Advances in lithium analysis in solids by means of laser-induced breakdown spectroscopy: an exploratory study     

Cécile Fabre  Marie-Christine BoironJean Dubessy  Aliouka ChabironBernard Charoy  Tomas Martin Crespo 《Geochimica et cosmochimica acta》2002,66(8):1401-1407

Lithium is an important geochemical tracer for fluids or solids. However, because the electron microprobe cannot detect Li, variations of Li abundance at the micrometric scale are most often estimated from bulk analyses. In this study, the Li intense emission line at 670.706 nm in optical emission spectroscopy was used to perfect the analysis of Li at the micrometric scale by means of laser-induced breakdown spectroscopy (LIBS). To estimate lithium content for different geological materials, LIBS calibration of the emission line at 670.706 nm was achieved by use of synthetic glasses and natural minerals. The detection limit for this method is ∼5 ppm Li. Three applications to geological materials show the potential of LIBS for lithium determination, namely for Li-bearing minerals, melt inclusions, quartz, and associated fluid inclusions.For spodumene and petalite from granite pegmatite dikes (Portugal), the Li₂O concentrations are 7.6 ± 1.6 wt% and 6.3 ± 1.3 wt%, respectively, by use of LIBS. These values agree with ion microprobe analyses, bulk analyses, or both. For eucryptite crystals, the Li concentrations are scattered because grain size is smaller than the LIBS spatial resolution (6 to 8 μm). Lithium concentrations of melt inclusions from the Streltsovka U deposit (Siberia) are in the range of 2 to 6.2 wt% (Li₂O) for Li-rich daughter minerals. Lithium estimations on silicate glasses display values between 90 and 400 ppm.Lithium was also analyzed as a trace element in quartz. Transverse profiles were performed in hydrothermal barren quartz veins from the Spanish Central System (Sierra de Guadarrama). The highest Li concentrations (250 to 370 ppm) were found in specific growth bands in conjunction with the observed variation in optical cathodoluminescence intensity. Considering the fluid inclusion analysis, the source of fluid responsible to the Li enrichment in quartz is probably high-salinity fluids derived from sedimentary basins.  相似文献   

Uncertainties in quantitative time-lapse seismic analysis   总被引：1，自引：0，他引：1  

Martin Landrø 《Geophysical Prospecting》2002,50(5):527-538

Most seismic time-lapse studies so far have been of a qualitative nature. Identification of areas with minor or no seismic changes has been used to plan new infill drilling targets. Increased accuracy in seismic acquisition methods, in both conventional streamer surveys and newer methods such as multicomponent sea-bed seismic and permanent sensors, opens possibilities for the next step: quantitative time-lapse analysis. Quantitative methods here mean the estimation of, for instance, a change in fluid saturation from 20% water to 90% water or the estimation of a pore pressure change of 5 MPa. Explicit expressions for the uncertainties associated with estimated changes in, for instance, reservoir pressure and fluid saturation are derived. These formulae can be used to compare relative uncertainties between estimated parameters as well as to identify the critical factors in various estimation techniques. The importance of accurate rock physics input, as well as that of highly repeatable time-lapse seismic data, is emphasized. Furthermore, uncertainty analysis can be used to find optimal weight factors when the same parameter (e.g. saturation change) is estimated by two or three different techniques.  相似文献   

电离层水平不均匀性对无线电掩星资料反演的影响   总被引：2，自引：4，他引：2       下载免费PDF全文

张训械  曾桢  胡雄  Per Hoeg  G.B.Larsen  B.S.Martin  C.R.Jakob 《地球物理学报》2002,45(Z1):24-29

电离层水平不均匀结构是引起掩星资料反演的主要误差源.本文模拟不均匀结构对无线电掩星资料反演的影响.首先利用3-D全球射线追踪技术进行了模拟.结果指出:电离层电子密度20%的变化可能引起GPS的时延增加约12m.其次,将90%的掩星时延对应的路径长度,定义为电离层掩星测量的水平分辨率,其值为1200-2000 km.最后,计算了不同纬度电离层当地正午、子夜和日出时的电离层水平不对称指数.它表明:低纬夏季日出时,不对称指数达-78%,反演结果可能有较大误差.  相似文献   

