Fluid inclusions in microstructures of shocked quartz from the Keurusselkä impact site,Central Finland     

Matti Poutiainen  Pasi Heikkilä 《Meteoritics & planetary science》2013,48(6):1043-1049

Granitoid rock samples from the assumed center of the Keurusselkä impact site were subjected to a systematic study of fluid‐inclusion compositions and densities in various microstructures of the shocked quartz. The results are consistent with the following impact‐induced model of formation. After cessation of all major regional tectonic activity and advanced erosional uplift of the Fennoscandian shield, a meteorite impact (approximately 1.1 Ga) caused the formation of planar fractures (PFs) and planar deformation features (PDFs) and the migration of shock‐liberated metamorphic fluid (CO₂ ± H₂O) to the glass in the PDFs. Postimpact annealing of the PDFs led to the formation of CO₂ (±H₂O) fluid‐inclusion decorated PDFs. The scarce fluid‐inclusion implosion textures (IPs) suggest a shock pressure of 7.6–10 GPa. The postimpact pressure release and associated heating initiated hydrothermal activity that caused re‐opening of some PFs and their partial filling by moderate‐salinity/high temperature (>200 °C) H₂O (+ chlorite + quartz) and moderate‐density CO₂. The youngest postimpact endogenic sub‐ and nonplanar microfractures (MFs) are characterized by low‐density CO₂ and low‐salinity/low‐temperature (<200 °C) H₂O.  相似文献   

Elimination of Interferences in the Determination of Palladium,Platinum and Rhodium Mass Fractions in Moss Samples using ICP‐MS/MS          下载免费PDF全文

Terhi Suoranta  Syed N. H. Bokhari  Thomas Meisel  Matti Niemelä  Paavo Perämäki 《Geostandards and Geoanalytical Research》2016,40(4):559-569

Moss samples (Pleurozium schreberi) exposed to traffic‐related emission of Pd, Pt and Rh were analysed in this study. Successful elimination of interferences was achieved in the determination of Pd, Pt and Rh mass fractions in these samples using inductively coupled plasma‐tandem mass spectrometry (ICP‐MS/MS). Based on the results, a reliable determination of Pd, Pt and Rh mass fractions in microwave‐digested moss samples was obtained using ammonia (10% NH₃ in He) in the collision/reaction cell when ¹⁰³Rh was measured either on‐mass (103→103) or with mass‐shift (103→171) and mass‐shifts for ¹⁰⁸Pd (108→159) and ¹⁹⁵Pt (195→229) were used. The ICP‐MS/MS procedure was validated using BCR‐723 (road dust) as a reference material. In addition, a good agreement between the ICP‐MS/MS results and the results obtained with cloud point extraction and quadrupole ICP‐MS was observed for the moss samples.  相似文献   

Model simulations of the annual cycle of the landfast ice thickness in the East Siberian Sea     

YANG Yu  Matti Leppranta  LI Zhijun  Bin Cheng  ZHAI Mengxi  Denis Demchev 《极地研究(英文版)》2015,(2)

The annual cycle of the thickness and temperature of landfast sea ice in the East Siberian Sea has been examined using a one-dimensional thermodynamic model. The model was calibrated for the year Augus...  相似文献   

Surface temperature inversion in the palsa and pounu fields of northern Finland     

Hiroshi Tabuchi  Matti Seppälä 《Polar Science》2012,6(3-4):237-251

A very large surface inversion, which would not have been detected at the official recording height of 2 m above the mire surface, was recorded at the snow surface of an earth hummock in Lapland. The maximum inversion was 35 °C, and the monthly temperature departure was 7.8 °C in December 1992. The characteristics of the surface inversion are compared with conditions during another winter when no long inversion periods occurred. The presence of this surface inversion may explain the formation of new permafrost in pounus, even when official records showed no unusually low temperatures.  相似文献   

Winter precipitation trends for two selected European regions over the last 500 years and their possible dynamical background     

C. Matti  A. Pauling  M. Küttel  H. Wanner 《Theoretical and Applied Climatology》2009,95(1-2):9-26

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Preliminary results on relationship between thermal diffusivity and porosity of sea ice in the Antarctic     

石立琼  白乙拉  李志军  程斌  Leppairanta  Matti 《极地研究(英文版)》2009,20(1):72-80

The in situ sea-ice temperature, salinity and density observed from Chinese Antarctic Zhongshan Station have been applied to calculate the vertical profile of sea ice porosity. Based on numerical method, a number of schemes on sea-ice thermal diffusivity versus porosity have been accessed and one optimized scheme is identified by an optimal control model with an advanced distributing parameter system. For simplicity, the internal heating source item was neglected in the heat conduction equation during the identification procedure. In order to illustrate the applicability of this identified scheme, the vertical ice temperature profiles have been simulated and compared with measurements, respectively by using identified scheme and by classical thermodynamic formulae.The comparisons indicated that the scheme describing sea-ice thermal diffusivity and porosity is reasonable. In spite of a minor improvement of accuracy of results against in situ data, the identified scheme has a more physical meaning and could be used potentially in various applications.  相似文献   

State of disequilibrium between ²³⁸U, ²³⁴U, ²²⁶Ra and ²²²Rn in groundwater from bedrock     

