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81.
Roland Eichhorn Georg Loth Allen Kennedy 《Contributions to Mineralogy and Petrology》2001,142(2):147-162
The U-Pb SHRIMP age determinations of zircons from the Habach terrane (Tauern Window, Austria) reveal a complex evolution of this basement unit, which is exposed in the Penninic domain of the Alpine orogen. The oldest components are found in zircons of a metamorphosed granitoid clast, of a migmatitic leucosome, and of a meta-rhyolitic (Variscan) tuff which bear cores of Archean age. The U-Pb ages of discordant zircon cores of the same rocks range between 540 and 520 Ma. It is assumed that the latter zircons were originally also of Archean origin and suffered severe lead loss, whilst being incorporated into Early-Cambrian volcanic arc magmas. The provenance region of the Archean (2.64-2.06 Ga) zircons is assumed to be a terrane of Gondwana affinity: i.e., the West African craton (Hoggar Shield, Reguibat Shield). The Caledonian metamorphism left a pervasive structural imprint in amphibolite facies on rocks of the Habach terrane; it is postdated by discordant zircons of a migmatitic leucosome at <440 Ma (presumably ca. 420 Ma). Alpine and Variscan upper greenschist- to amphibolite-facies conditions caused partial lead loss in zircons of a muscovite gneiss ('white schist') only, where extensive fluid flow and brittle deformation due to its position near a nappe-sole thrust enhanced the grains' susceptibility to isotopic disturbance. The Habach terrane - an active continental margin with ensialic back-arc development - showed subduction-induced magmatic activity approx. between 550 and 507 Ma. Back-arc diorites and arc basalts were intruded by ultramafic sills and subsequently by small patches of mantle-dominated unaltered and (in the vicinity of a major tungsten deposit) altered granitoids. Fore-arc (shales) and back-arc (greywackes, cherts) basin sediments as well as arc and back-arc magmatites were not only nappe-stacked by the Caledonian compressional regime closing the presumably narrow oceanic back-arc basin and squeezing mafic to ultramafic cumulates out of high-level magma chambers (496-482 Ma). It also induced uplift and erosion of deeply rooted crystalline complexes and triggered the development of a successor basin filled with predominantly clastic greywacke-arkosic sediments. The study demonstrates that the basement rocks exposed in the Habach terrane might be the 'missing link' between similar units of the more westerly positioned External domain (i.e., Aar, Aiguilles Rouges, Mont Blanc) and the Austroalpine domain to the east (Oetztal, Silvretta). 相似文献
82.
Run products from high pressure experiments at 800-1,200 °C and 5-14 GPa (corresponding to depths of 150 to 420 km) on a serpentine bulk composition [close to Mg3Si2O5(OH)4] were analysed by optical microscopy, micro-Raman spectroscopy and electron microprobe. All charges exhibit strong chemical zoning. Fluid, melt and hydrous solids were mostly concentrated at the top, bottom and along the wall of the capsules. The central part of the charge was devoid of H2O. Both fluid and hydrous magnesian phases exhibit a Mg/Si ratio higher than forsterite. In contrast, the centre of the capsule was enriched in SiO2. The observed zoning can neither be explained by gravitational settling nor by a thermal gradient alone. Most likely the fluid was separated from the solids by surface forces and thereby established the chemical gradient by preferentially dissolving MgO. If strong chemical zoning is taken into account, the occurrence of more phases than allowed by the phase rule can be explained by separating the bulk into several domains of different bulk compositions. Results indicate that small amounts of F increase the stability field of clinohumite, Mg9Si4O16(OH,F)2, compared to OH-clinohumite in pure MSH previously reported. Clinohumite coexists with enstatite up to 975 °C at 5 GPa, and up to 1,100 °C at 12 GPa. At 14 GPa (close to the !/#-Mg2SiO4 transition) phase E becomes the most important water carrier. The new results indicate that clinohumite could be an important mantle mineral for transporting water into the Earth's transition zone due to its high thermal stability compared to other important water carriers such as serpentine and phase A. 相似文献
83.
