Pretreatment of high strength waste emulsions by combined vibratory shear enhanced process with Fenton oxidation     

W. J. Zhang  M. Zhang  F. Xiao  L. P. Fang  D. S. Wang 《International Journal of Environmental Science and Technology》2014,11(3):731-738

Pretreatment of waste emulsions with high organic content by a combined process of vibratory shear enhanced process and Fenton’s oxidation prior to biological treatment was investigated. Vibrating membrane had shown good performance in chemical oxygen demand and oil removals and the mitigation of concentration polarization. However, the permeate after filtration processing still contained high content of organics. Thus, additional Fenton oxidation was applied to reduce the organic loading, and improve the biodegradability of the wastewater. The optimal molar ratio of ferrous iron to hydrogen peroxide was 0.05 obtained from the jar-test experiments. Removal of organics was enhanced by increasing hydrogen peroxide dosage, while efficiency of hydrogen peroxide reached maximum of 1.11(w/w) at the hydrogen peroxide dosage of 6.8 g/L. Furthermore, the biological experiments indicated that the high concentration of organics could inhibit microbial activity, which decreased the chemical oxygen demand degradation rates. The adaptive period of the microbe was greatly shortened using Fenton’s reagent at the low dosages. The improvement of the biodegradability could be explained by partial mineralization and chemical transformation of parent organic compounds after Fenton oxidation.  相似文献   

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid     

Tao Wang  Xin Jiang  Congying Wang  Fang Wang  Yongrong Bian  Guifen Yu 《Environmental Earth Sciences》2014,71(2):773-782

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.  相似文献   

Exploring the effects of data quality,data worth,and redundancy of CO2 gas pressure and saturation data on reservoir characterization through PEST inversion     

Zhufeng Fang  Zhangshuan Hou  Guang Lin  Dave Engel  Yilin Fang  Paul Eslinger 《Environmental Earth Sciences》2014,71(7):3025-3037

This study examined the impacts of reservoir properties on carbon dioxide (CO₂) migration after subsurface injection and evaluated the possibility of characterizing reservoir properties using CO₂ monitoring data such as spatial–temporal distributions of gas pressure, which can be reasonably monitored in practice. The injection reservoir was assumed to be located 1,400–1,500 m below the ground surface such that CO₂ remained in the supercritical state. The reservoir was assumed to contain layers with alternating conductive and resistive properties, which is analogous to actual geological formations such as the Mount Simon Sandstone unit. The CO₂ injection simulation used a cylindrical grid setting in which the injection well was situated at the center of the domain, which extended out 8,000 m from the injection well. The CO₂ migration was simulated using the latest version of the simulator, subsurface transport over multiple phases (the water–salt–CO₂–energy module), developed by Pacific Northwest National Laboratory. A nonlinear parameter estimation and optimization modeling software package, Parameter ESTimation (PEST), is adopted for automated reservoir parameter estimation. The effects of data quality, data worth, and data redundancy were explored regarding the detectability of reservoir parameters using gas pressure monitoring data, by comparing PEST inversion results using data with different levels of noises, various numbers of monitoring wells and locations, and different data collection spacing and temporal sampling intervals. This study yielded insight into the use of CO₂ monitoring data for reservoir characterization and how to design the monitoring system to optimize data worth and reduce data redundancy. The feasibility of using CO₂ saturation data for improving reservoir characterization was also discussed.  相似文献   

Assessment of soil salinization based on a low-cost method and its influencing factors in a semi-arid agricultural area,northwest China   总被引：13，自引：9，他引：4  

Jianhua Wu  Peiyue Li  Hui Qian  Yuan Fang 《Environmental Earth Sciences》2014,71(8):3465-3475

An investigation of soil salinization was carried out in the Nanshantaizi area (Northwest China) with WET Sensor. This device can measure such soil parameters as bulk soil electrical conductivity, water content, and the pore water electrical conductivity that are important for soil salinization assessments. A distribution map of soil salinization was produced, and the factors influencing soil salinization and its processes were discussed in detail. The study shows that moderately salinized to salt soils are mainly observed in the alluvial plain, where groundwater level is high and lateral recharge water contains high salinity. Nanshantaizi is covered by slightly salinized soils. The soil salinization distribution estimated by WET Sensor is generally consistent with the actual levels of salinization. Soil salinity in Nanshantaizi is mostly of natural origin and accumulated salts could leach to deeper soils or aquifers by water percolation during irrigation. Groundwater evaporation, groundwater level depth and quality of recharge water are important factors influencing soil salinization in the alluvial plain.  相似文献   

Changes in the critical erosion velocity for sediment colonized by biofilm     

Hongwei Fang  Qianqian Shang  Minghong Chen  Guojian He 《Sedimentology》2014,61(3):648-659

