Atmospheric inputs of trace metals to the northeast Atlantic Ocean: the importance of southeasterly flow     

Lucinda Spokes  Tim Jickells  Kym Jarvis 《Marine Chemistry》2001,76(4)

The study of aerosols and rainwater presented here demonstrates that episodic atmospheric deposition events associated with southeasterly flow are quantitatively significant for large areas of the North Atlantic Ocean. This paper considers aluminium and manganese, with predominantly crustal sources, and lead and zinc, which are mobilised into the atmosphere primarily through anthropogenic activity. High levels of all trace metals are associated with southeasterly flow from Europe as the air passes over heavily populated and industrialised regions before reaching the northeast Atlantic Ocean. Fluxes calculated using the 1% HNO₃ acid soluble metal concentration show that, although the climatological norm for this area is westerly flow, short-lived southeasterly transport events dominate the input of trace metals to this ocean region. This material may be toxic to phytoplankton or may be represent a new source of nutrients to the biological community. A significant decrease in atmospheric lead levels in polluted air is seen between June 1996 and May 1997, reflecting the decrease in use of leaded fuels in Europe. Comparing atmospheric flux values to sediment trap metal fluxes shows that the atmosphere represents the dominant source of zinc to the deep ocean, whereas an additional, non-atmospheric, manganese source this required, perhaps from mobilisation of sedimentary material from the continental shelf or long range advection of manganese rich Saharan material.  相似文献   

Ion and neutral sources and sinks within Saturn's inner magnetosphere: Cassini results     

E.C. Sittler Jr.  N. Andre  M. Burger  A. Coates  D. Reisenfeld  A. Persoon  H.T. Smith  R.E. Hartle  M.D. Shappirio  D.J. McComas 《Planetary and Space Science》2008,56(1):3-18

Using ion-electron fluid parameters derived from Cassini Plasma Spectrometer (CAPS) observations within Saturn's inner magnetosphere as presented in Sittler et al. [2006a. Cassini observations of Saturn's inner plasmasphere: Saturn orbit insertion results. Planet. Space Sci., 54, 1197-1210], one can estimate the ion total flux tube content, N_IONL², for protons, H⁺, and water group ions, W⁺, as a function of radial distance or dipole L shell. In Sittler et al. [2005. Preliminary results on Saturn's inner plasmasphere as observed by Cassini: comparison with Voyager. Geophys. Res. Lett. 32(14), L14S04), it was shown that protons and water group ions dominated the plasmasphere composition. Using the ion-electron fluid parameters as boundary condition for each L shell traversed by the Cassini spacecraft, we self-consistently solve for the ambipolar electric field and the ion distribution along each of those field lines. Temperature anisotropies from Voyager plasma observations are used with (T_⊥/T_∥)_W⁺∼5 and (T_⊥/T_∥)_H⁺∼2. The radio and plasma wave science (RPWS) electron density observations from previous publications are used to indirectly confirm usage of the above temperature anisotropies for water group ions and protons. In the case of electrons we assume they are isotropic due to their short scattering time scales. When the above is done, our calculation show N_IONL² for H⁺ and W⁺ peaking near Dione's L shell with values similar to that found from Voyager plasma observations. We are able to show that water molecules are the dominant source of ions within Saturn's inner magnetosphere. We estimate the ion production rate S_ION∼10²⁷ ions/s as function of dipole L using N_H⁺, N_W⁺ and the time scale for ion loss due to radial transport τ_D and ion-electron recombination τ_REC. The ion production shows localized peaks near the L shells of Tethys, Dione and Rhea, but not Enceladus. We then estimate the neutral production rate, S_W, from our ion production rate, S_ION, and the time scale for loss of neutrals by ionization, τ_ION, and charge exchange, τ_CH. The estimated source rate for water molecules shows a pronounced peak near Enceladus’ L shell L∼4, with a value S_W∼2×10²⁸ mol/s.  相似文献   

Derivation of density and temperature from the Cassini–Huygens CAPS electron spectrometer     

G.R. Lewis  N. Andr  C.S. Arridge  A.J. Coates  L.K. Gilbert  D.R. Linder  A.M. Rymer 《Planetary and Space Science》2008,56(7):901-912

In this paper we present two methods to derive electron fluid parameters from the CAPS–ELS spectrometer on board the Cassini spacecraft currently in orbit around Saturn. In the first part of the paper we give a basic overview of the instrument and describe the challenges inherent in the derivation of density and temperature values using these techniques. We then describe a method to calculate electron moments by integrating the particle distribution function. We also describe a second technique in which we fit the electron energy spectrum with a Gaussian curve and use the peak energy of this curve to derive density and temperature values. We then compare the two methods with particular emphasis on their application to Cassini SOI observations in the saturnian environment and point out the limitations of the two techniques. We will show that results from the two very different methods are in agreement when the physical properties of the environment and of the observed electron populations have been inferred from inspection of the raw data. Finally we will suggest future developments that will remove these limitations.  相似文献   

