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41.
Removal of Lead,Copper, Zinc and Cadmium from Water Using Phosphate Rock   总被引:2,自引:0,他引:2  
Removal of Pb^2+, Cu^2+, Zn^2+ and Cd^2+ from aqueous solutions by sorption on a natural phosphate rock (FAP) was investigated. The effects of the contact time and initial metal concentration were examined in the batch method. The percentage sorption of heavy metals from solution ranges generally between 50% and 99%. The amount of sorbed metal ions follows the order Cu〉Pb〉Cd〉Zn. Heavy metal immobilization was attributed to both surface complexation of metal ions on the surface of FAP grains and partial dissolution and precipitation of a heavy metal-containing phosphate. The very low desorption ratio of heavy metals further supports the effectiveness of FAP as an alternative and low-cost material to remove toxic Pb^2+, Cu^2+, Zn^2+ and Cd^2+ from polluted waters.  相似文献   
42.
Expansions of the functions (r/a)cos jv and (r/a)m sin jv of the elliptic motion are extended to highly eccentric orbits, 0.6627 ... <e<1. The new expansions are developed in powers of (e–e*), wheree* is a fixed value of the eccentricity. The coefficients of these expansions are expressed in terms of the derivatives of Hansen's coefficients with respect to the eccentricity. The new expansions are convergent for values of the eccentricity such that |e–e*|<(e*), where the radius of convergence (e*) is the same of the extended solution of Kepler's equation. The new expansions are intrinsically related to Lagrange's series.  相似文献   
43.
The spatial resolution of digital elevation models (DEMs) is an important factor for reliable landslide studies. Multi-interferometric techniques such as persistent scatterer interferometric synthetic aperture radar (PSInSAR) are used to evaluate the landslide state of activity and its ground deformation velocity, which is commonly measured along the satellite line of sight (LOS). In order to compare velocities measured by different satellites in different periods, their values can be projected along the steepest slope direction, which is the most probable direction of real movement. In order to achieve this result, DEM-derived products are needed. In this paper, the effectiveness of different DEM resolutions was evaluated in order to project ground deformation velocities measured by means of PSInSAR technique in two different case studies in the Messina Province (Sicily, southern Italy): San Fratello and Giampilieri. Three DEMs were used: (i) a 20-m resolution DEM of the Italian Military Geographic Institute (IGM), (ii) a 2-m resolution DEM derived from airborne laser scanning (ALS) light detection and ranging (LiDAR) data for the San Fratello 2010 landslide, and (iii) a 1-m resolution DEM derived from ALS LiDAR data for the area of Giampilieri. The evaluation of the applied method effectiveness was performed by comparing the DEMs elevation with those of each single permanent scatterer (PS) and projecting the measured velocities along the steepest slope direction. Results highlight that the higher DEM resolution is more suitable for this type of analysis; in particular, the PS located nearby the watershed divides is affected by geometrical problems when their velocities are projected along the steepest slope.  相似文献   
44.
Abstract. In 1997, Artegiani et al. depicted for the first time the seasonal climatology of the Adriatic Sea; they used the ATOS data set, formed by 5540 oceanographic stations sampled over this continental basin from 1911 to 1980. Lately, two Italian institutes working on the Adriatic Sea for long time, IBM and IRPEM, merged their recent data sets for the northernmost part of the basin. This yielded 3600 new oceanographic stations, concentrated in an area where 809 ATOS stations were located. The new data were quality checked, and then a seasonal climatology was drawn up as a first analysis step. The new climatology differed significantly from the ATOS results; this could be explained, at least partially, by the climatic changes that have occurred on this area. For example, air temperature increased significantly over northern Italy starting from 1988. Variations of the observed air temperature and Po River runoff qualitatively agree with sea surface temperature and salinity variations. A preliminary computation of heat fluxes based on ECMWF reanalysis confirms an increased heat flux to the Northern Adriatic Sea starting from 1988.  相似文献   
45.
46.
ABSTRACT