In flowing water the incipient motion of sediment can be affected by the presence of microbial biofilm growth. This article documents a series of flume experiments using non‐uniform sediments, in which sediment entrainment was investigated for cases where the sediment was immersed in deionized water, so that no biofilm developed, and for cases where a bio‐sediment was cultivated by placing the sediment in a mixture of natural water and nutrient solution. Differences in entrainment and the velocity at incipient motion were measured over an eight week period, as biofilm grew. It was found that the incipient motion phenomena were quite distinct between the two kinds of sediment. Sediment with biofilm was more stable and, over time, incipient velocity increased to a threshold level, before declining. Biofilm development is clearly an important control on the stability of sediments, especially in eutrophic water bodies. Two incipient velocity formulas were derived for sliding and rolling conditions. Film water theory was utilized to describe the cohesive force between sediment particles and the adhesive force generated by biofilm was introduced into the formula derivation; the time variation characteristics of biofilm strength and the features of the substrate were also taken into consideration. Such analyses can help to predict sediment transport changes due to biofilm presence in nutrient‐rich water bodies.  相似文献   

哈萨克斯坦萨亚克铜矿田代表性矿区矽卡岩矿物的组成及其意义研究   总被引：3，自引：0，他引：3  

安芳  王居里  朱永峰  Eleonora Seitmuratova 《矿床地质》2014,33(3):521-540

哈萨克斯坦萨亚克铜矿田产于晚石炭世闪长玢岩、石英闪长玢岩或花岗闪长玢岩与中石炭统灰岩的接触带上,铜矿体呈透镜状、脉状产于矽卡岩中。其成矿期可以划分为4个阶段：石榴子石矽卡岩阶段（Ⅰ）、绿帘石-石榴子石矽卡岩阶段（Ⅱ）、磁铁矿阶段（Ⅲ）和石英-硫化物阶段（Ⅳ）。铜矿化主要发生在石英-硫化物阶段,形成石英、黄铁矿、黄铜矿、磁黄铁矿,呈浸染状或脉状产于不同类型的矽卡岩或块状磁铁矿中。矽卡岩中的石榴子石有3种类型：石榴子石矽卡岩中的钙铁榴石（Grt-a）、交代钙铁榴石的含Al钙铁榴石（Grt-b）和绿帘石-石榴子石矽卡岩中具有环带结构的石榴子石（Grt-c）。从第一类到第三类石榴子石,平均w（Al₂O₃）从<1%逐渐升高至~5%;分子式中平均Fe³⁺原子数从2.15逐渐降低至1.57,显示成矿体系中Al的摩尔浓度逐渐升高、氧逸度逐渐降低。绿帘石-石榴子石矽卡岩中发育少量辉石,属于钙铁辉石-透辉石系列,在辉石分类图中落于普通辉石范围内。矽卡岩的地质特征、矿物组合和矿物化学特征表明,萨亚克矽卡岩是与花岗岩类侵入岩有关的岩浆热液与灰岩通过接触交代反应形成的钙质矽卡岩,随着矽卡岩化和成矿作用的进行,成矿体系的温度和氧逸度逐渐降低、pH值升高,导致磁铁矿和黄铁矿-磁黄铁矿-黄铜矿矿物组合依次发生沉淀。  相似文献   

云南石林世界地质公园阿诗玛石柱碳酸盐岩 显微特征及沉积环境     

彭阳  陈安泽  钱方 《地质论评》2014,60(5):1109-1112

云南石林世界地质公园阿诗玛石柱,其岩石地层是呈水平产状的中二叠统茅口组厚层块状灰岩,但其构成岩石的具体岩性却未见做过详细工作。笔者等经公园管理部门同意,自下而上分别在阿诗玛石柱背侧底部、下部、中部、上部和顶部共采集样品五块,对其岩石学特征及沉积微相作了详细研究,弄清了这一世界著名景点自下而上的岩石构成及沉积相。底部为高能浅滩相灰色厚层块状具平行层理生屑颗粒灰岩,构成阿诗玛脚部。下部为中能浅潮下灰色厚层块状虫筳生屑泥粒灰岩,构成阿诗玛腿部。中部为中能浅潮下灰色厚层块状砂屑泥粒灰岩,构成阿诗玛腰部。上部为中能浅潮下灰色厚层块状具生物扰动含砂屑生屑泥粒灰岩,构成阿诗玛胸部;顶部为高能浅滩相灰色厚层块状砂屑生屑颗粒灰岩,构成阿诗玛头部。其中含有大量生物化石碎屑:有孔虫、三叶虫、藻类、介形虫、腕足、苔藓虫、虫筳、海百合茎、双壳类,为高能浅滩相和中等能量浅潮下环境。希能为石林形成过程研究和科学普及提供参考。  相似文献   