Efficient methods for solving water flow in variably saturated soils under prescribed flux infiltration     

Xiaoxian Zhang  A. Glyn Bengough  John W. Crawford  Iain M. Young 《Journal of Hydrology》2002,260(1-4):75-87

The non-linear solvers in numerical solutions of water flow in variably saturated soils are prone to convergence difficulties. Many aspects can give rise to such difficulties and in this paper we address the gravity term and the prescribed-flux boundary in the Picard iteration. The problem of the gravity term in the Picard iteration is iteration-to-iteration oscillation as the gravity term is treated, by analogy with the time-step advance technique, ‘explicitly’ in the iteration. The proposed method for the gravity term is an improvement of the ‘implicit’ approach of Zhang and Ewen [Water Resour. Res. 36 (2000) 2777] by extending it to heterogeneous soil and approximating the inter-nodal hydraulic conductivity in the diffusive term and the gravity term with the same scheme. The prescribed-flux boundary in traditional methods also gives rise to iteration-to-iteration oscillation because there is no feedback to the flux in the solution at the new iteration. To reduce such oscillation, a new method is proposed to provide such a feedback to the flux. Comparison with traditional Picard and Newton iteration methods for a wide range of problems show that a combination of these two proposed methods greatly improves the stability and consequently the computational efficiency, making the use of small time step and/or under-relaxation solely for convergence unnecessary.  相似文献   

Modelling Seismic Waves Around Underground Openings in Fractured Rock     

M.W. Hildyard  R.P. Young 《Pure and Applied Geophysics》2002,159(1-3):247-276

—?The potential for large excavation-induced seismic events may be recognised, even if the timing of an event may be inherently unpredictable. In this case, modelling the wave propagation from a potential event could allow the dynamic motions around an excavation to be projected, and for areas of danger to be anticipated. However, the above and other potential applications require accurate models of wave interaction with the openings, as well as with the fractured rock which surrounds such excavations. This paper considers real recorded waveforms and how well these waveforms are modelled by explicit mechanical models of the source, the medium and the excavation. Models of experiments at three different scales of the problem are presented: small and large amplitude waveforms recorded around a deep-level mining tunnel in a synthetic rockburst experiment; waveforms from laboratory experiments of waves through plates of steel representing fractures; waveforms from active pulses in an acoustic emission experiment in a small volume of fractured rock at the surface of an underground excavation. The results show that elastic wave propagation around an excavation was a first approximation for small amplitude waves, but was less successful for modelling large amplitude waves and more fractured rock. Fractures in the models were represented explicitly with displacement discontinuities. Waveforms through known fracture geometries were particularly well-reproduced, and indicate the importance of fracture stiffness, the in situ stress state, and stress-dependence of the fractures in such models. Overall, the models are sufficiently successful at representing recorded behaviour, to be encouraging for the goal of representing accurate wave motions around excavations.  相似文献   

The molecular universe     

Helen J Fraser  Martin R S McCoustra  David A Williams 《Astronomy& Geophysics》2002,43(2):2.10-2.18

Helen J Fraser , Martin R S McCoustra and David A Williams present a simple guide to astrochemistry.
Molecules play a fundamental role in many regions of our universe. The science where chemistry and astronomy overlap is known as astrochemistry, a branch of astronomy that has risen in importance over recent years. In this article we review the significance of chemistry in several astronomical years. IN this article we review the significance of chemistry in several astronomical environments including the early universe, interstellar clouds, starforming regions and protoplanetary disks. We discuss theoretical models, laboratory experiments and observational data, and present several recent and exciting results that challenge our perception of the "molecular universe".  相似文献   

Multiparametric Traveltime Inversion     

Biloti  Ricardo  Santos  Lúcio T.  Tygel  Martin 《Studia Geophysica et Geodaetica》2002,46(2):177-192

