spring overturn in Lake Algonquin. The deep mixing would have greatly increased the thermal conductive capacity of this extensive lake, causing suppression of summer surface lakewater temperatures and reduction of onshore growing-degree days. Alternatively, a rapid flow of meltwater, buoyed on sediment-charged (denser) lakewater, may have kept the lake surface cold in summer. Other factors such as wind-shifted pollen deposition and possible effects from the Younger Dryas North Atlantic cooling could have contributed to the Great Lakes climatic reversal, but further studies are needed to resolve their relative significance.Contribution to Climo Locarno — Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate ProgramGeological Survey of Canada Contribution 58 890  相似文献   

Noble gases in the Allende and Abee meteorites and a gas-rich mineral fraction: investigation by stepwise heating     

B. Srinivasan  Roy S. Lewis  Edward Anders 《Geochimica et cosmochimica acta》1978,42(2):183-198

Noble gases in three meteoritic samples were examined by stepwise heating, in an attempt to relate peaks in the outgassing curves to specific minerals: NeKrXe in Allende (C3V) and an Allende residue insoluble in HF-HCl, and Xe in Abee (E4). In Allende, chromite and carbon contain most of the trapped Ne (²⁰Ne/²²Ne ≈ 8.7) and anomalous Xe enriched in light and heavy isotopes, and release it at ~850°C (bulk meteorite) or 1000°C (residue). Mineral Q, containing most of the trapped Ar, Kr, Xe as well as some Ne (²⁰Ne/²²Ne ≈ 10.4), releases its gases mainly between 1200 and 1600°C, well above the release temperatures of organic polymers (300–500°) or amorphous carbon (800–1000°). The high noble-gas release temperature, ready solubility in oxidizing acids, and correlation with acid-soluble Fe and Cr all point to an inorganic rather than carbonaceous nature of Q.All the radiogenic ¹²⁹Xe is contained in HCl, HF-soluble minerals, and is distributed as follows over the peaks in the release curve: Attend 1000° (75%), 1300° (25%); Abee (data of Hohenberg and Reynolds, 1969) ~850° (15%), 1100° (60%), 1300° (25%). No conclusive identifications of host phases can yet be given; possible candidates are troilite and silicates for Allende, and djerfisherite, troilite and silicates for Abee.Mineral Q strongly absorbs air xenon, and releases some of it only at 800–1000°C. Dilution by air Xe from Q and other minerals may explain why temperature fractions from bulk meteorites often contain less ^124–130Xe for a given enrichment in heavy isotopes than does xenon from etched chromitecarbon samples, although chromite-carbon is the source of the anomalous xenon in either case. Air xenon contamination thus is an important source of error in the derivation of fission xenon spectra.  相似文献   

Evolution of the Bonneville shoreline scarp in west-central Utah: Comparison of scarp-analysis methods and implications for the diffusion model of hillslope evolution     

J.D. Pelletier  S.B. DeLong  A.H. Al-Suwaidi  M. Cline  Y. Lewis  J.L. Psillas  B. Yanites 《Geomorphology》2006,74(1-4):257-270

Wave-cut pluvial shoreline scarps are ideal natural experiments in hillslope evolution because the ages of these scarps are often precisely known and because they form with a range of heights, alluvial textures, and microclimates (i.e., orientation). Previous work using midpoint-slope methods on pluvial scarps in the Basin and Range concluded that scarp evolution is nonlinear and microclimatically controlled. The purpose of this study was to further examine the influence of scarp height, texture and microclimate in an attempt to calibrate a nonlinear model of scarp evolution. To do this, over 150 profiles of the Bonneville shoreline in the adjacent Snake and Tule Valleys, west-central Utah were collected and analyzed by fitting the entire scarp profile to diffusion-equation solutions, taking into account uncertainty in the initial scarp angle. In contrast to previous studies, this analysis revealed no evidence for nonlinearity or microclimatic control. To understand the reason for this discrepancy, we undertook a systematic study of the accuracy of each scarp-analysis method. The midpoint-slope-inverse method was found to yield biased results, with systematically higher diffusion ages for young, tall scarps. The slope-offset method is unbiased but has limited resolution because it requires many scarp profiles to yield a single diffusion age. A method that incorporates the full scarp profile and uncertainty in the initial scarp angle was found to be the most accurate technique. The application of the full-scarp method to the Bonneville shoreline supports the use of a linear diffusion model for scarps up to 20 m in height. Scarp orientation had no discernable effect on diffusivity values. Soil texture was found to have a weak but significant inverse relationship with diffusivity values.  相似文献   

CO₂ solubility and speciation in intermediate (andesitic) melts: the role of H₂O and composition     