Comparison of Blast-Induced Damage Between Presplit and Smooth Blasting of High Rock Slope     

Yingguo Hu  Wenbo Lu  Ming Chen  Peng Yan  Jianhua Yang 《Rock Mechanics and Rock Engineering》2014,47(4):1307-1320

This paper focuses on the comparison of damage induced by smooth blasting and presplit blasting based on the excavation of high rock slope. The whole damage process of the smooth blasting and presplit blasting excavation method is studied by using a cumulative blasting damage numerical simulation technology based on the secondary development of the dynamic finite element code LS-DYNA. The results demonstrate that, in the case of contour blasting with the method of smooth blasting, the total damage of rock slope is a result of cumulated damage induced by the production hole, buffering hole, and smooth hole. Among the total damage, the blasting of the production hole is the main resource, followed by the smooth and buffering holes. For the presplit blasting, the final damage of rock slope is mainly induced by presplit blasting itself. The spatial distribution characteristics of the final damage zone of two methods are compared. Two classes of damage zone could be found in smooth blasting excavation; one of them is the columnar high-degree damage zone around the slope surface and the other is the low-degree damage zone located in the middle of the slope. But in the case of presplit blasting, there is only the columnar high-degree damage zone around the slope surface. Finally, a damage control suggestion for two blasting excavation methods is proposed and verified based on the excavation of the temporary shiplock slopes of the Three Gorges Project in China.  相似文献   

从洋壳俯冲到陆壳俯冲和碰撞：来自羌塘中西部地区榴辉岩和蓝片岩地球化学的证据   总被引：5，自引：2，他引：3  

张修政  董永胜  李才  解超明  王明  邓明荣  张乐 《岩石学报》2014,30(10):2821-2834

羌塘中部晚三叠世低温/高压变质带是目前青藏高原内部延伸规模最大的高压变质带,但大量关键高压变质岩石出露地区地球化学资料匮乏,严重制约了对高压变质带原岩建造以及构造演化的全面认识。本文以羌塘中西部地区尚无地球化学资料的果干加年山榴辉岩和红脊山蓝片岩为研究对象,进行了系统的地球化学以及原岩恢复工作。研究表明,果干加年山榴辉岩呈透镜状产于围岩石榴石多硅白云母片岩和少量大理岩中,其原岩为亚碱性玄武岩,具有较低的稀土总量(∑REE=51.19×10-6~59.43×10-6)和轻稀土亏损的特征[(La/Yb)N=0.59~0.70],不具有Nb、Ta、Ti的亏损,与典型的N-MORB特征一致,暗示其原岩可能来源于亏损的地幔源区,形成于洋中脊环境。红脊山地区基性蓝片岩的原岩为碱性玄武岩-亚碱性玄武岩,具有高的TiO2(2.97%~4.14%)和P2O5(0.29%~0.48%)含量,富集轻稀土元素[(La/Yb)N=6.10~11.6]和高场强元素,地球化学特征类似于OIB。但是这些基性蓝片岩与大量的陆源碎屑岩伴生产出,且具有明显的硅铝质上地壳物质混染的特征,与南羌塘地区二叠纪大陆板内基性岩墙的产出特征以及地壳混染特征一致,可能是其俯冲消减的产物。通过本文研究结果并结合区域内已识别出的E-MORB型洋壳和洋岛/海山物质深俯冲的证据,我们认为羌塘中部晚三叠世高压变质带以洋壳物质深俯冲为主,同时亦保留了部分陆壳物质俯冲的证据,暗示大洋向北俯冲消减结束之后,又牵引至少一部分南羌塘北缘陆壳物质经历了随后的俯冲过程。  相似文献   

冀东双山子群变质火山岩的地球化学、锆石U-Pb年代学及其对岩石成因和构造背景的制约   总被引：6，自引：5，他引：1  

郭荣荣  刘树文  白翔  张立飞  王伟  胡方泱  阎明 《岩石学报》2014,30(10):2885-2904

冀东双山子群是一套出露于青龙县东部变质程度较低的火山沉积地层,其中火山岩地层主要由变质玄武岩、安山岩和英安岩-流纹岩组成。全岩地球化学分析表明变玄武岩呈现拉斑玄武岩的地球化学特征,起源于尖晶石二辉橄榄岩12%~25%的部分熔融,变质安山岩与变质英安岩-流纹岩形成于弧下地幔部分熔融,该熔体受到地壳物质混染。LA-ICPMS锆石U-Pb定年表明本群变质安山岩形成于2514±16Ma,而变质流纹岩形成于2522±8Ma,二者均受到~2450和~2300Ma的后期热事件扰动。结合本群变质火山岩的岩石组合、地球化学特征和岩石成因,该套岩石可能形成于活动大陆边缘弧相关构造背景。  相似文献