Matti Asikainen 《Geochimica et cosmochimica acta》1981,45(2):201-206

Approximately one thousand drilled wells were investigated for their natural radioactivity. The determinations of ²³⁸U, ²³⁴U, ²²⁶Ra and ²²²Rn from 310 samples showed a high state of radioactive disequilibrium between the members of the uranium series present in water. The ${}^{238}\text{U}{}^{226}\text{Ra}$ activity ratio usually fell in the range 1–20 and the ${}^{238}\text{U}{}^{222}\text{Rn}$ activity ratio in the range 1–20 × 10^?4, the highest activity ratios being from samples with an elevated uranium content. The ${}^{234}\text{U}{}^{238}\text{U}$ activity ratio varied between 0.76 and 4.67, the most frequent values showing a 60% excess of ²³⁴U in the samples. Most of the ${}^{234}\text{U}{}^{238}\text{U}$ activity ratios near unity were found in samples with a high uranium content. Several drilled wells with anomalously high uranium contents were found in southern Finland. The average ²²⁶Ra and ²²²Rn contents of these wells were not exceptionally high, which suggests high mobility of uranium in groundwater from the areas involved.  相似文献   

Age differences between Rb---Sr whole rock and U---Pb zircon ages of syn- and postorogenic Svecokarelian granitoids in Sottunga, SW Finland     

Eric Welin  Matti Vaasjoki  Veli Suominen 《Lithos》1983,16(4):297-305

The U---Pb age on pooled data of zircnos from the postorogenic Svecokarelian Mosshaga granite is 1788 ± 11 Ma (2 σ). The corresponding Rb---Sr whole rock age is 1742 ± 34 Ma (2 σ). The Mosshaga granite intrudes a synorogenic granodiorite, which has a U---Pb zircon age of 1889 ± 10 Ma and a Rb---Sr whole rock age of 1850 ± 28 Ma. The age differences between the U---Pb zircon ages and Rb---Sr whole rock ages are concluded to be geologically significant. It is shown that the Mosshaga pluton cooled rapidly and as a consequence the Rb---Sr isotopic system closed at a time very close to the crystallization of the zircons. A commonly observed feldspar and biotite alteration in Svecokarelian granitoids indicates migration of Rb and Sr isotopes in the whole rock system which may lead to apparently younger Rb---Sr ages.  相似文献   

Genesis of Palaeoproterozoic iron skarns in the Misi region, northern Finland     

Tero Niiranen  Irmeli Mänttäri  Matti Poutiainen  Nicholas H. S. Oliver  Jodie A. Miller 《Mineralium Deposita》2005,40(2):192-217

Sodic alteration is widespread in Palaeoproterozoic greenstone and schist belts of the northern Fennoscandian shield. In the Misi region that forms the easternmost part of the Peräpohja schist belt, several small magnetite deposits show intimate spatial relationships with intensely albitised gabbros, raising the possibility that regional sodic alteration released iron, which was subsequently accumulated into deposits. Two of these magnetite deposits, Raajärvi and Puro display a typical paragenesis as follows (from oldest to youngest): (1) diopside, (2) actinolite/tremolite-magnetite ± chlorite, biotite, and (3) serpentine ± hematite, chlorite. Mass balance calculations suggest that significant amounts of Fe, Ca, Mg, K, Cu, V, and Ba were lost, and Na and Si gained during the albitisation of the gabbro, at near-constant Al, Ga, Ti, and Zr. Significant amounts of Si, Ca, Fe, and Na were enriched in the formation of skarn related to magnetite deposits. Fe and V leached from country rocks deposited during the skarn-alteration and formed the vanadium rich iron deposits while Cu passed through the system without significant precipitation due to low sulphur fugasity. Variations in Na, Ca, Mg, K, and Ba contents reflect the composition of the infiltrating fluid during alteration. Conventional heating-freezing measurements and proton-induced X-ray emission (PIXE) analyses of the fluid inclusions related to actinolite/tremolite-magnetite stage alteration indicate that the fluids that caused the alteration and the Fe-mineralisation were complex, oxidised, highly saline H₂O ± CO₂ fluids that contained high amounts of Na, Ca, K, Fe, and Ba as well as elevated concentrations of Cu, Zn, and Pb. The oxygen isotope thermometry suggest that temperature during the Fe-mineralisation stage was between 390 and 490°C. Calculated δ¹⁸O_fluid values of 6.1–9.8‰ SMOW and δ¹³C values of calcites in the ores and skarns were between ?7.7 and 10.9‰ PDB and most likely reflect admixture of ¹³C depleted, possibly magmatic fluids with the marble wall rocks that show δ¹³C_calcite values of 13‰ PDB. The SIMS U–Pb data on the zircons in the albitised gabbro next to the Raajärvi and Puro deposits suggest that intrusion of the gabbro took place at 2123±7 Ma and was accompanied by the formation of diopside skarn. The TIMS data on the metasomatic titanites related to sodic alteration yielded ages of 2062±3 and 2017±3 Ma. Iron was probably stripped from the mafic country rocks by sodic alteration between 2123 and 2017 Ma, driven by repeated brine influxes. Subsequently, the metal-rich brine was focused by a fault system and the iron was precipitated from this fluid by a combination of wall rock reaction, fluid mixing, and a drop in the temperature.  相似文献   

Kriging made easy or assessing the linear unbiased minimum variance estimate by adapting the projection theorem     

Matti Heikkilä  Esko Koistinen 《Mineralium Deposita》1984,19(1):2-6

A new approach has been arrived at for determining the linear unbiased minimum variance estimate of ore reserves, or the Kriging. The approach rests heavily on geometric intuition, which reduces the estimation to the simple task of determining an orthogonal projection. First, the problem is presented and solved in ordinary three-dimensional space. The result is stated in matrix formulation, lending itself to a simple generalization in higher dimensions. Then, the general problem is stated in random-variable notation and solved via the results derived. Finally, an illustrative example is given to demonstrate the new approach.  相似文献