The Venusian induced magnetosphere: A case study of plasma and magnetic field measurements on the Venus Express mission     

E. Kallio  T.L. Zhang  R. Jarvinen  P. Janhunen  J.-A. Sauvaud  J.-J. Thocaven  H. Andersson  K. Brinkfeldt  M. Holmström  M. Yamauchi  W. Baumjohann  A.J. Coates  D.O. Kataria  K.C. Hsieh  M. Grande  T. Säles  P. Riihelä  N. Krupp  J.G. Luhmann  S. Orsini  A. Mura  M. Maggi  P. Brandt  K. Szego  R.A. Frahm  J.R. Sharber  P. Bochsler 《Planetary and Space Science》2008,56(6):796-801

Plasma and magnetic field measurements made onboard the Venus Express on June 1, 2006, are analyzed and compared with predictions of a global model. It is shown that in the orbit studied, the plasma and magnetic field observations obtained near the North Pole under solar minimum conditions were qualitatively and, in many cases also, quantitatively in agreement with the general picture obtained using a global numerical quasi-neutral hybrid model of the solar wind interaction (HYB-Venus). In instances where the orbit of Venus Express crossed a boundary referred to as the magnetic pileup boundary (MPB), field line tracing supports the suggestion that the MPB separates the region that is magnetically connected to the fluctuating magnetosheath field from a region that is magnetically connected to the induced magnetotail lobes.  相似文献   

Ejection-velocity distributions from impacts into coarse-grained sand     

Mark J. CINTALA  Lucinda BERTHOUD  Friedrich H RZ 《Meteoritics & planetary science》1999,34(4):605-623

Abstract— Velocities of ejecta from seven impacts of aluminum projectiles into coarse-grained sand have been measured with a laser-based apparatus that produces stroboscopic photographs of individual grains in ballistic flight. Speeds and angles of the majority of the ejecta can then be measured very precisely. There appears to be little effect of impact velocity on the functional relationship between the scaled, radial launch position and either the speed or angle of ejection; the seven experiments covered a range of impact velocities from 0.8 to 1.9 kms^—1. The measured ejection speeds follow power-law distributions, as predicted by dimensional analysis, but the angle of ejection is not constant throughout a given event as predicted. Indeed, the angle of ejection declines gradually with increasing radial distance from the impact point, but there are indications that the angle increases again as the position of the final crater's rim is approached. The exponents determined from scaled crater dimensions and ejection-speed distributions are substantially different. Although this might imply that assumptions used in the dimensional analysis are not valid, it is also possible that the coarse sand, whose component grains were comparable in dimension to the diameter of the impactors, instead presented a target that was more of an inhomogeneous aggregate of large fragments than a uniform, continuous medium.  相似文献   

Structured ionospheric outflow during the Cassini T55-T59 Titan flybys     

N.J.T. Edberg  K. Ågren  M.W. Morooka  S.W.H. Cowley  A.J. Coates  M.K. Dougherty 《Planetary and Space Science》2011,59(8):788-797

During the final three of the five consecutive and similar Cassini Titan flybys T55-T59 we observe a region characterized by high plasma densities (electron densities of 1-8 cm⁻³) in the tail/nightside of Titan. This region is observed progressively farther downtail from pass to pass and is interpreted as a plume of ionospheric plasma escaping Titan, which appears steady in both location and time. The ions in this plasma plume are moving in the direction away from Titan and are a mixture of both light and heavy ions with composition revealing that their origin are in Titan's ionosphere, while the electrons are more isotropically distributed. Magnetic field measurements indicate the presence of a current sheet at the inner edge of this region. We discuss the mechanisms behind this outflow, and suggest that it could be caused by ambipolar diffusion, magnetic moment pumping or dispersive Alfvén waves.  相似文献   

El Niño-Southern Oscillation: Related Probabilities of Fatalities from Natural Perils in Australia   总被引：1，自引：0，他引：1  

