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61.
The gravity anomaly field of the Tyrrhenian basin and surrounding regions reflects the complex series of geodynamic events active in this area since the Oligocene–Miocene. They can resume in lithospheric thinning and asthenospheric rising beneath the Tyrrhenian Basin, coexisting with the roll-back subduction of the African plate margin westward sinking beneath the Calabrian Arc. The geographic closeness between these processes implies an intense perturbation of the mantle thermal regime and an interference at regional scale between the related gravity effects.A model of the litho-asthenospheric structure of this region is suggested, showing a reasonable agreement with both the evidences in terms of regional gravity anomaly pattern and the results concerning thermal state and petro-physical features of the mantle. The first phase of this study consisted of the computation of the isotherms in the crust–mantle system beneath the Tyrrhenian Basin and, afterwards, of the density distribution within the partially melted upwelling asthenosphere. The second phase consisted of a temperature/density modelling of the slab subducting beneath the Calabrian Arc. Finally, a 21 / 2 interpretation of gravity data was carried out by including as constraints the results previously obtained. Thus, the final result depicts a model matching both gravity, thermal and petrographic data. They provide (a) a better definition of the thermal regime of the passive mantle rise beneath the Tyrrhenian basin by means of the estimation of the moderate asthenospheric heating and (b) a model of lithospheric slab subducting with rates that could be smaller than generally suggested in previous works.  相似文献   
62.
The meaning of the large variety of seismic waveforms showing different frequencies associated with volcanic activity is still uncertain. No definitive model for source dynamics has been proposed yet. At present, seismic models explaining the origin of the spectral content of the seismic signal are mainly linked to geometrical features of the volcanic conduit and to resonant effects induced by pressure fluctuations in a fluid-filled conduit. Such models assume the physical system to be in a steady state over a long interval of time. At Stromboli, the seismicity produced by each of the three active vents is not stable and can suddenly change in time. Therefore, the application of stable resonator models appears to be unwarranted.On the basis of infrared image analyses, atmospheric pressure, and seismic wavefield signals, we show that different frequency contents and different explosive styles occur at Stromboli at the same time at different vents. Moreover, we give evidence to support the idea that seismicity and explosivity are both controlled by a variable gas flow regime released during explosions at the top of the magma column. We have recognized two main pressure regimes, controlling the explositivity at Stromboli: one is impulsive, short and possibly produced by a gas accumulation beneath a cap rock; the other has an intermittent regime feature, and lasts longer. We demonstrate how the first one generates a monochromatic low-frequency wavefield, while the second shows a high-frequency spectrum where the frequency content depends on pressure fluctuations and on pressure gradient. We suggest different pressure growth and gas flow in the magma as the common source for both explosive style and seismic wavefield.  相似文献   
63.
Biotites from mafic rocks occurring at different stratigraphic levels of the Ivrea-Verbano Mafic Complex are studied. The rocks are gabbros and diorites. All the biotites are intermediate between phlogopite and annite [0.282 (up to 7.14 and 9.32 wt%, respectively) with respect to those of the diorites (up to 1.26 and 6.26 wt%, respectively). Systematic compositional variations support the substitution model 2 IV Si+( IV R2+)2 IV Al+ VI Ti (R2+=Fe+Mg+Mn) in gabbros and IV Si+ VI Al IV Al+ VI Ti in diorites. A predominance of disordered stacking sequences, coexisting with 1M, 2M 1 and 3T polytypes was observed in all biotites. It was possible to carry out structural refinements only on three biotites-2M 1 from diorites (R-values between 2.68 and 3.77) and one biotite-1M from gabbros (R-value=3.09). It was shown that: (1) the reduced thickness of the tetrahedral sheet in Ba-rich biotites supports the coupled substitution IV Si+ XII K IV Al+ XII Ba; (2) the interlayer site geometry is affected by the whole layer chemistry and does not reflect only local chemical variations; (3) in two samples of the 2M 1 polytype, the M(1) octahedral site is larger and more distorted than the M(2) sites because of the preferential ordering of Fe2+ in the M(1) site, whereas one sample shows complete cation disorder in the octahedral sites. Biotite-1M shows that Fe2+ can also be located in the M(2) site. Some of the differences between the biotites of gabbros and diorites (e.g. Ba concentration and exchange vectors) may be linked to the host rock composition and to its crystallization process. Biotite occurs in trace amounts in gabbros and its crystallization is related to the interstitial melt which contributed to the adcumulus growth of the main rock forming phases and became highly enriched in K, Ba and Ti. Diorites are the result of equilibrium crystallization of a residual melt rich in incompatible elements, where biotite is a major constituent.  相似文献   
64.
In this study we evaluated the capability of a 213 nm laser ablation system coupled to a quadrupole-based ICP-MS in delivering accurate and precise U-Pb ages on zircons and monazites. Four zircon samples ( ca. 50 Ma to ca. 600 Ma) and four monazite samples ( ca. 30 Ma to ca. 1390 Ma) of known ages were analysed utilising laser ablation pits with diameters of 20 μm and 60 μm. Instrument mass bias and laser induced time-dependent elemental fractionation were corrected for by calibration against a matrix-matched reference material. Tera-Wasserburg plots of the calculated U-Pb data were employed to assess, and correct for, common Pb contributions. The results indicated that the LA-ICP-MS technique employed in this study allowed precise and accurate U-Pb isotope dating of zircon and monazite on sample areas 20 μm in diameter. At this spot size, the precisions achieved for single spot 206Pb/238U ages, were better than 5% (2s) for monazites and zircons with ages down to 30 Ma and 50 Ma, respectively. The precisions reported are comparable to those generally reported in SIMS and LA-MC-ICP-MS U-Pb isotope determinations.  相似文献   
65.
