Kinetics of peptide hydrolysis and amino acid decomposition at high temperature     

Qian Y  Engel MH  Macko SA  Carpenter S  Deming JW 《Geochimica et cosmochimica acta》1993,57(14):3281-3293

Dipeptide hydrolysis and amino acid decomposition appear to follow a first-order rate law. The hydrolysis rate increases exponentially with increasing temperature in aqueous solution at both 265 atm and water steam pressures over the temperature range of 100 to 220 degrees C. Dipeptide hydrolysis has a lower apparent activation energy at 265 atm (44.1 KJ/mol) than at water steam pressure (98.9 KJ/mol). At lower temperatures (<200-220 degrees C), the rate of peptide bond hydrolysis is faster at 265 atm than at water steam pressure. At higher temperatures (>200-220 degrees C), however, peptide bond hydrolysis is slower at 265 atm than at water steam pressure. In aqueous solution, amino acid decomposition rates also increase exponentially with increasing temperature. Amino acid decomposition rates are much higher at 265 atm than at water steam pressure over the entire temperature range investigated.  相似文献   

敦煌北部岩浆-变质杂岩构造环境初步探讨:对中亚造山带南缘扩展方式的启示     

石梦岩  程南南  侯泉林  吴春明  闫全人  张国成  张谦  王浩 《岩石学报》2021,37(12):3673-3686

中亚造山带南缘如何向南扩展，对深入理解增生型造山作用和大陆地壳生长机制以及中亚构造域与特提斯构造域的衔接具有重要科学意义。作为中亚造山带南缘的关键构造单元，敦煌构造带大地构造属性长期备受关注且颇有争议。传统观点认为敦煌构造带是古亚洲洋南侧的前寒武纪稳定大陆地块，以刚性块体的形式参与了中亚造山带南缘的最终拼贴过程。然而，近年来研究认为敦煌构造带卷入了古亚洲洋南部的俯冲增生造山过程，属于中亚造山带南缘的增生系统。显然，这一争议限制了对中亚造山带南缘向南扩展方式及增生造山过程的理解。敦煌北部三危山地区出露一套古生代岩浆-变质杂岩，是解开这一争论的关键。本文综合前人研究基础及新的资料，归纳了这套岩浆-变质杂岩的野外岩石-构造组合、地球化学和年代学等方面特征：该岩浆-变质杂岩整体显示"二元结构"特征，即较老的增生杂岩为基底，弧岩浆岩侵入或不整合覆盖其上；其中岩浆岩属于中钾-高钾钙碱性系列中酸性岩浆岩，富集大离子亲石元素（LILE）和轻稀土元素（LREE），亏损高场强元素（HFSE），与典型的弧岩浆岩类似，并且微量元素组成特征反映中酸性岩浆的源区与俯冲沉积物部分熔融有关；岩浆作用大致归为510Ma、460~410Ma和370~360Ma三期。岩浆岩中结晶锆石不一致的ε_Hf（t）值（既有正值，又有负值）以及继承锆石的存在表明，岩浆源区既有古老地壳物质的加入，也有新生地壳物质的形成。以上这些特征与发育在增生杂岩之上的增生弧十分类似，因此本文提出敦煌北部岩浆-变质杂岩的属性为古生代增生弧，并且该增生弧与其南部的红柳峡俯冲增生杂岩共同勾勒出敦煌构造带自北向南增生弧-增生杂岩的基本构造格架，即敦煌构造带的大地构造属性实为造山带而非稳定地块。结合区域地质背景及敦煌地区与北山地区古生代至早中生代构造-热事件的对应关系，认为敦煌造山带属于中亚造山带中段南缘的增生系统，中亚造山带中段以增生弧-增生杂岩的形式向南扩展至敦煌地区。  相似文献   

《北京旅游图集》设计与编制研究   总被引：2，自引：0，他引：2  

钱金凯 《测绘学报》1992,21(4):299-306

  相似文献   

Indium Enrichment in the Meng'entaolegai Ag-Pb-Zn Deposit, Inner Mongolia, China   总被引：3，自引：0，他引：3  

Qian Zhang    Xiaoqing Zhu    Yuliang He  Junjie Jiang  Dapeng Wang 《Resource Geology》2006,56(3):337-346