In conventional seismic processing, the classical algorithm of Hubral and Krey is routinely applied to extract an initial macrovelocity model that consists of a stack of homogeneous layers bounded by curved interfaces. Input for the algorithm are identified primary reflections together with normal moveout (NMO) velocities, as derived from a previous velocity analysis conducted on common midpoint (CMP) data. This work presents a modified version of the Hubral and Krey algorithm that is designed to extend the original version in two ways, namely (a) it makes an advantageous use of previously obtained common-reflection-surface (CRS) attributes as its input and (b) it also allows for gradient layer velocities in depth. A new strategy to recover interfaces as optimized cubic splines is also proposed. Some synthetic examples are provided to illustrate and explain the implementation of the method.  相似文献   

Architecture and evolution of syn-rift clastic depositional systems towards the tip of a major fault segment, Suez Rift, Egypt   总被引：1，自引：0，他引：1  

M. J. Young  R. L. Gawthorpe  I. R. Sharp† 《Basin Research》2002,14(1):1-23

ABSTRACT This paper investigates syn‐rift stratigraphic architecture and facies relationships along a 7 km long strike section towards the tip of a major, basin‐bounding normal fault segment (Thal Fault) in the Suez Rift, Egypt. In this location, the fault is composed of two precursor fault strands, Gushea and Abu Ideimat, linked by a jog or transfer fault. We document a Miocene syn‐rift succession, deposited more than c. 5.5 Myr after rift initiation, that is composed of a range of carbonate‐clastic facies associated with coarse‐grained deltaic, shoreface and offshore depositional systems. Key regionally correlatable stratal surfaces within this succession define time equivalent stratal units that exhibit variability in thickness and architecture, related to the interplay of both regional and local controls, in particular, the evolution of two, small‐scale (<6 km long) precursor fault strands (Gushea and Abu Ideimat). Integration of structural and stratigraphic data indicates that the boundary (relay ramp) between these two fault strands was a relative high during much of the rift event, with hard‐linkage and considerable displacement accumulation not occurring until at least c. 7.5 Myr after rift initiation. This is because: (i) the preserved stratigraphy is thinner in the hanging wall of the strand boundary; (ii) a eustatic sea‐level fall with an amplitude of 100 m generated more than 25 m of incision at the strand boundary, a region that has a final fault displacement of c. 600 m; and (iii) the fault strand boundary persisted as a footwall low and transport pathway for coarse‐grained deltas entering the basin. This study indicates that variability in stratal thickness and stratigraphic architecture towards the tip of the Thal Fault was related to the linkage history of two small‐scale (c. 6 km long) precursor fault segments. We suggest that similar, small‐scale stratal variability may occur repeatedly along the entire length of major basin‐bounding fault segments due to the process of fault growth by the linkage of smaller scale precursor strands.  相似文献   

Stresses and strains in a twisted subduction zone—Fiordland, New Zealand     

Martin Reyners  Russell Robinson  Aasha Pancha  Peter McGinty 《Geophysical Journal International》2002,148(3):637-648

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Identification of geomorphic process units in Kärkevagge, northern Sweden, by remote sensing and digital terrain analysis     

Annett Bartsch  Martin Gude  Christer Jonasson  & Dieter Scherer 《Geografiska Annaler: Series A, Physical Geography》2002,84(3-4):171-178

Sediment transport processes in the Kärkevagge are investigated concerning their spatial and temporal characteristics due to long–term monitoring. Within this study remote sensing techniques and GIS modelling in connection with geomorphic mapping are applied for identification and characterization of geomorphic process units. Relationships between geomorphometric parameters and slope processes like solifluction, talus creep and rockfall have been analysed. Multitemporal Landsat–TM5 scenes are used as source for landcover characteristics (Normalized Difference Vegetation Index) after preprocessing involving orthorectification and topographic normalization in order to remove possible terrain–induced effects. Additionally, a digital elevation model with a resolution of 20 m for the Kärkevagge catchment is developed and parameters like slope gradient, slope aspect and profile curvature are extracted as input for the analysis of the sediment transport system. The combination of landcover information, geomorphometrical and topological features allows the definition of areas for single process activities. They show specific sediment displacement characteristics depending on material conditions, topological and geometrical features. Geomorphic process units, which show a homogenous composition, are extracted from these available layers.  相似文献