I. Kuhnel  L. Coates 《Natural Hazards》2000,22(2):117-138

The interannual variability of flood, bushfire andheatwave fatality data for eastern Australia duringthe period 1876–1991 was analysed with respect to thephase of the El Niño-Southern Oscillation (ENSO)and the associated values of the Southern OscillationIndex (SOI). Heatwaves were found to be the mostserious peril in terms of the total number offatalities, while floods ranked first in the fatalityevent day statistics. None of the three monthly(absolute value) fatality data sets showed significantcorrelations with the corresponding values of the SOI,while the correlation analysis of annual (July toJune) data led to significant correlation coefficientsof 0.5 for floods and -0.3 for bushfires. AdditionalSOI value-related classification of the standardisedfatality event days into several ENSO categoriesconfirmed the correlation trends by showing anincrease (decrease) in the standardised bushfire(flood) fatality event day frequencies with increasingvalues of the SOI. In contrast to that, thestandardised heatwave fatality data showed aninconclusive distribution pattern, which hints at theinfluence of other possible factors (such as airpollution) on heatwave-related fatality numbers.The results of a risk assessment analysis have shownthat the probability of reaching the mean annualnumber of flood-fatality event days is roughly fourtimes higher during La Niña seasons (80%) thanthe corresponding probability associated with ElNiño periods (18%). The correspondingprobabilities associated with the mean bushfire andheatwave fatality event days displayed a reversedpattern, with the probabilities of El Niño-relatedyears being roughly twice as high as those associatedwith La Niña seasons (70% and 30% for bushfires,and 60% and 25% for heatwaves, respectively).Further probability calculations performed on thetotals of fatalities from all three perils identifiedthe La Niña years as potentially the mostdangerous in terms of suffering fatalities from theseperils. Furthermore, they highlighted the significantdifferences between the means of fatality event daynumbers recorded during years of extreme SOI values(9.8 for La Niña, and 9.1 for El Niño seasons)and those marked by near-zero SOI values (6.6). Themajor reason for the increase in risk associated withextreme ENSO phases was the higher variability ofthese perils during the respective seasons.  相似文献   

Factors controlling the solubility of aerosol trace metals in the atmosphere and on mixing into seawater     

Lucinda J. Spokes  Tim D. Jickells 《Aquatic Geochemistry》1995,1(4):355-374

Previous work has shown that the type and pH history of an aerosol governs trace metal solubility in rainwater. This study concentrates on the crustal elements Al, Fe and Mn and identifies additional processes which affect dissolution not only in the atmosphere but also on mixing into seawater. Aerosol dissolution experiments (at aerosol concentrations of about 30 mg 1^–1) show manganese exhibiting high solubility at the low pH values typical of clouds (54±2.5% at pH 2, with results expressed in mole percent units) with 85% of this increase occurring within 6 hours of acidification. The percentage dissolution decreases to 50% at pH values representative of rainwater (pH 5.5) and to 26±4% at pH 8, typical of seawater. No such dramatic solution phase removal occurs at pH 8 in the presence of inorganic anions (to a final solubility of 44±2%). Thus the extent of manganese dissolution depends strongly on whether aerosols are cycled through acidic environments and on subsequent inorganic complexation once rainwater mixes into sea. Aluminium shows highest dissolution (7.1±0.6%) at low pH with 78% of this increase occurring within 6 hours of acidification. Rapid solution phase removal occurs on increasing the pH to that representative of rainwater (to 0.9±0.4% with 87% of this decrease occurring within 15 min). As a consequence of acid cycling and aluminium's amphoteric nature, solubility is enhanced at seawater pH (2.3±0.3%) over that in rain. Iron shows a strong pH-solubility relationship with highest solubility at low pH (4.7±0.2%), 70% of this value being reached within 6 hours of acidification, and decreasing rapidly to 0.17% as pH is raised to 8. Addition of inorganic anions at pH 8 to simulate mixing into seawater causes a further decrease in solubility, perhaps due to anion induced colloid destabilisation. Photochemical reduction also effects solubility under low pH conditions with Fe(II) comprising 1% of the total iron in the Saharan Aerosol used and 8.4% in an Urban material at a pH of 2. This element shows rapid solution phase removal with increasing particulate load which is tentatively rationalised in terms of a simple Kd approach.  相似文献   

Bioaccumulation of chromium and its effects on reproduction in Neanthes arenaceodentata (polychaeta)     

Philip S Oshida  Lucinda S Word 《Marine environmental research》1982,7(3):167-174

The levels of hexavalent chromium (Cr VI) that caused diminished reproductive ability in the polychaete Neanthes arenaceodentata were determined. Changes in numbers of offspring and time of spawning caused by Cr VI at 1 to 38 ug/litre during two generations of exposure (309 days) were measured. Time to spawning was unaffected but it was found that reductions in numbers of offsprings occurred at 16 to 38 μl/litre. Bioaccumulation of chromium was also measured and found to be proportional to exposure levels; however, a direct relationship between tissue concentration and reduced numbers of offspring could not be established.  相似文献   

Trial of a tractor dredger for cockles in Burry Inlet, South Wales     

Cotter  A. J. R.; Walker  P.; Coates  P.; Cook  W.; Dare  P. J. 《ICES Journal of Marine Science》1997,54(1):72-83

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