Trace element partitioning between type B CAI melts and melilite and spinel: Implications for trace element distribution during CAI formation     

C.C. Lundstrom  A.L. Sutton  W.F. McDonough 《Geochimica et cosmochimica acta》2006,70(13):3421-3435

Calcium- and aluminum-rich inclusions (CAIs), occurring in chondritic meteorites and considered the oldest materials in the solar system, can provide critical information about the environment and time scale of creation of planetary materials. However, interpretation of the trace element and isotope compositions of CAIs, particularly the light elements Li, Be, and B, is hampered by the lack of constraint on melilite-melt and spinel-melt partition coefficients. We determined melilite-melt and spinel-melt partition coefficients for 21 elements by performing controlled cooling rate (2 °C/h) experiments at 1 atmosphere pressure in sealed platinum capsules using a synthetic type B CAI melt. Trace element concentrations were measured by secondary ion mass spectrometry (SIMS) and/or laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Melilites vary only slightly in composition, ranging from Åk_31-43. Results for the partitioning of trace elements between melilite and melt in three experiments and between spinel and melt in two experiments show that partition coefficients are independent of trace element concentration, are in good agreement for different analytical techniques (SIMS and LA-ICP-MS), and are in agreement with previous measurements in the literature. Partition coefficients between intermediate composition melilites and CAI melt are the following: Li, 0.5; Be, 1.0; B, 0.22; Rb, 0.012; Sr, 0.68; Zr, 0.004; Nb, 0.003; Cs, 0.002; Ba, 0.018; La, 0.056; Nd, 0.065; Sm, 0.073; Eu, 0.67; Er, 0.037; Yb, 0.018; Hf, 0.001; Ta, 0.003; Pb, 0.15; U, 0.001; Th, 0.002. Site size energetics analysis is used to assess isovalent partitioning into the different cation sites. The Young’s modulus deduced from +2 cations partitioning into the melilite X site agrees well with the bulk modulus of melilite based on X-ray diffraction methods. The changes in light element partitioning as melilite composition varies are predicted and used in several models of fractional crystallization to evaluate if the observed Li, Be, and B systematics in Allende CAI 3529-41 are consistent with crystallization from a melt. Models of crystallization agree reasonably well with observed light element variations in areas previously interpreted to be unperturbed by secondary processes [Chaussidon, M., Robert, F., McKeegan, K.D., 2006. Li and B isotopic variations in an Allende CAI: Evidence for the in situ decay of short-lived ¹⁰Be and for the possible presence of the short-lived nuclide ⁷Be in the early solar system. Geochim. Cosmochim. Acta70, 224-245], indicating that the trends of light elements could reflect fractional crystallization of a melt. In contrast, areas interpreted to have been affected by alteration processes are not consistent with crystallization models.  相似文献   

Spectroscopy of K-complex asteroids: Parent bodies of carbonaceous meteorites?     

Beth Ellen Clark  Maureen E. Ockert-Bell  David Nesvorny  Schelte J. Bus 《Icarus》2009,202(1):119-133

This is the first focused study of non-Eos K asteroids. We have observed a total of 30 K-complex objects (12 K-2 Sk- and 13 Xk-type asteroids (from the Bus taxonomy), plus 3 K-candidates from previous work) and we present an analysis of their spectral properties from 0.4 to 2.5 μm. We targeted these asteroids because their previous observations are spectrally similar enough to suggest a possible compositional relationship. All objects have exhibited spectral redness in the visible wavelengths and minor absorptions near 1 micron. If, as suggested, K-complex asteroids (including K, Xk, and Sk) are the parent bodies of carbonaceous meteorites, knowledge of K-asteroid properties and distribution is essential to our understanding of the cosmochemical importance of some of the most primitive meteorite materials in our collection. This paper presents initial results of our analysis of telescopic data, with supporting analysis of laboratory measurements of meteorite analogs. Our results indicate that K-complex asteroids are distinct from other main belt asteroid types (S, B, C, F, and G). They do not appear to be a subset of these other types. K asteroids nearly span the range of band center positions and geometric albedos exhibited by the carbonaceous chondrites (CO, CM, CV, CH, CK, CR, and CI). We find that B-, C-, F- and G-type asteroids tend to be darker than meteorites, and can have band centers longer than any of the chondrites measured here. This could indicate that K-complex asteroids are better spectral analogues for the majority of our carbonaceous meteorites than the traditional B-, C-, F- and G-matches suggested in the literature. This paper present first results of our ongoing survey to determine K-type mineralogy, meteorite linkages, and significance to the geology of the asteroid regions.  相似文献   

