A geochemical model for evaluating theories on the genesis of Florida''s sedimentary phosphate deposits     

Martha W. Gilliland 《Mathematical Geology》1976,8(3):219-242

Present ionic concentrations of Ca ⁺⁺,HCO ₃ ^- ,and HPO ₄ ⁼ in surface and groundwater runoff in Florida indicate that phosphorus is being concentrated in rock through dissolution and reprecipitation, with calcium phosphate increasing at the expense of calcium carbonate. Analog computer simulation of a systems model of this process suggests that significant enrichment can occur in 20 million years. The degree of enrichment depends on the supply of new phosphorus to Florida through rain and oceanic exchange processes. If the calcium phosphate content of original rock is 0.5 to 1.0 percent (0.52 to 1.05 percent P ₂ O ₅),a formation with 10 to 20 percent calcium phosphate (CaPO ₄ or 10.5 to 21.0 percent P ₂ O ₅)as in the Hawthorn Formation (Miocene)may result. Nutrient upwelling along the continental slope coupled with transport to the estuaries by lateral eddy diffusion can supply an additional 400 mg P|m ² |yr which, if deposited, would result in a sediment with a 4.3 percent CaPO ₄ (4.5 percent P ₂ O ₅)content. If this is enriched later by resolution, 40 percent CaPO ₄ (42 percent P ₂ O ₅)results. Through geologic time, the ocean may be considered as a source of phosphorus to the land through rain or estuarine sediment.  相似文献   

The potential listing of Acropora species under the US Endangered Species Act     

Precht WF  Robbart ML  Aronson RB 《Marine pollution bulletin》2004,49(7-8):534-536

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Central Configurations of the Symmetric Restricted 4-Body Problem     

Martha Alvarez-Ramírez  Joaquín Delgado 《Celestial Mechanics and Dynamical Astronomy》2003,87(4):371-381

We consider the symmetric planar (3 + 1)-body problem with finite masses m ₁ = m ₂ = 1, m ₃ = µ and one small mass m ₄ = . We count the number of central configurations of the restricted case = 0, where the finite masses remain in an equilateral triangle configuration, by means of the bifurcation diagram with as the parameter. The diagram shows a folding bifurcation at a value consistent with that found numerically by Meyer [9] and it is shown that for small > 0 the bifurcation diagram persists, thus leading to an exact count of central configurations and a folding bifurcation for small m ₄ > 0.  相似文献   

The cultural context of forest degradation in adjacent Purépechan communities, Michoacán, Mexico     

Martha A Works  Keith S Hadley 《The Geographical journal》2004,170(1):22-38

Recent changes in the cultural and forest landscapes of the Meseta Purépecha in Michoacán, Mexico as a result of forest degradation underscore the complexity of forest change processes in the tropical highlands of Latin America. Differences in community perception and forest structure and composition between the furniture-making and lumber-producing towns of Pichátaro and Sevina, Purépechan indigenous communities located amidst pine forests on Michoacán's volcanic plateau illustrate the dynamics of this process. We base our comparisons on interviews and field measures of forest structure. Our results show dramatic changes in the forests and cultural landscapes of both communities during the past decade. Following high regional timber exports during the early 1990s, Sevina shifted from a self-sufficient to a timber importation community. By comparison, communal forests and individual parcels in Pichátaro continue to provide wood for approximately 300 wood shops. Field data and forest stand maps confirm the perception of forest degradation in both communities. While Pichátaro has maintained a larger and more diverse forest base to date, stand structure data indicate selective harvesting has led to a shift in dominance toward the less economically desirable pine species and oak. Deforestation and degradation of Sevina and Pichátaro's community forests are symptomatic of both the Meseta Purépecha and Mexico in general. Current forest conditions in both communities justify local, regional, and national concerns regarding declining biodiversity and sustainable economies.  相似文献   

Comparison of Linear Regression Models for Quantitative Geochemical Analysis: An Example Using X-Ray Fluorescence Spectrometry   总被引：1，自引：0，他引：1  

Mirna Guevara  Surendra P. Verma  Fernando Velasco-Tapia  Rufino Lozano-Santa Cruz  Patricia Girón 《Geostandards and Geoanalytical Research》2005,29(3):271-284

This paper presents statistical aspects related to the calibration process and a comparison of different regression approaches of relevance to almost all analytical techniques. The models for ordinary least-squares (OLS), weighted least-squares (WLS), and maximum likelihood fitting (MLF) were evaluated and, as a case study, X-ray fluorescence (XRF) calibration curves for major elements in geochemical reference materials were used. The results showed that WLS and MLF models were statistically more consistent in comparison with the usually applied OLS approach. The use of uncertainty on independent and dependent variables during the calibration process and the calculation of final uncertainty on individual results using error propagation equations are the novel aspects of our work.  相似文献   

Petrogenesis of the Eocene and Mio–Pliocene alkaline basaltic magmatism in Meseta Chile Chico, southern Patagonia, Chile: Evidence for the participation of two slab windows     

Felipe Espinoza  Diego Morata  Ewan Pelleter  Ren  C. Maury  Manuel Su  rez  Yves Lagabrielle  Mireille Polv    Herv  Bellon  Joseph Cotten  Rita De la Cruz  Christelle Guivel 《Lithos》2005,82(3-4):315-343