Abstract. The Meng'entaolegai In-rich Ag-Pb-Zn deposit is located in the eastern part of Inner Mongolia. It is one of the In-richest deposits in China. Large amounts of quartz and sulfide minerals constitute a hydrothermal quartz-sulfide vein deposit within a Hercynian acidic granite massif, which occupies an area of about 400 km². Thirty-six orebodies, controlled strictly by the E-W trend faults, are found in the orefield of 6 km in length from east to west and 200 to 1,000 m in width from south to north. The ore minerals are mainly galena, sphalerite and pyrite, and subordinate chalcopyrite, arsenopyrite, cassiterite and stannite with many Ag-minerals. The gangue minerals are mainly quartz, calcite, sericite and chlorite. Economic components of the deposit are dominated by Pb andZn (reserves of Pb and Zn are 0.17 Mt and 0.37 Mt, and their grades are 1 % and 2.3 %, respectively), with Ag, Sn, In and Cd (1,800 t Ag, >2,000 t Sn, >500 t In and 1,800 t Cd) as by-products. Indium is highly enriched in ores and its contents are 9 to 295 ppm in ores and 85 to 2,660 ppm in sphalerite. Analytical results show that the ore-forming fluid of this deposit contains 0.8–3.5 ppm In and 4–36 ppm Sn, and the two elements show a very good positive correlation with a correlation coefficient of 0.8672, while the correlation between In and Zn in the ore-forming fluids, with a correlation coefficient of 0.5723, is not as good as that between In and Sn. This indicates that indium has an affinity with tin in the ore-forming fluids. The authors think that this is probably the main reason why those In-rich deposits spread over the world are simultaneously enriched in tin.  相似文献   

Application of the QUILF thermobarometer to the peralkaline trachytes and pantellerites of the Eburru volcanic complex, East African Rift, Kenya   总被引：1，自引：0，他引：1  

Minghua Ren  Peter A. Omenda  Elizabeth Y. Anthony  John C. White  Ray Macdonald  D.K. Bailey   《Lithos》2006,91(1-4):109-124

The Quaternary Eburru volcanic complex in the south-central Kenya Rift consists of pantelleritic trachytes and pantellerites. The phenocryst assemblage in the trachytes is sanidine + fayalite + ferrohedenbergite + aenigmatite ± quartz ± ilmenite ± magnetite ± pyrrhotite ± pyrite. In the pantellerites, the assemblage is sanidine + quartz + ferrohedenbergite + fayalite + aenigmatite + ferrorichterite + pyrrhotite ± apatite, although fayalite, ferrohedenbergite and ilmenite are absent from more evolved rocks (e.g. with SiO₂ > 71%). QUILF temperature calculations for the trachytes range from 709 to 793 °C and for the pantellerites 668–708 °C, the latter temperatures being among the lowest recorded for peralkaline silicic magmas. The QUILF thermobarometer demonstrates that the Eburru magmas crystallized at relatively low oxidation states (ΔFMQ + 0.5 to − 1.6) for both trachytes and pantellerites. The trachytes and pantellerites evolved along separate liquid lines of descent, the trachytes possibly deriving from a more mafic parent by fractional crystallization and the pantellerites from extreme fractionation of comenditic magmas.  相似文献   

Study of geothermal water intrusion due to groundwater exploitation in the Puebla Valley aquifer system, Mexico   总被引：1，自引：1，他引：1  

E. Leticia Flores-Márquez  Gabriel Jiménez-Suárez  Raymundo G. Martínez-Serrano  René E. Chávez  Daniel Silva Pérez 《Hydrogeology Journal》2006,14(7):1216-1230

Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m³. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.  相似文献   

Soil quality changes in land degradation as indicated by soil chemical, biochemical and microbiological properties in a karst area of southwest Guizhou, China   总被引：7，自引：0，他引：7  

Pingjiu Zhang  Lianqing Li  Genxing Pan  Jingchen Ren 《Environmental Geology》2006,51(4):609-619