P.L. King  J.R. Holloway 《Geochimica et cosmochimica acta》2002,66(9):1627-1640

We determined total CO₂ solubilities in andesite melts with a range of compositions. Melts were equilibrated with excess C-O(-H) fluid at 1 GPa and 1300°C then quenched to glasses. Samples were analyzed using an electron microprobe for major elements, ion microprobe for C-O-H volatiles, and Fourier transform infrared spectroscopy for molecular H₂O, OH⁻, molecular CO₂, and CO₃²⁻. CO₂ solubility was determined in hydrous andesite glasses and we found that H₂O content has a strong influence on C-O speciation and total CO₂ solubility. In anhydrous andesite melts with ∼60 wt.% SiO₂, total CO₂ solubility is ∼0.3 wt.% at 1300°C and 1 GPa and total CO₂ solubility increases by about 0.06 wt.% per wt.% of total H₂O. As total H₂O increases from ∼0 to ∼3.4 wt.%, molecular CO₂ decreases (from 0.07 ± 0.01 wt.% to ∼0.01 wt.%) and CO₃²⁻ increases (from 0.24 ± 0.04 wt.% to 0.57 ± 0.09 wt.%). Molecular CO₂ increases as the calculated mole fraction of CO₂ in the fluid increases, showing Henrian behavior. In contrast, CO₃²⁻ decreases as the calculated mole fraction of CO₂ in the fluid increases, indicating that CO₃²⁻ solubility is strongly dependent on the availability of reactive oxygens in the melt. These findings have implications for CO₂ degassing. If substantial H₂O is present, total CO₂ solubility is higher and CO₂ will degas at relatively shallow levels compared to a drier melt. Total CO₂ solubility was also examined in andesitic glasses with additional Ca, K, or Mg and low H₂O contents (<1 wt.%). We found that total CO₂ solubility is negatively correlated with (Si + Al) cation mole fraction and positively correlated with cations with large Gibbs free energy of decarbonation or high charge-to-radius ratios (e.g., Ca). Combining our andesite data with data from the literature, we find that molecular CO₂ is more abundant in highly polymerized melts with high ionic porosities (>∼48.3%), and low nonbridging oxygen/tetrahedral oxygen (<∼0.3). Carbonate dominates most silicate melts and is most abundant in depolymerized melts with low ionic porosities, high nonbridging oxygen/tetrahedral oxygen (>∼0.3), and abundant cations with large Gibbs free energy of decarbonation or high charge-to-radius ratio. In natural silicate melt, the oxygens in the carbonate are likely associated with tetrahedral and network-modifying cations (including Ca, H, or H-bonds) or a combinations of those cations.  相似文献   

Virtual vegetables and adopted sheep: ethical relation, authenticity and Internet-mediated food production technologies   总被引：2，自引：1，他引：2  

Lewis Holloway 《Area》2002,34(1):70-81

Associating ideas related to cultural geographies of 'quality' food production and consumption with recent discussion of Internet technologies, virtuality and simulation, this paper examines two newly constituted Internet enterprises offering customers 'virtual' experiences of food production, and 'quality' food products in which they have invested. The paper shows how these enterprises are associated with particular types of geographical and ethical relation, and a search for 'authentic', connected, relationships with food, farming, locality and 'nature'. These relationships are constituted in an assemblage of things held together by flows of food, products, money and electronic communication. The paper ends by suggesting a number of theoretical ideas that might usefully be explored in empirical research into Internet-mediated food production.  相似文献   

Mineralogy and origin of stichtite in chromite-bearing serpentinites     

Lewis D. Ashwal  Bruce Cairncross 《Contributions to Mineralogy and Petrology》1997,127(1-2):75-86

Stichtite, a rare (14 known localities worldwide) hydrated carbonate-hydroxide of Mg and Cr with ideal formula Mg₆Cr₂ (OH)₁₆ CO₃ · 4H₂O, occurs exclusively in Cr-rich serpentinites of ophiolites or greenstone belts. Physical properties (hardness = 1.5–2, specific gravity = 2.16–2.2, perfect basal [0001] cleavage, grain size commonly < 100 μm) resemble talc, but the mineral has an attractive purple to lilac color; chemical analyses demonstrate it to be a non-silicate. Stichtite generally occurs as irregular to rounded masses (< 1 cm – 30 cm across) and as veinlets (< 1 mm – > 2 cm wide) within serpentinite. Macroscopic and microscopic textures, such as crosscutting veinlets and stringers, demonstrate that stichtite formation invariably post-dated serpentinization. In some specimens stichtite surrounds relict grains of Cr-rich spinel; in others stichtite has completely replaced euhedral or subhedral chromites. Chemical analyses of stichtites reveal substantial substitution of Al and Fe³⁺ for Cr in specimens from many localities, reflecting a possible compositional continuum between stichtite and rhombohedral polymorphs hydrotalcite (Mg₆Al₂ (OH)₁₆ CO₃ · 4H₂O) and pyroaurite (Mg₆Fe₂ (OH)₁₆ CO₃ · 4H₂O). We report the first electron microprobe analyses of stichtites from seven localities, and summarize all available published chemical data. Stichtites very likely inherited part of their trivalent cation chemistry from precursor Cr-rich spinels, but stichtite growth apparently post-dated characteristic “ferritchromit” alteration, as demonstrated by the depletion of Al and enrichment in Fe³⁺ in stichtite relative to primary chromite core compositions. Stichtite appears to form by reaction between serpentine and altered chromite, during addition of substantial fluid, either as separate H₂O and CO₂ phases, or as a mixed volatile phase. Such reactions must involve removal of substantial SiO₂, possibly by transport and remote deposition of silica by throughgoing aqueous and carbonic fluid. Received: 4 April 1996 / Accepted: 16 September 1996  相似文献