The critical need for hydrological observations in support of water resources management, particularly during extreme events, has transformed traditional methods of hydrological data management. This transformation has given rise to a framework of e-monitoring the hydrological cycle, the aim of which is to improve understanding of the nature of water. New trends in data science, coupled with increasing technological evolution, make the new generation of data systems more agile and responsive to the needs and expectations for efficient and effective data sharing and service delivery. The WMO Hydrological Observing System was designed around the integration of observations, data exchange, research, data processing, modelling and forecasting, in such a way that societal needs for disaster risk reduction, improved sustainability of environmental resources, climate resilience and economic growth can be effectively met. With its implementation of conceptual functionalities for sustainable data management, the WHOS operational architecture is hydrology’s system for the future.  相似文献   
47.
Marine environments are continuously being threatened by a large number of xenobiotics from anthropogenic sources. Even in sparsely populated and relatively pristine areas, such as Antarctica, hazardous chemicals can pose a serious environmental problem. The main aims of the present study were to (1) validate and optimize an analytical technique utilizing a microtitre-plate photometer to ascertain background levels of esterase activities in the Antarctic bivalve Adamussium colbecki, (2) carry out in situ monitoring of esterase activities to assess any potential environmental impacts of the Italian Scientific Antarctic Base "Terra Nova Bay" on the surrounding marine area. Results showed the presence of organophosphorous-sensitive cholinesterase (ChE) and carboxylesterase (CbE) activities in the gills of A. colbecki and optimal assay conditions were comparable with those found for bivalve species from temperate areas. A higher sensitivity of ChE versus acetylthiocholine activity in A. colbecki to chlorpyrifos compared to species from temperate areas may also be inferred. The in situ study indicated no differences in the environmental quality of the three study sites located around the Italian Base.  相似文献   
48.
This paper presents two examples of application of Synthetic Aperture Radar (SAR) interferometry (InSAR) to typical geomorphological problems. The principles of InSAR are introduced, taking care to clarify the limits and the potential of this technique for geomorphological studies. The application of InSAR to the quantification of landform attributes such as the slope and to the estimation of landform variations is investigated. Two case studies are presented. A first case study focuses on the problem of measuring landform attributes by interferometric SAR data. The interferometric result is compared with the corresponding one obtained by a Digital Elevation Model (DEM). In the second case study, the use of InSAR for the estimation of landform variations caused by a landslide is detailed.  相似文献   
49.
The results of photometric observations of Centaur object Chiron carried out at the Observatório do Pico dos Dias (OPD, Brazil), the Estación Astrof?&#x0301;sica de Bosque Alegre (EABA, Argentina), and Complejo Astronómico El Leoncito (CASLEO, Argentina) from 1997 to 2001 are presented here. The analysis of the photometric data shows that the brightness of Chiron reached a minimum value in 1999 and began increasing again in 2000. The absolute magnitude, HV, varied from 7.26 in June 1999 to 5.78 in April 2001. The data tend to indicate that Chiron is starting a new outburst of activity which is compatible with a sporadic cometary behavior not related to heliocentric distance.  相似文献   
50.
The Sardinia-Corsica batholith was structured in the late stage of the Hercynian orogenesis. The granitoids intrude mainly metamorphic complexes grading from zeolite up to amphibolite facies. The batholith is heterogeneous consisting of complexes with different affinity, chemical composition, age and degree of deformation. The present paper reports major-and trace-element data for selected samples coming only from Sardinian outcrops.

The rocks range from gabbro-diorite to tonalite, monzogranite and leucogranite. The two latter lithologies are the most abundant, gabbrodiorites and tonalites occurring in minor amounts and mainly in northern-central Sardinia. Over 75% of the granitoids contain microgranular enclaves of magmatic origin. The age of the rocks falls in the interval between 307 and 281 Ma. Sr isotope initial ratios are high, ranging between 0.7083 and 0.7107.

REE, Rb, Sr, Ba, Zr, Th, Ta, Hf, Co and Sc abundances were determined on selected samples. All elements follow three types of trends vs. CaO, which is used as differentiation index. Two trends show positive and negative correlations while the third one shows a bell-shaped pattern. LREE have different degrees of enrichment (La = 20−120× ch) and HREE show variable fractionation with prevailing (Tb/Yb)n<1. The two peraluminous samples have very different geochemical characteristics.

From the geochemical point of view all the rocks coming from the Sardinian segment of the batholith display a typical calc-alkaline chemical character showing the imprint of both “normal and mature” continental arc geodynamic environments.

Geochemical trends suggest some petrogenetic constraints. The complete sequence of differentiation can be neither the product of crystal/liquid fractionation processes starting from a single basic parent magma nor the product of an AFC process. On the contrary, a two-stage model can be proposed. In the first stage a mafic melt of subcrustal origin interacted with monzogranitic magmas derived from 25–35% degree of melting of a crustal biotite amphibolitic source. Such a mixing process acted together with a crystal/liquid fractionation process to give tonalites and granodiorites. In the second stage lesser degrees of melting of the same crustal source could give the late-stage leucogranitic masses.

A possible scenario, able to take into account field and geochemical data, can be suggested for the genesis of this suite and we propose it as a working model for future investigations.  相似文献   

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