The Aptian-Albian 'Scisti a Fucoidi' varicoloured pelagic sediments in central Italy, show a 'couplet' alternation of carbonate-rich/carbonate-poor layers, which are interpreted as the sedimentary expression of precession (frequency 19–23 kyr). Carbonate content, chromatic variation, and planktonic foraminiferal abundance were analysed at a 1-cm spacing for a 10-m interval of the Piobbico core, specifically drilled through this formation. Spectral analysis of these parameters shows a prominent signal equated to the c . 100 kyr cycle of orbital eccentricity at a sedimentation rate of 5 mm kyr−1. The coherency of the spectral response of each parameter suggests that a single mechanism controlled the whole sedimentary record. Detailed study of planktonic foraminiferal distribution of the same section at 1-mm scale resolves the Milankovitch frequencies of 41 kyr and 18 to 23 kyr, equated with the obliquity and precessional cycles. But foraminiferal abundance is not in phase with carbonate content, which was largely controlled by calcareous nannofossils, but peaked at intermediate carbonate values. The proposed model for explaining the discrepancy at the precessional level is that foraminifera thrived at intermediate values of the precession index, when the environment was only moderately fertile but stable, while during highs of the precession index, mixing of the water column increased fertility and caused calcareous nannofossil blooms and restriction of planktonic foraminifera to few and tolerant species. The resulting bimodality of foraminiferal abundance per precessional cycle appears to be recorded in the spectrum by peaks at the 11 and 14 kyr levels. Cross correlation of foraminiferal abundances with the calcium carbonate curve over 1–2 Myr intervals produces discrepant results (apparent phase lags) which we attribute to differences in the response to the fundamental eccentricity cycles.  相似文献   
66.
67.
In this contribution we evaluate the capabilities of laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) using a 12 μm spot size. Precision, accuracy and detection limits were assessed on the USGS BCR-2G reference material. We demonstrate that the 12 μm LA-ICP-MS analyses of experimentally-grown amphibole and garnet are in excellent agreement with secondary ion mass spectrometry (SIMS) trace element determinations on the same crystals. The 12 μm spot size configuration was subsequently used to determine trace element crystal-melt partition coefficients (Dc/m) for a wide range of trace elements in amphibole in equilibrium with a basanitic melt. The following strategy to determine accurately and evaluate Dc/m is proposed. One or more major elements determined previously by electron probe microanalysis (EPMA) was used to ensure consistency between EPMA and the composition of the aerosol produced by the laser ablation. Measured Dc/m values were successively evaluated using the lattice strain model. The use of this strategy significantly improved the precision and accuracy of Dc/m determination when a LA-ICP-MS configuration with a high spatial resolution was employed.  相似文献   
68.
A gravity investigation was carried out in the Somma–Vesuvius complex area (Campania, Italy) based on a dataset recently enlarged with new measurements. These cover the volcanic top and fill some other important spatial gaps in previous surveys. Besides the new gravity map of the Vesuvius, we also present the results of a 3D inverse modelling, carried out by using constraints from deep well exploration and seismic reflection surveys. The resulting density model provides a complete reconstruction of the top of the carbonate basement. This is relevant mostly on the western side of the survey area, where no significant information was previously available. Other new information regards the Somma–Vesuvius structure. It consists of an annular volume of rocks around the volcanic vent and that extends down to the carbonate basement. It results to be denser with respect to the surrounding sedimentary cover of the Campanian Plain and to the material located just along the central axis of the volcanic structure. The coherence between these features and other geophysical evidences from previous studies, will be discussed together with the other results of this research.  相似文献   
69.
An experimental facility has been developed to investigate magma-water interaction (MWI). The facility operates in a high-pressure and high-temperature environment, with temperatures up to 1,200°C and pressures up to 200 MPa. Cylindrical sample-holders (20 by 180 mm in size) are heated conductively to yield a three phase (melt, crystals and gas) system, and then water (or other fluid) is injected into the sample through a capillary tube (diameter 0.5 mm, length ca. 1,000 mm) under controlled conditions. Pressure, volume and temperature changes are continuously recorded during every phase of the experiments. To test this facility, MWI is studied at subliquidus temperatures (800 and 900°C) and pressure (8 MPa), using a leucite tephrite sample with two different initial grain sizes. Because of the grain-size dependence of sintering, the two starting materials produce magmas with different textures at the same temperature: porous magma for large initial grain sizes and dense magma for small initial grain sizes. In these experiments 1.5 g of water at room temperature is injected into 6.0 g of partially molten sample at velocities ranging from 1 to 3 m/s. We find that the extent of fragmentation and transport caused by MWI are mainly controlled by the texture of the interacting sample with explosive interaction occurring only for porous magmas.  相似文献   
70.
An analysis of the field scaling power spectrum yields useful information about the source distribution, but it is uncertain whether deterministic, random, fractal or mixed approaches have to be used for the interpretation. To this end, the scaling properties of potential field spectra are analysed for a number of different source models of geological interest. Besides the models of Naidu (purely random sources) and Spector and Grant (gross block statistical ensembles) we consider other types of density and magnetization distributions with spectral exponents in the fractal range, such as a single homogeneous body with a random white source distribution. Spectral slopes in the fractal range are obtained.
We also study the effects of important natural sources, such as salt domes and sedimentary basins, representing them with simple Gaussians or combinations of Gaussian signals. The same spectral slopes as for gravity signals generated by 3-D fractal source distributions are found for them. Hence the power law decay of the field is not a characteristic only of fractal source models.
If a 3-D fractal source distribution is assumed a priori , a way of verifying the goodness of the model is to examine the whitened field at source level. The probability that the whitened field derives from a random white population is estimated for synthetic and real anomalies by applying the usual statistical tests.  相似文献   
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