Roland Otto 《Hydrogeology Journal》2001,9(5):498-511
In the southeastern Holstein region, located to the east of the metropolitan zone of Hamburg, northern Germany, a groundwater
investigation program was conducted from 1984 to 2000 by the State Agency for Nature and Environment (Landesamt für Natur
und Umwelt, LANU) of Schleswig-Holstein, Germany, with the aim of providing long-term, ecologically acceptable groundwater
management plans for the region. The focal point of the investigation comprised the determination of groundwater recharge
rates. The investigation method was based on the transfer of available lysimeter results from other regions to comparable
regions within the area studied. With the help of lysimeter equations, potential amounts of percolation water were calculated.
The groundwater recharge rate was then determined after subtraction of the surface runoff which was calculated for the entire
area. All computations were performed with a spreadsheet program. Groundwater recharge rates were calculated for two areas.
One consisted of roughly determining groundwater recharge rates for the total region (1,392 km2) of southeastern Holstein. The overall goal of these investigations was to identify potential areas of water exploitation.
Areas in which groundwater recharge rates are high and groundwater outflow is low are particularly suited to water exploitation,
since inflow rates into deeper aquifers are high. These areas are located on the flanks of the Elbe and Stecknitz River valleys.
Subsurface groundwater runoff to these lowlands would be reduced through groundwater withdrawal. However, the resulting decline
in shallow groundwater tables would be so small that it would have no detrimental ecological effects. Groundwater recharge
rates were also calculated for a 110-km2 area in the outskirts of Hamburg (Grosshansdorf model area) which is intensively developed for water supply. These investigations
showed that the amount of groundwater recharge is already being withdrawn to a large extent. Approximately 65% of the recharge
rate is currently withdrawn by the waterworks in this area, thus making further increases in exploitation rates unjustifiable
from an ecological point of view.
Electronic Publication 相似文献
84.
J. M. Léger J. Haines C. Chateau G. Bocquillon M. W. Schmidt S. Hull F. Gorelli A. Lesauze R. Marchand 《Physics and Chemistry of Minerals》2001,28(6):388-398
The structure of the cristobalite-like polymorph of phosphorus oxynitride PON has been refined using neutron powder diffraction
data. It is tetragonal, space group I&4macr;2d, Z=4. The four P–(O,N) distances are equal but the tetrahedron is compressed along c. In AX2 or ABX4 compounds, the tetragonal I&4macr;2d or I&4macr; structure is obtained when the average ratio of the cation to anion radius is below 1.186, whereas the tetragonal P41212 or orthorhombic C2221 structure is obtained at low temperatures for larger ratios. The cell parameters of this PON polymorph have been determined
as a function of hydrostatic pressure by in situ angle dispersive X-ray powder diffraction in a diamond-anvil cell. Under
truly hydrostatic pressure, a strong anisotropic behavior is observed with the c parameter being nearly incompressible. Very slight anisotropic stress strongly modifies the high-pressure behavior. According
to the pressure-temperature conditions of treatment, three phases, cristobalite-, moganite-, and quartz-like, have been obtained
by quenching experiments, and the P–T phase diagram of PON was derived. The high-pressure behavior of the α-quartz, moganite, and cristobalite-like polymorphs
of PON and SiO2 is discussed.
Received: 7 August 2000 / Accepted: 21 January 2001 相似文献
85.