Not only the nutritional status and biological activity but also the soil ecological functioning or soil health has been impacted profoundly by land degradation in the karst area of southwest China where the karst ecosystems are generally considered as extremely vulnerable to land degradation under intensified land-use changes. The objectives of this study are to elucidate the changes in overall soil quality by a holistic approach of soil nutritional, biological activity, and soil health indicators in the karst area as impacted by intense cultivation and vegetation degradation. Topsoil samples were collected on selected eco-tesserae in a sequence of land degradation in a karst area of southwest Guizhou in 2004. The soil nutrient pools of organic carbon (C_org), extractable extracellular carbon (C_ext), total soil nitrogen (N_t), alkali-hydrolyzable nitrogen (N_ah), total phosphorus (P_t), available phosphorus (P_a) were analyzed by wet soil chemistry. The soil biological properties were studied by means of measurements of microbial biomass carbon (both by fumigation–extraction, FE-C_mic, and by calculation from substrate-incubation respiration, SIR-C_mic) of respiration [respiration without addition of substrates, basal respiration (BR), and potential respiration (PR) with substrate-incubation] and of soil enzyme activities (invertase, urease, and alkaline phosphatase). Soil health status was assessed by simple indices of C_mic/C_org and BR/C_mic in conjunction with bacterial community structures determined by polymerase chain reaction and denaturing gradient gel electrophoresis. While the nutritional pool parameters, such as C_org and C_ext, described basically the changes in soil life-supporting capacity with cultivation interference and vegetation declined, those parameters of biological activity such as FE-C_mic, SIR, and SIR-C_mic as well as bacterial community structures measured by molecular method evidenced well the changes in soil functioning for ecosystem health with the land degradation.  相似文献   

Threshold velocity for wind erosion: the effects of porous fences   总被引：3，自引：0，他引：3  

Zhibao Dong  Guangqiang Qian  Wanyin Luo  Hongtao Wang 《Environmental Geology》2006,51(3):471-475

Porous fence is a kind of artificial windbreak that has many practical applications. The threshold wind velocities at different distances downwind from porous fences were measured and the corresponding characteristics of particle movement observed to assess their shelter effect. It is found that the fence’s porosity is the key factor that determines the resulting shelter effect. The area near a fence can be typically classified into five regions, each with a different mode of particle movement. Dense fences, and especially solid fences, favor the accumulation of sand upwind of the fences. Fences with porosities of 0.3–0.4 produce the maximum threshold wind velocity; those with porosities of 0.3–0.6 (depending on the fence height) provide the maximum effective shelter distance. It is confirmed that the fence porosities of 0.3–0.4 that have been proposed for practical application in previous research are the most effective for abating wind erosion.  相似文献   

Water–rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China     

Qian Hui  Yang Zhenghua  Li Yunfeng  Xu Wancai  Sun Yaqiao 《Environmental Geology》2006,50(2):229-236

In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na⁺, SiO₂ and Cl⁻, as well as the increase of K⁺, Ca²⁺, Mg²⁺, SO ₄ ²⁻ and HCO ₃ ⁻ . Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO₂. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed.  相似文献   

Optimization of SAGD Well Elevation     

Jason A. McLennan  Weishan Ren  Oy Leuangthong  C. V. Deutsch 《Natural Resources Research》2006,15(2):119-127

The application of steam-assisted gravity drainage (SAGD) to recover heavy oil sands is becoming increasingly important in the northern Alberta McMurray Formation because of the vast resources/reserves accessible with this mechanism. Selecting the stratigraphic elevations of SAGD well pairs is a vital decision for reservoir evaluation and planning. The inherent uncertainty in the distribution of geological variables significantly influences this decision. Geostatistical simulation is used to capture geological uncertainty, which is used can be transformed into a distribution of the best possible well pair elevations. A simple exhaustive calculation scheme is used to determine the optimum stratigraphic location of a SAGD well pair where the recovery R is maximized. There are three basic steps to the methodology: (1) model the uncertainty in the top continuous bitumen (TCB) and bottom continuous bitumen (BCB) surfaces, (2) calculate the recovery at all possible elevation increments within the TCB and BCB interval, and (3) identify the elevation that maximizes R. This is repeated for multiple TCB/BCB pairs of surfaces to assess uncertainty. The methodology is described and implemented on a subset of data from the Athabasca Oilsands in Fort McMurray, Alberta.  相似文献