Delineation of capture zones for municipal wells in fractured dolomite, Sturgeon Bay, Wisconsin, USA   总被引：1，自引：1，他引：1  

Todd W. Rayne  Kenneth R. Bradbury  Maureen A. Muldoon 《Hydrogeology Journal》2001,9(5):432-450

A wellhead protection study for the city of Sturgeon Bay, Wisconsin, USA, demonstrates the necessity of combining detailed hydrostratigraphic analysis with groundwater modeling to delineate zones of contribution for municipal wells in a fractured dolomite aquifer. A numerical model (MODFLOW) was combined with a particle tracking code (MODPATH) to simulate the regional groundwater system and to delineate capture zones for municipal wells. The hydrostratigraphic model included vertical and horizontal fractures and high-permeability zones. Correlating stratigraphic interpretations with field data such as geophysical logs, packer tests, and fracture mapping resulted in the construction of a numerical model with five high-permeability zones related to bedding planes or facies changes. These zones serve as major conduits for horizontal groundwater flow. Dipping fracture zones were simulated as thin high-permeability layers. The locations of exposed bedrock and surficial karst features were used to identify areas of enhanced recharge. Model results show the vulnerability of the municipal wells to pollution. Capture zones for the wells extend several kilometers north and south from the city. Travel times from recharge areas to all wells were generally less than one year. The high seasonal variability of recharge in the study area made the use of a transient model necessary. Electronic Publication  相似文献   

Magnetic polarity during the Middle Jurassic as recorded in the Summerville and Curtis Formations     

Maureen B. Steiner 《Earth and Planetary Science Letters》1978,38(2):331-345

Three-quarters of the Summerville Formation and a small portion of the Curtis Formation of central Utah have been sampled at close stratigraphic spacing. The two formations constitute an intertonguing marine-marginal marine, tidal flat sequence representing middle Callovian time. The magnetic polarity sequence observed is dominantly reversed with a few relatively short normal intervals. The age of these formations corresponds to some portion of time within the Jurassic oceanic quiet zone. The fact that normal polarity was not prominent in these formations casts some doubt upon the hypothesis that a long period of normal polarity was the cause of the quiet zone. Furthermore, a literature compilation indicates that normal polarity did not dominate the Jurassic as had been thought. The pole position determined from the Middle Jurassic Summerville Formation slightly revises earlier results and suggests a tiny amount of apparent polar motion relative to North American between Late Triassic and Middle Jurassic time.  相似文献   

Geochemical approach to estimate the quality of water entering abandoned underground coalmines     

Pradeep?Mugunthan  Kathleen?M.?McDonough  David?A.?DzombakEmail author 《Environmental Geology》2004,45(6):769-780

Geochemical modeling was employed to estimate the chemistry of water infiltrating into abandoned underground flooded and unflooded coalmines of the Uniontown syncline, Fayette County, Pennsylvania. This was done to help evaluate factors governing the long-term evolution of coalmine discharge water quality in the Uniontown syncline area. The subsurface structure and lithology was delineated using borehole, mine shaft, and stratigraphic information. Hydrogeologic analyses indicated that most of the recharge to mine voids occurs in the zones of shallow overburden cover of less than 20 m in thickness. The water–rock contact period in the recharge areas of the overburden was estimated to be 5 days or greater for the flooded mines, and a day or less for the unflooded mines. Flow-through reaction-path models were applied to the topsoil and shale–sandstone lithological units identified in the recharge areas. The model predicted water entering the flooded mines at a pH of 6.65, alkalinity of 6.92 mequiv. l^–1 and a total sulfate concentration of 7.33 mM, and the unflooded mines at a pH of 6.68, alkalinity of 6.99 mequiv. l^–1 and a total sulfate concentration of 3.08 mM. The model predictions for the flooded and unflooded mines are consistent with groundwater data from the study site, indicating the usefulness of this approach in evaluating the contribution of overburden chemistry to the evolution of mine discharge quality.  相似文献   

The southeast Australian lithospheric mantle: isotopic and geochemical constraints on its growth and evolution     