Hans Güsten Günther Heinrich Ralf W. H. Schmidt Ulrich Schurath 《Journal of Atmospheric Chemistry》1992,14(1-4):73-84
A small, lightweight (1.5 kg) and fast-response ozone sensor for direct eddy flux measurements has been built. The basis for detection is the chemiluminescence of an organic dye adsorbed on dry silica gel in the reaction with ozone. The chemiluminescence is monitored with a cheap and small blue-sensitive photomultiplier. At a flow rate of 100 l min-1 the ozone sensor has a 90% response time of significantly better than 0.1 s with a detection limit lower than 50 ppt at S/N=3. There are no interferences from other atmospheric trace gases like NOx, H2O2 and PAN. Water vapour and SO2 enhance the chemiluminescence efficiency of the ozone sensor. Since their response times are 22 seconds and 30 minutes, respectively, no correlation between rapid ozone fluctuations and those of these two trace gases is noticed by the ozone sensor when operating at a frequency of 10 Hz.The ozone sensor was tested for several weeks in continuous measurements of ozone fluxes and deposition velocities over different croplands using the eddy correlation technique. Good agreement was found between ozone dry deposition velocities derived from profile measurements and by eddy correlation. 相似文献
86.
87.
Dr. Klaus Schmidt 《International Journal of Earth Sciences》1960,50(1):416-424
Zusammenfassung Im Botewgebiet der Stara Planina (Hochbalkan) liegt inmitten paläozoischer, mesozoischer und tertiärer Schichten ein 30 km langer und 12 km breiter Granitkomplex, der als autochthone Einheit, aber auch als Deckscholle gedeutet worden ist. Die Deckennatur des Komplexes wird durch die großtektonischen Verhältnisse eindeutig belegt. Der Bewegungsplan besitzt meridionale Symmetrie, die tektonischen Haupttransporte erfolgten von S nach N. Groß- und Kleingefüge entsprechen einander. Das Liegende der Decke besitzt keine einheitliche Prägung. Diskordante Lagerungsverhältnisse lassen variszische, kimmerische, kretazische, laramische und pyrenäische Bewegungen erkennen. 相似文献
88.
Construction, observation site and instrumentation are described of an 80-m meteorological observation tower, erected in Vlaardingen, The Netherlands, for studies in connection with air pollution problems along the Nieuwe Waterweg. From measurements made regularly in the period April 1967–April 1968 summaries are given of wind profile parameters and gustiness averages. Case histories are presented of an air pollution episode lasting several days, and of an hourly average wind direction difference of 120 ° over 70 m. 相似文献
89.
Separation of electrostatic charge during the transport of particles by wind adds a force to the gravitational and fluid forces that determine trajectories of particles moving by saltation. Evaluating this electrostatic force requires the electric field strength very near the saltation surface, and charge-to-mass ratios for the moving particles. Field mill readings 4 cm above the surface in a moderate blizzard showed electric field strength as high as +30 kV m-1. Another experiment gave charge-to-mass ratios of individual saltation particles in low-level drifting that ranged between +72 C kg-1 and -208 C kg-1. From these measurements, we estimated electrostatic forces as large as the gravitational force on some saltating particles. Including forces of this magnitude in the equations of motion significantly alters predicted saltation trajectories from those for uncharged particles. Predictions appear reasonable that for some saltating particles, the electrostatic force prevents new surface impacts. These results should help improve models of energy transfer in the planetary boundary layer during blizzards and sandstorms. 相似文献
90.
ABSTRACT Groundwater level fluctuations are caused by spatial and temporal superposition of processes within and outside the aquifer system. Most of the subsurface processes are usually observed on a small scale. Upscaling to the regional scale, as required for future climate change scenarios, is difficult due to data scarcity and increasing complexity. In contrast to the limited availability of system characteristics, high-resolution data records of groundwater hydrographs are more generally available. Exploiting the information contained in these records should thus be a priority for analysis of the chronical lack of data describing groundwater system characteristics. This study analyses the applicability of 63 indices derived from daily hydrographs to quantify different dynamics of groundwater levels in unconfined gravel aquifers from three groundwater regions (Bavaria, Germany). Based on the results of two different skill tests, the study aids index selection for different dynamic components of groundwater hydrographs. 相似文献