The Meseta Chile Chico (MCC, 46.4°S) is the westernmost exposure of Eocene (lower basaltic sequence, LBS; 55–40 Ma, K–Ar ages) and Mio–Pliocene (upper basaltic sequence, UBS; 16–4 Ma, K–Ar ages) flood basalt volcanism in Patagonia. The MCC is located south of the Lago General Carrera-Buenos Aires (LGCBA), southeast from the present day Chile Triple Junction (CTJ), east of the actual volcanic gap between Southern South Volcanic Zone and Austral Volcanic Zone (SSVZ and AVZ, respectively) and just above the inferred location of the South Chile Ridge segment subducted at 6 Ma (SCR-1). Erupted products consist of mainly ne-normative olivine basalt with minor hy-normative tholeiites basalt, trachybasalt and basanite. MCC lavas are alkaline (42.7–53.1 wt.% SiO₂, 3–8 wt.% Na₂O+K₂O) and relatively primitive (Ni: 133–360 ppm, Cr: 161–193 ppm, Co: 35–72 ppm, 4–16.5 MgO wt.%). They have a marked OIB-like signature, as shown by their isotopic compositions (⁸⁷Sr/⁸⁶Sr_o=0.70311–0.70414 and εNd=+4.7–+5.1) and their incompatible trace elements ratios (Ba/La=10–20, La/Nb=0.46–1.09, Ce/Pb=15.52–27.5, Sr/La<25), reflecting deep mantle origin. UBS-primitive lavas have characteristics similar to those of the Eocene LBS basalts, while UBS-intermediate lavas show geochemical imprints (La/Nb>1, Sr/La>25, low Ce/Pb, Nb/U) compatible with contamination by arc/slab-derived and/or crustal components. We propose that the genesis and extrusion of magmas is related to the opening of two slab windows due to the subduction of two active ridge segments beneath Patagonia during Eocene and Mio–Pliocene.  相似文献   

Marine geochemistry—2: scavenging redux     

Edward D. Goldberg  Minoru Koide  Kathe Bertine  Vern Hodge  Martha Stallard  Darko Martincic  Nevenka Mikac  Marco Branica  Jamal K. Abaychi 《Applied Geochemistry》1988,3(6)

Inorganic surfaces sorb dissolved and particulate phases from seawater onto organic films from a variety of sources. Heavy metals such as Au, Pt, Mn and Cd come to the coatings primarily from particulate phases. This observation confirms a previous finding of this laboratory for the uptake of U, Pu and Po. With depth in the open ocean there are greater contributions from the dissolved phases. Microbial and photochemical processes can enrich surfaces in some metals through reduction reactions. Copper and Mn enrichments in the films are attributed to the photo-reductions of Cu(II) to Cu(I) and manganese oxides to Mn(II), respectively, while the uptake of Mo is a consequence of the reduction, mediated by organisms, of molybdate to Mo(V) or Mo(IV). Cadmium, on the other hand, appears to be bioaccumulated in the films.  相似文献   

Salt marsh cliff stability in the oosterschelde     

Martha M. Van Eerdt 《地球表面变化过程与地形》1985,10(2):95-106

Salt marsh cliff erosion in the Oosterschelde, due to basal scour and small-scale failure, was monitored during a two-year period using reference stakes. The composite marsh cliffs have a cantilever profile. Their stability is evaluated from beam failure analysis. A model is proposed, in which the cantilever weight is taken as the motive force; the major resistive force is the tensile strength. By substituting height, undermining width and soil mechanical properties of the cliff in the model, one can identify the cliffs that are likely to fail. Salt marsh cliffs, which combine a large tensile strength due to roots at the top of the profile with a large compressive stress at the cliff base due to the sandy texture of the subsoil, display the highest resistance to beam failure. The critical cliff dimensions, observed in the field, correspond with the values calculated from the proposed model of beam failure.  相似文献   

A Computer Model for Simulating Water Quality and Quantity in a Wellfield in an Alluvial Aquifer     

Martha W. Gilliland  Quang M. Nguyen 《Ground water》1987,25(2):151-159

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Response of L-shaped rigid foundations embedded in a uniform half-space to traveling seismic waves     

Martha Surez  Javier Avils  Francisco J. Snchez-Sesma 《Soil Dynamics and Earthquake Engineering》2002,22(8)

A simplified indirect boundary element method is applied to compute the impedance functions for L-shaped rigid foundations embedded in a homogeneous viscoelastic half-space. In this method, the waves generated by the 3D vibrating foundation are constructed from radiating sources located on the actual boundary of the foundation. The impedance functions together with the free-field displacements and tractions generated along the soil–foundation interface are used to calculate the foundation input motion for incident P, S and Rayleigh waves. This is accomplished by application of Iguchi's averaging method which, in turn, is verified by comparison with results obtained rigorously using the relation between the solutions of the basic radiation (impedance functions) and scattering (input motions) problems. Numerical results are presented for both surface-supported and embedded foundations. It is shown how the seismic response of L-shaped foundations with symmetrical wings differs from that of enveloping square foundations. The effects of inclination and azimuth of the earthquake excitation are examined as well. These results should be of use in analyses of soil–structure interaction to account for the traveling wave effects usually overlooked in practice.  相似文献