William F. McDonough  Malcolm T. McCulloch 《Earth and Planetary Science Letters》1987,86(2-4)

Trace elements and isotopic compositions of whole rocks and mineral separates are reported for 15 spinel-bearing harzburgite and lherzolite xenoliths from southeastern Australia. These samples have an exceedingly large range in isotopic compositions, with⁸⁷Sr/⁸⁶Sr ranging from 0.70248 to 0.70834 and ε_Nd values ranging from +12.7 to −6.3. This range in isotopic compositions can be found in xenoliths from a single locality. The isotopic compositions of clinopyroxene separates and their whole rocks were found to be different in some xenoliths. Samples containing small glass pockets, which replace pre-existing hydrous minerals, generally show only small differences in isotopic composition between clinopyroxene and whole rock. In a modally metasomatized peridotite, significant differences in the Sr and Nd isotopic compositions of a coexisting phlogopite-clinopyroxene pair are present. Coexisting clinopyroxenes and orthopyroxenes from an anhydrous lherzolite have Sr isotopic compositions that are significantly different (0.70248 versus 0.70314), and yield an apparent age of 625 Ma, similar to that found previously by Dasch and Green [1]. However, the Nd isotopic compositions of the clinopyroxene and orthopyroxene are identical indicating recent (within 40 Ma) re-equilibration of Nd.Sr and Nd concentrations in the whole rocks and clinopyroxenes show an excellent positive correlation, and have an average Sr/Nd ratio of 15. This ratio is similar to the primitive mantle value, as well as that found in primitive MORBs and OIBs, but is much lower than that measured in island arc basalts and what might be predicted for a subduction zone-derived fluid. This indicates that a significant proportion of the Sr and Nd in these peridotites is introduced as a basaltic melt with intraplate chemical characteristics.The isotopic compositions of the peridotites reflect long-term, small-scale heterogeneities in the continental lithospheric mantle, and are in marked contrast to the near uniform isotopic compositions of the host alkali basalts (⁸⁷Sr/⁸⁶Sr= 0.7038–0.7041andε_Nd = +3.6 to +2.9). A minimum of three evolutionary stages are identified in the growth of the continental lithospheric mantle: an early basalt depletion event, recording the initial development and stabilization of the lithospheric mantle, followed by at least two enrichment episodes. These observations are consistent with continental lithospheric mantle growth involving the underplating of refractory peridotite diapirs.  相似文献   

Sodic Pyroxene and Sodic Amphibole as Potential Reference Materials for In Situ Lithium Isotope Determinations by SIMS     

Michael A.W. Marks  Roberta L. Rudnick  Thomas Ludwig  Horst Marschall  Thomas Zack  Ralf Halama  William F. McDonough  Detlef Rost  Thomas Wenzel  Edward P. Vicenzi  Ivan P. Savov  Rainer Altherr  Gregor Markl 《Geostandards and Geoanalytical Research》2008,32(3):295-310

Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g^?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g^?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g^?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ⁷Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ⁷Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request.  相似文献   

Community Stories: Explaining Resistance to Street Tree-Planting Programs in Detroit,Michigan, USA     

Christine E. Carmichael  Maureen H. McDonough 《社会与自然资源》2019,32(5):588-605

Non-profit organizations are key actors in urban and community forestry (UCF) initiatives, and sometimes city residents resist their efforts. Between 2011-2014, 24 percent of residents offered a street tree in Detroit, Michigan, USA submitted a “no-tree request.” Differing views on decision-making emerged as a main reason for resistance to tree planting. This study used interviews with city residents, and those within a non-profit organization, between 2014-2016 to understand reasons for conflict over decision-making between these groups. Heritage narratives, or selective representations of the city’s history and character, helped explain conflict over tree planting. Residents who wanted greater decision-making power in tree planting assumed they would be responsible for stewardship, reflecting their historical experiences within the city. The organization’s dominant heritage narrative emphasized that residents held misperceptions of trees based on negative past experiences, and required education on benefits of trees. Recommendations for integrating heritage narratives into UCF efforts are provided.  相似文献   

Two-dimensional modelling of subduction zone anisotropy with application to southwestern Japan     

Maureen D. Long  Bradford H. Hager  Maarten V. de Hoop  Rob D. van der Hilst 《Geophysical Journal International》2007,170(2):839-856

We present a series of 2-D numerical models of viscous flow in the mantle wedge induced by a subducting lithospheric plate. We use a kinematically defined slab geometry approximating the subduction of the Philippine Sea plate beneath Eurasia. Through finite element modelling we explore the effects of different rheological and thermal constraints (e.g. a low-viscosity region in the wedge corner, power law versus Newtonian rheology, the inclusion of thermal buoyancy forces and a temperature-dependent viscosity law) on the velocity and finite strain field in the mantle wedge. From the numerical flow models we construct models of anisotropy in the wedge by calculating the evolution of the finite strain ellipse and combining its geometry with appropriate elastic constants for effective transversely isotropic mantle material. We then predict shear wave splitting for stations located above the model domain using expressions derived from anisotropic perturbation theory, and compare the predictions to ∼500 previously published shear wave splitting measurements from seventeen stations of the broad-band F-net array located in southwestern Japan. Although the use of different model parameters can have a substantial effect on the character of the finite strain field, the effect on the average predicted splitting parameters is small. However, the variations with backazimuth and ray parameter of individual splitting intensity measurements at a given station for different models are often different, and rigorous analysis of details in the splitting patterns allows us to discriminate among different rheological models for flow in the mantle wedge. The splitting observed in southwestern Japan agrees well with the predictions of trench-perpendicular flow in the mantle wedge along with B-type olivine fabric dominating in a region from the wedge corner to about 125 km from the trench.  相似文献   

Lipids of marine Archaea: Patterns and provenance in the water-column and sediments   总被引：1，自引：0，他引：1  

Courtney Turich  Katherine H. Freeman  Maureen Conte  Stuart G. Wakeham 《Geochimica et cosmochimica acta》2007,71(13):3272-3291

We measured archaeal lipid distributions from globally distributed samples of freshwater, marine, and hypersaline suspended particulate matter. Cluster analysis of relative lipid distributions identified four distinct groups, including: (1) marine epipelagic (<100 m) waters, (2) marine mesopelagic (200-1500 m) and upwelling waters, (3) freshwater/estuarine waters, and (4) hypersaline waters. A pronounced difference in lipid composition patterns is the near absence of ring-containing glycerol dialkyl glycerol tetraethers (GDGTs) at high salinity. Different archaeal communities populate marine (mesophilic Crenarchaeota and Euryarchaeota), and hypersaline environments (halophilic Euryarchaeota) and community shifts can regulate differences in lipid patterns between marine and hypersaline waters. We propose that community changes within meosphilic marine Archaea also regulate the lipid patterns distinguishing epipelagic and mesopelagic/upwelling zones. Changes in the relative amounts of crenarchaeol and caldarchaeol and low relative abundances of ringed structures in surface waters differentiate lipids from the epipelagic and mesopelagic/upwelling waters. Patterns of lipids in mesopelagic (and upwelling) waters are similar to those expected of the ammonia-oxidizing Group I Crenarchaeota, with predominance of crenarchaeol and abundant cyclic GDGTs; non-metric multidimensional analysis (NMDS) shows this pattern is associated with high nitrate concentrations. In contrast, limited culture evidence indicates marine Group II Euryarchaeota may be capable of producing mainly caldarchaeol and some, but not all, of the ringed GDGTs and we suggest that these organisms, along with the Crenarchaeota, contribute to lipids in epipelagic marine waters. Calculated TEX₈₆ temperatures in mesopelagic samples (reported here and in published data sets) are always much warmer than measured in situ temperatures. We propose lipids used in the temperature proxy derive from both Euryarchaeaota and Crenarchaeota, and observed values of TEX₈₆ are subject to changes in their ecology as influenced by nutrient fluctuations or other perturbations. Applications of published core-top TEX₈₆-SST correlations require that (1) the surface waters are always composed of similar communities with the same temperature response and (2) that deeper water GDGT production is not transported to the sediments. Our lipid distribution patterns demonstrate both surface-water archaeal community differences (which accompany greater nutrient influxes, shoaling of mesopelagic Crenarchaeota during upwelling periods, and possibly due to an influx of terrestrial Archaea), and changes in organic matter transport through the water column can affect the distribution of lipids recorded in sediments. We therefore suggest that reported temperature shifts in ancient applications indicate TEX₈₆ lipids recorded not only temperature changes, but also changes in archaeal ecology, nutrient concentrations, and possibly oceanographic conditions.  相似文献